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1.
Laboratory experiments document that liquid iron reacts chemically with silicates at high pressures (>/=2.4 x 10(10) Pascals) and temperatures. In particular, (Mg,Fe)SiO(3) perovskite, the most abundant mineral of Earth's lower mantle, is expected to react with liquid iron to produce metallic alloys (FeO and FeSi) and nonmetallic silicates (SiO(2) stishovite and MgSiO(3) perovskite) at the pressures of the core-mantle boundary, 14 x 10(10) Pascals. The experimental observations, in conjunction with seismological data, suggest that the lowermost 200 to 300 kilometers of Earth's mantle, the D" layer, may be an extremely heterogeneous region as a result of chemical reactions between the silicate mantle and the liquid iron alloy of Earth's core. The combined thermal-chemical-electrical boundary layer resulting from such reactions offers a plausible explanation for the complex behavior of seismic waves near the core-mantle boundary and could influence Earth's magnetic field observed at the surface. 相似文献
2.
Ohta K Onoda S Hirose K Sinmyo R Shimizu K Sata N Ohishi Y Yasuhara A 《Science (New York, N.Y.)》2008,320(5872):89-91
Recent discovery of a phase transition from perovskite to post-perovskite suggests that the physical properties of Earth's lowermost mantle, called the D' layer, may be different from those of the overlying mantle. We report that the electrical conductivity of (Mg0.9Fe0.1)SiO3 post-perovskite is >10(2) siemens per meter and does not vary greatly with temperature at the conditions of the D' layer. A post-perovskite layer above the core-mantle boundary would, by electromagnetic coupling, enhance the exchange of angular momentum between the fluid core and the solid mantle, which can explain the observed changes in the length of a day on decadal time scales. Heterogeneity in the conductivity of the lowermost mantle is likely to depend on changes in chemistry of the boundary region, not fluctuations in temperature. 相似文献
3.
The melting curve of iron, the primary constituent of Earth's core, has been measured to pressures of 250 gigapascals with a combination of static and dynamic techniques. The melting temperature of iron at the pressure of the core-mantle boundary (136 gigapascals) is 4800 +/- 200 K. whereas at the inner core-outer core boundary (330 gigapascals), it is 7600 +/- 500 K. Corrected for melting point depression resulting from the presence of impurities, a melting temperature for iron-rich alloy of 6600 K at the inner core-outer core boundary and a maximum temperature of 6900 K at Earth's center are inferred. This latter value is the first experimental upper bound on the temperature at Earth's center, and these results imply that the temperature of the lower mantle is significantly less than that of the outer core. 相似文献
4.
Badro J Fiquet G Guyot F Rueff JP Struzhkin VV Vankó G Monaco G 《Science (New York, N.Y.)》2003,300(5620):789-791
We measured the spin state of iron in ferropericlase (Mg0.83Fe0.17)O at high pressure and found a high-spin to low-spin transition occurring in the 60- to 70-gigapascal pressure range, corresponding to depths of 2000 kilometers in Earth's lower mantle. This transition implies that the partition coefficient of iron between ferropericlase and magnesium silicate perovskite, the two main constituents of the lower mantle, may increase by several orders of magnitude, depleting the perovskite phase of its iron. The lower mantle may then be composed of two different layers. The upper layer would consist of a phase mixture with about equal partitioning of iron between magnesium silicate perovskite and ferropericlase, whereas the lower layer would consist of almost iron-free perovskite and iron-rich ferropericlase. This stratification is likely to have profound implications for the transport properties of Earth's lowermost mantle. 相似文献
5.
Chemical interaction of Earth's mantle with the liquid outer core should influence the mantle's iron content. Osmium isotope ratios in Hawaiian lavas indicate a mass flux of 相似文献
6.
Calculations with data for asteroidal cores indicate that Earth's outer core may have a rhenium/osmium ratio at least 20 percent greater than that of the chondritic upper mantle, potentially leading to an outer core with an osmium-187/osmium-188 ratio at least 8 percent greater than that of chondrites. Because of the much greater abundance of osmium in the outer core relative to the mantle, even a small addition of metal to a plume ascending from the D" layer would transfer the enriched isotopic signature to the mixture. Sources of certain plume-derived systems seem to have osmium-187/osmium-l88 ratios 5 to 20 percent greater than that for chondrites, consistent with the ascent of a plume from the core-mantle boundary. 相似文献
7.
