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1.
Summary. The absorption of urea and a number of its derivatives by different soils was investigated using a slurry-type procedure. The materials could be listed in the following order of increasing tendancy to be adsorbed: urea, fenuron, methylurea, phenylurea, monuron, monolinuron, diuron. linuron, neburon and chloroxuron. Both N -aryl and N -alkyl substituents appeared to play a part in adsorption. Increasing chain length in the alkyl substituents and chloro- and chlorophenoxy substitution in the aryl substituent increased adsorption. There was no relationship between adsorption and water solubility.
Organic matter content was the only soil property that could be related to adsorptive capacity. The evidence of Langmuir isothermal equilibrium plots suggests that only a fraction of the total soil surface is available for the adsorption of substituted ureas.
L'adsorption Je l'uré de ses dérivés sur dfférents sols  相似文献   

2.
Rates of degradation of isoproturon, diuron and metsulfuron-methyl were measured in two soils incubated at two temperatures (5 and 25 °C) with soil moisture at a matric potential of ?5 kPa. Rates of change in soil solution concentration were also measured after extraction of water from the soil using a centrifugation technique. The data, in general, indicated a more rapid rate of decline in aqueous-phase concentrations of herbicide than in total soil concentrations, and hence a progressive increase in partition coefficient in favour of the adsorbed phase. In all of the incubations, however, adsorption of the herbicide was initially less than that measured using standard equilibration techniques that involved shaking with large volumes of solution relative to weights of soil. This may be explained by the ready availability of more adsorption sites in the shaken systems. With isoproturon and diuron, the changes in adsorption with time were similar at the two incubation temperatures. This indicates that the apparent changes in adsorption with these two compounds were not caused by preferential degradation in the soil solution, but by a slow equilibration with adsorption sites. The results with the weakly adsorbed compound metsulfuron-methyl, however, suggested the possibility of preferential degradation in the solution phase because, when degradation was slow, the absolute amounts adsorbed remained constant or increased slightly, even although solution concentrations declined. Implications of the results for pesticide behaviour in soils in the field are discussed.  相似文献   

3.
Thiabendazole is strongly adsorbed on soils, and is not readily extracted by conventional solvents. two-phase solvent system consisting of a mixture of aqueous ammonium chloride solution (pH 10), ethanol and chloroform was developed which extracted thiabendazole from a range of soils including high-organic fen peat soils and mushroom compost. Subsequent partition of the extract between organic solvents and acid or alkaline solutions provided sufficient clean-up for assay by ultraviolet or fluorescence spectroscopy, of concentrations of less than 1 mg thiabendazole kg?1 of soil. Investigation of the adsorption of thiabendazole from aqueous solution by soils indicated the importance of both soil organic and mineral matter and the adsorption of both neutral and protonated molecules.  相似文献   

4.
Long-term sorption of diuron and isoproturon by a clay loam soil was investigated for nine weeks at two herbicide doses (0·6 or 3 mg kg−1) and two soil moisture contents (35 or 62% w/w, i.e. 3·16 or 1 kPa) by measuring changes in herbicide concentrations in the soil solution sampled by means of glass microfibre filters in presence of sodium azide (200 mg litre−1) which inhibited biodegradation for more than four weeks. After the first day equilibration period, where adsorption mainly occurred (>70% adsorbed), herbicide concentrations in the soil solution decreased (about 50% for diuron; up to 38% for isoproturon) for two weeks but equilibration required about one month. Small amounts of herbicides were sorbed during this process (<10% of the initial (24-h) adsorption). These were similar for both herbicides, although diuron was initially more adsorbed. Values of the partition coefficients of herbicides between soil and soil solution were increased (75–125% for diuron; 29–67% for isoproturon). High soil moisture enhanced sorption speed for both herbicides and increased final sorption only for diuron. Sodium azide inhibited long-term sorption of the more stable diuron and this effect was reversed by low temperature only at the low soil moisture. Sodium azide action might be complex (competition, effect on soil micro-organisms) and was not elucidated.  相似文献   

5.
Data for the adsorption of ethyl methylphosphonofluoridate from aqueous and the vapour phases onto montmorillonite and kaolinite clays, onto soil organic matter preparations, and onto a limited number of soils are reported. These show that the phosphonofluoridate was absorbed from the vapour phase onto the dry clay preparations by physical-chemical forces but was not adsorbed by the organic soil materials. In a general way adsorption onto dry soils could be related to their clay contents when the organic matter contents were low. Water was found to compete effectively with the phosphonofluoridate for adsorption sites, and it is concluded that this molecule will be most effectively retained by dry soils low in organic matter and rich in clay. Mechanisms for its adsorption onto clays are discussed.  相似文献   

