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1.
Zusammenfassung Samenuntersuchungen an 12 Eichenarten und -formen, 20 Birkenarten und 14 Ahornarten zeigten, daß die Samen der Eichen und Ahorne, nordamerikanischer Birken und Ahorne nordasiatischer Abstammung in der Ukraine praktisch von Schädinsekten nicht beschädigt werden, während der Samenertrag der heimischen durch Schadinsekten stark herabgemindert wird.Die Widerstandsstärke der Samen gegen Schädlinge ändert sich. nicht nur bei den verschiedenen Arten, sondern auch innerhalb der Bäume einer Art je nach ihrem physiologischen Zustand. Die Widerstandsfaktoren der Samen gegen Schädinsekten sind entweder anatomisch-morphologische Besonderheiten (Schalenstärke), oder das Vorhandensein von Schutzstoffen in den Samen oder beide zusammen. Besonders deutlich sind diese Faktoren in den Eicheln von Bäumen der nordamerikanischen Abstammung gegen Eichelrüssler ausgeprägt. Chromatographische Analyse der Auszüge aus den widerstandsfähigen Samen der Schmidt'schen Birke und des Eschenahorns zeigten, daß für die Rolle der Schutzstoffe die Phenolstoffe verantwortlich sind von denen z. B. die Chlorogensäure ermittelt wurde.
12 , 20 14 - , - , - - . . - / /, . - . , , , , .
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2.
The extractives of shirakamba (Betula platyphylla Sukatchev var.japonica Hara) leaves were investigated. Two lignan glycosides were isolated, and their structures were elucidated to be 1-(4-hydroxy-3-methoxyphenyl)-2-[1-(3--l-rhamnopyranosyloxypropyl)-3-hydroxyphenoxy]-1,3-propanediol (I) and a new 2,3-dihydro-2-arylbenzofuran configuration neolignan,cis-2,3-dihydro-2-(4--l-rhamnopyranosyloxy-3-methoxyphenyl)-3-hydroxymethyl-7-hydroxy-5-benzofuranpropanol (II). These neolignan rhamnosides were newly found in shirakamba.  相似文献   

3.
Trials were established at three sites in Uganda to test the suitability of multipurpose trees (MPTs) as upperstorey in crop lands to provide poles, small timber and fuelwood. The three sites were Kachwekano District Farm Institute (1°16 S, 29°57 E, 2000 m.a.s.l.) in Kabale District, Kabanyolo University Farm (0°28 N, 32°27 E, 1250 m.a.s.l.) in Mpigi District and Bushenyi District Farm Institute (0°34 S, 30°13 E, 1610 m.a.s.l.) in Bushenyi District. The MPTs were planted in single rows at intra spacing of 2 m and each plot contained seven or nine trees. On both sides of the tree row, crops were raised. Data on crop yields were collected every season, while data on the growth of the trees were collected four times each year.In terms of tree growth,Grevillea robusta, Casuarina cunninghamiana andAlnus acuminata performed well with height growth of 1.8–2.4 m per year at Kachwekano, while at BushenyiGrevillea robusta, Casuarina junghuhniana, Cupressus lusitanica andCedrela serrulata averaged 1.6–2.0 m height per year. At Kabanyolo,Melia azedarach, Cassia siamea, Jacaranda mimosifolia, Grevillea robusta andMaesopsis eminii had height increments ranging from 1.8–2.7 m annually. Crop yields were affected by the presence of the MPTs, withMaesopsis eminii being the most competitive (averaging 60% reduction, over five seasons). The crop rows nearest to the tree line were the most affected. OnlyAlnus acuminata seems to have had a positive effect on crop yields. The installation of a root mesh to reduce tree root competition for nutrients and water in four species increased yields in plots with MPTs by 5% (Melia azedarach) to 152% (Maesopsis eminii), but the control plot still had significantly higher bean yields, suggesting that shading could also be important. In the case of maize, suppression seems to be due mainly to root competition because after its elimination yields obtained thereafter did not differ significantly from those of the control except for the Maesopsis plots. The negative influence of the MPTs could, therefore, be minimized by periodically pruning the tree crowns and roots.  相似文献   

