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1.
The stearyl methacrylate modified polysiloxane/nanocomposite was synthesized by graft copolymerization between stearyl methacrylate modified polysiloxane with pendent epoxy groups and amino-functionalized nano silica. Then it was utilized to fabricate the superhydrophobic cotton fabric by one-step method. The structures, chemical compositions, thermal properties, surface morphology and wettability were characterized by Fourier Transform Infrared Spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS), Thermo-gravimetric analyzer (TGA), Scanning electron microscopy (SEM) and Static contact angle analyzer. Results showed that a hydrophobic polysiloxane film and many nano-scaled tubercles were coated on the surface of the treated cotton fabrics plus their inherent microscaled roughness, which were the reasons why cotton fabric changed from hydrophilicity to hydrophobicity. In addition, with increase of the amount of nanocomposite, hydrophobicity of the treated cotton fabric would be enhanced; water contact angle of this fabric could attain 157°, which was higher than 141.5° reached by the fabric treated with stearyl methacrylate modified polysiloxane. The superhydrophobic cotton fabric also possessed favorable washing durability. On the other hand, its air permeability, color and softness would not be influenced instead.  相似文献   

2.
A novel dodecylphenylsiloxane oligomer resin/nanocomposite (PHDESR-SiO2) was prepared by graft copolymerization between dodecyl modified phenylsiloxane resin with pendent epoxy groups (PHDESR) and amino-functionalized silica nanoparticles (BTEPA-SiO2). PHDESR-SiO2 was then used to prepare a super hydrophobic surface on cotton fabric by a facile solution-immersion process method. Chemical structures, chemical compositions, wettability, surface morphology, and thermal properties were investigated by Fourier Transform Infrared Spectrum (FT-IR), 1H-NMR spectrum, X-ray photoelectron spectroscopy (XPS), static contact angle analyzer, scanning electron microscopy (SEM), Particle size distribution (PSD) and thermo-gravimetric analysis (TGA). The results showed that the target product PHDESR-SiO2 has an anticipative structure with many micro/nanostructure tubercles, a cross-linked network hydrophobic organosilicon resin film and many clusters of cylindrical dodecyl molecular brushes. This created super hydrophobic structure on the surface of the treated cotton fabrics. XPS analysis indicated that the long carbon chain groups had a slight tendency to enrich the film-air interface. In addition, PHDESR-SiO2 can provide good hydrophobicity for the treated fabric. As the dose of PHDESR-SiO2 increased, the hydrophobicity of the treated fabric enhanced and consequently the water static contact angle reached 152.5 °. This had little influence on the softness, color, and gas permeability of the fabrics. This makes it slightly stiff at high doses, and the super-hydrophobic cotton fabric also had good launderability.  相似文献   

3.
In this study, durable antibacterial cotton fabrics were prepared by a simple two-step impregnation method. Firstly, thioglycolic acid (TGA) was grafted onto cotton fabric via esterification with the hydroxyl groups of cellulose, then silver nanoparticles (Ag NPs) were immobilized on the cotton fabric surface via coordination bonds with the TGA thiol groups. As a result, the mean size of Ag NPs coating on the cotton fabric is around 74 nm, and these functionalized cotton fabrics show superior antibacterial properties and excellent laundering durability. After withstand 50 laundering cycles, the obtained cotton fabrics still showed outstanding bacterial reduction rates (BR) against both S. aureus and E. coli, and the rates are all higher than 97 %. Therefore, this method to prepare antibacterial cotton fabric shows great potential applications in socks, cosmetic, and medical textiles.  相似文献   

4.
N-halamine precursor 2,2,6,6-tetramethyl piperidinol (TMP), a hindered amine light stabilizer, was bonded onto cotton fabric by using 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. A variety of treating conditions including TMP concentration, curing temperature and time, and catalyst were studied. The treated fabrics were characterized using FTIR spectra and scanning electron microscope (SEM). The cotton fabric treated with TMP precursor could be rendered biocidal upon exposure to dilute household bleach. The chlorinated cotton swatches showed great efficacy and inactivated 100 % of Staphylococcus aureus with 7.1 log reduction with 5 min of contact and 83.25 % of E. coli O157:H7 at 10 min of contact. In addition, the wrinkle recovery angle of the treated cotton fabrics increased from 229 ° of untreated cotton fabrics to 253 °. This study provided a practical finishing process to produce cotton fabrics with easy care and antibacterial functionalities at the same time.  相似文献   

