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1.
Recycled polyols from waste polyurethane (PU) foams were grafted onto PU to improve the properties such as tensile strength, shape recovery, low-temperature flexibility, and water compatibility. The recycled polyol was either purified by column chromatography before grafting or was used directly for grafting. The soft segment melting temperature of PU did not notably increase with the addition of polyol, whereas the glass transition temperature increased with increased polyol content. The tensile strength sharply increased at low polyol content and decreased at high polyol content, while the strain at break did not significantly change with an increase in polyol content. The shape recovery at 10 oC notably improved compared with unmodified PU and remained high after four cyclic tests. Polyol-grafted PU demonstrated better lowtemperature flexibility and reduced the water vapor permeability of PU membranes. Overall, grafting recycled polyol onto PU significantly improved the tensile stress, shape recovery, and low-temperature flexibility of PU. 相似文献
2.
The grafted 3,5-dimethylphenyl group remarkably improved the low temperature flexibility of a polyurethane (PU) copolymer.
The rigid and blunt shape of 3,5-dimethylphenyl was designed to interrupt molecular interactions and to disturb the close
contact between PU chains and, thus, to improve the flexibility at extremely low temperature, while maintaining high and reproducible
tensile and shape memory properties at ambient temperature. The effect of the 3,5-dimethylphenyl group on the flexibility
of PU was tested at −30 °C together with a linear PU, and the reason for the exceptional flexibility at low temperature is
discussed. 相似文献
3.
Effect of the pendant n-butyl group on shape recovery and tensile properties of polyurethane (PU) block copolymer was investigated. The grafted n-butyl group was intended to keep PU chains away and to deter molecular interaction between PU chains by its flexible chains,
and thus improve shape recovery at subzero temperature while maintaining high and reproducible tensile properties and shape
recovery at ambient temperature. The attachment of n-butyl group did not make any change in the molecular interaction and phase separation of hard and soft segments in PU structure
as judged from IR and DSC analysis. Cross-link density and intrinsic viscosity increased with the increase of n-butyl content due to the partial cross-linking by the linking reagent. Shape recovery and shape retention were not diminished
after cyclic shape memory tests. Finally, the effect of n-butyl group on low temperature shape recovery was compared with linear ones and the potential application of this finding
was discussed. 相似文献
4.
Alizarin-series dyes (alizarin, alizarin red S, alizarin yellow GG, or mordant orange) are grafted onto shape memory polyurethane (PU) through an allophanate bonding, and the photoluminescence and the low-temperature flexibility of the resulting PUs are tested. The PU is mainly composed of 4,4′-methylenebis(phenylisocyanate) (MDI), poly (tetramethyleneglycol) (PTMG), and 1,4-butanediol (BD), and the dye is connected, through another MDI, to the carbamate moiety of the PU chain. The PUs with different dye contents are characterized, and their shape recovery and photoluminescence properties are compared. With respect to the tensile mechanical properties, the maximum stress increases up to 50 MPa, and the strain remains above 1000 % even after the dye is grafted onto the PU. The shape recovery is as high as 99 %, and the shape retention improves as the dye content increases. Finally, the photoluminescence of the PUs is demonstrated by the luminescent light emission test, and the dye-grafted PU shows excellent low-temperature flexibility compared with that of linear PU. 相似文献
5.
The prepolymer and the final polyurethane (PU) block copolymer were synthesized by reacting 4,4-methylene bis(phenylisocyanate)
with poly(tetramethylene glycol) and the prepolymer with 1,4-butanediol as a chain extender, respectively, to investigate
the relation between phase separation and it’s resulting properties. According to FT-IR data, the phase separation of hard
and soft segments in the prepolymer and the PU block copolymer grew bigger by increasing the hard segment content, and the
PU showed more dominant phase separation than the prepolymer. The heat of fusion due to soft segments decreased in both the
prepolymer and the PU by increasing the hard segment content, whereas the heat of fusion due to hard segments increased in
the PU did not appear in the prepolymers. The breaking stress and modulus of the prepolymer increased by increasing the hard
segment content, and the elongation at break decreased gradually, and the PU showed the highest breaking stress and modulus
at 58 % hard segment content. However, the best shape recovery of the PU was obtained at 47 % hard segment content due to
the existence of proper interaction among the hard segments for shape memory effect. Consequently, the mechanical properties
and shape memory effect of the PU were influenced by the degree of phase separation, depending on the incorporation of chain
extender as well as the hard segment content. 相似文献
6.
