共查询到20条相似文献，搜索用时 31 毫秒
1.
The roles of structural imperfections in InGaN-based blue light-emitting diodes and laser diodes 总被引：2，自引：0，他引：2
S Nakamura 《Science (New York, N.Y.)》1998,281(5379):955-961
REVIEW High-efficiency light-emitting diodes emitting amber, green, blue, and ultraviolet light have been obtained through the use of an InGaN active layer instead of a GaN active layer. The localized energy states caused by In composition fluctuation in the InGaN active layer are related to the high efficiency of the InGaN-based emitting devices. The blue and green InGaN quantum-well structure light-emitting diodes with luminous efficiencies of 5 and 30 lumens per watt, respectively, can be made despite the large number of threading dislocations (1 x 10(8) to 1 x 10(12) cm-2). Epitaxially laterally overgrown GaN on sapphire reduces the number of threading dislocations originating from the interface of the GaN epilayer with the sapphire substrate. InGaN multi-quantum-well structure laser diodes formed on the GaN layer above the SiO2 mask area can have a lifetime of more than 10,000 hours. Dislocations increase the threshold current density of the laser diodes. 相似文献
2.
JR Sheats H Antoniadis M Hueschen W Leonard J Miller R Moon D Roitman A Stocking 《Science (New York, N.Y.)》1996,273(5277):884-888
Electroluminescence from organic materials has the potential to enable low-cost, full-color flat-panel displays, as well as other emissive products. Some materials have now demonstrated adequate efficiencies (1 to 15 lumens/watt) and lifetimes (>5000 hours) for practical use; however, the factors that govern lifetime remain poorly understood. This article provides a brief review of device principles and applications requirements and focuses on the understanding of reliability issues. 相似文献
3.
Studies on the long-term degradation of organic light-emitting devices (OLEDs) based on tris(8-hydroxyquinoline) aluminum (AlQ3), the most widely used electroluminescent molecule, reveal that injection of holes in AlQ3 is the main cause of device degradation. The transport of holes into AlQ3 caused a decrease in its fluorescence quantum efficiency, thus showing that cationic AlQ3 species are unstable and that their degradation products are fluorescence quenchers. These findings explain the success of different approaches to stabilizing OLEDs, such as doping of the hole transport layer, introducing a buffer layer at the hole-injecting contact, and using mixed emitting layers of hole and electron transporting molecules. 相似文献
4.
McCarthy MA Liu B Donoghue EP Kravchenko I Kim DY So F Rinzler AG 《Science (New York, N.Y.)》2011,332(6029):570-573
Intrinsic nonuniformity in the polycrystalline-silicon backplane transistors of active matrix organic light-emitting diode displays severely limits display size. Organic semiconductors might provide an alternative, but their mobility remains too low to be useful in the conventional thin-film transistor design. Here we demonstrate an organic channel light-emitting transistor operating at low voltage, with low power dissipation, and high aperture ratio, in the three primary colors. The high level of performance is enabled by a single-wall carbon nanotube network source electrode that permits integration of the drive transistor and the light emitter into an efficient single stacked device. The performance demonstrated is comparable to that of polycrystalline-silicon backplane transistor-driven display pixels. 相似文献
5.
Fuel cells are uniquely capable of overcoming combustion efficiency limitations (e.g., the Carnot cycle). However, the linking of fuel cells (an energy conversion device) and hydrogen (an energy carrier) has emphasized investment in proton-exchange membrane fuel cells as part of a larger hydrogen economy and thus relegated fuel cells to a future technology. In contrast, solid oxide fuel cells are capable of operating on conventional fuels (as well as hydrogen) today. The main issue for solid oxide fuel cells is high operating temperature (about 800°C) and the resulting materials and cost limitations and operating complexities (e.g., thermal cycling). Recent solid oxide fuel cells results have demonstrated extremely high power densities of about 2 watts per square centimeter at 650°C along with flexible fueling, thus enabling higher efficiency within the current fuel infrastructure. Newly developed, high-conductivity electrolytes and nanostructured electrode designs provide a path for further performance improvement at much lower temperatures, down to ~350°C, thus providing opportunity to transform the way we convert and store energy. 相似文献
6.