4.
This paper describes characterization of diterpenes of the bark of Japanese cypress,Chamaecyparis obtusa (S. and Z.) Endl, without the resinous stem canker to learn the difference between the cypress bark affected with the canker. A diterpene dimer and two diterpenes, 6,12-dihydroxyabieta-8,11,13-trien-7-one and 6,12-dihydroxyabieta-5,8,11, 13-tetraen-7-one, were firstly isolated from Japanese cypress. The dimer, 6-(abieta-6,8,11, 13-tetraenyl-12-oxy)-7-methoxyabieta-8,11,13-trien-12-ol, was a new compound. It is a terpene indicative ofC. obtusa not infected with the resinous stem canker. Five known diterpenes were also isolated.  相似文献   

5.
Summary The reaction of ferric chloride with the lignin model guaiacol affords primarily a complex mixture of coupled guaiacol oligomers. Major components were the symmetrical carbon-carbon coupled dimer 3,3-dimethoxy-[1,1-biphenyl]-4,4diol and the trimer 3,3,5-trimethoxy-[1,1:3,1-terphenyl]-4,4,4-triol which were isolated by preparative HPLC and characterized by 1HNMR spectroscopy and mass spectrometry. An unstable component believed to be a 4,4-diphenoquinone derived from the trimer was also prominent. The reaction of chromium trioxide with guaiacol yields the same dimer, trimer and diphenoquinone as well as 2-methoxy-p-benzoquinone. The major product with chromium trioxide, however, is an inert, highly insoluble polymer which was shown by degradation to contain guaiacol oligomers bound or crosslinked by hydroxylated chromium species. Magnetic susceptibility measurements clearly indicated that the valency of chromium in the polymer was + 3. It is postulated that similar complexes formed from phenolic lignin units are responsible for the weather resistance of chromium trioxide treated wood surfaces. In a broader context this study is relevant to the fixation of hexavalent chromium from a range of widely used wood preservative formulations.The authors wish to thank the following: Tom Syers (CSIRO Division of Forest Products) for technical assistance, Mary Reilly (CSIRO Division of Forest Products) for NMR spectral determinations and Ivan Vit (CSIRO Division of Chemicals and Polymers) for mass spectral determinations  相似文献   

6.
Synthesis of isoacteoside, a dihydroxyphenylethyl glycoside   总被引：1，自引：0，他引：1  
The total chemical synthesis of isoacteoside (1), 2-(3,4-dihydroxyphenyl)ethyl 6-O-caffeoyl-3-O-(-l-rhamnopyranosyl)--d-glucopyranoside, is described. An acteoside acetate with benzyl groups at the catechols (3: 2-(3,4-dibenzyloxyphenyl)ethyl 2,6-di-O-acetyl-4-O-[3,4-bis(O-benzyl)caffeoyl]-3-O-(-l-rhamnopyranosyl)--d-glucopyranoside) was treated with a solution of methy-lamine in methanol (MeNH2 in MeOH) to perform both deacetylation and caffeoyl migration, affording an isoacteoside derivative with benzyl groups at the catechols4b: 2-(3,4-dibenzyloxyphenyl)ethyl 6-O-[3,4-bis(O-benzyl) caffeoyl] -3-O-(-l-rhamnopyranosyl)--d-glucopyranoside —in 34% yield. Debenzylation of4b was successfully accomplished by catalytic transfer hydrogenation using 1,4-cyclohexadiene to give the target compound isoacteoside (1) in 54% yield.1H and13C nuclear magnetic resonance spectral data of the synthesized isoacteoside (1) were identical with those of the natural isoacteoside isolated fromPaulownia tomentosa (Thumb.) Steud.Part of this research was presented at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 2001  相似文献   

