共查询到20条相似文献，搜索用时 257 毫秒
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厚芯竹帘胶合板制备的研究 总被引：1，自引：0，他引：1
将毛竹径向剖分加工成保持竹壁原有厚度和削度的等厚竹片，侧立串合成厚芯板，与竹帘（席）组坯压制成一种厚芯竹帘胶合板，有利于提高竹材利用率和降低胶粘剂使用量。试验结果表明：厚芯竹帘胶合板的物理力学性能达到ＪＧ／Ｔ３０２６—１９９５竹胶合板模板标准的要求。 相似文献
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为降低胶合板模板用胶黏剂成本,提高企业经济效益,以尿素与苯酚摩尔比为试验因素,进行了苯酚-尿素-甲醛共聚树脂(PUF树脂)合成试验。在PUF树脂胶合板检测结果的基础上,对不同摩尔比PUF树脂的胶合与耐水性能进行评价与优化,并通过PY-TRACE1310 ISQ裂解-气/质联用仪与Netzsch STA449F3综合热分析仪等现代仪器对PUF树脂各阶段产物和热学特性进行分析。研究发现当尿素与苯酚的摩尔比增大到0.5时,PUF树脂的胶合与耐水性能仍可达到Ⅰ类胶合板国家标准,超过0.5以后,产品的胶合强度与耐水性则有较大幅度下降。结果表明,在该试验特定条件下,尿素与苯酚的摩尔比为0.5是可行的,产品具有良好的胶合与耐水性能,较PF树脂生产成本降低了23%,具有良好的生产应用前景。 相似文献
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韩健 《中南林业科技大学学报(自然科学版)》2006,26(5):74-78
以竹胶合板用酚醛树脂合成工艺为基础,按不同的尿素与苯酚摩尔比．合成一系列苯酚-尿素-甲醛共聚型树脂胶粘剂(PUF),并用该系列胶粘剂压制竹帘胶合板．通过对竹帘胶合板进行性能检测和检测结果分析,表明随尿素与苯酚摩尔比的增加,竹帘胶合板的力学性能总体呈下降趋势,但对静曲强度、弹性模量和冲击强度的影响不显著,对保存强度有很大的影响,将尿素与苯酚的摩尔比控耐在0．5以下时,产品可以达到国家相关标准的要求． 相似文献
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本文针对竹碎料混凝土模板易霉变的缺陷，采用线性回归分析法探讨了板材防霉性能与其密度的关系，同时采用五种防霉剂对竹碎料进行降糖防霉处理试验。结果表明，板材密度与防霉性能呈显著线性正相关，自制NPFB防霉剂效果理想，压制的防霉竹碎料混凝土模板物理力学性能达到JG／T3026—1995建筑工业竹胶合板模板行业标准。 相似文献
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三聚氰胺脲醛树脂改性酚醛树脂胶粘剂的研究 总被引：2，自引：0，他引：2
采用常规合成的脲醛(UF)或酚醛(PF)树脂胶对多层胶合板贴面时，很容易出现开胶或透胶现象。本研究采用三聚氰胺脲醛(MUF)树脂对PF树脂进行改性，生产浅色改性PF胶粘剂，探讨了MUF与PF树脂摩尔比、混合比、热压条件等对胶液的粘度、缩合度、稳定性、胶层颜色及胶合质量的影响。结果表明，改性后的浅色酚醛树脂胶粘剂筘存性好、固化后胶层近似木材本色、高强耐水、耐候，用来压制的多层实木复合地板可达到GB9846．1～12-88Ⅰ类胶合板要求。 相似文献
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杨海兵甘卫星潘礼成张一甫韦宝善 《林产工业》2015,(7):29-33
以麦芽糖、三聚氰胺和甲醛为主要原料在碱性条件下合成麦芽糖-三聚氰胺-甲醛共缩聚树脂（MMF树脂）,对MMF树脂合成工艺进行探讨并研究了麦芽糖与三聚氰胺的摩尔比（M_（mal）/M_（mel））对MMF树脂的储存稳定性、胶合强度、分子结构以及分子量的影响。结果表明：MMF树脂优化合成工艺的缩聚温度为88~90℃、pH值为9.0~9.5、麦芽糖与三聚氰胺的摩尔比（M_（mal）/M_（mel））为0.1~0.3;MMF树脂的储存期比MF树脂的储存期延长20d左右;当麦芽糖与三聚氰胺的摩尔比低于0.3时,胶合板强度达到国家标准Ⅰ类胶合板要求;FT-IR表明MMF树脂分子结构连接方式主要以醚键和亚甲基键为主;GPC表明MMF树脂数均分子量为1600~1750。 相似文献
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用H2O2做固化促进剂改进酚醛刨花板性能 总被引：1，自引：1，他引：0
采用H2O2（双氧水）作为促进树脂固化加速剂可缩短刨花板热压时间．本试验探讨用H2O2做固化促进剂来改进酚醛刨花板性能的可能性。结果表明，该方法可以改善酚醛树脂的固化程度，从而提高刨花板的主要物理力学性能。 相似文献
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Influence of the melamine content in melamine-urea-formaldehyde resins on formaldehyde emission and cured resin structure 总被引：6，自引：0，他引：6
The effect of melamine content in melamine-urea-formaldehyde (MUF) resins on the formaldehyde emission and resin structure was investigated using six MUF resins synthesized with different F/(M + U) and M/U molar ratios. The formaldehyde emission from the plywood decreased as the F/(M + U) molar ratio decreased and the M/ U molar ratio increased. In addition, the bond performance was enhanced as the M/U molar ratio increased in the