5.
Textiles, especially those made of natural fibers, are suitable medium for the growth of microorganisms which causes disease transmission, stink, colorful spots, and reduction in fabric strength. This research focuses on the antimicrobial finishing of cotton fabrics using colloidal solution of silver nanoparticles. Due to the difficulties of adding a new step to the finishing process of cotton textiles, efforts have been made to combine the antimicrobial treatment with the conventional finishing processes. For this purpose two chemical finishes of Fixapret ECO as a crosslinking agent and Cellofix ME as a resin former have been used in anti crease finishing of cotton fabric and their effects were evaluated. The properties of the samples have been investigated by measuring the resistant of samples against bacteria, crease recovery angle, abrasion, and washing fastness. The results showed that treated samples by pad-dry method have the best antibacterial effect with a direct relation between the increase in drying temperature and antibacterial properties. However, the washing and abrasion fastness were not at the acceptable level. Co-application of the colloidal solution of silver nanoparticles with the crease resistant materials improved both fastness properties while at the same time limited the direct contact between the nanoparticles and the bacteria so the antibacterial efficiency was reduced. Subsequently, it was concluded that the antibacterial finishing method should be selected according to the end uses. In addition, antibacterial treatment could be one of the multi-purpose finishes for cotton fabric.  相似文献   

6.
In this study, chitosan and pentasodium tripolyphosphate (TPP)-based bilayers were fabricated on the cationized woven cotton fabrics via layer-by-layer (LBL) self-assembly technique. The initial cationic charges on cotton fabric were produced through the aminization procedure involving the covalent attachment of reactive dye to cotton fabric and subsequent reductive cleavage of the dye to free amine. Different numbers of bilayers (1, 5, and 10) consisting of chitosan/TPP have been deposited on the fabrics. The surface morphology, cationic group content, chemical surface modification, whiteness index, surface tension and antibacterial properties of the modified cotton samples were investigated using scanning electron microscopy (SEM), methylene blue test, FTIR, reflectance spectroscopy, water contact angle measurements and antibacterial test, respectively. The bacterial inhibition experiments demonstrated that the modified cotton fabric with the addition of chitosan/TPP bilayers can increase the degree of inhibition on E. coli and S. aureus bacteria. The utilized LBL method was an easy and cost-effective procedure for developing of novel antibacterial textiles with the highly attractive feature in the medical and hygienic products.  相似文献   

7.
The cotton fabric was modified with dopamine methacrylamide (DMA) based on mussel-inspired reaction and polymerized with zwitterionic sulfobetaine methacrylate (SBMA) through free radical polymerization reaction. The poly(DMA-SBMA) contained not only key chemical constituents of dopamine hydrochloride, which strongly adsorbed to fabric substrates, but also hydrophilic groups, providing a hydrophilic surface for fabric due to its strong interaction with water via electrostatic interactions. The chemical structure, surface topography, and surface wettability of the fabric were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and contact angle experiments, respectively. The results showed that the water contact angle (WCA) of the treated fabric was ~0 °, whereas the underwater oil contact angle (OCA) was ~161 °, as compared to ~25 ° for the control one. It is expected that as-prepared fabrics could be applied in oil/water separation due to such special superhydrophilicity and superoleophobicity.  相似文献   

8.
α,ω-di[(4-butoxy-piperazin-1-yl)-phosphinic acid methyl ether]-terminated linear polysiloxane (PNPDMS) was synthesized and utilized as the flame retardant and hydrophobing agent. The flame retardance and thermal decomposition behaviors of cotton fabrics were systematically estimated by limiting oxygen index (LOI), thermogravimetric analysis and vertical burning test, respectively. It was found that the LOI of cotton fabric treated with PNPDMS enhanced to 29.82 % compared with cotton fabric without treatment, whose LOI was only 18.00 %. The treated cotton fabric showed a shorter char length, a shorter After-flame time, and no After-glow time as revealed in vertical burning test. The mechanical property in treated cotton fabric was slightly decrease. Furthermore, the grade of water repellency of treated cotton fabric reached to 90 and water contact angle (WCA) increased to 141.90° compared with cotton fabric without treatment whose WCA was 62.80°. The result showed that the cotton fabric treated with PNPDMS exhibited excellent flame retardance and hydrophobic properties.  相似文献   

