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Medium density fibreboard (MDF) was produced from fibres treated with maleated polypropylene wax. The objectives of this study were to investigate the effect of fibre treatment with maleated polypropylene wax on the advancing and receding contact angle and wicking of MDF panels by the Wilhelmy plate method; to verify the chemical reactions occurring between fibres and maleated polypropylene wax by infrared spectroscopy, and to verify if there are relationships with the water absorption of panels. Three maleated polypropylene wax contents (0, 3, 5%) and two resin types (urea–formaldehyde, UF and melamine–urea–formaldehyde, MUF) were considered in this study. Our results showed that the treatment increased the advancing contact angle of panels bonded with UF resin. The receding contact angles of MDF panels produced from treated fibres with 5% maleated polypropylene wax content were also increased by the treatment. Also, the wicking was reduced by the treatment independent of the maleated polypropylene wax content. Reductions of the wicking were 59% for panels bonded with UF resin and 73% for panels bonded with MUF. Relationships between the wicking and water absorption were observed. Chemical analysis realized by infrared spectroscopy did not detect the presence of an esterification reaction between wood fibres and anhydride groups of the maleated polypropylene wax. This suggests, therefore, that an esterification reaction did not take place or that chemical modifications were so small that they are not visible by infrared spectroscopy. 相似文献
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Jürgen Follrich Alfred Teischinger Wolfgang Gindl Ulrich Müller 《Wood Science and Technology》2007,41(6):501-509
To evaluate the effect of grain orientation on the adhesive bond strength, three-layered Norway spruce wood specimens were
tested in shear. The two axial-oriented outer layers were jointed with the middle layer using three typical glues for load
bearing constructions, i.e. one-component polyurethane (PUR), melamine–urea–formaldehyde (MUF) and phenol–resorcinol–formaldehyde
(PRF). The grain orientation of the middle layers was varied from 0° (parallel to grain of the surface layer) to 90° (perpendicular
to grain of the surface layer) in incremental steps of 10°. Samples with middle layers oriented parallel to the outer layers
showed shear values in the range of solid spruce wood. Decreased shear strength values were expected for increased grain angles
of the middle layer. However, no explicit tendency was observed for the shear strength in dependence of the grain direction.
In general, MUF-bonded samples showed slightly higher shear strength values compared with PUR- and PRF-bonded specimens. 相似文献
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《Wood material science & engineering》2013,8(4):185-189