MUF resins with a fixed F/(M + U) molar ratio. Quantitative solution13C-NMR spectra of MUF resins revealed that the MUF resins with a high melamine content consisted of more highly branched crosslinkage structure and free melamine compared to the resins with low melamine contents. Furthermore, solid-state13C CP-MAS NMR spectra of cured MUF resins proved that more methylol groups, dimethylene ether, and branched methylene structures were present in the MUF resins with a higher F/(M + U) molar ratio, leading to increased bond strength and formaldehyde emission. There is no significant difference in the linkage structure of the cured resins with the same F/(M + U) and different M/U molar ratios except the ratios of carbonyl carbon of urea and triazine carbon of melamine. Therefore, the lower formaldehyde emission from cured MUF resins with a higher M/U molar ratio might be ascribed to the stronger linkages between triazine carbons of melamine than those of urea carbons. Consequently, the melamine contributed to strong crosslinking linkages in the cured resin structures, leading to lower formaldehyde emission and better bond performance.Part of this work was presented at the 48th Annual Meeting of the Japan Wood Research Society, Shizuoka, April 1998 相似文献
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《Wood material science & engineering》2013,8(2):168-177
AbstractLignin was extracted from some underutilized plant materials using soda–anthraquinone and soda–anthraquinone–ethanol pulping chemicals. Soda–anthraquinone–ethanol gave higher lignin yield, ranging from 44.47% to 50.41% versus 39.40% to 47.92% of soda-anthraquinone. The isolated lignin was used as a partial substitution for phenol in preparation of lignin-phenol-formaldehyde. The free formaldehyde of the resins ranges from 0.25% to 0.67% versus 1.23% of phenol-formaldehyde (PF) resin used as control. The bonding effectiveness of the resin was evaluated when used as glue for board preparation. The density of the board ranges from 333.54 Kg/m3 to 363.84 Kg/m3. The result revealed that Musa sapientum-, Musa parasidiaca- and Tithonia diversifolia- soda–anthraquinone-derived resins, and soda-anthraquinone–ethanol-derived resin of M. parasidiaca and T. diversifolia had boards with better modulus of rupture (MOR) and modulus of elasticity (MOE) than the board obtained using PF resin. 相似文献
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按酚醛(PF)树脂的制备工艺,采用CaO和NaOH为复合催化剂,在碱性条件下制备了95%～200%的系列尿素改性酚醛(PUF)树脂,贮存期达30 d以上。该系列PUF树脂压制的杨木三合板,胶合强度符合Ⅱ类胶合板要求,甲醛释放量<0.5 mg/L,符合E0级。其中选用尿素/苯酚(U/P)质量比为1.5∶1,甲醛与尿素-苯酚(F/(U+P))物质的量的比值为0.97的配方制胶,结合13C NMR分析手段,监控投料甲醛在反应过程中形成的亚甲基、羟甲基和亚甲基醚键的含量变化,以及最终PUF树脂的亚甲基(32.4%)、羟甲基(57%)和亚甲基醚键(10%)的结构比例。 相似文献
