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1.
Mine‐land reclamation for biomass production is often achieved by means of large applications of N and organic C with amendments that could create soil conditions favorable for N2O production and emissions. To investigate this possibility, we conducted a laboratory experiment using mine soil collected from an active surface coal mine site near Philipsburg, Pennsylvania. During a 37‐d incubation period, we measured N2O and CO2 fluxes from non‐amended soil and from soil amended with ammonium nitrate (L + F), composted poultry manure (Comp), poultry manure alone (Man) and mixed with 3 rates of paper mill sludge (PMS) to obtain carbon to nitrogen ratios of 14, 20 and 27 (Man + PMS14, 20 and 27), each at 60% and 80% water filled pore space (WFPS). Results showed that manure alone leads to a greater emission of N2O under laboratory conditions than with L + F. However, composting manure effectively reduced the emissions compared to that of L + F despite a large addition of organic C and N. Composted manure‐treated soil emitted less than all other manure‐based treatments at both 60% and 80% WFPS. The emissions were greater from soil amended with the Man + PMS treatments compared to non‐amended and L + F‐amended soil, and it increased during periods of intense microbial activity created by the application of manure and PMS. Higher water content increased emissions particularly during periods of intense microbial activity coupled with inorganic N availability. Cumulative N2O emissions from manure‐treated soils represented less than 0·1% loss of total applied N. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

2.
Drainage and cultivation of organic soils often result in large nitrous oxide (N2O) emissions. The objective of this study was to assess the impacts of nitrogen (N) fertilizer on N2O emissions from a cultivated organic soil located south of Montréal, QC, Canada, drained in 1930 and used since then for vegetable production. Fluxes of N2O were measured weekly from May 2004 to November 2005 when snow cover was absent in irrigated and non‐irrigated plots receiving 0, 100 or 150 kg N ha−1 as NH4NO3. Soil mineral N content, gas concentrations, temperature, water table height and water content were also measured to help explain variations in N2O emissions. Annual emissions during the experiment were large, ranging from 3.6 to 40.2 kg N2O‐N ha−1 year−1. The N2O emissions were decreased by N fertilizer addition in the non‐irrigated site but not in the irrigated site. The absence of a positive influence of soil mineral N content on N2O emissions was probably in part because up to 571 kg N ha−1 were mineralized during the snow‐free season. Emissions of N2O were positively correlated to soil CO2 emissions and to variables associated with the extent of soil aeration such as soil oxygen concentration, precipitation and soil water table height, thereby indicating that soil moisture/aeration and carbon bioavailability were the main controls of N2O emission. The large N2O emissions observed in this study indicate that drained cultivated organic soils in eastern Canada have a potential for N2O‐N losses similar to, or greater than, organic soils located in northern Europe.  相似文献   

3.
Nitrous oxide (N2O) emissions comprise the major share of agriculture's contribution to greenhouse gases; however, our understanding of what is actually happening in the field remains incomplete, especially concerning the multiple interactions between agricultural practices and N2O emissions. Soil compaction induces major changes in the soil structure and the key variables controlling N2O emissions. Our objective was to analyse the ability of a process‐based model (Nitrous Oxide Emissions (NOE)) to simulate the impact of soil compaction on N2O emission kinetics obtained from field experiments. We used automatic chambers to continuously monitor N2O and CO2 emissions on uncompacted and compacted areas in sugar beet fields during 2 years. Soil compaction led to smaller CO2 emissions and larger N2O emissions by inducing anoxic conditions favourable for denitrification. Cumulative N2O emissions during the crop cycles were 944 and 977 g N ha−1 in uncompacted plots and 1448 and 1382 g N ha−1 in compacted plots in 2007 and 2008, respectively. The NOE model ( Hénault et al., 2005 ) simulated 106 and 138 g N2O‐N ha−1 in uncompacted plots and 1550 and 650 g N2O‐N ha−1 in compacted plots in 2007 and 2008, respectively, markedly under‐estimating the nitrification rates and associated N2O emissions. We modified the model on the basis of published results in order to better simulate nitrification and account for varying N2O fractions of total end‐products in response to varying soil water and nitrate contents. The modified model (NOE2) better predicted nitrification rates and N2O emissions following fertilizer addition. Using a fine vertical separation of soil layers of configurable, but constant, thickness (1 cm) also improved the simulations. NOE2 predicted 428 and 416 g N‐N2O ha−1 in uncompacted plots and 1559 and 1032 g N‐ N2O ha−1 in compacted plots in 2007 and 2008, respectively. These results show that a simple process‐based model can be used to predict successfully the post‐fertilizer addition kinetics of N2O emissions and the impact of soil compaction on these emissions. However, large emissions later on during the cropping cycle were not captured by the model, emphasizing the need for further research.  相似文献   