Abstract One of the main disadvantages of wood is hygroscopicity resulting from its polar character. The sorption–desorption of water causes unwanted swelling and shrinkage in wood. Thermal modification substantially reduces this inconvenient feature. Unfortunately, the same chemical changes that reduce water sorption alter the polar character of the material and result in poorer wetting of thermally treated wood by waterborne adhesives. Gluability of thermally modified beech (Fagus silvatica L.) and birch (Betula pubescens Ehrh.) wood with two commercial amino resins, melamine–urea–formaldehyde (MUF) and melamine–formaldehyde (MF), and a two-component polyurethane (PUR) adhesive was investigated. Both wood species were modified according to two temperature regimes: 160°C and 190°C. Shear strengths of the joints were then determined according to EN 205:2003 standard. The results showed that thermally modified beech and birch wood can be effectively glued not only with commercially available PUR adhesives, but also with aqueous MF and MUF resins. The resultant shear strengths of the joints were limited by the strength of the thermally modified substrate. 相似文献
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稻壳的外表面覆盖有二氧化硅膜,使用传统的脲醛树脂(UF)和酚醛树脂胶(PF)生产的100％的稻壳板难以达到木质刨花板的质量指标。本研究采用以异氰酸酯(ISO)改性的脲醛树脂和酚醛树脂胶制造稻壳-木材复合材料。稻壳与木片的混合比例为1:1,施胶量为7％,设计密度0.8g/cm3。试验结果表明,3:4的ISO/UF、2:5的ISO/PF、改性胶粘剂制备的板材的物理力学性能达到国标刨花板二等品的要求;用3:4的ISO/PF改性胶粘剂制备的板材达到优等品的要求。 相似文献
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我国木材工业用胶黏剂产业现状及发展趋势 总被引：1，自引：0，他引：1
在我国木材工业中,三醛胶使用量较大,同时其他胶种的应用领域不仅局限在木材工业,交义较多,不易统计,笔者主要通过分析和总结我国三醛胶产业现状来论述我国木材工业用胶黏剂产业发展趋势,提出了市场需求是推动木材工业用胶黏剂产业发展的原动力的观点。 相似文献
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三聚氰胺改性低毒脲醛树脂耐水性研究 总被引：1，自引：0，他引：1
不同摩尔比的两类低毒脲醛树脂(JQ21未改性,JQ22与5%三聚氰胺共聚),分别与不同质量比的三聚氰胺树脂混合,并在不同的固化体系中固化,用于胶合板的压制.对胶合板的胶合性能及甲醛释放量进行了研究.实验结果表明:固化体系不同,胶接强度也不相同;随着摩尔比的增加,胶接强度提高,甲醛释放量亦相应提高;同时采用共聚和共混两种方法进行改性的脲醛树脂,其胶接强度和甲醛释放量均优于单一的采用共混改性的脲醛树脂;并且混合胶液中三聚氰胺的比例越低,胶接性能越筹,甲醛释放量变化逐渐趋于平稳. 相似文献
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The technology of liquefying processed-waste bamboo with phenol is investigated by single factor trials and an orthogonal
design. We studied the preparation technology and properties of adhesives from this phenol-liquefied bamboo with formaldehyde
(BPF). The results show that temperature has a significant effect on liquefaction. The effect of the mass ratio of phenol
to bamboo comes second and the catalyst dosage within the range of 2%–4% is the least effective. The optimum conditions of
liquefaction are as follows: a mass ratio of phenol to bamboo 3.5, a catalyst dosage of 4%, liquefying temperature 145°C and
liquefying time 60 min. The liquefaction rate of bamboo reached 99.1%. For the preparation of the adhesive, a mass ratio of
liquefied bamboo products to formaldehyde (37%) is 100 to 164.8–199.5, while the ratio 100 to 108.2 is the best. This adhesive
has a lower curing temperature than that of normal PF resin. At a hot-press temperature of 130 or 140°C, this new adhesive
provides excellent bonding strength of plywood. The most favorable temperature for hot-pressing is 140°C.
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Translated from Chemistry and Industry of Forest Products, 2007, 27(6): 65–70 [译自: 林产化学与工业] 相似文献
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Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to examine the chemical emissions from the glued wood
samples at elevated temperatures (150, 200, 250, 300, 350, 400, 450, and 500°C). Two wood species, Douglas-fir (Pseudotsuga menziesii) and southern pine (Pinus palustris), one structural adhesive, phenol–resorcinol–formaldehyde (PRF), PRF-bonded Douglas-fir, and PRF-bonded southern pine were
evaluated. The volatile compounds with a mass range of 35–300 m/z emitted from the pyrolysis samples were separated by gas