T Okuchi 《Science (New York, N.Y.)》1997,278(5344):1781-1784
Because of dissolution of lighter elements such as sulfur, carbon, hydrogen, and oxygen, Earth's outer core is about 10 percent less dense than molten iron at the relevant pressure and temperature conditions. To determine whether hydrogen can account for a major part of the density deficit and is therefore an important constituent in the molten iron outer core, the hydrogen concentration in molten iron was measured at 7.5 gigapascals. From these measurements, the metal-silicate melt partitioning coefficient of hydrogen was determined as a function of temperature. If the magma ocean of primordial Earth was hydrous, more than 95 mole percent of H2O in this ocean should have reacted with iron to form FeHx, and about 60 percent of the density deficit is reconciled by adding hydrogen to the core. 相似文献
8.
Dynamic compression of Earth materials 总被引：1，自引：0，他引：1
Ahrens TJ 《Science (New York, N.Y.)》1980,207(4435):1035-1041
Shock wave techniques have been used to investigate the pressuredensity relations of metals, silicates, and oxides over the entire range of pressures present in the earth (3.7 x 10(6) bars at the center). In many materials of geophysical interest, such as iron, wüstite, calcium oxide, and forsterite, major shock-induced phase changes dominate the compression behavior below pressures of 10(6) bars. The shock wave data for the high-pressure phases of these minerals lead to important inferences about the composition of the lower mantle and outer, liquid core of the earth. The lower mantle of the earth appears to have a slightly higher density than is inferred to correspond to the behavior of an olivine-rich assembiage of the same composition as the upper mantle. The core has a density some 10 percent less than that of pure iron and may have 9 to 12 percent sulfur or about 8 percent oxygen by weight. 相似文献
9.
Rotation and Magnetism of Earth's Inner Core 总被引：1，自引：0，他引：1
Three-dimensional numerical simulations of the geodynamo suggest that a super- rotation of Earth's solid inner core relative to the mantle is maintained by magnetic coupling between the inner core and an eastward thermal wind in the fluid outer core. This mechanism, which is analogous to a synchronous motor, also plays a fundamental role in the generation of Earth's magnetic field. 相似文献
10.
Physics of iron at Earth's core conditions 总被引：1，自引：0，他引：1
Laio A Bernard S Chiarotti GL Scandolo S Tosatti E 《Science (New York, N.Y.)》2000,287(5455):1027-1030
The bulk properties of iron at the pressure and temperature conditions of Earth's core were determined by a method that combines first-principles and classical molecular dynamic simulations. The theory indicates that (i) the iron melting temperature at inner-core boundary (ICB) pressure (330 gigapascals) is 5400 (+/-400) kelvin; (ii) liquid iron at ICB conditions is about 6% denser than Earth's outer core; and (iii) the shear modulus of solid iron close to its melting line is 140 gigapascals, consistent with the seismic value for the inner core. These results reconcile melting temperature estimates based on sound velocity shock wave data with those based on diamond anvil cell experiments. 相似文献
11.
12.
The abundances of siderophile elements in the Earth's silicate mantle are too high for the mantle to have been in equilibrium with iron in the core if equilibrium occurred at low pressures and temperatures. It has been proposed that this problem may be solved if equilibrium occurred at high pressures and temperatures. Experimental determination of the distribution of siderophile elements between liquid metal and liquid silicate at 100 kilobar and 2000 degrees C demonstrates that it is unlikely that siderophile element abundances were established by simple metal-silicate equilibrium, which indicates that the segregation of the core from the mantle was a complex process. 相似文献
13.
Kerr RA 《Science (New York, N.Y.)》2000,290(5495):1274b-1275b
On page 1338, a group of geophysicists suggests that the mysterious boundary between Earth's molten iron core and its rocky mantle most resembles an inverted sea floor, with liquid-iron-laced sediments collecting on the roof of the core. They argue that a slow, inverted rain of precipitates rising to the core-mantle boundary and settling into a kilometers-thick layer might explain a variety of observations, from a subtle nodding of Earth's axis to seismic speed zones at the boundary. Their story will be difficult to verify, however, because painting a portrait of the core-mantle boundary depends on very indirect geophysical evidence. 相似文献
14.
Temperature gradients in a low-shear-velocity province in the lowermost mantle (D' region) beneath the central Pacific Ocean were inferred from the observation of a rapid S-wave velocity increase overlying a rapid decrease. These paired seismic discontinuities are attributed to a phase change from perovskite to post-perovskite and then back to perovskite as the temperature increases with depth. Iron enrichment could explain the occurrence of post-perovskite several hundred kilometers above the core-mantle boundary in this warm, chemically distinct province. The double phase-boundary crossing directly constrains the lowermost mantle temperature gradients. Assuming a standard but unconstrained choice of thermal conductivity, the regional core-mantle boundary heat flux (approximately 85 +/- 25 milliwatts per square meter), comparable to the average at Earth's surface, was estimated, along with a lower bound on global core-mantle boundary heat flow in the range of 13 +/- 4 terawatts. Mapped velocity-contrast variations indicate that the lens of post-perovskite minerals thins and vanishes over 1000 kilometers laterally toward the margin of the chemical distinct region as a result of a approximately 500-kelvin temperature increase. 相似文献
15.