4.
In this study emissions of N2O from arable soils are summarized using data from long‐term N2O monitoring experiments. The field experiments were conducted at six sites in Germany between 1992 and 1997. The annual N‐application rate ranged from 0 to 350 kg N ha—1. Mineral and organic N‐fertilizer applications were temporarily split adapted to the growth stage of each crop. N‐fertilizer input and N‐yield by the crops were used to calculate the In/Out‐balance. The closed chamber technique was applied to monitor the N2O fluxes from soil into the atmosphere. If possible, plants were included in the covers. Annual N2O emission values were based on flux rate measurements of an entire year. The annual N2O losses ranged from 0.53 to 16.78 kg N2O‐N ha—1 with higher N2O emissions from organically fertilized plots as compared to minerally fertilized plots. Approximately 50% of the total annual emissions occurred during winter. No significant relationship between annual N2O emissions and the respective N‐fertilization rate was found. This was attributed to site‐ and crop‐specific effects on N2O emission. The calculation of the N2O emission per unit N‐yield from winter cereal plots indicates that the site effect on N2O emission is more important than the effect of N‐fertilization. From unfertilized soils at the sites Braunschweig and Timmerlah a N‐yield of 60.0 kg N ha—1 a—1 and N2O emissions of 2 kg N ha—1 a—1 were measured. This high background emission was assigned to the amount and turnover of soil organic matter. For a crop rotation at the sites Braunschweig and Timmerlah the N In/Out‐balance over a period of four years was identified as a suitable predictor of N2O emissions. This parameter characterizes the efficiency of N‐fertilization for crop production and allows for N‐mineralization from the soil.  相似文献   

5.
Agricultural soils are the main anthropogenic source of nitrous oxide (N2O), largely because of nitrogen (N) fertilizer use. Commonly, N2O emissions are expressed as a function of N application rate. This suggests that smaller fertilizer applications always lead to smaller N2O emissions. Here we argue that, because of global demand for agricultural products, agronomic conditions should be included when assessing N2O emissions. Expressing N2O emissions in relation to crop productivity (expressed as above‐ground N uptake: ‘yield‐scaled N2O emissions') can express the N2O efficiency of a cropping system. We show how conventional relationships between N application rate, N uptake and N2O emissions can result in minimal yield‐scaled N2O emissions at intermediate fertilizer‐N rates. Key findings of a meta‐analysis on yield‐scaled N2O emissions by non‐leguminous annual crops (19 independent studies and 147 data points) revealed that yield‐scaled N2O emissions were smallest (8.4 g N2O‐N kg−1N uptake) at application rates of approximately 180–190 kg N ha−1 and increased sharply after that (26.8 g N2O‐N kg−1 N uptake at 301 kg N ha−1). If the above‐ground N surplus was equal to or smaller than zero, yield‐scaled N2O emissions remained stable and relatively small. At an N surplus of 90 kg N ha−1 yield‐scaled emissions increased threefold. Furthermore, a negative relation between N use efficiency and yield‐scaled N2O emissions was found. Therefore, we argue that agricultural management practices to reduce N2O emissions should focus on optimizing fertilizer‐N use efficiency under median rates of N input, rather than on minimizing N application rates.  相似文献   