基于一些合理假设与近似，建立了具有欧姆接触载流子注入的双层有机电致发光器件的解析模型．模型中计算参数只有空穴和电子输运层的厚度、迁移率、外加电压及材料参数Fh和Fe，且这些参数都是可以通过测量得到的．研究了材料参数Fh，Fe对器件复合电流密度的影响及空穴输运层厚度和载流子迁移率对器件电场强度和复合电流密度的影响．结果表明：空穴输运层厚度和载流子迁移率引起电场强度的重新分布，进而对复合电流密度产生影响；接触限制电极注入少数载流子的器件可以取得比欧姆接触注入多数载流子的器件更高的复合电流． 相似文献
7.
Organic electroluminescent devices are light-emitting diodes in which the active materials consist entirely of organic materials. Here, the fabrication of a white light-emitting organic electroluminescent device made from vacuum-deposited organic thin films is reported. In this device, three emitter layers with different carrier transport properties, each emitting blue, green, or red light, are used to generate white light. Bright white light, over 2000 candelas per square meter, nearly as bright as a fluorescent lamp, was successfully obtained at low drive voltages such as 15 to 16 volts. The applications of such a device include paper-thin light sources, which are particularly useful for places that require lightweight illumination devices, such as in aircraft and space shuttles. Other uses are a backlight for liquid crystal display as well as full color displays, achieved by combining the emitters with micropatterned color filters. 相似文献
8.
The spin-polarized organic light-emitting diode (spin-OLED) has been a long-sought device within the field of organic spintronics. We designed, fabricated, and studied a spin-OLED with ferromagnetic electrodes that acts as a bipolar organic spin valve (OSV), based on a deuterated derivative of poly(phenylene-vinylene) with small hyperfine interaction. In the double-injection limit, the device shows ~1% spin valve magneto-electroluminescence (MEL) response, which follows the ferromagnetic electrode coercive fields and originates from the bipolar spin-polarized space charge-limited current. In stark contrast to the response properties of homopolar OSV devices, the MEL response in the double-injection device is practically independent of bias voltage, and its temperature dependence follows that of the ferromagnetic electrode magnetization. Our findings provide a pathway for organic displays controlled by external magnetic fields. 相似文献
9.
G Scamarcio F Capasso C Sirtori J Faist AL Hutchinson DL Sivco AY Cho 《Science (New York, N.Y.)》1997,276(5313):773-776
A quantum-cascade long-wavelength infrared laser based on superlattice active regions has been demonstrated. In this source, electrons injected by tunneling emit photons corresponding to the energy gap (minigap) between two superlattice conduction bands (minibands). A distinctive design feature is the high oscillator strength of the optical transition. Pulsed operation at a wavelength of about 8 micrometers with peak powers ranging from approximately 0.80 watt at 80 kelvin to 0.2 watt at 200 kelvin has been demonstrated in a superlattice with 1-nanometer-thick AlInAs barriers and 4.3-nanometer-thick GaInAs quantum wells grown by molecular beam epitaxy. These results demonstrate the potential of strongly coupled superlattices as infrared laser materials for high-power sources in which the wavelength can be tailored by design. 相似文献
10.
Zhang M Fang S Zakhidov AA Lee SB Aliev AE Williams CD Atkinson KR Baughman RH 《Science (New York, N.Y.)》2005,309(5738):1215-1219
Individual carbon nanotubes are like minute bits of string, and many trillions of these invisible strings must be assembled to make useful macroscopic articles. We demonstrated such assembly at rates above 7 meters per minute by cooperatively rotating carbon nanotubes in vertically oriented nanotube arrays (forests) and made 5-centimeter-wide, meter-long transparent sheets. These self-supporting nanotube sheets are initially formed as a highly anisotropic electronically conducting aerogel that can be densified into strong sheets that are as thin as 50 nanometers. The measured gravimetric strength of orthogonally oriented sheet arrays exceeds that of sheets of high-strength steel. These nanotube sheets have been used in laboratory demonstrations for the microwave bonding of plastics and for making transparent, highly elastomeric electrodes; planar sources of polarized broad-band radiation; conducting appliqués; and flexible organic light-emitting diodes. 相似文献
11.
