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1.
An apparatus was constructed to measure diffusivity of krypton-85 and gas permeability in an enclosed core of soil of field structure or in other porous material. Sample enclosure decreased water loss by evaporation, reduced mass flow caused by changes in ambient temperature and pressure during diffusion measurement, and allowed subsequent measurement of gas permeability without further sample disturbance. When a bundle of tubes was used as a test sample to calibrate the apparatus, the resistances to diffusion and viscous flow agreed approximately with those calculated from the tube size and number. Gas movement was measured in dry sieved soil and in undisturbed cores of silty loam soil to illustrate the practical value of the method. In the dry cores, diffusivity relative to free air (DA/Do) was greater in ploughed soil, 0.18, than in direct drilled soil, 0.14, nearly in proportion to the greater air porosity in the ploughed soil, but air permeability in ploughed soil was four times greater than in direct drilled soil and was about 1 000 times greater than in compacted sieved soil. 相似文献
2.
Jay D. Jabro Upendra M. Sainju William B. Stevens Robert G. Evans 《Archives of Agronomy and Soil Science》2013,59(1):1-9
Diffusion coefficients (D) of CO2 at 0–10 cm layers in undisturbed and tilled soil conditions were estimated using the Penman (Penman HL. 1940. Gas and vapor movement in soil, 1. The diffusion of vapours through porous solids. J Agric Sci. 30:437–463), Millington–Quirk (Millington RJ, Quirk JP. 1960. Transport in porous media. In: Van Baren FA, editor. Transactions of the 7th International Congress of Soil Science. Vol. 1. Amsterdam: Elsevier. p. 97–106), Ridgwell et al. (Ridgwell AJ, Marshall SJ, Gregson K. 1999. Consumption of atmospheric methane by soils: A process-based model. Global Biogeochem Cy. 13:59–70), Troeh et al. (Troeh FR, Jabro JD, Kirkham D. 1982. Gaseous diffusion equations for porous materials. Geoderma. 27:239–258) and Moldrup et al. (Moldrup P, Kruse CW, Rolston DE, Yamaguchi T. 1996. Modeling diffusion and reaction in soils: III. Predicting gas diffusivity from the Campbell soil–water retention model. Soil Sci. 161:366–375) models. Soil bulk density and volumetric soil water content (θv) at 0–10 cm were measured on 14 April, 2 June and 12 July 2005 at 0–10 cm depth in no-till (NT) and conventional till (CT) malt barley and undisturbed soil grass–alfalfa (UGA) systems. Air-filled porosity (ε) was calculated from total soil porosity and θv measurements. Both soil air porosity and estimated CO2 diffusivity at the 0–10 cm depth were significantly affected by tillage. Results of CO2 diffusion coefficients in the soil followed trends similar to those for soil ε data. The CT tended to have significantly greater estimated soil CO2 diffusion coefficients than the NT and UGA treatments. The relationship between D/D 0, and air-filled porosity was well described by a power (R 2 = 0.985) function. The model is useful for predicting CO2 gas-diffusion coefficients in undisturbed and tilled soils at various ranges of ε where actual gas D measurements are time-consuming, costly and infeasible. 相似文献
3.
Accurate quantification of soil gas diffusion is essential to understand the gas transport mechanism in soils, especially for soil greenhouse gas emissions. To date, the performance of soil gas diffusivity (Dp/D0, where Dp is the soil gas diffusion coefficient and D0 is the diffusion coefficient in free air) models has seldom been evaluated for no-tilled and tilled volcanic ash soils. In the present study, six commonly used models were evaluated for volcanic ash soils under two treatments by comparing the predicted and measured soil gas diffusivities at water potentials of pF 1.3–3. The Buckingham-Burdine-Campbell (BBC), soil-water-characteristic-dependent (SWC-dependent), and two-region extended Archie’s Law (2EAL) models showed better performance for both no-tilled and tilled volcanic ash soils, which is likely because porosity and pore size parameters of bimodal soils were taken into consideration in these models. Since the BBC model showed better accuracy than the SWC-dependent and 2EAL models and required fewer, more easily measurable parameters, this study recommends the BBC model for predicting soil gas diffusivity of volcanic ash soil under different tillage managements. In future studies, the BBC model should be further tested at water potentials of pF > 3, and may be improved by including the parameters of pore continuity and saturation. 相似文献
4.