6.
Given high mineralization rates of soil organic matter addition of organic fertilizers such as compost and manure is a particularly important component of soil fertility management under irrigated subtropical conditions as in Oman. However, such applications are often accompanied by high leaching and volatilization losses of N. Two experiments were therefore conducted to quantify the effects of additions of activated charcoal and tannin either to compost in the field or directly to the soil. In the compost experiment, activated charcoal and tannins were added to compost made from goat manure and plant material at a rate of either 0.5 t activated charcoal ha?1, 0.8 t tannin extract ha?1, or 0.6 t activated charcoal and tannin ha?1 in a mixed application. Subsequently, emissions of CO2, N2O, and NH3 volatilization were determined for 69 d of composting. The results were verified in a 20‐d soil incubation experiment in which C and N emissions from a soil amended with goat manure (equivalent to 135 kg N ha?1) and additional amendments of either 3 t activated charcoal ha?1, or 2 t tannin extract ha?1, or the sum of both additives were determined. While activated charcoal failed to affect the measured parameters, both experiments showed that peaks of gaseous CO2 and N emission were reduced and/or occurred at different times when tannin was applied to compost and soil. Application of tannins to compost reduced cumulative gaseous C emissions by 40% and of N by 36% compared with the non‐amended compost. Tannins applied directly to the soil reduced emission of N2O by 17% and volatilization of NH3 by 51% compared to the control. However, emissions of all gases increased in compost amended with activated charcoal, and the organic C concentration of the activated charcoal amended soil increased significantly compared to the control. Based on these results, tannins appear to be a promising amendment to reduce gaseous emissions from composts, particularly under subtropical conditions.  相似文献   

7.
On the main Japanese island of Honshu, bark or sawdust is often added to cattle excreta as part of the composting process. Dairy farmers sometimes need to dispose of manure that is excess to their requirements by spreading it on their grasslands. We assessed the effect of application of bark- or sawdust-containing manure at different rates on annual nitrous oxide (N2O) and methane (CH4) emissions from a grassland soil. Nitrous oxide and CH4 fluxes from an orchardgrass (Dactylis glomerata L.) grassland that received this manure at 0, 50, 100, 200, or 300?Mg?ha?1?yr?1 were measured over a two-year period by using closed chambers. Two-way analysis of variance (ANOVA) was employed to examine the effect of annual manure application rates and years on annual N2O and CH4 emissions. Annual N2O emissions ranged from 0.47 to 3.03?kg?N?ha?1?yr?1 and increased with increasing manure application rate. Nitrous oxide emissions during the 140-day period following manure application increased with increasing manure application rate, with the total nitrogen concentration in the manure, and with cumulative precipitation during the 140-day period. However, manure application rate did not affect the N2O emission factors of the manure. The overall average N2O emission factor was 0.068%. Annual CH4 emissions ranged from ?1.12 to 0.01?kg?C?ha?1?yr?1. The annual manure application rate did not affect annual CH4 emissions.  相似文献   

8.
Soil carbon (C) content, often found at elevated levels in manured soils, can play a critical role in regulating nitrous oxide emissions. Nitrate availability and oxygen status are the other primary drivers of emissions, yet the interaction of these three variables and the dynamics of the denitrification process are inadequately known. Emissions of N2O and N2 were measured from two New York State soils that were historically managed either with regular cattle manure applications (M) or without manure (NM). For 168 h, repacked soil cores were maintained at 80 % water-filled pore space after the application of 0, 50, 100, and 200 kg ha?1 of labeled K15NO3. Significant differences were found in the N2O emission profiles between the two treatments with a simultaneous increasing trend in emissions with higher fertilizer applications. The M soil produced 53-, 15.5-, and 8.6-fold increases in N2O emissions over the NM soil at the 50-, 100-, and 200-kg ha?1 N rates, respectively. Additionally, the mean ratio of nitrous oxide to total denitrification (N2O/(N2O + N2)) was higher for M soil. It increased to values of 0.17, 0.25, and 0.43 for fertilizer rates of 50, 100, and 200 kg ha?1, respectively, in contrast to ratios in the NM soil of 0.01, 0.03, and 0.14.  相似文献   

