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1.
Mei Huang Dongdan Cai Yanhua Liu Jun Sun Jianjun Wang Chuanxiang Qin Lixing Dai Yamaura Kazuo 《Fibers and Polymers》2012,13(8):955-962
The hydrogels of atactic poly (vinyl alcohol) (a-PVA) and syndiotactic poly (vinyl alcohol) (s-PVA) with different blend ratios were prepared by freezing-thawing processes. The effect of s-PVA on gelation behavior of the blend was investigated in terms of gelation temperature (T gel) and hydrogel melting temperature (T gm). And swelling behavior, crystallization, thermal properties, morphology of the blend hydrogels were also studied. With the increase of s-PVA, T gel of the blend solution and T gm of the blend hydrogels increase. Both crystallinity and crystallite dimensions based on the XRD profiles are nearly monotonically increasing functions of s-PVA content. FTIR results indicate the number of hydrogen bonds raises with s-PVA increasing. DSC results demonstrate s-PVA favors improvement of hydrogels thermal stability. According to SEM images of hydrogels, the increase of cross-linking caused by s-PVA in the blend hydrogels results in denser structure, which in turn leads to increased gel fraction (G) and Hardness. 50/50 (a-PVA/s-PVA) blend hydrogel has a denser structure with EWC of 73.6 %, hardness of 22.8 HA and T m of 236.15 °C. The result indicates blending a-PVA and s-PVA is a useful method to form the hydrogel having good thermal stability and relative high degree of swelling. 相似文献
2.
To synthesize a series of novel temperature sensitive hydrogels, N-tert-butylacrylamide (NtBA) and acrylamide (AAm) were used as the comonomers and polymerized by free-radical crosslinking copolymerizarion. The poly(ethylene glycol) (PEG) with molecular weight of 400, 4000 and 6000 g·mol-1 was used as the porogen. The equilibrium swelling capacity, swelling/deswelling kinetics and diffusion parameters of obtained hydrogels were systematically evaluated. As revealed by SEM micrographs, the macroporous structure of hydrogels can be modulated by the crosslinking level, PEG molecular weight and dosage. FTIR analysis demonstrated that the porogen PEG was completely leached out of the gel matrix. Compared with the conventional hydrogels, the PEG-modified (PGel) hydrogels exhibited enhanced temperature sensitivity and superior kinetics during the swelling, deswelling and pulsatile swelling processes. Controlled release of salicylic acid also demonstrated the good usability of PGel hydrogel, which rendered it great potential for controlled drug delivery systems. 相似文献
3.
Erdener Karadağ Zehra Deniz Kasim Semiha Kundakcı Ömer Barış Üzüm 《Fibers and Polymers》2017,18(1):9-21
In this report, it was to investigate that the swelling and dye sorption properties of a series of novel hybrid composite hydrogel sorbent systems containing polysaccharide/clay polyelectrolyte based on acrylamide/potassium 3-sulfopropyl methacrylate and sodium alginate, and clay such as bentonite were synthesized with free radical solution polymerization by using ammonium persulfate/N,N,N’,N’-tetramethylethylenediamine as redox initiating pair in presence of poly(ethylene glycol) diacrylate as a crosslinker. Swelling experiments were performed in water at 25 °C, gravimetrically. The hydrogels, the semi-interpenetrating polymer networks, and the hybrid composite hydrogel systems that synthesized in this study have showed high water absorbency. Some swelling and diffusion properties were calculated, and they were discussed for the hybrid hydrogel systems prepared under various formulations. The equilibrium percentage swelling degree of highly swollen hybrid composite hydrogel systems ranges are 718-2055 %. FT-IR analysis and SEM technique were applied for characterization. For sorption of water-soluble cationic dye such as lauths violet into the hydrogel systems was studied by batch sorption technique at 25 °C. For equilibrium sorption studies, dye sorption percentage, dye uptake performance, and partition coefficient of the hydrogel systems have been investigated. The values of dye sorption percentage of the hydrogels were changed among 87.11-96.39 %. Consequently, the hydrogel systems developed in this study could serve as a potential device for water and dye sorbent. 相似文献
4.