7.
The effects of stilbene glucosides and related compounds on termite feeding behavior were investigated using paper disc methods against the subterranean termite Reticulitermes speratus. The stilbene-rich fraction and isorhapontin (3-methoxy-3,4, 5-trihydroxystilbene-3--d-glucoside) from bark extracts of Picea glehnii showed avoidance by termites in choice tests. In the no-choice tests using compounds purified from the stilbene-rich fraction, the largest feeding deterrent effect was observed for piceid (3,4,5-trihydroxystilbene-3--d-glucoside), followed by isorhapontin, and astringin (3,3,4,5-tetrahydroxystilbene-3--d-glucoside), at the concentrations from 0.63 to 2.5µmol/disc. No change in activity was observed at retentions of more than 5.0µmol/disc. When the activities of isorhapontin and its aglycone derivative (isorhapontigenin: 3-methoxy-3,4,5-trihydroxystilbene) were compared with that of taxifolin (3,3,4,5,7-pentahydroxyflavanone) in the no-choice test, the stilbenes exhibited a larger antifeedant potential. Methylation of isorhapontigenin increased its termiticidal activity.Part of this study was presented at the 32nd Annual Meeting of the International Research Group on Wood Preservation, 2001  相似文献   

8.
Zusammenfassung Unterschiedliche Vektoreignungen können zwischen Rassen, Morphen und Altersstadien einer Blattlausart auftreten. Es wurden verschiedene Morphen vonMacrosiphum euphorbiae (Thomas) undAcyrthosiphon pisum (Harris) hinsichtlich ihrer Übertragungsfähigkeit für das persistente Enationenvirus der Erbse geprüft. Dabei erwiesen sich ovipare Weibchen und adulte Männchen vonM. euphorbiae als ungeeignete Überträger, während die gleichen Morphen von zweiA. pisum-Populationen die Virose übertrugen. Auch die Fundatrix desA. pisum-BastardsTrifolium pratense rot XSarothamnus scoparius grün übertrug zu einem relativ hohen Prozentsatz. Ovipare Weibchen und Männchen der inaktiven RasseLotus uliginosus gelb konnten keine Infektion bewirken; die persistente Virusübertragungsfähigkeit ist im Falle vonAcyrthosiphon pisum (Harris) offenbar ein genetisch fixiertes Merkmal.
Summary Different vector abilities may exist between races, morphs and development instars of a given aphid species. Several morphs ofMacrosiphum euphorbiae (Thomas) and ofAcyrthosiphon pisum (Harris) were tested in their transmission ability for the persistent pea enation mosaic virus. Oviparous females and adult males ofM. euphorbiae proved insuitable for transmission, the corresponding morphs of twoA. pisum-populations, however, were successful in transmitting. The fundatrix of theA. pisum hybridTrifolium pratense red xSarothamnus scoparius green transmitted to a relatively high percentage. Oviparous females and males of the inactiv raceLotus uliginosus yellow failed completely in transmitting; in the present case ofA. pisum the transmission character of the persistent virus evidently is genetically fixed.
Résumé Différentes aptitudes de vecteur peuvent se trouver entre les races, les morphes et les périodes d'âge d'une espèce de pucerons. Différentes morphes deMacrosiphum euphorbiae (Thomas) et deAcyrthosiphon pisum (Harris) ont été examinées en ce qui concerne leurs aptitudes de transmettre le virus persistant du pois(pea enation mosaic). En ce cas les femelles ovipares et les mâles adultes deM. euphorbiae se montraient impropres à la transmission, pendant que les mêmes morphes de deux populations deA. pisum transmettaient la virose. C'était la fondatrice du bâtard deA. pisum Trifolium pratense rouge avecSarothamnus scoparius vert qui transmettait à une pourcentage relativement haute. Les femelles ovipares et les mâles de la race «inactive» deLotus uliginosus jaune ne pouvaient pas effectuer d'infection; en cas deAcyrthosiphon pisum (Harris), l'aptitude persistante à transmettre le virus évidemment est un caractère fixé d'une façon génétique.
, . Macrosiphum euphorbiae (Thomas) Acyrthosiphon pisum (Harris) peaenation mosaic virus). M. euphorbiae , {A. pisum} . A. pisum-Trifolium pratense Sarothamnus scoparius . «» Lotus uliginosus ; Acrythosiphon pisum (Harris) .
