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1.
Chemical Composition of Precipitation in Beijing Area, Northern China   总被引:1,自引:0,他引:1  
Variations of anions (SO4 2-, NO3 -,NO2 -, Cl- and F-),cations (K+,Na+, Ca2+, Mg2+ and +) and pH values in precipitation, througfall and stemflow samples collected overa four-year period (1995–1998) in Beijing (two sitesZhongguancun and Mangshan) are presented. The annualvolume-weighted range of pH values were 6.57–7.11 inprecipitation, 5.46–6.86 in thoughfall and 5.32–6.41 instemflow. The fominant anion was , while Ca+and NH4 + were the main cations in precipitation,throughfall and stemflow. Most of ion concentrations with precipitation, throughfall and stemflow volume showed negative correlation, except for some ones. Significant correlationvalues were also found between ions (SO4 2-,NO3 -, Cl-, F-, Ca2+,Mg2+ andNa+) in precipitation, throughfall and stemflow indicatedthe common sources of these ions such as coal combustion,automobile emission and fertilizers application. Compared toprecipitation, there was an increased ion concentration inthroughfall or in stemflow. Changes of ion concentrations werein Quercus liatungensis Koiz. and Pinus tabulaefornisCarr. throughfall (or stemflow) because of different crown andbark qualities of tree species.  相似文献   

2.
The influence of tree species and soil properties on throughfall fluxes were studied for 5 tree species, growing on initially identical soil. In three mixed deciduous forests with different soil properties, throughfall fluxes of 11 elements were measured during 2 yr for 100 to 150 yr old individuals of Fagus sylvatica L., Quercus robur L., Carpinus betulus L., Tilia cordata Mill. and Acer platanoides L.. Throughfall : precipitation flux ratios were: PO4 3? (11 to 37), K+ (7 to 22), Mn2+ (5 to 14), Mg2+ (3 to 9), Ca2+ (3 to 5), Cl? (1.9 to 2.6), Na+ (1.1 to 2.2), NH4 + (1.5 to 2), SO4 2? (1.5 to 2.1), NO3 ? (0.7 to 1.3) and H+ (0.1 to 0.5). The annual input of S to the soil by throughfall was for Fagus 22 to 29, Quercus 25 to 37, Carpinus 20 to 25, Tilia 24 and Acer 29 kg ha?1. The annual input of N to the soil by throughfall was for Fagus 20 to 29, Quercus 14 to 22, Carpinus 15 to 22, Tilia 22 and Acer 20 kg ha?1. Throughfall fluxes of Na+ and Cl? differed between species, depending on different canopy filtering capacity of sea aerosol, and were greatest for Fagus and Quercus. Throughfall of Ca2+, Mg2+ and K+ were characterized by increased flux from poor to rich sites, with the greatest soil effect on Carpinus, and by a high leaching part, which increased in the same manner. Manganese throughfall showed especially soil effects, characterized of decreased flux from poor to rich sites, but also species effects, of which Carpinus had the greatest flux. pH in throughfall showed a pronounced seasonal variation with pH 6 to 6.5 for Fagus in the foliated season and pH 4.0 to 4.3 in the defoliated season. Carpinus and especially Quercus had lower pH at the poor site, but the differences decreased at the richer sites. The calculated annual acid input to the trees was 4 to 12 times greater than the H+ flux measured as pH in throughfall. An inorganic anion deficit in throughfall, probably due to the presence of organic anions, was proportional to K+, Ca2+ and Mg2+.  相似文献   