Because of its high resistivity and subsequent low electroactivity, sulfur is not normally considered a room-temperature battery cathode. An elemental sulfur cathode has been made with a measured capacity of over 900 ampere.hours per kilogram, more than 90 percent of the theoretical storage capacity of solid sulfur at room temperature, accessed by means of a lightweight, highly conductive, aqueous polysulfide interface through the electrocatalyzed reaction S + H(2)O + 2e(-) --> HS(-) + OH(-). This solid sulfur cathode was first used in a battery with an aluminum anode for an overall discharge reaction 2Al + 3S + 3OH(-) + 3H(2)O --> 2Al(OH)(3) + 3HS(-), giving a cell potential of 1.3 volts. The theoretical specific energy of the aluminum-sulfur battery (based on potassium salts) is 910 watt.hours per kilogram with an experimental specific energy of up to 220 watt.hours per kilogram. 相似文献
12.
Thermal conductivity of monolithic organic aerogels 总被引：1，自引：0，他引：1
Lu X Arduini-Schuster MC Kuhn J Nilsson O Fricke J Pekala RW 《Science (New York, N.Y.)》1992,255(5047):971-972
The total thermal conductivity lambda of resorcinol-formaldehyde aerogel monoliths has been measured as a function of density rho in the range from rho = 80 to 300 kilograms per cubic meter. A record-low conductivity value in air at 300 K of lambda approximately 0.012 watt per meter per kelvin was found for rho approximately 157 kilograms per cubic meter. Caloric measurements under variation of gas pressure as well as spectral infrared transmission measurements allowed the determination of solid conductivity, gaseous conductivity, and radiative conductivity as a function of density. The development of such low conductivity materials is of great interest with respect to the substitution of environmentally harmful insulating foams made from chlorofluorocarbons. 相似文献
13.
We have developed a biomechanical energy harvester that generates electricity during human walking with little extra effort. Unlike conventional human-powered generators that use positive muscle work, our technology assists muscles in performing negative work, analogous to regenerative braking in hybrid cars, where energy normally dissipated during braking drives a generator instead. The energy harvester mounts at the knee and selectively engages power generation at the end of the swing phase, thus assisting deceleration of the joint. Test subjects walking with one device on each leg produced an average of 5 watts of electricity, which is about 10 times that of shoe-mounted devices. The cost of harvesting-the additional metabolic power required to produce 1 watt of electricity-is less than one-eighth of that for conventional human power generation. Producing substantial electricity with little extra effort makes this method well-suited for charging powered prosthetic limbs and other portable medical devices. 相似文献
14.
A simple and general postdeposition electrode patterning technique for active organic electronic devices is demonstrated and is applied to patterning the metal cathodes of organic light-emitting devices. Selective lift-off of the metal cathode layer is achieved by pressing a prepatterned, metal-coated silicon stamp on the unpatterned device layers. Under pressure, the metal coating on the stamp cold-welds to the metal cathode coating the underlying organic films. Subsequent separation of the stamp from the substrate results in removal of the cathode metal in the regions contacted by the stamp, resulting in submicrometer feature definition. A 17x17 passive matrix display, with a pixel size of 440 micrometers by 320 micrometers, was fabricated with this process. Cold-welding followed by lift-off of the cathode metal allows simple, cost-effective, and high-throughput large-area fabrication of organic electronic devices. 相似文献
15.
Schaedler TA Jacobsen AJ Torrents A Sorensen AE Lian J Greer JR Valdevit L Carter WB 《Science (New York, N.Y.)》2011,334(6058):962-965
Ultralight (<10 milligrams per cubic centimeter) cellular materials are desirable for thermal insulation; battery electrodes; catalyst supports; and acoustic, vibration, or shock energy damping. We present ultralight materials based on periodic hollow-tube microlattices. These materials are fabricated by starting with a template formed by self-propagating photopolymer waveguide prototyping, coating the template by electroless nickel plating, and subsequently etching away the template. The resulting metallic microlattices exhibit densities ρ ≥ 0.9 milligram per cubic centimeter, complete recovery after compression exceeding 50% strain, and energy absorption similar to elastomers. Young's modulus E scales with density as E ~ ρ(2), in contrast to the E ~ ρ(3) scaling observed for ultralight aerogels and carbon nanotube foams with stochastic architecture. We attribute these properties to structural hierarchy at the nanometer, micrometer, and millimeter scales. 相似文献
16.