6.
R. GROVER 《Weed Research》1973,13(1):51-58
Summary. The adsorption of acid, n-butyl, and iso-octyl ester forms of 2,4-D (2,4- dichloiophenoxyacetic acid) was studied for several Canadian prairie soils. The k values for the acid ranged from 0·09 to 1·30 and were correlated to the soil organic matter and not to the clay content. The Q , values (μg adsorbed/g of organic matter) for the acid were 7–2±l. The n-butyl and the iso-octyl esters hydrolysed to the acid form in the aqueous medium and this process was accelerated in the presence of the moist soil. Consequently, the k values for the esters, using slurry type adsorption experiments, or their distribution coefficients, using leaching columns, could not be determined. It was concluded that the adsorptive behavior of the two esters in moist soil was similar to that of the acid form.
Comportement des formes actde, et ester du 2,4-D quant à leur adsorption dans tes sols  相似文献   

7.
The adsorption of diuron and isoproturon by a clay loam soil at 35% (3-16 kPa) and 62% (1 kPa) soil moisture content was studied by means of glass microfibre filters capable of sampling soil solution for herbicide analysis. Adsorption was rapid, with 40–80% of the final (24 h) sorption being achieved within 2 min. These equilibria were achieved more rapidly for diuron, which was also the more highly adsorbed. Adsorption of both herbicides was favoured by low soil moisture initially, but was enhanced by higher soil moistures at sorption times greater than 30 min. However, increasing the soil moisture from 31% (10 kPa) to 62% (1 kPa) had little effect on the final soil sorption capacity. Regarding the water status in the soil, it is thought that adsorption took place in small pores (<3 μm). Herbicides diffused rapidly into small pores and adsorption by wet soil was delayed for a short period of time (about 30 min).  相似文献   

8.
Retention by a glass fibre filter of the liquid phase of a clay loam soil treated with 14C-diuron provides a novel method for analysis of the herbicide in soil solution. At 26.3% (w/w) soil moisture content, less than 10% of the applied diuron was found in solution, and this percentage decreased slightly with diuron dose. The herbicide was rapidly adsorbed on soil during the first day, but adsorption continued and the concentration of diuron in solution could be further reduced by 36–50% during the following 6 days. Drying the soil after treatment, with possible crystallization of herbicide applied at high doses, tended to fix the solution concentrations. Ethanol (3% v/v) in soil water favoured herbicide dissolution. Increasing soil moisture to 36.3% (w/w) slightly decreased the concentration of the herbicide in solution, but increased the percentage held in solution. Frost and a drying-rewetting cycle had little or no subsequent effect on diuron concentration in soil solution.  相似文献   

9.
Herbicides are still used to control weeds on hard surfaces, including municipal, private and industrial sites. Used under unfavourable conditions, especially when rain occurs shortly after application, herbicides may run off to surface waters. Such losses of herbicides from hard surfaces are estimated to be much higher than for herbicides used in arable fields. In this study, three kinds of hard surface were evaluated: asphalt, concrete surface and gravel (fine and coarse). Three herbicides were applied: glyphosate, diuron and diflufenican. Adsorption isotherms of diuron and diflufenican to the three surfaces were determined. At different times after treatment with the herbicides, rainfall was simulated by use of a rain-droplet spray nozzle, and the run-off was collected for analysis. After this run-off event, the materials were immersed in water to measure desorption which, together with the compound in the run-off, gave a measure of the dislodgable residues. The apolar herbicides diuron and especially diflufenican adsorbed strongly to asphalt. The polar herbicide glyphosate lost 75% in run-off from asphalt but was adsorbed strongly to soil and concrete pavement.  相似文献   

10.
Summary. A bioassay was used to study, adsorption of prometryne, simazine, linuron and pyrazon by fibrous peat, sphagnum moss, muck soil and bentonite as 1 % mixtures with quartz sand. Of these bentonite caused least reduction in bioactivity, and sphagnum moss reduced it only slightly more. Fibrous peat and muck soil were the most adsorptive. Prometryne, simazine and pyrazon were more highly adsorbed by fibrous peat than by muck soil, while for linuron the opposite occurred. Fibrous peat was approximately three, seven, thirteen and three times more adsorptive than bentonite for pyrazon, linuron, prometryne and simazine, respectively, while for muck soil the corresponding values were two, fourteen, seven and two. Studies with prometryne and five different soils indicated that percentage organic matter, cation-exchange capacity and specific surface area were all highly correlated with adsorption.  相似文献   