3.
Information on atmospheric inputs, water chemistry and hydrology were combined to evaluate elemental mass balances and assess temporal changes in elemental transport from 1983 through 1992 for the Arbutus Lake watershed. This watershed is located within a northern hardwood ecosystem at the Huntington Forest within the central Adirondack Mountains of New York (USA). Changes in water chemistry, including increasing NO3 ? concentrations (1.1 μmol c , L?1 yr-1), have been detected during this study period. Starting in 1991 hydrological flow has been measured from Arbutus Lake and these measurements were compared with predicted flow using the BROOK2 hydrological simulation model. The model adequately (r2=0.79) simulated flow from this catchment and was used to estimate drainage for earlier periods when direct hydrological measurements were not available. Modeled drainage water losses coupled with estimates of wet and dry atmospheric deposition were used to calculate solute budgets. Export of SO4 2? (831 mol c ha?1 yr?1) from the greater Arbutus Lake watershed exceeded estimates of atmospheric deposition in an adjacent hardwood stand suggesting an additional source of S. These large drainage losses of SO4 2? also contributed to the drainage fluxes of basic cations (Ca2+, Mg2+, K+ and Na+). Most of the atmospheric inputs of inorganic N were retained (average of 74% of wet precipitation and 85% total deposition) in the watershed. There were differences among years (56 to 228 mol ha?1 yr?1) in drainage water losses of N with greatest losses occurring during a warm, wet period (1989–1991).  相似文献   

4.
Characterization of the forest vegetation and soils in two adjacent; contrasting headwater lake basins located in Kejimkujik National Park, Nova Scotia was completed in 1980. Precipitation chemistry was studied during May to November, 1981–83 at two forested plots in each basin. There were 2012 stems ha-1 in Beaverskin basin and 1816 stems ha-1 in Pebbleloggitch basin. Beaverskin species composition was predominantly coniferous (72% of stems) while Pebbleloggitch was predominantly deciduous (52% of stems). Thickness and mass of organic soil layers were greater in Beaverskin. Mineral soil cation concentrations were similar. There were no differences between the basins in mean incident bulk precipitation pH. Mean volume-weighted pH for the period (73 collections) was 4.80. Sixteen percent of collections had a pH < 4.25. Sulphate deposition in incident bulk precipitation (May – November) ranged from 5.4–8.5 kg ha-1 during 1981–83 while NO inf3 sup- ranged from 0.04–0.93 kg ha-1. The partitioning of incident precipitation into throughfall varied considerably (69%–38%) year-to-year. Temporal flux of ions did not differ significantly. Amounts of all major ions in throughfall especially SO inf4 sup2- and base cations(Ca2+ + Mg2+ + K+ + Na+) were enriched.  相似文献   

5.
Deposition of non-seasalt base cations (Ca2+ + Mg2++ K+) in South Korea was mapped for 1994 to 1997 on a 11 × 14 km grid using the so-called inferential modeling technique. It is found that the annual mean wet deposition of non-seasalt base cations is about 290 eq ha-1 yr-1 with a maximum of 470 eq ha-1 yr-1 and a minimum of 120 eq ha-1 yr-1 while the annual mean dry deposition is about 130 eq ha-1 yr-1 with a maximum of 240 eq ha-1 yr-1 and a minimum 70 eq ha-1 yr-1. Theannual mean total deposition of non-seasalt Ca2+ + Mg2+ + K+ is found to be about 420 eq ha-1 yr-1 with the predominant range of 400 eq ha-1 yr-1 to 550 eq ha-1 yr-1 thatoccupies more than 45% of total deposition of non-seasalt base cations and dry deposition constitutes on average30% of the total base cation deposition. About 30% of the annualtotal deposition of sulfur is found counteracted by depositionof non-seasalt base cations over South Korea.  相似文献   