Light elements such as oxygen in Earth's core influence the physical properties of the iron alloys that exist in this region. Describing the high-pressure behavior of these materials at core conditions constrains models of core structure and dynamics. From x-ray diffraction measurements of iron monoxide (FeO) at high pressure and temperature, we show that sodium chloride (NaCl)-type (B1) FeO transforms to a cesium chloride (CsCl)-type (B2) phase above 240 gigapascals at 4000 kelvin with 2% density increase. The oxygen-bearing liquid in the middle of the outer core therefore has a modified Fe-O bonding environment that, according to our numerical simulations, suppresses convection. The phase-induced stratification is seismologically invisible but strongly affects the geodynamo. 相似文献
16.
Miyagi L Kanitpanyacharoen W Kaercher P Lee KK Wenk HR 《Science (New York, N.Y.)》2010,329(5999):1639-1641
Understanding deformation of mineral phases in the lowermost mantle is important for interpreting seismic anisotropy in Earth's interior. Recently, there has been considerable controversy regarding deformation-induced slip in MgSiO(3) post-perovskite. Here, we observe that (001) lattice planes are oriented at high angles to the compression direction immediately after transformation and before deformation. Upon compression from 148 gigapascals (GPa) to 185 GPa, this preferred orientation more than doubles in strength, implying slip on (001) lattice planes. This contrasts with a previous experiment that recorded preferred orientation likely generated during the phase transformation rather than deformation. If we use our results to model deformation and anisotropy development in the D' region of the lower mantle, shear-wave splitting (characterized by fast horizontally polarized shear waves) is consistent with seismic observations. 相似文献
17.
Earth's core is composed primarily of iron (Fe) with about 10% by weight of lighter elements. The lighter elements are progressively enriched in the liquid outer core as the core cools and the inner core crystallizes. Thermodynamic modeling of Fe-O-S liquids shows that immiscible liquids can exist at outer-core pressures (136 to 330 gigapascals) at temperatures below 5200 kelvin and lead to layering in the outer core if the concentrations of the lighter elements are high enough. We found no evidence for layering in the outer core in the travel times and wave forms of P4KP seismic waves that reflect internally in the core. The absence of layers therefore constrains outer-core compositions in the Fe-O-S system to be no richer than 6 +/- 1 weight % (wt %) O and 2 to 15 wt % S. A single core liquid composition of 10.5 +/- 3.5 wt % S and 1.5 +/- 1.5 wt % O is compatible with wave speeds and densities throughout the outer core. 相似文献
18.
High-pressure diamond-cell experiments indicate that the iron-magnesium partitioning between (Fe,Mg)SiO3-perovskite and magnesiowustite in Earth's lower mantle depends on the pressure, temperature, bulk iron/magnesium ratio, and ferric iron content. The perovskite stability field expands with increasing pressure and temperature. The ferric iron component preferentially dissolves in perovskite and raises the apparent total iron content but had little effect on the partitioning of the ferrous iron. The ferrous iron depletes in perovskite at the top of the lower mantle and gradually increases at greater depth. These changes in iron-magnesium composition should affect geochemical and geophysical properties of the deep interior. 相似文献
19.
Thermal convection experiments in a rapidly rotating hemispherical shell suggest a model in which the convection in Earth's liquid outer core is controlled by a thermally heterogeneous mantle. Experiments show that heterogeneous boundary heating induces an eastward flow in the core, which, at a sufficiently large magnitude, develops into a large-scale spiral with a sharp front. The front separates the warm and cold regions in the core and includes a narrow jet flowing from the core-mantle boundary to the inner-core boundary. The existence of this front in the core may explain the Pacific quiet zone in the secular variation of the geomagnetic field and the longitudinally heterogeneous structure of the solid inner core. 相似文献
20.
Yoder CF Konopliv AS Yuan DN Standish EM Folkner WM 《Science (New York, N.Y.)》2003,300(5617):299-303
The solar tidal deformation of Mars, measured by its k2 potential Love number, has been obtained from an analysis of Mars Global Surveyor radio tracking. The observed k2 of 0.153 +/- 0.017 is large enough to rule out a solid iron core and so indicates that at least the outer part of the core is liquid. The inferred core radius is between 1520 and 1840 kilometers and is independent of many interior properties, although partial melt of the mantle is one factor that could reduce core size. Ice-cap mass changes can be deduced from the seasonal variations in air pressure and the odd gravity harmonic J3, given knowledge of cap mass distribution with latitude. The south cap seasonal mass change is about 30 to 40% larger than that of the north cap. 相似文献