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CMC-g-PMMA改性稻壳碎料-水泥复合材料的性能 总被引：1，自引：0，他引：1
采用羧甲基纤维素与甲基丙烯酸甲酯的接枝共聚物(CMC-g-PMMA)作为改性剂对稻壳碎料进行表面处理,制成不同稻壳碎料含量的稻壳碎料-水泥复合材料(RHPC).对RHPC复合材料的密度、抗折性能、断面表面形貌、吸声性能、保温性能和燃烧性能进行测试和分析.结果表明:添加CMC-g-PMMA可大幅度提高RHPC复合材料的抗折强度和模量,当稻壳碎料含量为20%,CMC-g-PMMA添加量为1%时,抗折强度和模量分别为未添加助剂试样的2.27和2.71倍;声波频率为2 000 Hz以下,提高稻壳碎料含量后,水泥复合材料的吸声系数明显提高,1 000 Hz时,稻壳碎料含量为40%的试样的吸声系数高达0.67;制备的稻壳碎料-水泥复合材料为不燃性材料,具有良好的保温性能. 相似文献
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研究利用林木剩余物碎料和发泡聚苯乙烯并添加胶粘剂、助剂等进行加压制造复合材料.以导热系数、压缩强度、尺寸稳定性作为主要技术指标对复合材料进行评价,考察了木质碎料与聚苯乙烯泡沫不同配比、施胶量、密度等工艺参数对复合材料性能的影响,并利用扫描电镜对复合材料的界面进行了分析.结果表明:在设定密度范围内,由于胶粘剂、助剂和压力的共同作用,使木质碎料与发泡聚苯乙烯间形成蓬松状结合;正交试验确定的最佳工艺为:发泡聚苯乙烯与木材碎料配比为12∶88、施胶量12%、助剂2%、密度0.20g/cm3.用该工艺制造的复合材料达到相关标准要求. 相似文献
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以桐马酸酐甲酯改性杨木纤维(MEMA-PWF)为增强体、双酚A缩水甘油醚型环氧树脂(E51)/甲基四氢邻苯二甲酸酐(MeTHPA)为基体树脂,经热压成型制备杨木纤维增强环氧树脂复合材料.通过接触角测量、扫描电镜(SEM)分析表征了复合材料表面及断裂面结构形貌,并测试了复合材料的冲击强度、弯曲强度.实验结果表明,改性后的杨木纤维表面疏水性及其与环氧树脂基体界面相容性得到明显提高;以MEMA-PWF/环氧树脂体系制备的复合材料力学性能提高,冲击强度、弯曲强度分别达到7.95 kJ/m2、55.42 MPa,并具有较好的疏水性. 相似文献
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互花米草碎料板的生产工艺 总被引：1，自引：0，他引：1
研究以互花米草为原料,以脲醛树脂为胶黏剂制作碎料板的生产工艺。试验表明:在互花米草各部位中以杆部为原料制作出的碎料板性能最好;由于互花米草的表皮存在较高的硅物质,通过加大互花米草茎秆的粉碎程度,使表皮组织尽可能分散,能够显著提高碎料板的性能;互花米草碎料板存在内结合强度和吸水厚度膨胀率性能较差问题,作者尝试通过增加密度和施胶量对性能进行改善,结果表明增加施胶量效果较为明显;将互花米草与木质刨花混合制作木草复合碎料板,容易解决互花米草碎料板内结合强度低的问题,试验中当互花米草的质量分数为35%时,木草复合碎料板的内结合强度超过木质普通刨花板标准要求。 相似文献
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氢化萜烯马来酸酐合成环氧树脂的研究 总被引：5，自引：5，他引：0
以氢化萜烯马来酸酐(HTMA)为原料与环氧氯丙烷反应合成一种含桥环结构的饱和脂环基环氧树脂--氢化萜烯酯型环氧树脂(HTME).通过研究反应物料配比、反应温度与时间、催化剂用量、碱的用量与浓度以及溶剂类型等因素对合成反应的影响,确定了最佳合成反应条件,并经FT-IR及NMR光谱表征了环氧树脂的化学结构.该树脂为浅黄色透明液体,采用化学分析方法测定其环氧值3.5～3.9 mmol/g,黏度 1.7 Pa·s(50 ℃),酸值＜0.5 mg/g. 相似文献
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采用加速老化试验方法对竹复合管材的湿热老化性能及老化机理进行研究,探究不同湿热老化历时下竹复合管材拉伸、压缩和弯曲性能的变化。结果表明,在交变湿热应力作用下,竹复合管材拉伸强度、压缩强度、压缩弹性模量、弯曲强度和弯曲弹性模量随湿热老化时间延长呈幂指数降低,拉伸劣化大于弯曲,弯曲劣化大于压缩,模量劣化大于强度;湿热老化28次后,竹复合管材拉伸强度、压缩强度、压缩弹性模量、弯曲强度和弯曲弹性模量分别降低34.11%、25.64%、26.39%、26.14%和27.83%。交变湿热应力使结构层树脂和竹纤维均发生湿胀,结构层树脂湿胀率小于竹纤维,不均匀的湿胀使结构层树脂受拉、竹纤维受压,结构层树脂竹纤维界面产生剪切力,树脂开裂、脱落,纤维树脂界面形成孔洞和微裂纹降低有效应力传递,当剪切力大于界面粘结力时,界面损伤模式主要表现为脱粘以及剪切分层。 相似文献
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The aim of this study is to investigate the properties of CaCO3 in situ treated bamboo pulp fiber (BPF) composites that have been filled with epoxy resin by means of vacuum-assisted resin infusion (VARI). Un-treated and treated BPF were processed at a pressure of 0.24 MPa into BPF preforms. VARI was used to infuse epoxy resin through the BPF preforms to make BPF composites. The flexural properties, impact property, and thermal properties of the BPF composites were analyzed. CaCO3 with the loading of 30 wt% affects the performance of the composites. The flexural strength did not decrease and modulus of the treated BPF composites increased by 9.38%, while the impact strength decreased by 50.98%, compared to the control sample. Dynamic mechanical analysis revealed the maximum elastic moduli of the treated specimens increased by 1.19 times in the temperature range of ?20 to 120 °C. The thermal decomposition temperature of the composites was influenced by the effect of the crystal field and size effect of CaCO3. 相似文献