6.
To clarify the mechanisms of pH buffering in forest ecosystems, field observations of pH and ionic concentrations in precipitation (R), throughfall (Tf), stemflow (Sf), and leachates from organ c horizons (Lo) were conducted for three years at three stands in Tomakomai (TK) and Teshio (TS) in Hokkaido, northern Japan. Weighted mean rates of H+ input as wet deposition at TK and TS were estimated in the range from 0.3 to 1.0 and 0.4–0.6 kmolc ha?1 y?, respectively. While the net H+ flux was reduced significantly by the forest canopy, net fluxes of other ions by throughfall, especially for Na+, Cl?, and SO4 2?, were apparently greater than those by precipitation. The canopy modification of the H+ flux was more remarkable under deciduous stands than under coniferous stands, suggesting that the efficiency of conifers as the collectors of dry deposition is greater than that of deciduous ones. More than 50% of H+ flux due to throughfall was absorbed by the organic horizons and the weighted mean pH of Lo at TK and TS was in the range from 4.9 to 5.5 and 5.0–5.5, respectively. Results from field observation and field leaching experiments, showed that the major H+ sinks of the organic horizons are exchange reaction of Ca2+, Mg2+ and K+. Organic acids or organo-metallic complexes of lower pK(=5.0–5.5) played a significant role as counter anions in O horizons leachate in coniferous forests. Our results indicate the importance of biogeochemical modifications in the canopy and organic horizon in acid buffering mechanisms of forest ecosystems.  相似文献   

7.
A total of 51 lakes in southern Quebec, Canada, were sampled between 1985 and 1993 to study changes in water chemistry following reductions in SO2 emissions (main precursor of acid precipitation). Time series analysis of precipitation chemistry revealed significant reductions in concentrations and deposition of SO4 2- from 1981 to 1992 in southern Quebec as well as reductions in concentrations and deposition of base cations (Ca2+, Mg2+), NO3 - and H+ in the western section of the study area. Reductions in atmospheric inputs of SO4 2- have resulted in decreased lakewater SO4 2- concentrations in the majority of the lakes in our study, although only a small fraction (9 of 37 lakes used in the temporal analysis) have improved significantly in terms of acidity status (pH, acid neutralizing capacity – ANC). The main response of the lakes to decreased SO4 2- is a decrease in base cations (Ca2++Mg2+), which was observed in 17 of 37 lakes. Seventeen lakes also showed significant increases in dissolved organic carbon (DOC) over the period of study. The resulting increases in organic acidity as well as the decrease in base cations could both play a role in delaying the recovery of our lakes.  相似文献   

8.
Seasonal fluctuation of concentration and flux of major inorganic ions in throughfall, stem flow, snowpack and soil solution was investigated at a natural cool temperature mixed forest in Hokkaido, northern Japan, in order to clarify the effect of snowmelt on the solute dynamics in the forest soil in snow-dominated region. Na+, Ca2+, Mg2+, Cl? and SO4 2? concentrations in soil solution showed a large fluctuation in the snowmelt period. The percentage of output of these elements from soil during the snowmelt period in the annual output was as follows. Mg2+: 51%, Na+ and Cl?: 59 and 60%, SO4 2?: 65%, Ca2+: 77%. Our results indicated that the snowmelt event was very important to quantify the annual elemental budgets in this region. Although the leaching of base cation from the soil was larger than that of inputs and accumulation into the vegetation, annual decreasing rate of acid neutralization capacity (ANC(s)) from the soil was mostly affected by the base cation accumulation into the vegetation, related that the base cations weathering accompanied with bicarbonate was slow due to the acidic and weathered soil in the studied site. It is suggested that the weakly acidic soil which has low ANC(s) in snow-dominated region will be relatively sensitive to the future increase of acidic deposition.  相似文献   