The variability of gas diffusion in soil is not well known, but is important for assessing greenhouse gas emissions, soil decontamination, oxidation in soil and plant and root respiration. The goal of this study was to assess small‐scale variability of the relative soil‐gas diffusivity (Ds / Do, msoil air) using large intact soil monoliths and to compare Ds / Do calculation methods. Neon (Ne) was maintained constant at the lower boundary of three monoliths of two soils (a sand and an organic soil). Ne concentration was measured at large spatial and temporal frequencies. Calculation methods included the use of average concentration, and average Ds / Do per horizon, per section, or for the entire soil profile. Considering all sections of the monoliths, Ds / Do varied from 3.5 × 10−3 to 1.2 × 10−1 for the Ap horizon and from 4.8 × 10−3 to 8.3 × 10−1 for the Bf horizon in the sand and from 1.0 × 10−3 to 7.9 × 10−3 for the Ohp horizon and from 2.4 × 10−4 to 7.7 × 10−2 for the Of horizon in the organic soil. For the entire soil profile, variations in Ds / Do between monoliths reached 125% in the sand and 56% in the organic soil. The Ds / Do calculation method influenced the apparent variability (CV) of Ds / Do and, to a lesser extent, Ds / Do values of the overall soil profile. Differences in Ds / Do between monoliths could not be explained solely by the variability of total soil porosity and air‐filled porosity. Soil macroporosity (cracks and earthworm burrows) and layering greatly influenced variability of gas movement. Thus, the choice of sampling procedure, calculation method and modelling must be governed by the scale of the processes of interest and soil variability attributes. 相似文献
5.
6.
In order to determine if soil hydraulic properties present a direction‐dependent behavior, undisturbed samples were collected at different horizons and orientations (vertical, diagonal [45°], and horizontal) in structured soils in the Weichselian moraine region in northern Germany. The water‐retention curve (WRC), the saturated hydraulic conductivity (kf), and the air permeability (ka) were measured. The air‐filled porosity (?a) was determined, and pore‐continuity indices (ka/?a, ka/?a2, N) and blocked porosities (?b) were derived from the relationship between ka and ?a. The development of soil structures with defined forms and dimensions (e.g., platy by soil compaction or prismatic up to subangular‐blocky by swelling–shrinkage processes) and the presence of biopores can induce a direction‐dependent behavior of pore functions. Although the pore volume as a scalar is isotropic, the saturated hydraulic conductivity and air permeability (as a function of air‐filled porosity) can be anisotropic. This behavior was observed in pore‐continuity indices showing that the identification of soil structure can be used as a first parameter to estimate if hydraulic properties present a direction‐dependent behavior at the scale of the soil horizon. 相似文献
7.
J. A. CURRIE 《European Journal of Soil Science》1984,35(1):1-10
Samples of 1–2 mm crumbs from a clay loam under permanent pasture were equilibrated at -5 kPa water potential then compacted to varying degrees. Gas diffusion coefficients D, (hydrogen through air), were measured immediately on compaction, again after re-equilibration at -5 kPa, then at other water contents between saturation and dryness. The relationship between diffusion coefficient and air content, was, as elsewhere, in two parts (dD/d small for drainage of pores within crumbs; large for pores between crumbs), but the transition from one part to the other occurred at smaller air contents with increased compaction. The air content at which D approached zero as the samples wetted was greatest in the loosest soil. Compaction from a bulk density of 0.86–1.29 g cm?3 decreased the relative diffusion coefficient, D/D0 (D0 is the diffusion coefficient without impedance), from 0.35 to 0.22 (by 38%) at complete dryness, but from 0.19 to 0.035 (by 82%) in the soil initially at -5 kPa. On re-wetting and re-equilibrating at ?5 kPa, D/D0 decreased further to 0.008 (total 97%) because of extra water held in the now smaller pores of the compacted soil. No single relationship between D/D0 and fitted the results for even this one soil. 相似文献
8.