The polyurethane (PU) copolymer was laterally crosslinked with an extra MDI, in which a more rigid polycarbonatediol replaced the conventional poly(tetramethyleneglycol) as a soft segment. What is the impact of the possible molecular interaction between polycarbonate soft segments and lateral crosslinking. The structural change after crosslinking and the impact of new soft segment were followed by infrared spectra, crosslink density, UV-VIS spectra, and relative viscosity. The tensile stress could improve as much as 554 % by selecting the polycarbonate soft segment and the lateral crosslinking. Shape recovery was over 90 % for the entire series and reproducible for four test cycles. The adoption of polycarbonate soft segment and lateral crosslinking significantly could improve the tensile strength and shape recovery compared to PU with polyetherdiol or polyesterdiol soft segment. 相似文献
7.
Myeong Jun Jo Howon Choi Ga Hee Kim Woong-Ryeol Yu Miseon Park Yeontae Kim Jong Kyoo Park Ji Ho Youk 《Fibers and Polymers》2018,19(9):1799-1805
In order to develop epoxy shape memory polymers (ESMPs) with high switching temperature and excellent toughness for deployable space structures, the crosslink density and chain flexibility of candidate ESMP samples were tunned by adding two flexible poly(oxypropylene) diamines, Jeffamine D-230 (D230) and Jeffamine D-400 (D400), as a secondary curing agent. The desired switching temperature of ESMPs for deployable space structures was set within the range of 120-135°C. By adding D230 and D400, the switching temperature of the ESMPs could be adjusted to within this range by increasing their crosslink density, and their impact strength could be significantly increased due to the stress relaxation properties of the diamines’ flexible molecular chains. The modulus and tensile strength of the ESMPs increased, but elongation at break decreased, in proportion to the diamine content. The ESMPs with a suitable switching temperature for deployable space structures had a high elongation at break greater than 22 % and good shape recovery and shape fixity ratios. The larger the value of shape recovery ratio, the faster the shape recovery speed. 相似文献
8.
Heonyoung Jeong Jongshin Park Sunghoon Kim Jungmin Lee Narang Ahn Hyun-gyoo Roh 《Fibers and Polymers》2013,14(7):1082-1093
Thermoplastic polyurethanes were prepared using 90 % acetylated softwood kraft lignin, polyethylene glycol and 4,4-methylene diphenyl diisocyanate. Due to the glass transitions of the compatible soft and hard segment mixtures, the polyurethanes exhibited the first glass transitions at ?40 to 10 °C, and the transition temperatures increased with increasing hard segment content. Due to the glass transitions of the microphase separated hard domains, the second glass transitions occurred at 150 °C. The viscous responses during the second transitions decreased as the separated hard domains-induced chemical and physical crosslinks increased. The Young’s modulus and tensile strength increased with increasing hard segment content, whereas the breaking strain decreased. The phase morphology changed from an isolated hard domain structure to an interconnected one as the physical crosslinks increased, which caused drastic changes in the increasing or decreasing tendency of the tensile strength or breaking strain. Because of the phase morphology, the polyurethanes exhibited viscoplasticity or viscoelasticity. 相似文献
9.
Yong-Chan Chung Duy Khiem Nguyen Jae Won Choi Byoung Chul Chun 《Fibers and Polymers》2010,11(7):952-959
Effect of glucose cross-linking on the shape memory and mechanical properties of polyurethane (PU) block copolymer was investigated.
Glucose was selected due to its large number of free hydroxyl groups, easy availability, miscibility with other reactants,
and cyclic structure. The glycerol cross-linking did not affect the molecular interaction and phase separation of hard and
soft segments in polyurethane structure as judged from IR and DSC analysis. Viscosity of glucose cross-linked PU increased
after cross-linking due to the cross-linked structure. Maximum stress drastically improved with the adoption of glucose as
a cross-linker together with a slight increase in strain at break. Shape recovery also increased with the adoption of glucose
as a cross-linker, and shape recovery was not diminished after four cyclic shape recovery tests. In contrast, shape retention
significantly decreased if glucose was included for two different hard segment contents. Finally, glucose cross-linking was
compared with other cross-linkers used in shape memory polymer and the advantage of glucose cross-linking was discussed. 相似文献
10.