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9.
Zusammenfassung Es wurden in Kiefernkulturen Untersuchungen über die Tagesdynamik des Harzdruckes und der Intensität der Harzabsonderung geführt und die Ergebnisse in Beziehung zum Befallsgrad des KiefernknospentriebwicklersRhyacionia buoliana Schiff. gesetzt.Im Verlauf eines Tages variierte der Harzdruck wenig, die Intensität der Harzabsonderung dagegen stark. Die höchste Harzfluß-Intensität fällt in den Zeitraum zwischen 13 und 16 Uhr. Die Flugzeit des Wicklers, nach 18 Uhr, liegt somit außerhalb der Zeit des stärksten Harzflusses.Weder der Index der Harzfluß-Intensität noch jener des Harzdruckes zeigten eine Beziehung zur Stärke des Wicklerbefalls. Sie sind daher als Kriterien der Widerstandsfähigkeit einer Kulturkiefer gegenRh. buoliana, zumindest unter den Verhältnissen der Süd-Ukraine, nicht verwendbar.
Summary Studies on the diurnal rhythm of resin pressure and resin secretion in connection with the degree of pine-infestation byRhyacionia buoliana Schiff.In the course of one day pines in the age of 15 years showed only a small variation in resin pressure but a great one in secretion of resin. The maximal intensity of secretion was observed early in the afternoon. The moths ofRh. buoliana are flying after this time when the secretion of resin is low.There was no connection between resin pressure and secretion of resin on the one hand and the degree of pine-infestation byRh. buoliana on the other. The two factors are not suitable for indicating the degree of pine-infestation by this tortricid.
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10.
Zusammenfassung Die Altlarven 2. Generation der AmpferblattwespeAmetastegia glabrata Fall. sind im Obstbau als Schädling bekannt. Die Schäden entstehen bei dem Versuch der Larven, in Früchten Puppenkammern anzulegen.Üblicherweise verpuppen sich die Larven in den trockenen Stengeln der Nährpflanzen(Polygonaceae) oder anderem trockenem oder verholzten Pflanzenmaterial.Es wird über einen gesicherten Fall berichtet, in demAmetastegia glabrata-Larven in verarbeitetem Nutzholz (Plakattafel) schädlich geworden sind. Ein weiterer Fall konnte nicht völlig geklärt werden; jedoch waren auch hier Blaltwespen-Larven in einer Wohnung in verarbeitetes Nutzholz (Türrahmen) eingedrungen.Nach dem geringen Umfang der Schäden, die nur durch die Anlage kurzer Puppenkammern in weichen Holzteilen entstehen, istAmetastegia glabrata in die Gruppe der gelegentlichen Holzzerstörer einzureihen. Allerdings kann durch diese Art völlig gesundes Holz im Freiland angegriffen werden.Holzschutzsalze vom U-Typ genügen zur Vorbeugung nicht. Vorbeugungs- und Bekämpfungsmaßnahmen werden besprochen.
Summary Attack on wood by larvae of the dock sawfly Ametastegia glabiata Fall. (Hym., Tenthiedinidae) Normally the mature larvae of the last brood of the dock sawfly bore themselves for pupation into dry stems of plants.By the gnawing efforts in certain years of appearance in masses, however, they may attack fruit too, especially apples, and cause considerable damage by numerous gnawing spots.Besides these known injuries on fruitA. glabrata has now been stated in two cases as an occasionally dangerous animal to dry timber too.The damage caused is described by word and picture; preventive and curative measures are discussed.
Résumé Attaque du bois par des larves de la Tenthrenidé Ametastegia glabrata Fall. (Hym., Tenthredinidae) Normalment les larves adultes de l'A. glabrata se forent dans les tiges sèches des plantes pour la mé tamorphose.Cependant aussi des fruits, surtout des pommes, sont attaqués par le ronger pendant les anées quand ces insectes paraîssent en masse. Des dommages considérables sont provoqués aux points d'attaque nombreux.A côté de ces dommages connus aux fruits l'A. glabrata a été constaté en deux cas comme causeur de dommage par occasion en bois sec de construction.Les dommages sont décrits et figurés; des methodes preventives et curatives sont discutées.
? Ametastegia glabrata Fall. (Hym., Tenthredinidae) . , , , . Ametastegia glabrata Fall. ( ) . , .