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磷添加对南亚热带森林土壤有机碳氮矿化影响的培养实验研究 总被引：1，自引：0，他引：1
采用室内培养的方法,分析了磷添加对南亚热带鼎湖山马尾松林（PMF）、针阔叶混交林（PBMF）和季风常绿阔叶林（MEBF）土壤（0～10cm）CO小CH4排放／吸收和有机氮矿化的影响。结果表明：28周的培养,100mg磷添加处理土壤C—CO2累积排放量依次为PMF、PBMF和MEBF对照的82．4％、84．4％和102．8％,2000mg磷处理土壤依次为其对照的107．2％、101．2％和109．1％;100mg磷处理土壤CH4累积排放量依次为其对照的69．9％、102．7％和66．3％,2000mg磷处理土壤依次为其对照的-57．4％、25．3％和22．4％,其中,磷在处理初期较一致的提高土壤CO2和CH4排放,磷对土壤有机碳矿化的影响与森林的土壤状况有关,添加的磷浓度越高,其促进作用越强。1周的培养,100mg磷处理土壤有效氮净矿化量依次比PMF、PBMF和MEBF对照少37．06％、39．60％和28．62％,2000mg磷处理土壤依次比其对照少70．97％、84．14％和187．97％,100mg磷处理土壤硝态氮净矿化量依次比其对照少48．06％、40．45％和28．03％,2000mg磷处理土壤依次比其对照少254．09％、115．32％和238．50％,磷显著的抑制土壤有机氮的矿化和硝化。结果建议,在研究P对土壤有机碳氮矿化过程时应充分考虑土壤对P的吸附作用。 相似文献
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以脱脂大豆粉为原料制备大豆蛋白基胶黏剂(豆胶,S),以普通甲醛制备的酚醛树脂(PF_1)和高浓度甲醛制备的酚醛树脂(PF_2)为交联剂,使用前将两者直接混合得酚醛树脂改性豆胶(PF_1/S、PF_2/S)。利用差示扫描量热(DSC)、红外光谱(FT-IR)、动态热机械性能(DMA)和核磁共振碳谱(~(13) C NMR)分析对产品性能进行了测试与表征。结果表明:等物质的量之比条件下,高浓度甲醛较之普通甲醛制备的酚醛树脂改性豆胶胶合板干、湿剪切强度分别提高4.3%和11.6%,并且强度稳定性好;动态DSC分析表明,PF_2可以降低豆胶体系的固化温度和活化能,与豆胶的交联反应较容易;~(13) C NMR分析表明,PF_2体系羟甲基达88.73%,明显高于PF_1的80.91%;FT-IR分析证实酚醛树脂与豆胶中的氨基发生反应,并且PF_2反应效率更高;DMA分析表明,PF_2/S能够改善胶合产品的力学性能和热稳定性,降低豆胶的固化反应起始温度,提高固化反应速率。 相似文献
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The search for new value-added uses for oilseed and animal proteins led us to develop protein-based wood adhesives. Low-fat
soy and peanut flours and blood meal were hydrolyzed in an alkaline state, and PF-cross-linked protein resins were formulated
by reacting the protein hydrolyzates with phenol-formaldehyde (PF) in solid-tosolid ratios ranging from 70% to 50% hydrolyzates
and 30% to 50% PF. Physical properties of medium density fiberboard (MDF) bonded with protein-based phenolic resins were compared
to those of boards bonded with ureaformaldehyde (UF) and PF resins, and flakeboard bonded with soy protein-based phenolic
resin was compared to PF-bonded board. As MDF binders, adhesive properties of protein-based phenolic resins depended upon
protein content of proteinacious materials. MDF board bonded with blood-based phenolic resin was comparable to PF-bonded board
and met the requirements for exterior MDF. Boards bonded with soy-protein-based phenolic resin met requirements for interior
MDF, while peanut-based phenolic failed to meet some of the requirements. Flakeboard bonded with soy-protein-based phenolic
resins was inferior to PF-bonded board but outperformed PF-bonded board in accelerated aging tests. Although they exhibit
a slow curing rate, the cost effectiveness and superior dimensional stability of protein-based phenolic resins may make them
attractive for some uses. 相似文献
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