chromatography (GC) and identified by mass spectrometry (MS). The results indicated that compared to neat wood and resin film
samples, several additional pyrolysis products were observed for the PRF-bonded wood samples including (1) acetaldehyde and
butanedial for PRF-bonded Douglas-fir and (2) acetaldehyde, furfural, 2-furanmethanol, butanedial, 2,3-butanedione, cyclopropyl
carbinol, 1,2-benzenediol, and 1-(acetyloxy)-2-propanone for PRF-bonded southern pine. These additional compounds were possibly
associated with the interaction between wood and PRF resin. The results also indicated that bonded wood products would be
less thermally stable than those of neat wood and PRF resin samples. 相似文献
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The interference of copper based preservative treated southern yellow pine (SYP) on the cure of phenol-formaldehyde adhesives
was investigated by using differential scanning calorimetry (DSC). Copper preservatives used in this study include copper
azole (NS), alkali copper quat (ACQ)-type C (NW). Three commercial phenol-formaldehyde (PF) adhesives used for oriented strand
board (OSB) face area, core area and a plywood adhesive were studied. The curing peak temperature and peak time of OSB core
and face PF resin shifted to higher temperature and duration in the presence of CCA, NS, and NW-treated SYP compared to that
in untreated SYP. The above treatments interfere with the cure of OSB core and face PF resin. Untreated SYP showed a curing
accelerating effect on the cure of plywood adhesive, but the accelerating effect of copper-treated SYP on the cure of plywood
resin was not significant. 相似文献
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This study investigated the liquefaction of bamboo in phenol, which involved the effects of weight ratios of phenol to bamboo,
amount of catalyst, temperature, etc. The study showed that liquefaction could be accomplished with a phenol to bamboo weight
ratio of 2–1: 1, a 5% catalyst of HCl or BF3, and a temperature of 115°C. Liquefied bamboo formaldehyde (BLF) resin adhesive for exterior use could be obtained with a
phenol to formaldehyde molar ratio of 1:1.6–2.0. The curing behavior of BLF resin adhesive, studied by TG-DSC and IR analyses,
showed that BLF resin adhesives had a lower curing temperature than PF adhesives but had the same characteristic trough in
IR spectra as PF adhesives.
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Translated from Chemistry and Industry of Forest Products, 2004, 24(3) [译自: 林产化学与工业, 2004, 24(3)] 相似文献
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为获得无甲醛释放的环保胶合板,将热塑性树脂薄膜(低密度聚乙烯(LLDPE)、聚丙烯(PP)、聚氯乙烯(PVC))用作胶黏剂,并利用空气介质阻挡等离子体对热塑性树脂薄膜进行表面改性处理以提高薄膜与杨木单板的界面相容性,从而获得性能良好的环保胶合板。研究了等离子体处理对胶合板胶合性能的影响,并从等离子体处理对热塑性树脂薄膜表面化学组分及其对胶合板界面形貌的影响分析其胶合机理。结果表明:在等离子体处理功率为4.5 kW、处理时间为8 m/min的条件下处理热塑性树脂薄膜,胶合板的胶合强度得到显著提高,LLDPE/杨木胶合板的胶合强度从0.49 MPa增至0.81 MPa,PP/杨木胶合板的胶合强度从0.65 MPa提高到0.84 MPa,均达到Ⅱ类胶合板标准要求。其中用等离子体处理后PVC与杨木制备的胶合板能满足Ⅰ类胶合板的标准要求,胶合强度达到0.79 MPa。XPS分析表明,等离子体改性热塑性树脂薄膜的表面发生了氧化反应,引入了含氧官能团,提高了薄膜表面极性,有利于提高薄膜与杨木单板之间的相互作用,从而使得胶合板的界面胶合更为紧密,说明等离子体处理后树脂与杨木单板的相容性提高,树脂能在单板表面更好地附着。热塑性树脂薄膜与杨木单板制备的胶合板仅有极微量甲醛释放,其主要源于木材自身,远低于国家标准对人造板甲醛释放限量的要求。研究证明等离子体处理能明显改善热塑性树脂薄膜与杨木单板的界面相容性。 相似文献
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游离甲醛和人造板释放甲醛 总被引：20，自引：1，他引：20
甲醛是室内空气污染源，它常与甲醛系统粘接连在一起，本文根据国内外资料评述人造板甲醛释放量，分析了脲醛树脂的水解和人造板释放甲醛的机理，还介绍了甲醛的毒害，各国政府的有关法规以各种降低甲醛释放量的方法。 相似文献