Hydrogels, possessing high biocompatibility and adaptability to biological tissue, show great usability in medical applications. In this research, a series of novel cross-linked chitosan quaternary ammonium salt loading with gentamicin sulfate (CTMCSG) hydrogel films with different cross-linking degrees were successfully obtained by the reaction of chitosan quaternary ammonium salt (TMCS) and epichlorohydrin. Fourier transform infrared spectroscopy (FTIR), thermal analysis, and scanning electron microscope (SEM) were used to characterize the chemical structure and surface morphology of CTMCSG hydrogel films. The physicochemical property, gentamicin sulphate release behavior, cytotoxicity, and antibacterial activity of the CTMCSG against Escherichia coli and Staphylococcus aureus were determined. Experimental results demonstrated that CTMCSG hydrogel films exhibited good water stability, thermal stability, drug release capacity, as well as antibacterial property. The inhibition zone of CTMCSG hydrogel films against Escherichia coli and Staphylococcus aureus could be up to about 30 mm. Specifically, the increases in maximum decomposition temperature, mechanical property, water content, swelling degree, and a reduction in water vapor permeability of the hydrogel films were observed as the amount of the cross-linking agent increased. The results indicated that the CTMCSG-4 hydrogel film with an interesting physicochemical property, admirable antibacterial activity, and slight cytotoxicity showed the potential value as excellent antibacterial wound dressing. 相似文献
5.
Fabricating a hydrogel with high strength and toughness is still a challenge in many fields. Here, we prepared gliadin-based hydrogels by chemical cross-linking gliadin in acetic acid solution (GS) with glutaraldehyde (GA). Subsequently, the overall properties of the fabricated hydrogels were systematically investigated in terms of their mechanical properties, swelling ratio, weight loss, thermal stability, and the chemical/physical interactions in hydrogels. Results showed that the gliadin-based chemically cross-linked hydrogels exhibited excellent mechanical properties. The optimized hydrogel exhibited the compressive stress of 1.8 MPa at a strain of 70%, and an excellent self-recovery property after 30 cycles of loading-unloading treatments. The strength and toughness of the hydrogels could be tailored by adjusting the ratio of GS/GA. The chemical cross-linking (aldehyde-ammonia reaction) was the main molecular interaction in the hydrogels, including single-/multi-site crosslinking, and the hydrogen bond was the only physical cross-linking in the hydrogels. Moreover, the swelling ratio of the fabricated hydrogels performed a concentration negative-dependency in GA or GS concentration. And a higher GS concentration (40%) with an appropriate GA content (3.0%) could resist the degradation of hydrogels. In addition, the thermodynamic properties of hydrogels also improved by the GA addition. Overall, these findings suggested that gliadin can be applied for fabricating hydrogels with tunable mechanical properties, which will unlock the high-utilization of gliadin as biopolymer and biocompatible materials. 相似文献
6.
The present study deals with the utilization of psyllium and acrylic acid based hydrogels, synthesized under the influence
of γ-radiations, in sustained delivery of copper sulfate, used as a fungicide in agricultural fields. Swelling behavior of the
synthesized hydrogel was investigated in distilled water as functions of time, temperature, and pH. It was found that the
hydrogel showed maximum of 10,578 % swelling at 25 °C for 24 h. The hydrogel was then checked for its sustained fungicide
release behavior. It was observed that the hydrogel has been found to follow Non-Fickian type mechanism for the fungicide
release. The ‘n’ and ‘k’ have been found to be 0.71 and 7.61×10−3, respectively. 相似文献
7.
Quan Feng Xueqian Wang Anfang Wei Qufu Wei Dayin Hou Wei Luo Xinhua Liu Zongqian Wang 《Fibers and Polymers》2011,12(8):1025-1029
Ployacrylonitrile (PAN) nanofibers were formed by electrospinning. Amidoxime ployacrylonitrile (AOPAN) nanofibers were prepared
by reaction with hydroxylamine hydrochloride, which were used as the matrix for metal ions chelation. FTIR spectra of the
PAN nanofibers and AOPAN nanofibers were recorded for analysis of the surface chemical structures. The AOPAN conventional
fibers were also prepared for comparison, and surface morphologies of the modified PAN conventional fibers and PAN nanofibers
were observed by FESEM. Metal ions concentrations were calculated by AAS. The chelated isothermal process and kinetics parameters
of the modified PAN nanofibers and PAN conventional fibers were studied in this work. Results indicated that the saturated
coordinate capacity of AOPAN nanofibers to Cu2+, Cd2+ was 3.4482 and 4.5408 mmol/g (dry fiber) respectively, nearly two times higher than that of AOPAN conventional fibers. Besides,
the desorption rate of Cu2+ and Cd2+ from metal chelated AOPAN nanofibers was 87 and 92 % respectively in 1 mol/l nitric acid solution for 60 min. The isothermal
processes were found to be in conformity with Langmuir model. 相似文献
8.
