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1.
We studied the effect of repeated application (once every 2 d) of a fertilizer solution with different ratios of NH4+ - and NO3−-N on N2O emission from soil. After the excess fertilizer solution was drained from soil, the water content of soil was adjusted to 50% of the maximum water-holding capacity by suction at 6 × 103 Pa. Repeated application of NH4+- rich fertilizer solution stimulated nitrification in soil more than NO3−-rich fertilizer. Although the evolution of N2O through nitrifier denitrification tended to increase with the repeated addition of a fertilizer solution rich in NH4+ rather than in NO3−, the contribution of nitrifier denitrification remained at levels of 20 to 36% of the total emission regardless of the inorganic N composition. The total emission of N2O also tended to increase with the application of NH4+- rather than NO3−-rich fertilizer. It was suggested that the coupled process of nitrification and denitrification at micro-aerobic sites became important when fertilizer rich in NH4+ was applied to soil under relatively aerobic conditions.  相似文献   

2.
Gaseous N loss, through denitrification and NH3−volatilization, was monitored throughout the growing season after spring application of 15N labelled urea fertilizer to peaty gley soils supporting N-deficient Sitka spruce. From the 15N data, it was calculated that only about 0.28% of applied N was lost through NH3-volatilization, almost all within the first few days after fertilizer application. Approximately 0.05% of applied N was calculated to be lost through denitrification. Denitrification decreased slowly over a 4-month period after fertilizer application. Rates of NH3-volatilization correlated with available NH4+ in the litter layer, while for the early part of the study when N-losses were highest, denitrification rates correlated with available NO3− in the litter layer. Observations of gaseous N-loss are also discussed in relation to data from lysimetry, changes in soil pH, and the soil moisture regime.  相似文献   

3.
Soil properties may affect the decomposition of added organic materials and inorganic nitrogen (N) production in agricultural soils. Three soils, Potu (Pu), Sankengtzu (Sk) and Erhlin (Eh) soils, mixed with sewage sludge compost (SSC) at application rates of 0 (control), 25, 75 and 150 Mg ha−1 were selected from Taiwan for incubation for 112 days. The aim of the present study was to examine the effects of SSC application rates on the carbon decomposition rate, N transformation and pH changes in three soils with different initial soil pH values (4.8–7.7). The results indicated that the highest peaks of the CO2 evolution rate occurred after 3 days of incubation, for all treatments. The Pu soil (pH 4.8) had a relatively low rate of CO2 evolution, total amounts of CO2 evolution and percentage of added organic C loss, all of which resulted from inhibition of microbial activity under low pH. For the Pu and Sk soils, the concentration of NH4+-N reached its peak after 7–14 days of incubation, which indicated that ammonification might have occurred in the two soils with low initial pH values. NO3−-N rapidly accumulated in the first 7 days of incubation in the Eh soil (pH 7.7). The direction and extent of the soil pH changes were influenced by the N in the SSC and the initial soil pH. Ammonification of organic N in the SSC caused the soil pH to increase, whereas nitrification of mineralized N caused the soil pH to decline. Consequently, the initial soil pH greatly affected the rate of carbon decomposition, ammonification and nitrification of SSC.  相似文献   

4.
Low molecular weight organic acids exist widely in soils and have been implicated in many soil processes. The results in the present paper showed that the presence of organic anions led to a decrease in the adsorption of NO3−. The effect of citrate was much larger than that of oxalate and malate. Among different soils, the effect for Hyper-Rhodic Ferralsol and Rhodic Ferralsol was larger than that for Haplic Acrisol, which was related to the content of iron oxides in these soils. The effect of organic anions decreased with the increases in pH value and the amount of organic anions added. The organic anions depressed the adsorption of NO3− through two mechanisms, the competition of the organic anions for adsorption sites with NO3− and the change of soil surface charge caused by the specific adsorption of organic anions.  相似文献   