Soil air permeability is an important parameter which governs the aeration in soils that significantly promotes the root growth of field and grassland species and leads, in turn, to higher levels of evapotranspiration. The German Landfill Directive (2009) requires a rigid or a minimal shrinking capping system that ensures a high evapotranspiration rate to decrease the infiltration rate through the underlying waste body and therefore the leachate generation. This research is focussed on the questions if compacted glacial till can ensure the required rigidity and if and how air permeability is affected by soil compaction. The objective was to compare air‐filled porosity and the direction‐dependency of air permeability of a capping soil when assuming rigid and non‐rigid conditions considering a shrinkage factor. Intact soil cores were sampled in vertical and horizontal direction in 0.05, 0.2, 0.5, and 0.8 m depths at two profiles of a mineral landfill capping system at the Rastorf landfill in Northern Germany. Desiccation experiments were carried out on differently‐compacted soils and soil shrinkage was measured with a 3D laser triangulation device, while the air permeability was estimated with an air flow meter. The results indicate that the “engineered” soil structure which was predominately platy due to a layered installation, led to a more anisotropic behaviour and therefore to higher air permeability in horizontal than in vertical direction. The compacted installation of the capping system seems to be effective and observes the statutory required more‐or‐less rigid system, otherwise, soil shrinkage would lead to vertical cracks and a more pronounced isotropic behaviour. 相似文献
9.
The high input of mechanical energy in common agricultural practice can negatively affect soil structure. The impact of compaction (P) and rotovation (R) on soil pore characteristics was compared with those in soil from untreated reference (U) plots of a loamy sand soil receiving for 14 yr, either only mineral fertilizer (MF) or, in addition, animal manure (OF). Undisturbed soil cores were taken from two separate fields in consecutive years at an identical stage in the crop rotation. We measured soil organic carbon (OC), soil microbial biomass carbon (BC), and hot‐water extractable carbon (Chot). Water retention, air permeability and gas diffusivity were determined at ?100 hPa in both years and for a range of water potentials in one of the years. The continued addition of animal manure had increased OC, BC, and Chot compared with the soil receiving only mineral fertilizer. Soil under treatment OF had larger porosity than that from treatment MF. Treatment P eliminated this difference and significantly reduced the volume of macropores. This interaction between soil organic matter content and mechanical impact was also reflected in the gas diffusion data. Specific air permeability was mainly influenced by mechanical treatment. Modelling the diffusion data normalized to the inter‐aggregate pore space showed no significant treatment effects on pore‐connectivity, although there was a tendency of more water blockage in soil under treatment MF. More studies are needed to confirm this interpretation. Our studies indicate that organic manure increases soil porosity, but compaction reduces the related gas exchange effects to the level of compacted soils receiving mineral fertilizer. 相似文献
10.
Gas diffusion, fluid flow and derived pore continuity indices in relation to vehicle traffic and tillage 总被引：2，自引：0，他引：2
Relative gas diffusivity, air permeability and hydraulic conductivity were measured in undisturbed soil cores from tillage and traffic experiments. Continuity indices were taken as the quotient of relative diffusivity and air-filled porosity, and of air permeability and air-filled porosity (and the square of air-filled porosity). These were applied to individual measurements or to treatment means. More general continuity indices were derived from the changes in flow or diffusion with porosity, where the variations in porosity were due to both field variability and applied changes of water potential. These indices were the exponent in the relationship between relative diffusivity and air-filled porosity and the slope of log–log plots of air permeability and air-filled porosity or hydraulic conductivity and degree of saturation. Some physical significance was attached to the exponents by comparison with models of soil porosity. Positive intercepts of the relative diffusivity or air permeability plots on the air-filled porosity axes were taken as porosities blocked to gas movement.
Continuity indices and flow measurements showed differences between tillage and traffic treatments which did not necessarily reflect differences in bulk density. Intrinsic permeability was better estimated from air permeability than from unsaturated hydraulic conductivity. 相似文献
Continuity indices and flow measurements showed differences between tillage and traffic treatments which did not necessarily reflect differences in bulk density. Intrinsic permeability was better estimated from air permeability than from unsaturated hydraulic conductivity. 相似文献
11.
Investigation of the soil gas regime in a tillage experiment: 2. Apparent diffusion coefficients as a measure of soil structure In a soil tillage experiment with nursery stock on three different soils the apparent diffusion coefficients for CO2 were measured using soil cores of different depths at different times. Not-tilled, herbicide treated plots were compared with rototilled plots. The relationship between the relative apparent diffusion coefficient and the air content may be described by an exponential regression function Ds/Da = 0.0085 · e6.8EL, if all measurements are taken into the calculation. By dividing into different soil textures different regressions are obtained for the three studied soils: a sand, a silt and a clay loam. In many cases it is possible to show by the changing Ds(EL) regression changes of the soil structure with depth or as a result of tillage. In all these cases the soil of the not tilled plots turns out to be better structurized than that of the tilled ones, demonstrated by higher Ds-values at equal EL. The interpretation of the differences is being tried with the aid of soil pore tortuousity and continuity. Finally the measured Ds(EL) relationships are applied to characterize the soil gas regime for two seasons, using CO2 concentration profiles of the soil air on a day in summer and fall, respectively. It is shown, that CO2 production reaches farther down in summer than in fall. 相似文献
12.