Wheat (Triticum aestivum L) and barley (Hordeum vulgare L) are two important cereals cultivated worldwide. The effect of aleurone cell wall structure on water diffusion and distribution within wheat and barley grains was evaluated at different relative humidity levels. Time domain nuclear magnetic resonance was used to measure the transverse relaxation time T2 of grains. Two water states were distinguished within grains, namely W1 (lower mobility) and W2 (higher mobility). Grains with thicker aleurone layer cell walls had a higher W2. The water-absorption and desorption rates were mainly determined by the thickness of the aleurone cell walls and decreased with increasing cell wall thickness. The higher W2 values observed in grains with thicker aleurone cell walls with the a water content of 2.0% (w/w) and 12.1% (w/w) were probably related to a higher water motion within the grains, in response to higher porosity. Arabinoxylan and (1,3)(1,4)-β-glucan alternating multilayer films were prepared, each film had 20 layers, one layer was approximately 1 μm thick. The film was used as a model to simulate the aleurone layers. These results show that cell walls of the aleurone layer regulate the diffusion and distribution of water within grains. 相似文献
9.
滴灌量对冬小麦耗水特性和干物质积累分配的影响 总被引：2，自引：0，他引：2
为给滴灌冬小麦高产栽培的水分管理提供理论依据,在播前足墒和越冬前灌水750 m33·hm-2的条件下分析了起身后不同滴灌量(2550、3150和3750 m3·hm-2,分别用W1、W2、W3表示)对冬小麦耗水及干物质积累、分配的影响.结果表明,随滴灌量的减少,冬小麦孕穗期至花后20 d的0～100 cm土层含水量明显降低,但土壤含水量沿毛管的横向差异增大,总耗水量减少,土壤贮水的消耗量明显增加;群体的叶面积指数和干物质积累量降低,尤其是远离毛管处下降更明显;开花前营养器官贮藏同化物向籽粒的转运量、运转率及对籽粒的贡献率增加,开花后干物质同化量和对籽粒的贡献率显著降低;籽粒产量降低,灌溉水利用效率呈增加趋势.3个处理中,W2的水分利用效率最高,产量与W3差异不显著.在本试验条件下,起身后滴灌冬小麦的适宜灌溉定额为3150～3750 m3·hm2. 相似文献
10.
播种方式和灌水量对春小麦干物质和产量的影响 总被引：1，自引：0，他引：1
为筛选与新疆春小麦匀播技术配套的适宜灌水量,以春小麦品种新春34号为材料,进行二因素盆栽试验,设置匀播(U)和条播(D)2种播种方式,以及W75(拔节水)、W150(拔节水+扬花水)、W225(拔节水+扬花水+灌浆水)和W300(起身水+拔节水+扬花水+灌浆水)4个不同灌溉水平(每次灌水量75mm),研究了播种方式和灌水量对春小麦干物质和产量的影响。结果表明,与常规条播相比,匀播促进了小麦出苗20d后的分蘖,增加了有效分蘖,其中W75、W150、W225和W300条件下,匀播小麦的穗数分别提高25.62%、41.79%、43.39%、46.10%,分蘖成穗率分别提高20.15%、30.15%、30.68%、33.63%;匀播提高了小麦旗叶、倒二叶的SPAD值,延缓了叶片衰老,增强了群体生育后期的光合作用,且匀播方式下增大灌水量更有利于延长小麦叶片的功能期;匀播促进了小麦营养器官干物质的积累及其在花后向籽粒中的转运,有利于产量形成;在W75、W150、W225、W300条件下,匀播小麦产量较条播分别提高2.76%、4.41%、3.77%和3.42%,两种播种方式下W225处理产量均最大。因此,匀播方式下W225灌水模式最有利于春小麦生长发育和高产。 相似文献
11.