9.
Vegetable‐production systems often show high soil mineral‐N contents and, thus, are potential sources for the release of the climate‐relevant trace gas N2O from soils. Despite numerous investigations on N2O fluxes, information on the impact of vegetable‐production systems on N2O emissions in regions with winter frost is still rare. This present study aimed at measuring the annual N2O emissions and the total yield of a lettuce–cauliflower rotation at different fertilization rates on a Haplic Luvisol in a region exposed to winter frost (S Germany). We measured N2O emissions from plots fertilized with 0, 319, 401, and 528 kg N ha–1 (where the latter three amounts represented a strongly reduced N‐fertilization strategy, a target value system [TVS] in Germany, and the N amount fertilized under good agricultural practices). The N2O release from the treatments was 2.3, 5.7, 8.8, and 10.6 kg N2O‐N ha–1 y–1, respectively. The corresponding emission factors calculated on the basis of the total N input ranged between 1.3% and 1.6%. Winter emission accounted for 45% of the annual emissions, and a major part occurred after the incorporation of cauliflower residues. The annual N2O emission was positively correlated with the nitrate content of the top soil (0–25 cm) and with the N surpluses of the N balance. Reducing the amount of N fertilizer applied significantly reduced N2O fluxes. Since there was no significant effect on yields if fertilization was reduced from 528 kg N ha–1 according to “good agricultural practice” to 401 kg N ha–1 determined by the TVS, we recommend this optimized fertilization strategy.  相似文献   

10.
Maize(Zea mays L.), a staple crop in the North China Plain, contributing substantially to agricultural nitrous oxide(N_2O)emissions in this region. Many studies have focused on various agricultural management measures to reduce N_2O emissions. However, few have investigated soil N_2O emissions in intercropping systems. In the current study, we investigate whether maize-soybean intercropping treatments could reduce N_2O emission rates. Two differently configured maize-soybean intercropping treatments, 2:2 intercropping(two rows of maize and two rows of soybean, 2M2S) and 2:1 intercropping(two rows of maize and one row of soybean,2M1S), and monocultured maize(M) and soybean(S) treatments were performed using a static chamber method. The results showed no distinct yield advantage for the intercropping systems. The total N_2O production from the various treatments was 0.15 ± 0.04–113.85 ± 12.75 μg m~(-2) min~(-1). The cumulative N_2O emission from the M treatment was 16.9 ± 2.3 kg ha~(-1) over the entire growing season(three and a half months), which was significantly higher(P 0.05) than that of the 2M2S and 2M1S treatments by 36.6% and 32.2%, respectively. Two applications of nitrogen(N) fertilizer(as urea) at 240 kg N ha~(-1) each induced considerable soil N_2O fluxes. Short-term N_2O emissions(within one week after each of the two N applications) accounted for 74.4%–83.3% of the total emissions. Soil moisture, temperature, and inorganic N were significantly correlated with soil N_2O emissions(R~2= 0.246–0.365, n =192, P 0.001). Soil nitrate(NO_3~-) and moisture decreased in the intercropping treatments during the growing season. These results indicate that maize-soybean intercropping can reduce soil N_2O emissions relative to monocultured maize.  相似文献   