5.
Abstract. The effects of especially frequent nitrogen (N) additions (from 1959 to 1986, totalling 860 kg N ha−1) and liming (in 1958 and 1980, totalling 6000 kg CaCO3 ha−1) on CH4 uptake by a boreal forest soil were studied in a stand of Norway spruce. Except for a forested reference plot, the stand was clear-cut in January 1993 and the following year one-half of each clear-cut plot was prepared by mounding. Fluxes of CH4 were measured with static chambers in the autumn before clear-cutting and during the following four summers. The average CH4 uptake during 1993–96 in the forested reference plot was 82 μg CH4 m−2 h−1(ranging from 10 to 147 units). In the first summer after clear-cutting, the cleared plot showed 42% lower CH4 uptake rate than the forested reference plot, but thereafter the difference became less pronounced. The short-term decrease in CH4 consumption after clear-cutting was associated with increases in soil NH4+ and NO3−concentrations. Mounding tended at first to stimulate CH4 uptake but later to inhibit it. Neither liming nor N-fertilization had significant effects on CH4 consumption. Our results suggest that over the long term, in N-limited upland boreal forest soils, N addition does not decrease CH4 uptake by the soil.  相似文献   

6.
The formation of CH3ONO in 11 soils treated with HNO2 or NaNO2 in a closed system, was studied by measuring the concentration in the gas space above the soil and by absorbing CH3ONO in HI. The gaseous concentration of CH3ONO increased and then decreased following additions of HNO2 or NaNO2, and the production of CH3ONO increased with increasing concentrations of HNO2 or NaNO2 added to soils.
The amounts of CH3ONO trapped in HI were 13.5 to 20.4 times higher than those determined by integrating under the net production curves. The evolved CH3ONO amounted to 0.4 to 3.5% of added NO2−, and 4.2 to 50% of the gaseous forms of N absorbed by acidic KMnO4 solution. The CH3ONO evolved from soils was positively correlated with the methoxy content of the soils, and inversely related to soil pH, with negligible amounts being evolved from alkaline soils. The results show that CH3ONO is a product of NO2− decomposition in soils, and indicate that small concentrations of the gas may be produced in N–fertilized soils in which NO2− accumulates.  相似文献   

7.
The origin of highly acidic (pH<4.5) barren soils in the Klamath Mountains of northern California was examined. Soil parent material was mica schist that contained an average of 2,700 mg N kg−1, which corresponds to 7.1 Mg N ha−1 contained in a 10-cm thickness of bedrock. In situ soil solutions were dominated by H+, labile-monomeric Al3+ and NO3−, indicating that the barren area soils were nitrogen saturated—more mineral nitrogen available than required by biota. Leaching of excess NO3− has resulted in removal of nutrient cations and soil acidification. Nitrogen release rates from organic matter free soil ranged from 0.0163 to 0.0321 mg N kg−1 d−1. Nitrogen release rate from fresh ground rock was 0.0465 mg N kg−1 d−1. This study demonstrates that geologic nitrogen may represent a large and reactive nitrogen pool that can contribute significantly to soil acidification.  相似文献   

8.
Characteristics of the treatment processes inside a MSL system were investigated by using a laboratory-scale MSL system, which was set up in a D 10 × W 50 × H 73 cm acrylic box enclosing "soil mixture blocks" alternating with permeable zeolite layers. For the study of the treatment processes inside the system, wastewater, with mean concentrations (mg L−1) of COD: 70, T-N: 12, T-P: 0.9, was introduced into the system at a loading rate of 1,000 L m−2 d−1. Treatment processes in the MSL system were different for the COD, P and N pollutants. Eighty percent of COD was removed in the 1st soil layer among the 6 layers, and the removal rate increased as water moved down and finally reached 90% in the last layer of the system. Phosphorus concentration was lower under the soil mixture layers than under the permeable layers, presumably because P was adsorbed mainly by soil and mixed iron particles. The P concentration in water gradually decreased in the lower layers of the system. The concentration of PO43--P was generally lower in the aerated MSL system than in the non-aerated one. NH4+-N was adsorbed and nitrified in the upper part of the system. The NO3−-N concentration was lower in water under the soil mixture layers than under the permeable layers, indicating that denitrification mainly occurred in the soil mixture layers.  相似文献   

9.
Abstract. Inputs of acidity to the ground arise through two distinct routes: wet deposition which includes all acidity deposited in rain and snow and dry deposition, the direct sorption of SO2, NO2 or HNO3 gases by vegetation or soil surfaces. The acidity from dry deposition of SO2 and NO2 is created during the oxidation of deposited SO2 and NO2 to SO24 and NO3− respectively. The areas of Britain experiencing the largest wet deposition of acidity are the high rainfall areas of the west and north, in particular the west central highlands of Scotland, Galloway and Cumbria where inputs exceed 1 kp H+ ha−1 annually. Wet deposited acidity in the east coast regions of Britain is in the range 0.3–0.6 kg H+ ha−1 a−1. Monitoring data for rainfall acidity at rural sites throughout northern Britain show a decline in deposited acidity of about 50% during the last six years. Dry deposition is largest in the industrial midlands and southeast England and in the central lowlands of Scotland, where concentrations of SO2 are largest. In these regions the dry deposition of SO2 following oxidation may lead to acid inputs approaching 3 kg H+ ha−1 a−1 and greatly exceeding wet deposition.  相似文献   