Julia Ohmes Lena Marie Saure Fabian Schütt Marie Trenkel Andreas Seekamp Regina Scherließ Rainer Adelung Sabine Fuchs 《Marine drugs》2022,20(6)
Fucoidans, sulfated polysaccharides from brown algae, possess multiple bioactivities in regard to osteogenesis, angiogenesis, and inflammation, all representing key molecular processes for successful bone regeneration. To utilize fucoidans in regenerative medicine, a delivery system is needed which temporarily immobilizes the polysaccharide at the injured site. Hydrogels have become increasingly interesting biomaterials for the support of bone regeneration. Their structural resemblance with the extracellular matrix, their flexible shape, and capacity to deliver bioactive compounds or stem cells into the affected tissue make them promising materials for the support of healing processes. Especially injectable hydrogels stand out due to their minimal invasive application. In the current study, we developed an injectable thermosensitive hydrogel for the delivery of fucoidan based on chitosan, collagen, and β-glycerophosphate (β-GP). Physicochemical parameters such as gelation time, gelation temperature, swelling capacity, pH, and internal microstructure were studied. Further, human bone-derived mesenchymal stem cells (MSC) and human outgrowth endothelial cells (OEC) were cultured on top (2D) or inside the hydrogels (3D) to assess the biocompatibility. We found that the sol-gel transition occurred after approximately 1 min at 37 °C. Fucoidan integration into the hydrogel had no or only a minor impact on the mentioned physicochemical parameters compared to hydrogels which did not contain fucoidan. Release assays showed that 60% and 80% of the fucoidan was released from the hydrogel after two and six days, respectively. The hydrogel was biocompatible with MSC and OEC with a limitation for OEC encapsulation. This study demonstrates the potential of thermosensitive chitosan-collagen hydrogels as a delivery system for fucoidan and MSC for the use in regenerative medicine. 相似文献
12.
为探究水氮运筹对滴灌冬小麦产量和水氮利用效率的效应,于2019—2021年开展了连续2年小麦田间试验,设置2个施氮水平210（N1）和240（N2）kg·hm-2,4个灌水处理W1（不灌水）、W2（每次30 mm）、W3（每次45 mm）、W4（每次60 mm）,分析不同处理小麦产量及水氮利用率相关指标。结果表明,2019—2021年,施氮量和灌水量对冬小麦抽穗期、扬花期和灌浆期叶片净光合速率的影响为极显著（P<0.01）或显著（P<0.05）,且三个生育时期均以N2W4 处理最高,与N1W4和N2W3处理间没有显著差异;三个生育时期的土壤铵态氮和硝态氮含量均以N2W3、N1W4或N2W4处理最低。小麦越冬期、灌浆期和成熟期土壤铵态氮与产量和氮肥偏生产力（NPFP）均呈显著或极显著负相关;抽穗期、灌浆期和成熟期土壤硝态氮与产量和NPFP均呈显著或极显著负相关。2个年度,水氮运筹较对照显著提高了冬小麦的产量和水氮利用效率,产量增幅分别为38.9%~62.0%和40.9%~68.3%,水分利用效率（WUE）增幅分别为8.0%~15.7% 和10.1%~16.4%,NPFP增幅分别为38.9%~62.0%和40.9%~65.5%;冬小麦产量和WUE均以N2W4处理最高,N2W3处理次之,两者间没有显著性差异;但N2W3处理的水分利用效率均显著高于N2W4处理。综上,在本试验条件下,施氮量240 kg·hm-2、每次灌水45 mm（N2W3）为该地区滴灌冬小麦最佳水氮运筹组合,可以实现保障产量和提高水氮利用效率的目标。 相似文献
13.
Cross-linked hydrogels of chitosan/poly(vinyl alcohol) (PVA)/oxidized cellulose nanowhiskers (CNWs) were prepared by using oxidized CNWs as a cross-linker. The effects of the oxidation level of CNWs on the swelling behavior, thermal stability, viscoelastic properties and compressive strength of the hydrogels were studied. Chemical cross-links, hydrogen bonds, as well as nanofiller reinforcement between the three materials played a major role in determining the properties of the hydrogels. Swelling test results showed that the incorporation of oxidized CNWs decreased the water absorbability of the hydrogels due to the increase in cross-linking degree. Viscoelastic properties of the hydrogels with oxidized CNWs was increased by 537 % in storage modulus, from 4.65 kPa to 29.6 kPa. Compressive strength of 181.5 kPa at 50 % strain was observed from the cross-linked hydrogels, compared with 21.2 kPa of the non-cross-linked hydrogels. The thermal experiments showed that the chemical cross-linking slightly increase the resistance toward thermal degradation of the hydrogels. 相似文献
14.