11.
菜地土壤中氮肥的反硝化损失和N2O排放   总被引：4，自引：0，他引：4  
A field experiment was conducted on Chinese cabbage （Brassica campestris L. ssp. pekinensis （Lour.） Olsson） in a Nanjing suburb in 2003. The experiment included 4 treatments in a randomized complete block design with 3 replicates： zero chemical fertilizer N （CK）; urea at rates of 300 kg N ha^-1 （U300） and 600 kg N ha^-1 （U600）, both as basal and two topdressings; and polymer-coated urea at a rate of 180 kg N ha^-1 （PCU180） as a basal application. The acetylene inhibition technique was used to measure denitrification （N2 ＋ N2O） from intact soil cores and N2O emissions in the absence of acetylene. Results showed that compared to （3K total denitrification losses were significantly greater （P ≤ 0.05） in the PCU180, U300, and U600 treatments,while N2O emissions in the U300 and U600 treatments were significantly higher （P ≤ 0.05） than （3K. In the U300 and U600 treatments peaks of denitrification and N2O emission were usually observed after N application. In the polymer-coated urea treatment （PCU180） during the period 20 to 40 days after transplanting, higher denitrification rates and N2O fluxes occurred. Compared with urea, polymer-coated urea did not show any effect on reducing denitrification losses and N2O emissions in terms of percentage of applied N. As temperature gradually decreased from transplanting to harvest, denitrification rates and N2O emissions tended to decrease. A significant （P ≤0.01） positive correlation occurred between denitrification （r = 0.872） or N2O emission （r = 0.781） flux densities and soil temperature in the CK treatment with a stable nitrate content during the whole growing season.  相似文献   

12.
An increasing area of oilseed rape cultivation in Europe is used to produce biodiesel. However, a large amount of straw residue is often left in the field in autumn. Straw mineralization provides both carbon (C) and nitrogen (N) sources for emission of soil nitrous oxide (N2O), which is an important greenhouse gas with a high warming potential. Some studies have focused on soil N2O emissions immediately post-harvest; however, straw mineralization could possibly last over winter. Most field studies in winter have focused on freeze-thaw cycles. It is still not clear how straw mineralization affects soil N2O emissions in unfrozen wintertime conditions. We carried out a field experiment in northern Germany in winter 2014, adding straw and glucose as a source of C with three rates of N fertilizer (0, 30, and 60 kg N ha−1). During the 26 days of observation, cumulative N2O emission in treatments without C addition was negative at all N fertilizer levels. Straw addition produced –3.2, 11.2, and 5.0 mg N2O-N m−2 at 0, 30, and 60 kg N ha−1, respectively. Addition of glucose surprisingly caused –1.5, 74.6, and 165 mg N2O–N m−2 at 0, 30, and 60 kg N ha−1, respectively. This study demonstrates that oilseed rape straw does not cause high N2O emissions in wintertime when no extreme precipitation or freeze-thaw cycles are involved, and soil organic C content is low. However, N2O emission could be intensively stimulated, when both easily available organic C and nitrate are not limited and the soil temperature between 0 and 10°C. These results provide useful information on potential changes to N2O emissions that may occur due to the increased use of oilseed rape for biodiesel combined with less severe winters in the northern hemisphere driven by global warming.  相似文献   

13.
The effects of compost application on soil carbon sequestration potential and carbon budget of a tropical sandy soil was studied. Greenhouse gas emissions from soil surface and agricultural inputs (fertiliser and fossil fuel uses) were evaluated. The origin of soil organic carbon was identified by using stable carbon isotope. The CO2, CH4 and N2O emissions from soil were estimated in hill evergreen forest (NF) plot as reference, and in the corn cultivation plots with compost application rate at 30 Mg ha−1 y−1 (LC), and at 50 Mg ha−1 y−1 (HC). The total C emissions from soil surface were 8·54, 10·14 and 9·86 Mg C ha−1 y−1 for NF, HC and LC soils, respectively. Total N2O emissions from HC and LC plots (2·56 and 3·47 kg N2O ha−1 y−1) were significantly higher than from the NF plot (1·47 kg N2O ha−1 y−1). Total CO2 emissions from fuel uses of fertiliser, irrigation and machinery were about 10 per cent of total CO2 emissions. For soil carbon storage, since 1983, it has been increased significantly (12 Mg ha−1) under the application of 50 Mg ha−1 y−1 of compost but not with 30 Mg ha−1 y−1. The net C budget when balancing out carbon inputs and outputs from soil for NF, HC and LC soils were +3·24, −2·50 and +2·07 Mg C ha−1 y−1, respectively. Stable isotope of carbon (δ13C value) indicates that most of the increased soil carbon is derived from the compost inputs and/or corn biomass. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