9.
The fluxes recovered from washing branches and surrogatesurfaces were compared for two holm oak (Quercus ilex L.)forests in the Montseny mountains (NE Spain) differentiallyexposed to pollution. For 5 periods in May and June 1996 afterexposures ranging between 68–189 hr, 6 metacrylate plates and 8branches were extracted with distilled water. Also, a sequentialwashing of branches was undertaken, with 5 min separationsbetween the 3 initial washes, one hour between the 3rd and the4th, and 6 hr between the 4th and the last one. The compositionwas analysed for PO4 3-, SO4 2-,NO3 -, Cl, F, NH4 +,Ca2+, Mg2+, Na+, K+, Cu, Pb, Mn, Co, Ni and Zn. The applied techniques were consistent in that dry deposition would accountfor the throughfall fluxes of NO3 -, Cl-,Cu and Zn. Potassium and Mn would derive mostly from leaching and their fluxes were strongly related with the holm oak flower growth. ForMg2+ and SO4 2- either leaching or impaction of small particles or gases (for SO4 2-) could account forthe recovered fluxes. Also for Na+ and Ca2+ the experiments did not produce conclusive results. Ammonium, F, Pb,Co, and Na were under the detection limit of analyticaltechniques in the plate-wash. The exposed site presented higherleaf-wash and plate-wash fluxes for all elements. This wasattributed to its higher exposure to pollutants, and forleaching-derived elements, to its higher site fertility.  相似文献   

10.
The contribution of atmospheric acids to cation leaching from a podzolic soil under mature maple-birch forest in central Ontario was examined during 1983. The movement of base cations was associated largely with NO3 ?, SO4 2? and organic acid anions in surface soil horizons, with SO4 2? and NO3 ? below the effective rooting zone, and SO4 2? and HCO3 ? in streamflow. Mineral soil horizons could adsorb little additional SO4 2? or associated cations at current soil solution SO4 2? concentrations. Therefore it is concluded that the soil in situ lacks a strong affinity for SO4 2?. Current annual inputs to the forest of SO4 2? and NO3 ? in bulk precipitation (26.4 and 18.2 kg ha?1, equivalent to 8.8 kg S and 4.1 kg N ha?1 , respectively) contributed significantly to cation leaching from the soil. In order to maintain exchangeable cations in soil at current levels, a rate of weathering yielding 29.6, 5.0, 4.4 and 2.2 kg ha?1 yr?1 of Ca2+, Na+, Mg2+ and K+, respectively, would be required.  相似文献   

11.
Temporal changes in major solute concentrations in six Czech Republic lakes were monitored during the period 1984–1995. Four chronically-acidic lakes had decreasing concentrations of strong-acid anions (CSA = SO4 2- + NO3 - + Cl-), at rates of 3.0 to 9.0 μeq L-1 yr-1. Decreases in SO4 2-, NO3 -, and Cl- (at rates up to 5.1 μeq L-1 yr-1, 3.2 μeq L-1 yr-1, and 0.6 μeq L-1 yr-1, respectively) occurred. The response to the decrease in deposition of S was rapid and annual decline of SO4 2- in lake water was directly proportional to SO4 2- concentrations in the acidified lakes. Changes in NO3 - concentrations were modified by biological consumption within the lakes. The decline in CSA was accompanied in the four most acidic lakes by decreases in AlT, increases in pH at rates of 0.011 to 0.016 pH yr- 1, and decreases of Ca2+ and Mg2+ (but not Na+) in three lakes. The acid neutralizing capacity (ANC) increased significantly in all six lakes. Increases in base cation concentrations (CB = Ca2+ + Na+ + Mg2+ + K+) were the principal contributing factor to ANC increases in the two lakes with positive ANC, whereas decrease in CSA was the major factor in ANC increases in the four chronically-acidic lakes. The continued chemical recovery of these lakes depends on the uncertain trends in N deposition, the cycling of N in the lakes and their catchments, and the magnitude of the future decrease in S deposition.  相似文献   