Yasemin Işikver 《Fibers and Polymers》2017,18(11):2070-2078
In this study, anionic hydrogels were prepared using a crosslinker (N,N′-methylenebisacrylamide) through a free radical addition reaction in aqueous solutions of neutral acrylamide or 2-hydroxyethyl methacrylate monomer and anionic monomers, mesaconic acid or aconitic acid. Cationic dyes along with safranine (azine-), nile blue (oxazine-) and methylene blue (thiazine-) were selected as models of pollutants, and adsorption of these dyes onto the hydrogels was investigated. To examine the effect of concentration on adsorption, dye solutions prepared with a concentration range of 5–50 mg l?1 and 0.1 g hydrogel at 25 °C were exposed to the hydrogels until equilibrium was established. Dye adsorption onto the hydrogels was found to be an L type Giles adsorption isotherm. Monolayer sorption capacity and adsorption constant values were calculated from the Langmuir plots. To calculate RL values, a non-dimensional analysis was used and they were always found to be 0<R<1. In other words, the hydrogels were favorable for adsorption of these dyes. Aqueous solutions of dyes were observed to interact with hydrogels in the following order: oxazine > azine > thiazine. Furthermore, the higher the number of carboxyl groups in the hydrogel composition, the higher the adsorbed amount of substance. 相似文献
15.
A new hybrid ionic liquids solvent, 1-allyl-3-methylimidazolium chloride (AMIMCl) and glycine hydrochloride (Gly·HCl) was utilized to dissolve chitosan and fabricate chitosan/cellulose (Cs/Ce) blend films with chitosan proportion varying from 2 to 35 wt.% through solution casting method. FTIR, XRD, TG, SEM and EA were used to evaluate the prepared composites. Besides, the mechanical property and antibacterial activity were also analyzed. The shifting of the characteristic peaks of -NH and C=O for chitosan, similar crystal pattern with low intensity diffraction peaks at 2θ of around 20°, superior thermal stability (increased Tonset) with chitosan ratio below 10 wt.% in the composites suggested that the interactions via hydrogen bonds formed between chitosan and cellulose. Besides, the elemental analysis showed that the actual N% contents from the chitosan in the blend films were roughly equivalent to the theoretical value though the inevitable residue of ionic liquids. Furthermore, the blends not only presented compact structure but also processed high bacterial reduction to E. coli and S. aureus at pH 6.3, which indicated that the Cs/Ce blend films prepared via the Gly·HCl/AMIMCl dissolution method were suitable for production of degradable antibacterial materials. 相似文献
16.
Shaoxiong Si Ruchao Zhou Zuge Xing Hui Xu Yongfu Cai Qiyi Zhang 《Fibers and Polymers》2013,14(6):982-989
Methacrylated gelatin films with in situ-generated TiO2 nanoparticles containing varying weight percentages of gelatin (0 %, 0.5 %, 1 %, 2 % and 4 %) were successfully prepared as novel biomaterials. 1H-NMR spectroscopy confirmed their methacrylation with a 79 % degree of substitution. TiO2 nanoparticles were uniformly distributed in the films with the average particle size increasing from 85 to 130 nm in proportion to an increase in TiO2 concentration from 0.5 to 4 wt%. The water absorption of various gelatin methacrylamide/TiO2 films was in the range of 471–758 %, which was enough to prevent wound beds from exudates accumulation. And in vitro degradation test in PBS showed that the three-dimensional structure of all samples basically remained unchanged although more than or nearly half the mass of specimens decreased after 4 weeks’ degradation, and the pH levels of all sample solutions were maintained in an adequate range of 6.5–7.4 for cell and tissue growth during the whole process. The antibacterial activities of the films against E. coli and S. aureus were measured via a shake flask test and demonstrated good performance after the importation of TiO2 nanoparticles. Cytotoxicity testing revealed that all films had no cytotoxicity and showed favorable adherence in the presence of L929 cells. The results suggest that hybrid hydrogel films hold potential for antibacterial wound dressing and tissue engineering scaffold applications. 相似文献
17.