14.
Most of the nitrous oxide (N2O) in the atmosphere, thought to be involved in global warming, is emitted from soil. Although the main factors controlling the production of N2O in soil are well known, we need more quantitative data on the interactions of soil and the environment in the soil that affect the emission. We therefore studied the effects of irrigation, cropping (fallow, barley with grass undersown) and N fertilization (unfertilized, 103 kg N ha?1) on the composition of soil air and direct N2O emission from soil (using the closed chamber method) in a factorial field experiment on a well‐structured loamy clay soil during 1 June?22 October 1993. The measurements were made weekly during the growing season and three times after harvesting. The composition of the soil air did not indicate severe anoxia in any treatment or combination of treatments, but the accumulation of N2O in the soil air indicated that hypoxia was common. At the start of the irrigation the emissions were small, even though there was much ammonium and nitrate in the soil and therefore a potential for emission of N2O produced by both nitrification and denitrification. Larger emissions occurred later. The largest emissions were found when 60–90% of the soil pore space was filled with water. Irrigation and fertilization with N both roughly doubled the cumulative N2O emission. Growing a crop decreased it by a factor of 3–7. Most N2O was lost from the irrigated fertilized soil under fallow (3.5 kg N ha?1), and least from the unirrigated unfertilized soil under barley (0.1 kg N ha?1).  相似文献   

15.
Abstract

Nitrous oxide (N2O) emissions were measured and nitrogen (N) budgets were estimated for 2?years in the fertilizer, manure, control and bare plots established in a reed canary grass (Phalaris arundinacea L.) grassland in Southern Hokkaido, Japan. In the manure plot, beef cattle manure with bark was applied at a rate of 43–44?Mg fresh matter (236–310?kg?N)?ha?1?year?1, and a supplement of chemical fertilizer was also added to equalize the application rate of mineral N to that in the fertilizer plots (164–184?kg?N?ha?1?year?1). Grass was harvested twice per year. The total mineral N supply was estimated as the sum of the N deposition, chemical fertilizer application and gross mineralization of manure (GMm), soil (GMs), and root-litter (GMl). GMm, GMs and GMl were estimated by dividing the carbon dioxide production derived from the decomposition of soil organic matter, root-litter and manure by each C?:?N ratio (11.1 for soil, 15.5 for root-litter and 23.5 for manure). The N uptake in aboveground biomass for each growing season was equivalent to or greater than the external mineral N supply, which is composed of N deposition, chemical fertilizer application and GMm. However, there was a positive correlation between the N uptake in aboveground biomass and the total mineral N supply. It was assumed that 58% of the total mineral N supply was taken up by the grass. The N supply rates from soil and root-litter were estimated to be 331–384?kg?N?ha?1?year?1 and 94–165?kg?N?ha?1?year?1, respectively. These results indicated that the GMs and GMl also were significant inputs in the grassland N budget. The cumulative N2O flux for each season showed a significant positive correlation with mineral N surplus, which was calculated as the difference between the total mineral N supply and N uptake in aboveground biomass. The emission factor of N2O to mineral N surplus was estimated to be 1.2%. Furthermore, multiple regression analysis suggested that the N2O emission factor increased with an increase in precipitation. Consequently, soil and root-litter as well as chemical fertilizer and manure were found to be major sources of mineral N supply in the grassland, and an optimum balance between mineral N supply and N uptake is required for reducing N2O emission.  相似文献   