A series of shape memory polyurethane (PU) copolymers synthesized from 1,4-phenyldiisocyanate (PDI), poly(tetramethyleneglycol)
(PTMG), 1,4-butanediol (BD) as a chain extender, and glycerol as a cross-linking agent were tested for the mechanical properties
and the shape memory effect at the temperature 20 °C above melting temperature (T
m), and were compared with other PUs synthesized from 4,4′-methylene-bis-phenyldiisocyanate (MDI), PTMG, and BD. Mechanical
properties and shape memory effect were improved substantially by adopting both PDI and glycerol. Interestingly, enthalpy
of melting and T
m were not affected by the glycerol content. Vibration and shock absorption ability was investigated by measuring both loss
tan δ and storage modulus with dynamic mechanical analyzer (DMA). 相似文献
11.
The polyurethane (PU) copolymer was grafted with either 3-dimethylaminopropanol as a basic pendant group or 4-hydroxylphenylacetic acid as an acidic pendant group. The two types of PU were mixed in solution to form ion-pairing between acidic and basic pendant groups. The structural change after grafting and ion-pairing was followed by acid-base titration, infrared spectra, differential scanning calorimetry, and absolute viscosity. The tensile stress can be raised as much as 70 % by the control of the ion-pairing ratio of acidic and basic PUs. Shape recovery was over 80 % and reproducible for four test cycles. The minor control of tensile properties of PU was possible through the ion-pairing method. 相似文献
12.
Process parameters such as gelation and curing temperatures are parameters that influence the pultruded kenaf reinforced vinyl ester composites profile quality and performance. The effect of gelation and curing temperatures on mechanical (tensile, flexural and compression properties) and morphological properties of pultruded kenaf reinforced vinyl ester composites were analyzed. Obtained results indicated that increase of gelation and curing temperatures during the pultrusion process of kenaf reinforced vinyl ester composites influenced the mechanical properties of the composites. When the gelation and curing temperatures were increased, tensile strength, tensile modulus, flexural strength, flexural modulus and compressive strength were affected and they were either increased or decreased. The factors that influenced these results include improper curing, excessive curing, water diffusion, and the problems associated with interfacial bonding between fibre and matrices. The optimum values of the tensile strength for gelation and curing temperatures of kenaf pultruded composites were at 100 °C and 140 °C, tensile modulus at 80 °C and 180 °C, flexural strength at 100 ° and 140 °, flexural modulus at 120 ° and 180 °, and compressive strength at 120 °C and 180 °C, respectively. The scanning electron micrographs of tensile fractured samples clearly show that with the increase in gelation temperature, it creates the lumens between matrix and kenaf fibre thus reducing tensile properties whereas increasing the curing temperature caused less fibre pull out and enhanced fibre/matrix interfacial bonding. 相似文献
13.
Jong Shin Park Yong-Chan Chung Sang Do Lee Jae Whan Cho Byoung Chul Chun 《Fibers and Polymers》2008,9(6):661-666
The shape memory polyurethane (PU) copolymers cross-linked by celite, a porous inorganic material with enormous surface area
and hydroxyl groups on the surface, were prepared to see if the shape memory effect and the mechanical properties were improved.
The PU copolymers with different celite contents were compared and characterized by IR, DSC, DMA, and UTM. The melting temperatures
of PU soft segment were around 20 oC independent of celite content. The shape memory effect and mechanical properties were
dependent on the celite content, and the celite addition into the reaction mixture should be made in the middle of polymerization
to get the best shape memory and mechanical properties. The best mechanical properties were found at 0.2 wt% celite content
and its shape retention rate went up to 98 %. The inclusion of celite as a cross-linker increased both shape memory effect
and mechanical properties. The reasons underlining the improvements by adopting celite as a cross-linker are discussed in
this paper. 相似文献
14.