10.
Nitrogen leaching from soils in the Kopais area of Greece   总被引：1，自引：0，他引：1  
Abstract. The contribution of agriculture to the nitrogen pollution of surface and ground waters of calcareous lake soils in the Kopais area (190 km2) of Greece was studied over three cropping seasons. Sample fields were chosen from seven representative soil units under different crop rotations. The distribution of mineral N (NO3-N + NH4-N) throughout the soil profile and the concentration of NO3-N in the ground water and drainage water were measured and allocated to 6-month winter or spring periods. For all fields N was leached to the deeper soil layers and to the saturated zones by both excess winter rainfall and spring irrigation of different crops The amount of nitrogen leached depended on the amount of nitrogen fertilizer applied; the depth of leaching varied with the physical properties of the soils. Losses in individual fields accounted for the equivalent of 17.6–80.8% of the nitrogen applied to maize and 70.5–94.1% of that applied to wheat. For the whole region estimated minimum N losses ranged from 175, 912 to 783, 564 kg for the 6-month period. Nitrate concentrations in the ground and surface waters were often more than the EC target level of 25 mg/1.  相似文献   

11.
Soil microbial immobilization and plant uptake of N were evaluated for three forest types in Kochi, Shikoku district. During 196-d laboratory incubation, soil NO3-N production in the Hinoki cypress forest was negligible for the initial 40 d and then rapidly increased, whereas NO3-N production was rapid from the beginning in Japanese cedar and deciduous hardwood forests. Microbial immobilization of the labeled 15N decreased in the order of NH4-N>glycine-N>NO3-N. The 15N immobilization was higher for soil in the Hinoki cypress forest than other two soils. The delayed NO3-N production in the Hinoki cypress forest was likely related with low availability of NH4-N due to NH4-N immobilization and substantial NO3-N immobilization. In the field experiment, 15N uptake by roots decreased in the order of NH4-N>NO3-N>glycine-N. The absorption of the labeled 13C suggested direct uptake of organic N. The preference of N forms by root uptake was not different among forest types. Trees in three forest types can absorb inorganic and organic forms of N, suggesting trees absorb the N form that is the most abundant in the soil.  相似文献   

12.
Abstract. The recommended method of reducing the emission of NH3 while spreading manure is to plough or harrow the manure into the soil. This in turn increases the possibility of N2O emission. At two sites in southern Sweden emissions of NH3 and N2O were measured after spreading pig slurry by broadcasting and band spreading. The band spreading technique can be used in growing crops i.e. when nitrogen is most needed, and it is thought that the NH3 emission is smaller with this technique compared to broadcasting. The average NH3 loss was 50% of applied NH4+ during warm/dry conditions and 10% during cold/wet conditions. The N2O emission was always less than 1% of applied NH4+. When the NH3 emission decreased, the direct N2O emission increased. However, when taking into account the indirect N2O emission due to deposition of NH3 outside the field, the spreading techniques all produced similar total N2O emissions. The ammonia emission was not much lower for the band spreading technique compared to broadcasting, when compared on seven occasions.  相似文献   

13.
Abstract. We evaluated the effectiveness of capillary-wick samplers (PCAPS) for continuous monitoring of resident nitrate concentration in three 'soil-crop-climate' systems differing in soil type, land use and climate. These systems involved: (i) acid silty soils under a beech-oak forest affected by heavy N-NH4+ deposition in Belgium; (ii) silty soils under wheat cropping and a short rotation willow coppice plantation (SRC) in Belgium; and (iii) volcanic ash soils under plantain cultivation with and without urea fertilization in Colombia. The PCAPS continuously applied a suction of 0 to 5.4 kPa to the soil water below the effective rooting zone without the need for an auxiliary vacuum source. The nitrate concentrations showed large variations over time and ranged between 6–192 mg l–1 under forest, 19–143 mg l–1 under wheat, 11–47 mg l–1 under SRC and 3–138 mg l–1 under fertilized plantain. The analysis of the soil leachates collected with PCAPS confirms previous results dealing with leaching of nitrate and alkaline and alkaline-earth cations in similar 'soil-crop-climate' systems. It was concluded that PCAPS was a suitable tool to collect soil solutions and that it could help to assess nitrate leaching losses in various ecological or cropping conditions.  相似文献   