16.
A long-term field experiment was established to determine the influence of mineral fertilizer (NPK) or organic manure (composed of wheat straw, oil cake and cottonseed cake) on soil fertility. A tract of calcareous fluvo-aquic soil (aquic inceptisol) in the Fengqiu State Key Experimental Station for Ecological Agriculture (Fengqiu county, Henan province, China) was fertilized beginning in September 1989 and N2O emissions were examined during the maize and wheat growth seasons of 2002-2003. The study involved seven treatments: organic manure (OM), half-organic manure plus half-fertilizer N (1/2 OMN), fertilizer NPK (NPK), fertilizer NP (NP), fertilizer NK (NK), fertilizer PK (PK) and control (CK). Manured soils had higher organic C and N contents, but lower pH and bulk densities than soils receiving the various mineralized fertilizers especially those lacking P, indicating that long-term application of manures could efficiently prevent the leaching of applied N from and increase N content in the plowed layer. The application of manures and fertilizers at a rate of 300 kg N ha−1 year−1 significantly increased N2O emissions from 150 g N2O-N ha−1 year−1 in the CK treatment soil to 856 g N2O-N ha−1 year−1 in the OM treatment soil; however, there was no significant difference between the effect of fertilizer and manure on N2O emission. More N2O was released during the 102-day maize growth season than during the 236-day wheat growth season in the N-fertilized soils but not in N-unfertilized soils. N2O emission was significantly affected by soil moisture during the maize growth season and by soil temperature during the wheat growth season. In sum, this study showed that manure added to a soil tested did not result in greater N2O emission than treatment with a N-containing fertilizer, but did confer greater benefits for soil fertility and the environment.  相似文献   

17.
Abstract

Nitrous oxide (N2O) contributes to global climate change, and its emission from soil–crop systems depend on soil, environmental, and anthropogenic factors. Thus, we evaluated the variability of N2O emissions measured by microchambers (cross section: 184 cm2) from a groundnut–fallow–maize–fallow cropping system of the humid tropics. The crops received inorganic nitrogen (N) plus crop residues (NC), inorganic N alone as ammonium sulfate (RN), and half of the inorganic N along with crop residues and chicken manure (N1/2CM), amounting for the crop rotation to 322, 180, and 400 kg N ha?1 yr?1, respectively. The N2O fluxes during the groundnut–maize crop rotation were log‐normally distributed, and the frequency distributions were positively skewed. Daytime changes in N2O fluxes were inconsistent, and the 50% of total N2O emission during the 12 h measurement periods was attained earlier under maize (～11∶00 h) than groundnut covers (～13∶00 h). Spatial variability in each treatment with eight gas chambers was large but smaller during the cropping periods than the fallow, indicating masking efficiency of crop covers for the soil heterogeneity that was accelerated presumably by antecedent climatic variables. The temporal variability of N2O emissions was also large (coefficients of variation, CV, ranged from 60 to 81%), involving both input differences between treatments and measurement periods. As such, the relative deviation from the annual mean of total N2O emission was high during the period after a large N application with a maximum of +480%, due to addition of chicken manure. The seasonal contribution of summer and monsoon to N2O emissions was insignificant. However, intensive rainfall negatively (?0.65**) and the amount of added N from either source positively (0.83***) correlated with the integrated N2O emissions, and those were exponential. Results suggest that around noon (12∶00 h) gas collection could represent well the daily N2O fluxes, increasing the number or size of the gas chambers could minimize the large variability, and mainly the rainfall and N inputs regulated its emissions in the humid tropics of Malaysia.  相似文献   