Mitteilung aus dem Holzschutzlaboratorium der Farbenfabriken Bayer AG., Werb Uerdingen  相似文献   

11.
Summary In the introduction a historical survey is given about the development of the registration service of pests. It can be seen that originally informations of the appearance of pests was mostly given by agricultural and horticultural experts in special journals of agriculture and horticulture.It is well known that a registration service was set up when a Plant Protection Organisation was foundet. Its efficiency has never ceased since its beginnings. These efforts are foundet intensionally to register the existence of pests as completely as possible.The registration service starting first of all from the damage caused by the pests maybe well understood.Our research work being a continuous contribution to the systematic registration of pests generally shows in a number of examples the heterogeneous character of the problem which must be studied concerning the individual pests and difficulties which arise. This is shown with regard to someElaterides and also because of experiments withLaspeyresia funebrana Tr. during several years.In accordance withKirchner and F. P.Müller, Rostock, we propose to register systematically a number of pests on index cards according to uniform principles in the whole of Europe, to register the vertical and horizontal appearance of pests with the same measure, in the same periods of classification and in the same way (seeAuersch 1 to 3).We are encouraged to do so by a number of appreciated views of specialists from Germany and foreign countries however it is, not enaugh to see the great importance of the card index (card-register) and to acknowledge its practicability, but it can only prove its efficiency if it is generally introduced.The systematic registration of pests will enable us to gather in the course of time empirical data, the reliability and evidence of which will steadily increase.
Résumé On commence par livrer un aperçu historique sur le développement du système de rendre compte relativement aux plantes nuisibles. En lisant ces comptes rendus on peut reconnaître que les rapports donnés au début sur l'apparition des plantes nuisibles furent livrés en substance par la pratique agricole et jardinière par des revues spéciales de l' agriculture et de l'horticulture.Il est connu qu'avec l'établissement du service pour la protection des plantes on a établi un service de comptes rendus, au perfectionnement duquel on a travaillé dès son existance.Ces efforts furent influencés et activés par l'idée de saisir l'apparition des plantes nuisibles aussi complétement que possible. Le service des comptes rendus s'est orienté d'abord en première ligne aux dommages produits, ce qui est aisé à comprendre.Puisque notre traité doit être en général une contribution ultérieure à la connaissance systématique de l' apparition des plantes nuisibles, on explique au moyen de plusieurs exemples, comment sont différentes les questions se rapportant aux plantes nuisibles individuelles, questions qu'il faut ainsi prendre en considération et quelles difficultés en résultent. Cela est démontré pour quelques élatérides de même que sur la base d'examinations exécutées pendant plusieurs années avecLaspeyresia funebrana Tr.En concordance avecKirchner et F. P.Müller, Rostock, nous proposons de saisir systématiquement en classeurs à fiches une série de plantes nuisibles selon des points de vue uniformes, cela veut dire d'enregistrer dans les fiches proposées l'apparition verticale et horizontale des plantes nuisibles avec des mesures égales, dans les mêmes périodes d'examen et appréciation des qualités productives du sol et dans la même manière (voireAuersch 1 à 3).Nous sommes encouragés à faire ces propositions avant tout par des assentiments à notre disposition, qui nous ont été envoyés de la part des cercles compétents de notre pays et de l'é tranger. Il ne suffit pas cependant de reconnaître le fichier dans sa signification variée et d'apprécier son utilisation; le fichier peut faire ses preuves plutôt seulement, s'il est introduit en général. Au cours du temps il sera possible d'obtenir des valeurs expérimentelles par le fichement systématique des plantes nuisibles, dont la sûreté et faculté de déposition augmente constammant avec la durée de leur existence.
õ . : . . . . õ . . , . Elateriden uLaspeyresia funebrana Tr. . . . , , , . . ( 1 3.) . . , . . .
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12.
Summary It is stated that in the spreading of epizooties among small wild animals, a factor of biocoenosis played a main role, first of all some phenomena among small rodents, the field mice. In the spreading of rabies infection, a role is ascribed to an insect, theNecrophorus vespillo.The author suggests a research work to be done in that respect, and perhaps in the regions where rabies was never registered and are still free of rabies, as to establish what in a such biocoenosis is lacking that could be a factor of rabies epizooty.
Résumé A l'extension de grandes épizooties chez les animoux féroces, on considère que le grand rôle joue le facteur de biocenose, tout d'abord certains phénomènes entre les menus rongeurs, souris de champs. On attribute surtout le rôle de l'extension de l'épizootie de rage à l'insectNecrophorus vespillo. On recommende de faire des recherches dans ce but avec les autres branches de sciences naturelles et peut-être dans ces regions du monde où il n'y en avait pas et il n'y a pas aujourd'hui de rage, pour établir ce qu'il manque dans une telle biocenose et que peut être pourrait on prendre en considération comme le facteur des épisooties de rage.
, — . Necrophorus vespillo L. . , .
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13.
The study was conducted with the objective of studying tree species diversity and dominance and the associated changes in soil characteristics in a man-made forest established on formerly barren sodic land at Banthra Research Station (National Botanical Research Institute, Lucknow, India) (80° 45–53E, 26° 40–45N) over three decades. The results revealed that the forest has a moderate value for the tree species diversity index (H). The tree species Derris indica, Dalbergia sissoo, Azadirachta indica, Cassia siamea, Terminalia arjuna, Syzygium cumini, and Tectona grandis were found to be the major dominant species which may be considered suitable for planting on such degraded wastelands. There was a perceptible reduction in soil pH and exchangeable sodium percentage (ESP) and an increase in organic C and Ca2++Mg2+ cation contents over the past three decades, indicating that the sodicity has declined in the surface soil.  相似文献   