Lorenz MR 《Science (New York, N.Y.)》1968,159(3822):1419-1423
Electroluminescence from semiconductor diode light sources can occur as a result of the application of a direct current at a low voltage to a suitably doped crystal containing a p-n junction. In recent years, it has become apparent that in some materials the efficiency of conversion of electric energy to visible light can be appreciably high. Since light-emitting diodes are compatible with the present electronic circuitry, they have many potential applications. 相似文献
17.
刘巽浩 《中国农业大学学报》1982,(1):47-54
一个特定的农田生态系统有其一定的能量转换与物质循环的特点与效率。从宏观上对这方面的问题进行研究将有助于从一个侧面探讨农业战略上的一些重大问题。例如,我国农业走什么路子,是有机农业还是无机农业?是强调还是不强调能量的投入?重点将能量投放到高产地区还是低产地区?是重中原还是重边疆?等等。对于这些问题,认识上是有分歧的。为了探讨上述问题并为制定我国农业发展战略服务,我们在近年内先后实地考察了代表 相似文献
18.
土地利用方式对荒漠土壤有机碳和养分含量的影响 总被引：6，自引：1，他引：6
以未开垦荒漠土壤为对照,研究土地利用方式对荒漠土壤有机碳、全氮和速效磷含量的影响.结果表明,与未开垦荒地相比较,玉米地和刺槐苗圃地土壤总有机碳含量在0-20 cm土层深度分别增加了32%-68%和27%-136%,但是苜蓿地仅在0-10 cm土层增加了48%.在0-20 cm土层深度,玉米地颗粒有机碳含量增加了143%-167%,而苜蓿地和刺槐苗圃地则仅在0-10 cm土层分别增加了217%和550%.在0-30 cm土层深度,玉米地和刺槐苗圃地矿物结合态土壤有机碳含量与未开垦荒地之间差异不显著,而苜蓿地则显著低于未开垦荒地.不同土地利用方式之间矿物结合态有机碳含量的这种变化主要是由于土壤粘粒含量的变化所引起(r=0.69,P<0.01).玉米地和刺槐苗圃地0-30 cm土层土壤全氮含量分别增加了61%和64%,而苜蓿地全氮含量变化不大;玉米地和刺槐苗圃地0-30 cm土层土壤速效磷含量变化不显著,而苜蓿地则降低了80%. 相似文献
19.
采用二因素饱和D最优设计方法,对酒丢槽制作活性有机肥(以下简称活性有机肥)在水稻上进行了不同基肥和追肥施用量试验。结果表明,活性有机肥作基肥施用效果显著;通过模拟试验和优化选择,提出了水稻产量高于550 kg/667m2的农艺措施为:活性有机肥作基肥用量为25.15~39.72 kg/667m2,追肥用量14.34~22.126 kg/667m2,得到水稻产量高于600 kg/667m2的优化组合5个,其相应的农艺措施为:基肥用量29.06~46.88 kg/667m2,追肥用量9.31~21.12 kg/667m2。 相似文献
20.
Low-voltage organic transistors on plastic comprising high-dielectric constant gate insulators 总被引：1，自引：0，他引：1
CD Dimitrakopoulos S Purushothaman J Kymissis A Callegari JM Shaw 《Science (New York, N.Y.)》1999,283(5403):822-824
The gate bias dependence of the field-effect mobility in pentacene-based insulated gate field-effect transistors (IGFETs) was interpreted on the basis of the interaction of charge carriers with localized trap levels in the band gap. This understanding was used to design and fabricate IGFETs with mobility of more than 0.3 square centimeter per volt per second and current modulation of 10(5), with the use of amorphous metal oxide gate insulators. These values were obtained at operating voltage ranges as low as 5 volts, which are much smaller than previously reported results. An all-room-temperature fabrication process sequence was used, which enabled the demonstration of high-performance organic IGFETs on transparent plastic substrates, at low operating voltages for organic devices. 相似文献