18.
The nations that have ratified the Kyoto Protocol must set up an appropriate national inventory on N2O emissions from agricultural land use, in order to report properly on the achievements made in reducing greenhouse‐gas emissions. The search for the appropriate method is a controversial topic as it is subject to high uncertainty in particular associated to the upscaling from site measurements. In this study, all available data from Germany on annual N2O‐emission rates derived from field experiments of at least an entire year are summarized. From each study, only differences in soil properties on N input qualified as an individual data set. Under these premises, 101 treatments from 27 sites were found equally spread across Germany. The annual N application ranged from 0 to 400 kg N ha–1 and the annual emission rates from 0.04 to 17.1 kg ha–1. Annual emission factors (EFs), uncorrected for background emission, varied considerably from 0.18% to 15.54% of N applied. There was no nationwide correlation found for the relationship between N2O losses and N application, soil C, soil N, soil texture, or soil pH. However, site‐specific trends in the relationship between emission factor and mean soil aeration status, as expressed by the soil type and/or mean climatic conditions, were revealed. Regularly water‐logged soils were characterized by low emission factors as were soils from the drier regions (<600 mm y–1), whereas well‐aerated soils from the frost‐intensive regions showed exceptionally high emission factors. Since purely physical and chemical parameterization failed to describe N2O emissions from agricultural land use on the national scale, there must be a biological adaptation to mean site conditions, i.e., different microbial communities react differently to similar actual conditions in terms of N2O dynamics. Regardless of the point of view, the chapter on N2O soil dynamics cannot be closed yet, and new additional model concepts, process studies, and field measurements are needed.  相似文献   

19.
Experiments were conducted in an attempt to study the impact of using different organic residues as fertilizers on grain yield, magnitude of nitrous oxide (N2O) emissions, and soil characteristics. Five fertilizer treatments including conventional nitrogen (N) fertilizer, cow manure, rice straw, poultry manure, and sugarcane bagasse were applied in the rice field in 2012. The maximum reduction in seasonal N2O emissions (10–27%) was observed under the influence of rice straw application over conventional N fertilizer. The experiment was repeated for a second season in 2013 with the same treatments for further confirmation of the results obtained during the first year of experimentation. The application of rice straw also showed a slight advantage by increasing grain yield (4.38 t ha?1) compared to control. Important soil properties and plant growth parameters were studied and their relationships with N2O emission were worked out. The incorporation of organic residues helped in restoring and improving the soil health and effectively enhancing grain yield with reduced N2O emission from rice fields.  相似文献   

20.
Most published studies related to crop effects on denitrification are not continuous and are based on the growing period. The objective of this work was to evaluate the effect of different amounts of soybean stubble, under different soil moisture contents, on gaseous nitrogen (N) losses by denitrification from an agricultural soil. The following soil moisture treatments were reached by adding distilled water to soil cores of a typic Hapludoll: 50 and 100% of water‐filled porosity space (WFPS). Residue treatments included no application of residues, amendment with 2600 kg ha?1 of soybean residues, and amendment with 5200 kg ha?1 of soybean residues. Cumulative nitrous oxide + dinitrogen (N2O + N2) emissions displayed great variability, ranging between 0 and 581.91 µg N kg?1, which represented 0 to 3.93% of the N residue applied. Under 50% WFPS moisture conditions, statistical differences in cumulative N2O + N2 emissions between residue treatments were not detected (p = 0.21), whereas at saturation conditions, cumulative N2O + N2 emissions decreased with the application of increasing amounts of soybean residues (p = 0.017). Daily and cumulative N2O + N2 emissions significantly increased as soil moisture increased, except at soils amended with 5200 kg ha?1 of soybean residues; this lack of statistical difference was probably due to the immobilization of native mineral N. Under 50% WFPS soil moisture contents, aeration seemed to be the main factor controlling redox conditions, limiting the denitrification process, and preventing differences in N emissions between residue treatments. The application of soybean residues to saturated soils notably decreased N2O + N2 emissions by denitrification through a strong mineral N immobilization into organic and nondenitrifiable forms.  相似文献   

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