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Ultrasonic nondestructive evaluation (NDE) methods have been successfully applied for grading lumber and veneer at the in-plant level. To expand this application in wood composite production, further research is needed to elucidate the effect of differences of component elements within wood composite panels on the behavior of ultrasonic waves traveling through them. The objective of this study was to investigate the effects of the internal bonding of particleboard specimens containing component chips of different geometry on ultrasonic velocity. Commercial chips screened at four sizes were used to produce particleboard specimens with different internal bonding by controlling their out-of-press thickness at (a) a constant thickness for boards made of each chip size, and (b) four different thicknesses for boards made of the same chip size. Twenty-four boards were made with phenol-formaldehyde (PF) resin at 8% solid resin content in our laboratory. After the velocities of the waves traveling through the thickness of the boards were recorded, the internal bond strengths were tested. Results showed the density, internal bond state, and constituted chip geometry were the main factors influencing the velocity. NDE using ultrasonic waves is an available method to evaluate the internal bonding of particleboard with a density less than about 0.75g/cm3. With densities over that value, no significant changes of the velocity were found.Part of this paper was presented at the 48th annual meeting of the Japan Wood Research Society, Kochi, April 1998 相似文献
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平面密度分布对刨花板内结合强度的影响 总被引：1，自引：0，他引：1
平面密度变异是非单板类木质人造板所共有的一种结构现象 ,其变异程度和分布特征对板材性能有一定影响。本文利用单板条模拟 4种具有不同平面密度分布的刨花板 ,讨论了随机铺装刨花板坯模型的平面密度分布规律及试件大小与密度分布的关系 ,分析了密度以及平面密度分布对非单板类木质人造板内结合强度的影响。结果表明 :随机铺装刨花板的平面密度遵循正态分布规律 ;内结合强度受密度影响较大 ,密度增加有助于内结合强度提高 ,但密度过高将导致内结合强度下降 ;试件大小影响试件之间密度变异程度 ,适当增加试件尺寸 ,可降低内接合强度测试结果的离散性。 相似文献
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To determine shear strength we conducted uniaxial-tension tests of off-axis specimens and examined the proper off-axis angles. Sitka spruce (Picea sitchensis Carr.) and katsura (Cercidiphyllum japonicum Sieb. and Zucc.) were used for the studies. Uniaxial tension tests of the specimens with various off-axis angles were conducted, and the shear stress at failure was obtained. Independent of the tension tests, torsion tests were conducted, and the shear strengths were obtained. Comparing the data of the uniaxial tension and torsion tests, we examined the validity of estimating shear strength by the off-axis tension test. The shear strengths obtained from the tension tests coincided well with those measured by the torsion tests when the specimen had an off-axis angle of 15°–30°. In this off-axis angle range, the tensile stress perpendicular to the grain might have a serious influence on the shear strength, and we thought that the shear strength predicted by uniaxial tension tests should be treated as an approximate value despite the simplicity of the tension test. Other test methods should be adopted to obtain the precise shear strength of wood. 相似文献