9.
In the present paper, flame resistance property is imparted to cotton fabrics by N-methylol dimethylphos-phonopropionamide (Pyrovatex CP New, FR), melamine resin (Knittex CHN, CL), phosphoric acid catalyst (PA), and ZnO/nano-ZnO co-catalyst. The study shows that effectiveness of the FR-CL-PA reaction to form a crosslinked structure is enhanced by the co-catalytic reaction, resulting in enhancement of fabric’s compressional recovering ability. However, the low pH reaction weakened the fabrics, resulting in poor tensile strength and toughness, stiffer hand feel, brittle and tendered polymer layers, a less spongy fabric structure, and a roughened fabric surface with fuzzy fibrils. In addition, atmospheric pressure plasma jet (APPJ) was used to enhance materials properties by sputtering or etching effect. The roughening effect of plasma treatment enhances tensile properties of treated specimens. Nevertheless, the positive effect is negligible after post-treatment with flame-retardant agents. Moreover, the increased inter-yarn friction enhances the subjective stiffness of fabric and the rigid effect is even worse for plasma pre-treated cotton specimens subjected to flame-retardant treatment. However, plasma pre-treated specimens have a compressible structure after post-treatment with flame-retardant agents. Moreover, neutralization of flame-retardant-treated specimens helps minimize side effects of acidic finishing, irrespective of tensile and compression properties. The process also minimizes shear and bending rigid effect by removing unattached metal oxides from the fabrics.  相似文献   

10.
The main goal of present study was the fabrication of cotton fabric with special functions, including electrical conductivity, magnetic, antibacterial, and ultraviolet (UV) blocking. In this regard, the cotton fabric was primarily coated with graphene oxide and then reduction of graphene oxide and synthesis of magnetite nanoparticles accomplished in one step. The alkaline hydrolysis of magnetite precursors and reduction of graphene oxide was simultaneously performed using sodium hydroxide to produce reduced graphene oxide/Fe3O4 nanocomposite on the fabric surface. The prepared cotton fabrics were characterized with field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). The treated fabrics with reduced graphene oxide/Fe3O4 nanocomposite displayed a low electrical resistivity i.e. 80 kΩ/sq. Furthermore, the coated fabrics showed reasonable magnetic properties due to the presence of magnetite nanoparticles on the surface of cotton fabrics. Moreover, this process imparted proper antibacterial properties and UV blocking activity to cotton samples.  相似文献   

11.
Herein we report a simple and reproducible method for fabricating highly durable and robust superhydrophobic and superoleophilic cotton fabrics via simultaneous radiation-induced graft polymerization of glycidyl methacrylate and subsequent chemical modifications with aminopropyltriethoxysilane and hexamethyldisilazane. The chemical structure and the surface topography of the pristine and the modified cotton fabrics were investigated in detail by ATR-FTIR, XPS, and 29Si NMR, and a grafting layer was successfully immobilized onto the surface of the cotton fabric by forming covalent bonds. Multi-dimensional surface roughness was created by combining micro-sized fibers of the cotton fabric, nanoscaled protuberances of the grafting chain, and molecular level spherical projection points of silicon methyl. The superhydrophobic cotton fabric exhibited long-term stability, ultra-high durability and robustness, and maintained its properties even after 25 wash cycles. The fabric also showed excellent water repellency with a water contact angle of 153 ° and a high efficiency of oil/water separation (98 %). The superhydrophobic/superoleophilic cotton fabric developed in the present work exhibits important potential applications in superhydrophobic textiles and oil/water separation.  相似文献   

12.
A novel antibacterial agent polysulfopropylbetaine (PSPB) bearing carboxyl groups was synthesized and its application on cotton fabric to provide durable antibacterial property was also presented. The successful synthesis of PSPB and its immobilization onto the cotton fabric surface were verified by a series of tests including FTIR, 1H NMR, XPS and SEM. Viable cell counting method was employed to investigate antibacterial properties of the finished cotton fabrics. It was found that the cotton fabrics treated with PSPB were endowed with desirable antibacterial activity against both gram-negative bacteria Esherichia coli (E.coli, AATCC 6538) and gram-positive bacteria Staphylococcus aureus (S.aureus, AATCC 25922), with the bacterisotatic rates of 99.69 % and 99.95 %, respectively. Notably, the bacterial reduction rates still maintained over 90 % against both bacteria even after 50 consecutive laundering cycles. Moreover, tests concerning the hydrophilicity, air permeability, water vapor transmission, mechanical properties as well as thermal properties were carried out systematically. The experimental results indicated the hydrophilic performance, air permeability and moisture penetrability of the cotton fabrics finished with PSPB were improved greatly in spite of a slight reduction in thermal performance and little obvious influence on mechanical performance. The antibacterial cotton fabric has the potential to be applied in sportswear, underwear, household textiles, medical fields and much more.  相似文献   