Chengshu Xu Zaisheng Cai Jianwei Xing Yan Ren Weizhu Xu Wenzhao Shi 《Fibers and Polymers》2014,15(4):665-671
Waterborne polyurethane (WPU) prepolymer was synthesized using polypropylene carbonate polyol as the soft segment, dimethylolpropionic acid as a hydrophilic chain extender and isophorone diisocyanate. The prepolymer was modified with aminoethyl aminopropyl dimethicon (AEAPS) to prepare a series of WPU emulsions and films. The structures and the films properties of the WPUs were characterized by Fourier transform infrared spectrometry, gel permeation chromatography, atomic force microscopy, X-ray diffraction, thermogravimetric analysis, dynamic thermomechanical analysis, X-ray photoelectron spectroscopy, water contact angles and water absorption. It was found that pure polypropylene carbonate WPU had a wide molecular weight distribution and its microphase separation was not apparent between its hard and soft segments. The WPU also had a high glass transition temperature (24.5 °C) and its film had a high damping property (tan δ>0.40) from 12 °C to 42 °C. Modification with polysiloxane had enlarged the molecular weight, narrowed the molecular weight distribution and resulted in the microphase separation between the hard and soft segments of WPUs, and this amplified the damping temperature of the WPU films. Along with the increasing utilization of polysiloxane the thermolysis, water resistance and water contact angles of WPU films were improved while the orientation of their structure regularity declined. 相似文献
15.
A melt-process was used to prepare high molecular weight Poly(vinyl chloride) (PVC) films without the use of a conventional
plasticizer and heat stabilizer. Rigid PVC powder was swollen with dimethylformamide containing 4∼10 vol% water to reduce
its melting temperature. The swollen powder was pressed at a relatively low temperature of 75∼125 °C to form a film shape,
and then washed and dried. The visible light transmittance, X-ray diffraction, density and the tensile properties of the resulting
films were examined to estimate the success or failure of film formation. The films could be produced by not only the melt-process
but also a compression-process using the rigid, highly swollen PVC powder. The resulting films had no voids, which are generally
observed in PVC products formed by a solution process. The minimum temperature for these processes decreased with decreasing
water content in the mixture: The minimum temperatures according to the water content in the mixture to produce faultless
films through the melt-process were 4 %–105 °C, 6 %–115 °C, 8 and 10 %–125 °C, while those through the compression process
were 4 %–95 °C, 6 and 8 %–105 °C, 10 %–115 °C. 相似文献
16.
In this research, results of an experimental and artificial neural network fuzzy interface system (ANFIS) modeling of operating parameters on tensile strength of the carbon fibers are investigated. To do these experiments, the commercial polyacrylonitrile (PAN) fiber of Polyacryl Iran Corporation (PIC) was used as the precursors. The results show that increasing all of parameters improves tensile strength performance. ANFIS was applied to predict tensile strength of carbon fibers as a function of stabilization temperature at first stage (STFIS), stabilization temperature at second stage (STSS), stabilization temperature at third stage (STTS), stabilization temperature at fourth stage (STFOS), and carbonization temperature (CT). The optimum levels of influential factors, determined for tensile strength are STFIS 200 °C, STSS 225 °C, STTS 240 °C, STFOS 260 °C, CT, and 1400 °C. The modeling results showed that there is an excellent agreement between the experimental data and the predicted values. Furthermore, the fiber process is optimized applying differential evolution (DE) algorithm as an effective and robust optimization method. 相似文献
17.