14.
Abstract. Nitrate leaching and pasture ( Lolium perenne / Trifolium repens ) yields were measured on monolith lysimeters (80 cm diam. × 120 cm depth) of a Templeton sandy loam soil (Udic Ustochrept), following repeated applications of dairy shed effluent (DSE) or ammonium fertilizer (NH4Cl), under spray (50 mm/month) or flood (100 mm/month) irrigation. Applications of DSE at 400 kg N/ha per annum resulted in significantly less nitrate leaching (8–25 kg N/ha per yr) compared with NH4Cl (28–48kg N/ha per yr) ( P < 0.01). Over the two year period, the total mineral N (predominantly nitrate) leached was equivalent to 2.5–3.7% of the total N applied in the DSE and 8.7–9.8% of the N applied in the NH4Cl. There was a trend of slightly less nitrate leaching under the flood irrigation than under the spray irrigation, probably because of the greater potential for denitrification under the wetter conditions. Average nitrate concentrations in the leachate were generally below the drinking water standard except in the NH4Cl treatment under spray irrigation where it averaged 10 mg NO3-N/l over the two year period. DSE was equally as effective as NH4Cl in stimulating pasture dry matter production. Annual nitrogen uptakes were similar for the DSE (343 kg N/ha) and NH4Cl (332–344kg N/ha) treatments in the first year but were higher in the DSE (361–412 kg N/ha) than in the NH4Cl (324–340 kg N/ha) treatments in the second year. Pasture uptakes of phosphorus and sulphur were also higher in the DSE than in the NH4Cl treatments in the second year. The results emphasize the need to set different regulatory limits for land application of organic wastes of various types and for N fertilizers.  相似文献   

15.
Abstract. Rainfall has become less acid at Rothamsted and Saxmundham over the period 1969–83. The pH of rain at these two sites has increased from 4.4–4.6 to about 4.8–4.9; at Woburn it has remained approximately constant at 4.4–4.6. Amounts of NH4-N and NO3-N deposited at present are 10–15 and 5–10 kg ha−1 a−1 respectively. They have been increasing at Rothamsted and Woburn. Some 50–60 kg ha−1 a−1 of Cl and 25–35 kg ha−1 a−1 of SO4-S are presently deposited. Deposition of non-sea Cl and SO4-S has been increasing markedly at all three sites. Non-sea salts comprise 35% of the total salt deposition near the coast at Saxmundham, 58% inland at Rothamsted and Woburn.  相似文献   

16.
The effects of burning on the levels of soil organic matter, soil nitrogen, and soil microbial biomass were studied by carrying out experimental shifting cultivation at two sites, Niah and Bakam in Sarawak, Malaysia. Vegetation biomass was burned in plots (10 × 10 m2) at the rates of 0 (control), 100, 200, and 300 Mg ha−1 at the Niah site and 0, 20, and 100 Mg ha−1 at the Bakam site. At the Niah site, the levels of total C and N of the soils did not change throughout the experiment in spite of enhanced soil respiration until 2 months after burning. Although burning induced an increase in the amount of NH4-N of the soils, the readily available pool of N (the sum of the NH4-N, NO3-N, microbial biomass N, and extractable organic N pools) in the burned plots was depleted appreciably at the end of rice cultivation. The effects of burning on these properties tended to be substantial with increasing amounts of the vegetation biomass burned. On the other hand, the levels of total C and N and the readily available N pool at the Bakam site were low before burning compared with those at the Niah site, and the burning treatments did not affect them appreciably. While the rice yield at the Niah site reached the average value obtained in traditional shifting cultivation in Sarawak, that at the Bakam site was much lower. It was suggested that the flush of NH4-N induced by burning was one of the major factors for rice growth.  相似文献   