13.
In this work, we developed a new method that can achieve immobilization and protection of the Cu NPs coating on the cotton fabrics by a simple two-step impregnation method. Firstly, L-cysteine (Cys) was grafted onto cotton fabric via esterification with the hydroxyl groups of cellulose, then Cu NPs were introduced on the fabric surface in the presence of a protective reagent, citric acid. Due to the doubled stabilization acts of Cys and citric acid, the Cu NPs immobilized on the fabric surface showed an excellent antibacterial effect and outstanding laundering durability. As a result, the mean size of the Cu NPs coating on the cotton fabric is about 62.4 nm, and the modified cotton fabrics showed satisfactory antibacterial ability against both S. aureus and E. coli, which the bacterial reduction rates are all higher than 98 % even withstand 50 washing cycles. Therefore, this method to prepare antibacterial cotton fabrics showed great potential applications in socks, cosmetic, and medical textiles.  相似文献   

14.
Various shapes of ZnO — multi-petals, rod and spherical — were prepared and then applied on cotton fabric for UV-blocking and anti-bacterial properties. The ZnO particles were investigated by XRD and SEM. The as-prepared suspension was applied onto cotton fabrics via the pad-dry-cure process at 150 °C. The characteristics of the fabric coating were investigated by SEM, XRD and Atomic Absorption Spectroscopy (AAS). The UV-blocking effectiveness was measured with a UV-Vis spectrophotometer whilst the antibacterial activity was determined using the AATCC 147 method. The results of XRD and SEM on the ZnO powders show that we can produce various shapes of ZnO. The investigation by SEM and AAS clearly revealed that ZnO was effectively deposited on the cotton surface and that the adhesion was retained after washing ten cycles. The sphericals-shaped ZnO and multi-petals shaped ZnO coated fabrics show excellent UV-blocking properties. All treated samples showed good antibacterial activity against Staphylococcus Aureus. The shape of ZnO shows no considerable effect on antibacterial properties.  相似文献   

15.
The paper discusses a method to functionalize cotton fabrics using biologically active natural compounds to achieve the antibacterial characteristics required for medical application. The biologically active natural compounds include propolis, beeswax, and chitosan. Three 100 % cotton knitted fabrics with different degrees of compactness were impregnated in the emulsions containing the active ingredients and fabric variant G3 with the highest degree of impregnation was considered for the evaluation of the antibacterial properties and comfort characteristics. The results show that the treated cotton fabric had high antibacterial activity against both gram positive bacteria Staphylococcus aureus and Streptococcus β haemolytic, and gram negative bacteria Escherichia coli and Pseudomonas aeruginosa. The presence of the biologically active natural compounds on the cotton substrates modified the surface of the textile fibers as seen in the SEM images. The treatment also improved fabric comfort properties, the cotton substrates became less air permissive and more hygroscopic after the treatment. The experimental results indicated that propolis, beeswax and chitosan can be applied as an emulsion to functionalize cotton textile materials. The antibacterial performance of the functionalized fabrics suggested that the cotton fabrics treated with those biologically active natural compounds have the potentials to be used in medical fields.  相似文献   

16.
Waterborne polyurethane modified by acrylate/nano-ZnO (PUA/ZnO) was synthesized and used to improve the wet rubbing fastness of reactive dyed cotton fabric. The reaction conditions were optimized and the products were characterized by FT-IR, TG, DSC, SEM, and particle size distribution. The dyed cotton fabrics were finished with PUA/ZnO emulsion and the rubbing fastness, ultraviolet resistant property, and wearability of treated fabrics were measured. The wet rubbing fastness of treated fabrics was increased by about 0.5–1 rate to achieve 3–4 rate, and the ultraviolet protection factor (UPF) achieved 50+ level. The whiteness, air permeability, and elongation at break of treated fabric were not decreased significantly. SEM showed that the smooth and reticular coating on the surface of treated fabric reduced the mechanical friction force between dyed fabric and rubbing cloth, and thus improved the rubbing fastness. The decomposition temperature of finished fabric was increased by 50–80 °C.  相似文献   