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花生壳苯酚液化物-甲醛树脂胶用于集装箱底板试验 总被引：2，自引：0，他引：2
花生壳苯酚液化物-甲醛树脂胶粘剂是花生壳粉苯酚液化后的高反应活性产物与甲醛缩聚而成的高耐水性木材胶粘剂.探讨了花生壳苯酚液化物-甲醛树脂胶粘剂用于集装箱底板生产的最佳胶合工艺,检测了集装箱底板的各项物理力学性能和耐老化性能,并与传统酚醛胶及落叶松单宁胶进行了成本对比分析.结果表明,花生壳苯酚液化物-甲醛树脂胶粘剂的最佳胶合工艺为双面施胶量350 g/m2,热压时间1.2 min/mm,热压温度140℃;在此热压工艺条件下压制的集装箱底板的各项物理力学性能可以满足国家标准的要求,具有胶合强度高、耐老化性能优异、成本低廉等优点. 相似文献
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以脱脂大豆粉为原料制备大豆蛋白基胶黏剂(豆胶,S),以普通甲醛制备的酚醛树脂(PF_1)和高浓度甲醛制备的酚醛树脂(PF_2)为交联剂,使用前将两者直接混合得酚醛树脂改性豆胶(PF_1/S、PF_2/S)。利用差示扫描量热(DSC)、红外光谱(FT-IR)、动态热机械性能(DMA)和核磁共振碳谱(~(13) C NMR)分析对产品性能进行了测试与表征。结果表明:等物质的量之比条件下,高浓度甲醛较之普通甲醛制备的酚醛树脂改性豆胶胶合板干、湿剪切强度分别提高4.3%和11.6%,并且强度稳定性好;动态DSC分析表明,PF_2可以降低豆胶体系的固化温度和活化能,与豆胶的交联反应较容易;~(13) C NMR分析表明,PF_2体系羟甲基达88.73%,明显高于PF_1的80.91%;FT-IR分析证实酚醛树脂与豆胶中的氨基发生反应,并且PF_2反应效率更高;DMA分析表明,PF_2/S能够改善胶合产品的力学性能和热稳定性,降低豆胶的固化反应起始温度,提高固化反应速率。 相似文献
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《Wood material science & engineering》2013,8(2):83-89
Abstract To study the effect of grain angle on the adhesive bond strength in wood, three-part Norway spruce wood specimens were bonded and tested in tension. The two axially orientated outer parts of the specimens were joined with the middle part by means of three adhesives typically used for load-bearing constructions, i.e. one-component polyurethane (PUR), melamine–urea–formaldehyde (MUF) and phenol–resorcinol–formaldehyde (PRF). The grain angle of the middle part was varied from 0° (end grain to end grain) to 90° (flat grain to end grain) in incremental steps of 10°. In general, PRF- and MUF-bonded samples exhibited highest tensile strength at end grain to end grain orientation of the three parts, while specimens bonded with PUR showed only 25% of the strength measured for PRF and MUF, respectively. At high grain angles (90°) all specimens showed similar strength values in the range of 30% of maximum strength of MUF- and PRF-bonded specimens. To explain the changing strength levels at different grain angle a composite failure criterion was applied. 相似文献
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Amine Moubarik Hamid Reza Mansouri Antonio Pizzi Fatima Charrier Ahmed Allal Bertrand Charrier 《Wood Science and Technology》2013,47(4):675-683
A formaldehyde-free adhesive consisting of a corn flour/NaOH adhesive mixture and a mimosa tannin/hexamine intermediate component was developed and evaluated for application to wood panels such as particleboards. The main ingredients of this adhesive include corn flour, NaOH, mimosa tannin and hexamine. This study investigated the physical properties (rheological and thermal analysis) of corn flour/NaOH and mimosa tannin/hexamine adhesives as well as mechanical properties of particleboards produced with these adhesives. Thermomechanical (TMA) experiments indicate the best performance of the adhesives to be around the relative mass proportions of 50:50 between corn flour/NaOH and mimosa tannin/hexamine. Former NMR measurements on corn starch and mimosa tannin proved that the two components behave as a polymer blend rather than co-reacting. The laboratory results show that particleboards bonded with the adhesive at this optimal ratio show good mechanical properties. Moreover, the formaldehyde emission levels obtained from boards bonded with the optimal adhesive were considerably lower to those obtained from boards made with control urea formaldehyde. 相似文献