Mona Mossadeghi‐Bjrklund Nicholas Jarvis Mats Larsbo Johannes Forkman Thomas Keller 《Soil Use and Management》2019,35(3):367-377
The aim of this study was to quantify the effects of compaction on water flow patterns at the soil profile scale. Control and trafficked plots were established in field trials at two sites. The trafficked treatment was created by four passes track‐by‐track with a three‐axle dumper with a maximum wheel load of 5.8 Mg. One year later, dye‐tracing experiments were performed and several soil mechanical, physical and hydraulic properties were measured to help explain the dye patterns. Penetration resistance was measured to 50 cm depth, with saturated hydraulic conductivity (Ks), bulk density, and macroporosity and mesoporosity being measured on undisturbed soil cores sampled from three depths (10, 30 and 50 cm). Significant effects of the traffic treatment on the structural pore space were found at 30 cm depth for large mesopores (0.3–0.06 mm diameter), but not small mesopores (0.06–0.03 mm) or macroporosity (pores > 0.3 mm). At one of the sites, ponding was observed during the dye‐tracing experiments, especially in the trafficked plots, because of the presence of a compacted layer at plough depth characterized by a larger bulk density and smaller structural porosity and Ks values. Ponding did not induce any preferential transport of the dye solution into the subsoil at this site. In contrast, despite the presence of a compacted layer at 25–30 cm depth, a better developed structural porosity in the subsoil was noted at the other site which allowed preferential flow to reach to at least 1 m depth in both treatments. 相似文献
13.
Calibrating soil respiration measures with a dynamic flux apparatus using artificial soil media of varying porosity 总被引：5，自引：0，他引：5
Measurement of soil respiration to quantify ecosystem carbon cycling requires absolute, not relative, estimates of soil CO2 efflux. We describe a novel, automated efflux apparatus that can be used to test the accuracy of chamber‐based soil respiration measurements by generating known CO2 fluxes. Artificial soil is supported above an air‐filled footspace wherein the CO2 concentration is manipulated by mass flow controllers. The footspace is not pressurized so that the diffusion gradient between it and the air at the soil surface drives CO2 efflux. Chamber designs or measurement techniques can be affected by soil air volume, hence properties of the soil medium are critical. We characterized and utilized three artificial soils with diffusion coefficients ranging from 2.7 × 10?7 to 11.9 × 10?7 m2 s?1 and porosities of 0.26 to 0.46. Soil CO2 efflux rates were measured using a commercial dynamic closed‐chamber system (Li‐Cor 6400 photosynthesis system equipped with a 6400‐09 soil CO2 flux chamber). On the least porous soil, small underestimates (< 5%) of CO2 effluxes were observed, which increased as soil diffusivity and soil porosity increased, leading to underestimates as high as 25%. Differential measurement bias across media types illustrates the need for testing systems on several types of soil media. 相似文献
14.
C. RAPPOLDT 《European Journal of Soil Science》1995,46(2):169-177
The diffusivity of oxygen in soil was measured by periodically changing the gas above a soil core from nitrogen to air and vice versa. The concentration wave was measured as a function of depth with an oxygen electrode. For different Fourier components in the signal, phase shifts were calculated. The diffusivity follows from the increase of the phase shift with depth. Phase shifts are more suitable than signal amplitudes for the derivation of diffusivity. They are also easier to measure and do not require electrode calibration. For a clay soil with an air–filled porosity of about 0.05 m3 m?3 a local diffusivity of 0.9 × 10?9 m2 s?1 was measured. This is several orders of magnitude smaller than macroscopic values for entire core samples of the same soil type. This low value can be explained by the presence of locally water–saturated clay. 相似文献
15.