12.
Precipitation chemistry and atmospheric element-deposition in an agroecosystem at the North-Sea Coast of Schleswig-Holstein The objective of this study was to examine the chemistry of bulk precipitation and atmospheric element inputs in an arable soil near the North Sea coast of Schleswig-Holstein, North Germany. Bulk precipitation was collected at weekly intervals from November 1989 to October 1991. Precipitation amount, pH, electrical conductivity, and concentrations of Na+, K+, NH4+, Mg2+, Ca2+, Cl?, NO3?, and SO42? were recorded. The average volume-weighted pH was 5.5 and the average EC was 92 μS cm?1. Sodium and Cl? were with 64% and 76% the dominant ions (equivalent concentration) in bulk precipitation indicating the influence of the North Sea. The contribution of marine alkalinity to neutralization reactions of bulk precipitation was negligible (1%). The neutralizing substances NH3 (63%) and Carbonate (36%) were more important. Deposition rates were in 1990 and 1991 97.0 and 51.7 kg Na+ ha?1, 6.2 and 4.0 kg K+ ha?1, 15.0 and 8.4 kg Mg2+ ha?1, 13.2 and 10.4 kg Ca2+ ha?1, 12.3 and 9.5 kg NH4+-N ha?1, 8.0 and 5.9 kg NO3?-N ha?1, 168 and 83.1 kg Cl? ha?1 and 19.1 and 12.7 kg SO42?-S ha?1. In 1990 both more westerly winds and stronger wind-forces occurred than in 1991 and resulted in higher inputs of marine origin. Calculated on Cl? basis 93% of Na+, 55% of K+, 74% of Mg2+, 24% of Ca2+, and 36% of SO42? were of marine origin. Atmospheric input of marine origin supplied 39–72% of Mg and 21–37% of S requirement for crop production. The North Sea is an important source providing significant amounts of these elements to agricultural crops.  相似文献   

13.
The leaching of Ca, Mg, and K from canopies is a major pathway of these cations into forest soils. Our aim was to quantify rates of canopy leaching and to identify driving factors at the regional scale using annual fluxes of bulk precipitation and throughfall from 37 coniferous and deciduous forests of North and Central Europe. Total deposition of Ca, Mg, K, and H+ was estimated with Na as an index cation. The median canopy leaching increased in the order: Mg (0.11 kmolc ha–1 a–1) < Ca (0.31 kmolc ha–1 a–1) < K (0.39 kmolc ha–1 a–1). Canopy leaching of Ca and K was positively correlated with the calculated total H+ deposition and H+ buffered in the canopy, whereas canopy leaching of Mg was not. With contrasting effects, fluxes of SO4‐S and NH4‐N in throughfall explained to 64 % (P<0.001) of the Ca canopy leaching. Fluxes of NH4‐N and Ca were negatively correlated, suggesting that buffering of H+ by NH3 deposition reduced canopy leaching of Ca. Amount of bulk precipitation and SO4‐S in throughfall were identified as much weaker driving factors for canopy leaching of K (r2=0.28, P<0.01). Our results show that Ca is the dominant cation in buffering the H+ input in the canopy. At the regional and annual scale, canopy leaching of Mg appears to be unaffected by H+ deposition and H+ buffering in the canopy.  相似文献   

14.
Piirainen  S.  Finér  L.  Starr  M. 《Water, air, and soil pollution》1998,105(1-2):165-174
Nitrogen deposition, leaching, and retention were monitored in a mature spruce (Picea abies Karsten) dominated mixed boreal forest in eastern Finland. Bulk precipitation, throughfall, stemflow, and percolation through the podzolic soil profile were monitored from 1993 to 1996. Mean annual bulk deposition of total N was 3.83 kg ha-1, of which 33% was NH4 +, 26% was NO3 - , and 41% was organic N. Throughfall+stemflow flux of total N was 2.93 kg ha-1 yr-1. Sixty-four % of NH4 + and 38% of NO3 - in bulk precipitation was retained by tre three canopy. Organic N was released (0.27 kg ha-1 yr-1) from the tree canopy. Nitrate-N was retained and organic N was leached as the water passed through the ground vegetation and soil O-horizon. Ammonium-N and organic N were retained mainly in the E-horizon. The output of total N from the E-horizon was only 5% of the total N deposition in the forest stand during the study period and it was mainly as organic N. The output of inorganic N forms from under B-horizon was seasonal and occurred mainly at spring snowmelt.  相似文献   