14.
When (±)--oxo-guaiacylglycerol--(vanillic acid) ether (1) is degraded byFusarium solani M-13-1, the-ketone is initially reduced to giveerythro andthreo guaiacylglycerol--(vanillic acid) ethers (2), arylglycerol--aryl ethers, both of which are enantiomerically pure. The absolute configuration in each2 was determined by Mosher's method; the products were converted to,-di-(R)--methoxy--trifluoromethylphenylacetates (MTPA esters) (3) oferythro (-)- andthreo (+)-veratrylglycerol--(methyl vanillate) ethers (3), whose1H nuclear magnetic resonance (NMR) spectra were examined and compared with those of four di-(R)-MTPA ester (3) diastereomers from chemically synthesizederythro (±)-3 andthreo (±)-3. To assign the- and-MTPA-OCH3 peaks, the1H NMR scans of several compounds that have substructures of 3 and their 3,4,5-trimethoxyphenyl analogues were examined. When a racemic alcohol reacts with (R)-MTPA to give a pair of (R)-MTPA ester diastereomers, the value was defined as the absolute value of the difference in the1H chemical shifts of the peak between the diastereomers. It was found that the values of-MTPA-OCH3 were larger than those of-MTPA-OCH3 owing to a shielding effect of the veratryl ring located on the-MTPA-OCH3, and that the-MTPA-OCH3 peaks in the 3,4,5-trimethoxyphenyl compounds shifted downfield relative to those in the veratryl compounds. On the basis of the1h NMR data of (R)-MTPA esters, the absolute configuration of the four chemically prepared diastereomers (3) were determined. The catabolicerythro 3 [fromerythro (-)-3] andthreo 3 [fromthreo (+)-3] were identical to (R, S, R)-erythro 3 and (R, S, S)- threo 3, respectively. An hydrogen species in the fungal reduction would attack the-ketone fromre-face of both (R)-1 and (S)-1, givingerythro (S, R)-2 andthreo (S, S)-2, respectively.Part of this paper was presented at the 33rd Lignin Symposium, Tsukuba, November 1988  相似文献   