17.
Waterproof breathable layered fabrics allow water vapor passing through, but resist liquid water to pass. This ability of the fabrics to protect rain and snow water while allowing sweat vapor to evaporate from inside to outside atmosphere, leads them to be used as outdoor sportswear or protective clothing. The big challenge of enhanced hydrostatic resistance of these fabrics with proper breathability and thermal comfort has widened the research scope. This study presents an experimental investigation on hydrostatic resistance and thermal behavior of layered waterproof breathable fabrics. Six different types of hydrophobic and hydrophilic membrane laminated layered fabrics were evaluated by varying different fabric parameters in the experiment. Hydrostatic resistance and water vapor permeability of the laminated fabrics were measured by SDL ATLAS Hydrostatic Head Tester and PERMETEST respectively. Thermal properties were evaluated by ALAMBETA instrument. Moreover, FX-3300 air permeability tester was used to measure air permeability which represents the porosity of the fabrics and computer based See System software was used for water contact angle measurement on the outer fabric surface in order to determine the hydrophobic and hydrophilic properties. This experiment clearly discusses the influence of different fabric characteristics and parameters on hydrostatic resistance and thermal properties of the breathable laminated fabrics. The results show that fabric material composition, density, thickness, and hydrophobic and hydrophilic membranes have significant effects on hydrostatic resistance, breathability and thermal properties of different laminated fabrics.  相似文献   

18.
An alternative approach to application of chitosan based on layer by layer (LbL) assembled technique is studied in this paper. For this aim, chitosan (CHT) was used as a bio-based cationic polyelectrolyte and pentasodium tripolyphosphate (TPP) and poly(sodium 4-styrene sulfonate) (PSS) were selected as anionic polyelectrolyte. TPP/CHT and PSS/CHT based bilayers were fabricated on the cationized woven cotton fabrics via layer-by-layer self-assembly technique. The characterization of coatings on the fabric surface in terms of surface appearance, atomal content, and chemical bondings were made in detail through SEM, XPS, and FTIR-ATR analysis. Also, the antibacterial activity, air permeability, and water contact angle were measured. Surface analyses demonstrate the interaction between TPP, PSS and chitosan separately. XPS spectra also showed the existence of LbL deposition over cotton substrates in terms of both elemental composition and the presence of different types of bondings on the fabric surface. The antibacterial activity analysis revealed that the modified cotton fabric with the addition of CHT/TPP and CHT/PSS bilayers could increase the degree of inhibition on K. pneumanie and S. aureus bacteria.  相似文献   

19.
High performance cellulosic fabrics are of increasing attention as a wearable fabric with special functions. The current report deals with preparation of multifunctional cotton fabrics by using simple and facile layer by layer technique. Firstly, silver nitrate was reacted with carboxymethyl cellulose to prepare Ag nanoparticles-carboxymethyl cellulose composite. Multi-layers of the so-obtained composite were applied on the cotton fabrics using pad-dry-cure method. Ag nanoparticles were deposited with mean size of 18.2 nm onto cotton fabrics which served as a cross linker between carboxymethyl cellulose macromolecules and cotton macromolecular blocks. Application of composite multilayers brought new properties for the finished cloths such like coloration, ultraviolet resistance, electrical resistance and biocidal action. The ultraviolet transmission radiation was significantly reduced to 7-10 % after applying ten composite layers. Valuable antibacterial textiles which are required in different medical purposes could be successfully produced, as excellent antibacterial activities were achieved by using the reported method. The developed process can be easily adapted to the existing textile machinery, making it industrially viable to produce fabric’s versatility.  相似文献   

20.
Following the work done previously [1]. In this paper, the effect of various post-finishing agents on the low stress mechanical and surface properties of dyed cotton fabrics, as well as their handle value have been studied. The mechanical properties of the treated cotton fabrics were measured by the famous KES-FB system. It has been found that cotton fabric mechanical properties and fabric handle can be modified by not only the external finishing agents but also the internal finishing agents which are used for correcting the inherent defect of the fabrics. The results in this report will inform the textile industry in engineering required fabric properties with appropriate finishing processes.  相似文献   

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