This paper reports the fabrication of electrical heating elements based on the graphene/waterborne polyurethane (WPU) composite coated on polyester fabric with toughness like that of artificial leather. Samples were prepared with 0, 4, 8, and 16 wt% of graphene by using the knife edge method, and then, the samples were annealed from 100 oC to 160 °C. The graphene content had a large effect on the electrical and electrical heating properties. The surface resistivity was decreased by approximately 6 orders of magnitude with an increase from 0 wt% to 16 wt% graphene/WPU composite fabric. The electric heating properties were also improved, as indicated by the percolation threshold. Samples with various graphene contents were annealed, and it was found that the electrical and electrical heating properties were improved, and the most enhanced properties were obtained when the samples were annealed at 120 °C. The initial modulus and tensile strength were increased in comparison with those of 0 wt% and 16 wt% graphene/WPU composite coated on fabrics, but the elongation at break value was slightly decreased with an increasing graphene content. When the samples were annealed, initial modulus and tensile strength of samples were improved at 120 °C and 140 °C, and they were slightly decreased at 160 °C. However, the elongation at break showed an opposite tendency to the tensile strength. With the increase in content of graphene and annealing at 120 °C and 140 °C, the samples were more stiff and tough, and at 160 °C, the samples were softer. Therefore, graphene/WPU composite coated on polyester fabric by use of the annealing process may have applications in electrical heating elements due to its excellent heating performance and toughness like that of artificial leather. 相似文献
18.
Cellulose nanowhiskers were used to improve the performance of poly (lactic acid) (PLA). The nanocomposites mixed with three different molecular weight of poly (ethylene glycol) (PEG) were characterized by mechanical testing, thermal gravimetry and differential scanning calorimetry. The tensile test showed an increase in tensile strength and elongation at break with the addition of PEG to PLA/CNW nanocomposites, the thermal analysis results showed an increase of crystallization temperature (T c) and crystallization compatibility (larger crystallization and melting areas), which indicated that the cellulose nanowhiskers (CNW) and PEG or CNW alone should not be considered as nucleating agents for the PLA matrix; The CNW was homo-dispersed which contributed to decreasing mobility of polymer chain segments. The compatibility between hydrophobic PLA matrix and the hydrophilic CNW was improved by the addition of different molecular weight polymeric-PEG. The thermo gravimetric analysis indicated that the thermal stability of the different composites were reflected well in the region between 25 °C and 245 oC. The structure of the PLA/CNW/PEG composites was characterized by AFM, which showed that the CNW dispersed in the PLA matrix evenly. 相似文献
19.
The response of four potato cultivars to various temperatures was evaluated in respect to respiration, sugar and phenolic content, and ion leakage from cut tissue sections. Respiration decreased with decreasing temperature from 20° to 0°C but after 24 hours at 0°C began to increase and reached a maximum after 10 days at 0°C, then drifted downward. No distinct break in an Arrhenius plot of the respiration data from 20° to 0°C was observed. Reducing and non-reducing sugars did not change initially between 20° and 0°C and did not increase until after 6 or 7 days at 0°C. The magnitude of the increase in sugars varied between cultivars. Only one cultivar significantly increased in phenolic content during chilling. Ion leakage remained constant from 20° to 0°C then showed a transient increase within 24 hours at 0°C. A sustained increase in leakage did not occur until after 10 days at 0°C. Cultivars varied in the rate and magnitude of the increase. The respiratory rise could not be attributed to an increase in sugar content or an increase in membrane permeability. Also, the initial increase in sugars preceded the sustained increase in ion leakage. Differences observed between cultivars in the parameters measured were not considered sufficient to explain differences in chilling sensitivity. 相似文献
20.
Synthesis and characterization of acrylic fibers-<Emphasis Type="Italic">g</Emphasis>-polyacrylamide
Graft copolymerization of acrylamide onto commercial acrylic fibers was carried out using benzoyl peroxide as a free-radical
initiator in aqueous medium within the 75–95 °C temperature range. In this study, the effects of initiator and monomer concentration,
the amount of fiber, polymerization time, and temperature on the graft yield were investigated. The optimum concentration
for initiator was found to be 2.0×10−3 mol/l and the optimum temperature of 85 °C. The activation energy of the reaction was calculated to as 35.81 kJ/mol at the
temperature interval of 75–95 °C. The structures and morphologies characterization of grafted fibers was investigated by Fourier
transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The thermogravimetric
analysis data showed that the thermal stability of the acrylic fibers increased with graft yield. The scanning electron photographs
showed that the homogeneous appearance of the fiber surface changed and a shell-like heterogeneous structure occurred at the
surface with an increasing degree of grafting. The moisture content, water absorption, dyeability, and antimicrobial activity
of grafted acrylic fibers were also reported. The results showed that grafting of polyAAm improved the moisture contain, water
absorption, dyeability, and antimicrobial activity of fiber. 相似文献