Xuebin Ma Tingting Xu Wei Chen Rui Wang Zheng Xu Zhiwen Ye Bo Chi 《Fibers and Polymers》2017,18(5):817-824
New applications call for many new requirements. In order to improve the toughness of aldehyde hyaluronic acid (A-HA) and adipic acid dihydrazide (ADH) hydrogel, the poly(ethylene glycol) (PEG) was added. PEG content and molecular weight have little effect on the gelation time, and the composite hydrogels can form in situ within 20 seconds at room temperature. The press test showed that the hydrogels containing PEG possessed a better compression resistance, after pressed more than five times, the composite hydrogels could restore. Rheological properties were measured to evaluate the working ability and the effect of PEG on hydrogels. By analyzing the shear viscosity (η γ=0.01), yield stress (σ 0) and threshold shear stress (σ c ), the addition of PEG can make the structure of composite hydrogels get loose and improve the shear resistance. Especially, PEG800 can enhance the antishear ability obviously. The amplitude sweep tests showed a broad linear viscoelastic region, indicating a wide processing range. In the meanwhile, we also found that PEG can improve the optical transmittance of xerogel evidently. 相似文献
18.
In this study, a kind of hydrogel nanofibers were successfully fabricated via solution blowing of chitosan (CS) and polylactic acid (PLA) solutions mixed with various contents of polyethylene glycol (PEG) to offer hydration. The nanofibers with PEG content varying were average 341-376 nm in diameter with smooth surface and distributed randomly forming three-dimension (3D) mats. Glutaraldehyde (GA) vapor was then applied to impart stability, and the cross-linking reaction mainly occurred between GA and hydroxyl groups which was confirmed by XPS. The hydrogel nanofibers showed quick absorption behavior, high equilibrate water absorption and good air permeability which could help the mats absorbing excess exudates, creating a moist wound healing environment and oxygen exchanging in wound healing. The mats also exhibited good antibacterial activities against E. coil. The combination advantages of nanofibers mats and hydrogel will help it find promising application in wound healing. 相似文献
19.
Jin Sook Kim Hyun Jeong Jeon Kyung Min Lee Jung Nam Im Ji Ho Youk 《Fibers and Polymers》2010,11(2):153-157
Polyacrylonitrile (PAN) nanoparticles were successfully prepared by dispersion polymerization of acrylonitrile (AN) in water
using 10 and 20 wt% of the poly(ethylene oxide)-b-PAN macromolecular RAFT (PEO-b-PAN macro-RAFT) agent (M
n=5,600 g/mol, PDI=1.15). The degrees of polymerization of the PEO and PAN blocks were 113 and 16, respectively. The PAN nanoparticles
had a crumpled spherical appearance and their sizes ranged from 50–80 nm. The degree of crystallinity of the PAN particles
was 23 %. The M
n
values of the PAN nanoparticles prepared with 10 and 20 wt% of the PEO-b-PAN macro-RAFT agent were 33,900 and 25,800 g/mol, respectively. The existence of the PEO block on the surface of the PAN
nanoparticles was confirmed by 1H NMR spectroscopy and XPS. 相似文献
20.
Superabsorbent polymers of carboxymethyl cellulose-graft-itaconic acid were synthesized using potassium persulfate as a free radical initiator in the presence of N,N′-methylene bisacrylamide as a crosslinker using solution polymerization technique. The structures of the grafted copolymers were characterized by FT-IR spectroscopy and thermogravimetric analysis. The effect of reaction variables such as concentration of carboxymethyl cellulose, itaconic acid, initiator, crosslinker, and neutralizing agent were optimized to achieve a hydrogel with high swelling capacity of 74 g/g (DI water) and 18 g/g (0.9 wt% NaCl solution). The swelling kinetics of the prepared SAP were analyzed by applying the Fickian diffusion model and the Schott’s pseudo second order kinetics model. The diffusion exponents in the Fickian model, n, showed values of 0.73-0.93, indicating that chain relaxation behavior during absorption had a large effect on total absorbency. 相似文献