17.
Abstract. Regular application of slurry manure in large quantities is thought to degrade soil structure and increase erodibility. One hypothesis links this to the large input of potassium which increases the exchangeable potassium percentage (EPP) and, thereby, dispersion. The effect of EPP on erodibility was quantified in three experiments. In the laboratory, eleven rainfall experiments were conducted using a silty topsoil from a typic Hapludalf which was fertilized to EPPs of 4 to 18%. Field rainfall experiments on 22 Inceptisols and Alfisols were used to examine whether the long-term application of monovalent cations (Na+, K+ and NH4+) with slurry manure had changed soil properties, especially erodibility. In addition, erodibilities of 32 soils determined with natural and simulated rains were taken from literature. The experiments on these 65 soils together covered a wide range of soils, slopes and rainfalls. Dispersion by a large percentage of highly hydrated ions (K+, Na+) reduced the infiltration rate faster, caused runoff up to 5 min earlier, and increased sediment concentrations by 15g/l compared to low EPP soils. These changes increased soil erodibility of the Universal Soil Loss Equation (USLE) by 0.021 t × h/N × ha (where N = Newtons) for each 1% increase in EPP + ESP (exchangeable sodium percentage). The ESP contributed little to this increase as ESP was less than 1/10 of EPP in the experiments.
Fields with long-term manure application had similar chemical, physical and microbiological soil properties as fields without slurry manure except for slightly greater pH (+ 0.6) and P (+ 17 mg/kg) values. We conclude that, as long as the potassium input and output are balanced, the long-term use of slurry manure does not increase erodibility.  相似文献   

18.
Abstract. A review of recent data shows that (i) dissolved CO2 has its greatest acidifying effect in soils with pH values above about 6.5, (ii) fertilizers containing NH−1+ ions or urea will acidify soil whether the ions are taken up directly by plants or are first nitrified, (iii) oxidation of nitrogen and sulphur in soil organic matter causes acidification especially after deforestation, and (iv) the acidifying effect of rainfall and dry deposition is due to sulphuric and nitric acids, SO2 and NH−1+ ions. A table is given showing the order of magnitude of each source of acidification.  相似文献   

19.
Abstract. The effect of increasing rates of nitrogen (N) fertilizer on the yield response of 3 or 4 consecutive winter cereal crops after ploughing out grass was investigated at six field sites on commercial farms in England and Wales. Amounts of N required for an economically optimum yield (>3 kg of grain for each kg of fertilizer N applied) ranged from 0 to 265 kg ha−1 and were dependent on soil N supply, but not on crop yield. Optimum N rates were large (mean 197 kg N ha−1) at three sites: two sites where cereals followed 2-year grass leys receiving low N inputs (<200 kg N ha−1), and at one site where a cut and grazed 4-year ley had received c . 315 kg N ha−1 of fertilizer N annually. At the other three sites where 4 and 5-year grass leys had received large regular amounts of organic manures (20–30 t or m3 ha−1) plus fertilizer N ( c . 300 kg ha−1 each year), optimum N rates were low (mean 93 kg N ha−1) and consistently over-estimated by the farmer by an average of 107 kg N ha−1. Optimum N rates generally increased in successive years after ploughing as the N supply from the soil declined. Determination of soil C:N ratio and mineral N (NO3N+NH4N) to 90 cm depth in autumn were helpful in assessing fertilizer N need. The results suggest there is scope to improve current fertilizer recommendations for cereals after grass by removing crop yield as a determinant and including an assessment of soil mineralizable N during the growing season.  相似文献   

20.
Abstract. We studied the effects of five diverse non-agricultural organic wastes on soil composition, grass yield and grass nitrogen use in a 3–year field experiment. The applied wastes were distillery pot ale, dairy salt whey, abattoir blood and gut contents, composted green waste (two annual applications each), and paper-mill sludge (one annual application). With the exception of N immobilization in the paper-mill sludge treatment, the wastes had no unfavourable effects on the soil. In the 2–year treatments, grass dry matter yields from the abattoir and distillery wastes (26.3 t ha−1) were larger than those from a NH4NO3 fertilizer treatment (24.3 t ha−1) and from the dairy waste (20.4 t ha−1) and composted waste (22.8 t ha−1). Yield and N recovery were impaired markedly after the single application of paper-mill sludge, both in the year of application and in the following year. The results demonstrated clear differences in the ability of the applied wastes to provide crop-available N. We conclude that in order to improve prediction of both the benefits and risks from waste recycling to land, more information should be gathered on soil/waste/crop interactions.  相似文献   

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