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The relationships between bending properties, compressive strength, tracheid length, microfibril angle, and ring characteristics
of 20-year-old Taiwania (Taiwania cryptomerioides Hay.) trees were examined. The trees came from different thinning and pruning treatments, but the practices showed no significant
effect on the investigated properties. The results showed that based on comparison with the literature, plantation-grown immature
Taiwania have noticeably lower average strength properties than mature trees of the same species. Wood density and bending
and compressive strengths were not related to either tracheid length or microfibril angle in young Taiwania. There were positive
relationships between bending strength and compressive strength. The wood density, ring width, earlywood width, earlywood
density, and latewood percentage were the most important predictors of strength by simple linear regressions. The wood density
and ring width/earlywood width may be considered as indicators for assessing the bending strength, while wood density and
latewood percentage were the best predictors of compressive strength by multiple linear regressions. 相似文献
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木纤维PP/PE共混物复合材料的流变和力学性能(英文) 总被引：2，自引：0，他引：2
For evaluation of the rheological and mechanical properties of highly filled wood plastic composites （WPCs）, polypropylene/polyethylene （PP/PE） blends were grafted with maleic anhydride （MAH） to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region （〈0.1%）. The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends. 相似文献
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Cryptomeria japonica (Japanese cedar) wood was liquefied using polyethylene glycol (PEG-400 and PEG-600)/glycerol as the solvent with H2SO4 as a catalyst. The blended epoxy resins were prepared by mixing the liquefied wood with epoxy resin of various weight ratios
and used for wood gluing. The results showed that blended epoxy resins could cure under room temperature with an exothermic
reaction. DSC thermoanalysis showed that increasing the blending amount of liquefied wood would shift the peak of curing reaction
to a higher temperature but with less heat released. Blended epoxy resins had a good dry bonding strength for wood when cured
at room temperature. However, curing with heat treatment could improve the wet bonding strength of blended epoxy resins, especially
for those prepared with PEG-400-liquefied wood. 相似文献
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以自主研制的新型木材防腐剂为防腐药剂,选择已经发生初期轻微蓝变的试件和没有腐朽的试件,通过施加防腐剂,接种白腐菌、软腐菌和褐腐菌试验,按照不同时间检测试件的顺纹抗压强度和失重,分析新型木材纳米防腐剂的抑菌性能及对不同菌种的抑菌效果。结果表明：防腐剂对褐腐菌具有较好的抑菌性能,在试验近90天的时间内基本保持顺纹抗压强度不变,并且试件失重很少,可见铜对褐腐菌作用效果显著;对白腐菌和软腐菌效果不明显,需要进行防腐剂复配的进一步试验;对已发生初期轻微蓝变的试件,施加防腐剂基本没有作用。 相似文献
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来源于木材、麦草、竹子和蔗渣的木质素磺酸钠与三聚氰胺、甲醛和焦亚硫酸钠合成出磺化木质素三聚氰胺甲醛超塑化剂(LSMF).系统研究了LSMF对砂浆减水率、抗压强度、抗折强度和加速碳化深度等应用性能的影响.结果表明,使用麦草基木质素磺酸钠合成出磺化度3.663mmol/g,特性黏度7.24mL/g的LSMF对砂浆的减水增强性能最好.当LSMF掺量为0.7%时,砂浆减水率为21.1%.硬化砂浆28d加速碳化深度为13mm,空白砂浆为34.5mm.掺加LSMF后,硬化砂浆28d抗压强度和抗折强度分别比空白砂浆提高37%和18%.LSMF超塑化剂为木质素高效利用提供了一种新的思路. 相似文献