P. H. NYE 《European Journal of Soil Science》1966,17(1):16-23
If an exchangeable ion in soil diffuses along a liquid and solid pathway, its diffusion coefficient may be expressed as where D, v, f, C are diffusion coefficient, volume fraction, impedance factor, and concentration terms and the suffixes l,S refer to liquid and solid. The self-diffusion coefficient of the ion is then where D′, D′t, and D′s, are self-diffusion coefficients. D and D′ will vary with concentration. In diffusion out of the soil to a zero sink, the appropriate average diffusion coefficient is, approximately, the self-diffusion coefficient in the undisturbed soil. Diffusion of one ion species is influenced by other ions diffusing in the system through the diffusion potential set up. When ions are diffusing to plant roots, the diffusion potential is likely to be small. A more likely, though more complicated, expression for D than the first equation above is derived by assuming the ion to follow solid and liquid pathways in series as well as in parallel. 相似文献
16.
A method is proposed which follows Darrah's experimental procedure and takes advantage of a mathematical solution provided by Carslaw & Jaeger to estimate the diffusion coefficients of adsorbed and non-adsorbed solutes in soil. The method requires only the values of the concentration of the solute at the input face of a uniform column of soil, Cs, and of the total amount, Qt, that has entered the soil after a specified time during which the surface of the block is in contact with a thin porous pad containing a known initial amount of solute, Q0, at concentration C0, expressed in the same units as Cs. In the Cs/C0 vs. Qt/Q0 space there is a unique relationship between the effective diffusion coefficient, De, of the solute in the soil and the contact conductance for this solute, h, between the pad and the soil surface. The proposed procedure is firstly to determine De, and h for a non-adsorbed solute in the experimental soil using the experimental values of Cs/C0 and Q/Q for that solute. This value of De, gives the diffusion impedance factor for the solute in the soil, f, which is assumed also to apply to adsorbed solutes. A first estimate of the effective diffusion coefficient of an adsorbed solute, 1Dea, is then made using f and the diffusion coefficient of the free solute in water, DL, obtained from the literature (i.e. 1Dea= DLf). Only if the solute is weakly adsorbed will the values of Cs/C0, and Qt/Q0 lie in Cs/C0, vs. Qt/Q0, space as defined by 1Dea and the contact conductance, h. Instead a second space relating Cs/C0 and Qt/Q0, is now constructed from nominated values of h and De, where De, is defined in terms of 1Dea, the adsorption coefficient, F , and the volumetric moisture content of the soil, θ. The position of the experimental values of Cs/C0, and Qt/Q0 within this new space defines h and the actual De, and F of the solute as it diffuses and is adsorbed in the soil. The advantages and limitations of the method are discussed. In particular, the method assumes that the adsorption process is linear and reversible. 相似文献
17.
By examining the symmetry between the distributions of particle‐size (PSD) and pore‐size (POD) in a soil, as hypothesized by early pore‐solid fractal (PSF) models, we found significant discrepancies in fractal dimensions between the PSD and the water retention curve (WRC) of a soil. Therefore, we developed an asymmetry‐based PSF model to estimate better the WRC directly from the PSD data of a soil. To do so, we adopted the concept of a microscopic arrangement of different‐sized particles to address such asymmetry, and evaluated the performance of the modified PSF model on five soil textural classes (coarse‐, moderately coarse‐, medium‐, moderately fine‐ and fine‐textured soils) using experimental PSD and WRC data from the UNSODA database (159 undisturbed soils for model calibration and 70 undisturbed soils for model validation). The fit of the symmetry‐based PSF model to the calibration dataset showed that the fractal dimension of the WRC (Dp) was slightly larger than that of cumulative mass distribution of particles (Ds) for most soils. The asymmetry‐based PSF model performed better than the symmetry‐based PSF model. In addition, the asymmetry‐based PSF model reduced the tendency to under estimate soil water content for a given matric head and the performance of the asymmetry‐based model was consistent irrespective of soil texture, indicating that the adoption of asymmetry between the PSD and the POD was adequate in predicting the WRC of a porous, particulate system such as soil. 相似文献
18.