15.
Einleitung In der 1. Mitteilung über die Lufttemperatur als Standortfaktor am Gr. Falkenstein ( = 49°05, = 13°17) siehe FW. Cbl.79, S. 362–373 (1960) ist über die Temperatur als Meßgröße der klimatologischen Standortserkundung und über den täglichen Temperaturgang in verschiedenen Seehöhen am Westhang berichtet worden. In der 2. Mitteilung, siehe FW. Cbl.80, S. 107–120 (1961) folgten die Ergebnisse der Temperaturregistrierungen an acht Klimastationen zwischen den Seehöhen 622 und 1307 m sowie eine Darstellung der vertikalen Temperaturverteilung an Hand von Monatsmitteln. In dieser 3. Mitteilung werden die Auswertungen der täglichen Ablesungen der Extremthermometer vorgelegt.  相似文献   

16.
The stilbene glucoside isorhapontin (5,4-dihydroxy-3-methoxystilbene-3--D-glucoside) is the major constituent of the ethyl acetate extracts fromPicea glehnii bark. Isorhapontin inhibited the hydrolytic activity ofTrichoderma cellobiohydrolase I (CBH I) for both bacterial microcrystalline cellulose and the soluble cellooligosaccharide celloheptaitol. The inhibitory effect for celloheptaitol, however, was more drastic than that for bacterial microcrystalline cellulose. The hydrolytic activity of the CBH I core domain for celloheptaitol was also inhibited by isorhapontin to a similar extent, suggesting that the interaction between isorhapontin and the core domain of CBH I is the reason for this phenomenon. The inhibition of CBH I activity by isorhapontin showed mixed noncompetitive and uncompetitive types in a concentration of the inhibitor of less than 125M. TheK i andK i values were estimated to be 57.2 and 33.3M, respectively. Whereas isorhapontin strongly inhibited CBH I activity, its aglycone isorhapontigenin (3-methoxy-3,5,4-trihydroxystilbene) showed almost no inhibition. Consequently, both the stilbenic and the-glucosidic structures in isorhapontin are essential for the inhibitory effect on CBH I activity. Isorhapontin also inhibited the activity ofTrichoderma endoglucanase I for celloheptaitol, whereas almost no effect was observed for the activities of both endoglucanases II and III.An outline of this work was presented at the 49th Annual Meeting of the Japan Wood Research Society, Tokyo, April 1999  相似文献   

17.
The inhibitory effects of 17 samples prepared from Thailand plants on 5-reductase activity were examined. The acetone extract of leaves ofArtocarpus altilis showed potent 5-reductase inhibitory activity. Fractionation guided by 5-reductase inhibition led to the isolation of 2-geranyl-2,3,4,4-tetrahydroxydihydrochalcone from the acetone extract of leaves ofA. altilis. This compound showed more potent inhibitory effect (IC50=38M) than-linolenic acid known as a naturally occurring potent inhibitor.  相似文献   

18.
Protein, oil, carbohydrate and starch contents of seed, which were collected from places with latitude 9° N to 32° N, longitude 72° E to 85° E and rainfall 40 to 400 cm, varied significantly (P<0.05) among 12 provenances. Interestingly, seed protein was positively correlated (r=0.838,P<0.05), and on the contrary, carbohydrate and starch were negatively correlated (r=–0.755,r=–0.623, respectively,P<0.05), with the latitude of the seed source. Significant variation for N, P, K, Ca and Mg in stems and leaves of one-year and three-year-old plants was also observed when these provenances were grown at Hisar (29°10 N, 75° 46 E, 215 m alt.), an arid region in north India. In general, provenances from north India at the age of three years had greater chemical and mineral contents than those from south India. Chlorophyll content was highly correlated with the latitude of the seed source, at the ages of one and three years (r=0.742,r=0.659,P<0.05, respectively), while crude protein of foliage at the age of three years was significantly correlated (r=0.673) with latitude. Dehradun, Jammu and Hisar provenances, from the north had comparatively greater concentrations of N, P and K at the age of three years as compared to those from south India. The results are useful from the points of view of genetical variation, and selection of superior provenances for arid conditions in north India.  相似文献   