15.
The atmospheric deposition of air pollutants at a forest edge was studied by means of monitoring canopy throughfall at the edge and at five different parallel lines in the forest behind the edge. The investigation was carried out at a pine forest on the Swedish west coast. Throughfall and bulk deposition samples were analyzed for volume, SO 4 2? , NO 3 ? , Cl?, NH 4 + , Na+, K+, Mg2+, Ca2+, and for pH. The results show that the throughfall flow at the edge was increased substantially for most ions. The ratios in throughfall flows between the edge and the line 50 m into the forest were for SO 4 2? , 1.5, NO 3 ? 2.9, NH 4 + 2.7, and Na+ 3.1. Since this effect is not only valid for forest edges but also for hillsides, hilltops, and edges between stands of different age, etc., there might be substantial areas which get much larger total deposition than the normally considered closed forest.  相似文献   

16.
The increasing demand for fertilizers and the fact that the world reserves of phosphorus (P) and potassium (K) are depletable make appropriate soil management a critical factor in agriculture. Techniques for the fertilizer use and soil acidity corrective are becoming increasingly necessary to minimize the cost of yield and increase the nutrient efficiency. In view of the aforementioned, the present study aimed to assess the effects of gypsum application on the leaching of cations in the soil profile. A completely randomized design in a 5 × 4 factorial arrangement, with five replicates, was used. The treatments corresponded to five gypsum rates (0, 1, 2, 4, and 8 magnesium (Mg) ha?1) applied on broadcast of soil and at four depth sampled (0–5, 6–10, 11–15, and 16–20 cm). Gypsum application increased the fertility in depth, with the leaching of cations. There was an increase in soil pH, exchangeable K+ and calcium (Ca2+), sulfur (S–SO42?), P, boron (B), and manganese (Mn) concentration, cation exchange capacity (CEC), K+ and Ca2+ saturation, Ca2+/Mg2+, Ca2+/K+, and K+/(Ca2+ + Mg2+) ratios, and electrical conductivity in soil depth. On the other hand, there was a decrease in exchangeable Mg2+ and potential acidity hydrogen and aluminum (H+ Al3+), available silicon (Si), Mg2+ saturation, and Ca2+/K+ and Mg2+/K+ ratio. These results demonstrate that the gypsum application in an Oxisol with 690 g kg?1 of clay improves the root system with a significant increase in the soil fertility in the profile.  相似文献   

17.
To evaluate ecosystem response to changing atmospheric deposition, element budgets were established over the period from 1973 to 1991 for a Norway Spruce (Picea abies (L.) Karst.) site. Budgets for Na+, Cl?, Ca2+, Mg2+, N, S and H+ were based on total deposition and seepage water fluxes. The deposition of Ca2+, Mg2+, particularly, of S and H+ decreased with time, while calculated N deposition remained constant at a high level. The decrease in Ca2+ deposition led to a reduction of Ca2+ fluxes with seepage water. The decrease of Mg2+ deposition did not have an effect on the output fluxes of Mg2+. The reversibility of soil and seepage water acidification by reduced S deposition was delayed by the release of previously accumulated soil SO 4 2? . The highest NO 3 ? fluxes were observed during the period of 1986 to 1988; NO 3 ? fluxes in general demonstrated a considerable annual and periodic variation. Total N accumulation in the ecosystem amounted to nearly 590 kg ha?1 yr?1 during the observation period. The major sink of N in the spruce site is the aggrading humus layer. The results emphasize the need for measurements over several years to make conclusions regarding the function of ecosystems in response to atmospheric deposition.  相似文献   