旨在从岩土力学性质的角度为崩岗侵蚀提供理论依据,采用直接剪切实验,对鄂东南崩岗区典型花岗岩风化岩土体剖面不同方向上原状土的抗剪强度进行测定,并分析了花岗岩风化岩土体抗剪强度在剖面尺度上的异向性及其影响因素。结果表明,饱和条件下,花岗岩风化岩土体黏聚力和内摩擦角的变化范围分别为3.19～19.26 kPa和26.50°～32.42°,其中B_2层黏聚力最大,而各层次间内摩擦角的差异并不明显(p0.05);黏聚力和内摩擦角均存在明显的异向性,其中水平方向总体大于垂直方向,且黏聚力的异向性较内摩擦角更明显。不同方向上抗剪强度的影响机理不同,其中,垂直于剖面方向上,黏聚力主要受毛管孔隙度(r=-0.97,p0.01)和粉粒含量(r=0.94,p0.05)的影响,而水平方向上仅与粉粒含量(r=0.91,p0.05)显著相关;而液限对水平方向上的内摩擦角影响显著(r=-0.99,p0.05)。对于花岗岩风化岩土体抗剪强度的异向性而言,其主要受自然含水率(r=-0.98,p0.01)、有机质(r=-0.93,p0.05)和塑限(r=-0.97,p0.05)影响。研究结果对于从力学稳定性角度揭示崩岗的发生机理具有重要意义。 相似文献
19.
Manfred Albertsen 《植物养料与土壤学杂志》1979,142(1):39-56
Carbon dioxide balance in the gas filled part of the unsaturated zone, demonstrated at a Podzol Carbon dioxide concentration (with a modified Miotke-probe) and moisture distribution (with a neutron-probe) in the unsaturated zone were measured on four test fields (coniferous forest, leafy wood, grass glade, sugar-beet field) in the Segeberger Forst, south of Schleswig-Holstein, Federal Republic of Germany, during September 1976 until August 1977 down to 250 cm depth. An evaluation method to calculate carbon dioxide production rates from any horizontal soil section and carbon dioxide emission rates was established and formulated in FortranIV for computer treatment. The calculation bases on Fick's diffusion laws, which describe the direct proportional relation between diffusive transport and concentration gradient with diffusivity as proportional factor. Special measurements on undisturbed soil samples from the test region showed a relation between diffusivity and the soil parameters water content and porosity, which permits the calculation of diffusivities from moisture data in any soil depth. Seasonal distribution curves of carbon dioxide concentration, production and emission are presented as evaluation result of all data. 相似文献
20.
Rachhpal Jassal Andy Black Mike Novak Kai Morgenstern Zoran Nesic David Gaumont-Guay 《Agricultural and Forest Meteorology》2005,130(3-4):176-192
To better understand the biotic and abiotic factors that control soil CO2 efflux, we compared seasonal and diurnal variations in simultaneously measured forest-floor CO2 effluxes and soil CO2 concentration profiles in a 54-year-old Douglas fir forest on the east coast of Vancouver Island. We used small solid-state infrared CO2 sensors for long-term continuous real-time measurement of CO2 concentrations at different depths, and measured half-hourly soil CO2 effluxes with an automated non-steady-state chamber. We describe a simple steady-state method to measure CO2 diffusivity in undisturbed soil cores. The method accounts for the CO2 production in the soil and uses an analytical solution to the diffusion equation. The diffusivity was related to air-filled porosity by a power law function, which was independent of soil depth. CO2 concentration at all depths increased with increase in soil temperature, likely due to a rise in CO2 production, and with increase in soil water content due to decreased diffusivity or increased CO2 production or both. It also increased with soil depth reaching almost 10 mmol mol−1 at the 50-cm depth. Annually, soil CO2 efflux was best described by an exponential function of soil temperature at the 5-cm depth, with the reference efflux at 10 °C (F10) of 2.6 μmol m−2 s−1 and the Q10 of 3.7. No evidence of displacement of CO2-rich soil air with rain was observed.Effluxes calculated from soil CO2 concentration gradients near the surface closely agreed with the measured effluxes. Calculations indicated that more than 75% of the soil CO2 efflux originated in the top 20 cm soil. Calculated CO2 production varied with soil temperature, soil water content and season, and when scaled to 10 °C also showed some diurnal variation. Soil CO2 efflux and concentrations as well as soil temperature at the 5-cm depth varied in phase. Changes in CO2 storage in the 0–50 cm soil layer were an order of magnitude smaller than measured effluxes. Soil CO2 efflux was proportional to CO2 concentration at the 50-cm depth with the slope determined by soil water content, which was consistent with a simple steady-state analytical model of diffusive transport of CO2 in the soil. The latter proved successful in calculating effluxes during 2004. 相似文献