19.
The present work was undertaken from the standpoint of radical-capturing ability with regard to the antioxidative ability of flavonoids, especially flavonols distributed widely in woody plants. In regard to the flavonols, six methyl derivatives were initially prepared from quercetin and its litinoside. Their radical-capturing constants were determined strictly by the stopped-flow spectroscopic method. It was proved that the radical-capturing ability of quercetin mainly involves the vicinal C3. and C4, hydroxyl groups and the C3 hydroxyl group. To clarify the reaction mechanism begun at the C3 hydroxyl group of quercetin, 5,7,3,4-tetramethylquercetin (TMQ), flavon-3-ol (F30) and so on were treated with 2,2-azo-bis-(2,4-dimethylvaleronitrile) (AMVN). Six products (1–6) containing one depside and its two hydrolytic products, two valeronitrile adducts, and others were isolated from the reaction mixture of TMQ and their structures determined by instrumental analyses. Similarly, F30 gave four products, 7–10, which corresponded to the above products 1–3 and 5 (one depside, its two hydrolytic products, and one adduct), respectively. 3,5,7,3,4-Pentamethylquercetin (PMQ) and flavon-3-O-methylate (F3M) gave no products. The quantitative change of the products with reaction time was determined spectroscopically. An initial reaction pathway for the radical-capturing reaction of flavon-3-ols with AMVN was proposed based on the products and their amounts. The main route — formation of depside and its hydrolytic products via ketohydroperoxide (3) or ketohydroperoxy radical (4) - was similar to that of the oxidation reaction of quercetin with quercetinase and light.Part of this paper was presented at the 46th and 47th annual meetings of the Japan Wood Research Society, Kumamoto and Kouchi, April 1996 and 1997  相似文献   

20.
Zusammenfassung In einer zweijährigen Versuchsserie wurde die Wirkung der Schutztauchung von Nadelholzpflanzen in DDT, Lindan WP und Lindan EC (1% a. S.) gegen Befall des Rüsselkäfers (Hylobius abietis L.) untersucht. Die Versuche wurden auf 43 Forstkulturen in ganz Schweden ausgeführt.Die Versuche bestätigten, daß der Rüsselkäfer im allgemeinen im südlichen und mitteren Schweden wesentlich stärker auftritt als in kälteren nördlichen Gebieten. In allen geographischen Regionen hatten die Insektizidbehandlungen gute Schutzwirkung während 2 Vegetationsperioden. Die Unterschiede in der Wirkung der 3 Präparate waren relativ gering. Lindan schützte die Pflanzen in beiden Vegetationsperioden mindestens ebenso gut wie DDT. Das beste Mittel war im allgemeinen Lindan WP. Nachhaltig ungü nstige Einflüsse der Präparate auf die Pflanzen wurden nicht nachgewiesen.
Summary Field experiments with insecticides against pine weevils (Hylobius abietis L.) in Sweden.The protection of conifer plants against attacks of the pine weevil (Hylobius abietis L.) by dipping in DDT, lindane WP and lindane EC (1% a. i.) was studied during two years. The experiments were carried out in 43 reforestation areas all over Sweden.The experiments confirmed that pine weevil attacks as a rule are considerably heavier in Southern and Central Sweden than in cooler, more northerly regions. In all regions the treatments with insecticides had a good protective effect during two vegetation periods. The differences in effect between the three insecticides were comparatively small. In both vegetation periods lindane gave at least as good protection as did DDT. Lindane WP was generally the best formulation. The experiments did not reveal any persistent negative effects of the treatments on the plants.
(Hylobius abietis L.) . (Hylobius abietis L.) 43- . (1% ). , , . . - . . . - .

Forstliche Hochschule, S 10 405 Stockholm 50/Schweden.  相似文献   

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