18.
A model deciduous forest soil (Schaffenaker loamy sand) was treated for 8 mo in the greenhouse in 25 cm reconstructed columns with simulated throughfall at pH 6.0 or 4.0, and SO4 2? levels of 12.8 or 24.8 mg L?1. Red oak seedlings grown in the microcosms showed no growth or foliar element response to the treatments. Sulfate loading had a greater impact on soil and leachate chemistry than pH. Higher available soil P in the A, horizon was associated with the pH 6.0 and high SO4 2?2 treatment combination. High SO4 2? loading also reduced exchangeable K+ in the A1?. Other soil horizons were unaffected by either treatment. Leachate chemistry was not significantly altered by througfall pH, but significantly greater export of Na+, Ca2+, Mg2+, Al3+, and NO3 ?, and lower SO4 2? loss, occurred with low SO4 ? input. Comparatively half as much NO3 ? loss was associated with high SO4 2? deposition. The high rate of NO3 ? leaching appeared responsible for greater equivalent mass loss of cations from the low SO4 2? treatment. Leachate removal of SO4 2? approximated input after 8 mo. The capacity of this soil to adsorb SO4 2? appeared relatively limited in the absence of normal element cycling. The sulfate component of simulated deciduous forest throughfall was shown to have a potentially greater impact than pH on ion leaching from forest soil. Additional consideration of the role of SO2? 4 deposition, in the context of throughfall rather than incident precipitation, is warranted in studies of acidic deposition effects on internal forest soil processes.  相似文献   

19.
[目的]通过对滨海地区盐碱土水盐动态变化规律的研究,为该地区的土壤利用以及植树造林提供科学依据。[方法]以天津大港地区刺槐林土壤为研究对象,研究不同土层的土壤水盐年份变化和盐分离子分布特征。[结果]试验地土壤全年含水量变化范围在11.9%~28.8%;含盐量变化范围在4.2%~18.4%。春(3—5月)秋(9—11月)季节土壤含水量低,含盐量高,土壤盐分含量随土层深度增加逐渐降低;夏季(6—8月),土壤含水量高,含盐量低,土壤盐分含量随土层深度的增加逐渐升高。pH值在7.37~8.39之间,土壤中K+,Na+,Ca2+,Mg2+和Cl-春季表层土壤(0—10cm)含量最高,分别为0.04,4.27,2.69,1.04和10.03g/kg。除SO2-4和HCO-3外,其他盐分离子在春季变异系数(29.99~162.98)明显大于夏秋季节(2.87~88.13)。[结论]不同土层的土壤含水量和含盐量随当地降雨量呈明显的季节性变化;试验地区土壤属于碱性土壤,随季节变化不明显;K+,Na+,Ca2+,Mg2+和Cl-与含盐量变化趋势保持一致,SO2-4和HCO-3随季节变化没有明显的规律性;春季各盐分离子在土壤中分布极为不均。  相似文献   

20.
Year-to-year variation in acidic deposition within a mature sugar maple-dominated forest and in leaching of ions from the associated podzolic soil were examined at the Turkey Lakes Watershed between 1981 and 1986. Below-canopy inputs to the soil of SO4 2? and NO3 ? in throughfall averaged 640 and 295 eq. ha?1 yr?1; the corresponding ranges were 493–917 and 261–443 eq. ha?1 yr?1. The contribution of atmospheric deposition to SO4 2? NO3 ? and Ca2+ leaching decreased over the six years. During the study period, the mean annual volume-weighted NO3 ? concentration decreased in throughfall and forest-floor percolate and increased in the mineral-soil solution collected below the effective rooting zone. A substantial shift in the balance between SO4 2? and NO3 ?leaching from the mineral soil was observed; leaching of SO4 2?decreased and NO3 ? leaching increased with time. Leaching of Ca2+ and Mg2+ from the soil was increased as a result of excess NO3 ? production in the soil. The calculated output of NO3 ? from the soil, which averaged 1505 eq. ha?1 yr?1, considerably exceeded the atmospheric deposition of NO3 ?, whereas SO4 2? outputs were only moderately greater than inputs.  相似文献   

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