11.
The adsorption of glyphosate in a slurry system by 9 soils was correlated with an arbitrary single point inorganic phosphate sorption index which gave a measure of unoccupied phosphate sorption capacity, but not with total phosphate sorption capacity at pH 2.6, the level of iron and aluminium soluble in Tamm's acid oxalate or with clay content, organic matter content or pH. It is concluded that inorganic phosphate excludes glyphosate from sorption sites. The extent of adsorption was higher than, though of the same order as, that of diuron though the two are not related. From consideration of the results of previous experiments with plants grown in culture solution it is suggested that the low phytotoxicity of glyphosate applied to the soil is not due simply to high adsorption. Rather it is the result of a combination of moderate adsorption and the low intrinsic activity of this compound when made available to the root system.  相似文献   

12.
Effect of orgunic matter added to soil on the adsrption of herhicides. Inffneuce of the composition of the organic matter By preliminary fractionation of two organic substrates (a wheat straw and a crushed lucerne hay) we tried to evaluate the adsorption capacity of their constituents (water-soluble and lipidic substances, hemicelluloses, cellulose and lignin) in soil. Terbutryne and diuron have different affinities with the constituents of the substrates. Lignin is more adsorbent than the other constituents. With regard to adsorption, isolated constitucents form heterogeneous and interacting classes. Consequently it is difficult to define the absorption capacity of non-decomposed organic materials on the basis of their composition. Mineralization, by modifying the composition, the variations in adsorptive power of carbon residues resulting from decomposition of the substrates in the soil.  相似文献   

13.
Studies were conducted to investigate the desorption of diuron and isoproturon adsorbed on undispersed clay loam soil, and the influence of residence time in soil on desorption. The soil was treated at 0·6 or 3 mg kg-1, at 70% moisture content and in the presence of sodium azide to prevent degradation. Measurement of herbicide concentrations in soil solution sampled by means of glass microfibre filters showed that adsorption mainly occurred for one day but long-term sorption proceeded for >two weeks. After a one-day or three-week residence time, soil solution was partly replaced (28%). Measurement of concentrations in solution showed rapid desorption, with equilibria being achieved within 1 h (diuron) or a few hours (isoproturon). After 16 successive desorptions done at 30-min or 12-h intervals, equilibration times tended to be longer. For the short residence time, desorption and long-term sorption could occur simultaneously and equilibration might be faster. Residence time had no significant effect on desorption kinetics nor on the small hysteresis observed for diuron. The aging effect, involving long-term sorption only, decreased the proportion of diuron removed from the soil by successive desorptions but, for isoproturon, desorption frequency and desorption kinetics were more important. © 1997 SCI  相似文献   

14.
The surface run-off of a number of pesticides (diuron, isoproturon, atrazine, alachlor, aclonifen, trifluralin, lindane and simazine), chosen for their range of adsorption behaviours, was studied using simulated rainfall applied to small plots over a short time (one hour). Pesticides were applied together onto bare soil using two different sandy loam soils from Jaillière and Coet Dan sites. The surface run-off samples were collected throughout the running of the event and concentrations of pesticides were measured in both liquid and solid phases. Sorption isotherms for isoproturon and diuron on Jaillière soil as well as eroded particles were measured under equilibrium conditions and compared to their partitioning during surface run-off. At the rainfall intensity used, both soils generated a large load of eroded particles. The average run-off flow rate increased with time for the Jalliére soil, while it remained relatively constant at a higher level for the Coet Dan soil. The concentrations of each pesticide in the run-off samples decreased as the experiments proceeded. The pesticides were classified into two types by their partitioning between the solid and liquid phases. Atrazine, simazine, diuron, isoproturon and alachlor were mainly transported in surface run-off water. By contrast, 90% of trifluralin and aclonifen was adsorbed onto eroded particles. Lindane was intermediate, with a 37% adsorption level. When the contribution of eroded particles was minor, the agrochemical concentrations were inversely proportional to the water flow rate. We have proposed a model that describes the mass of chemicals extracted from soil into surface water during a surface run-off event of a given average duration and flow rate. This model takes into account the dilution of the soil solution and the desorption of chemicals through two parameters called, respectively, the dilution factor and the extraction retardation factor. The desorption kinetic was the limiting step in the surface run-off of weakly sorbed chemicals, such as isoproturon. © 1999 Society of Chemical Industry  相似文献   

15.
Summary. The adsorption of simazine from, and subsequent desorption into, 0–01 M calcium chloride solution was investigated using twenty-three Rothamsted soil samples from sites differing greatly in cropping history and manurial treatment. Organic carbon content was the only factor related to the ability of the soils to sorb simazine; this accounted for 90% or more of the variation between soils Equilibrium was attained during adsorption in from fewer than 2 to more than 24 hr. Equilibrium during desorption was only occasionally attained within 24 hr. Differences between theoretically predicted and measured concentrations of simazine in solution following desorption were least for soils that attained equilibrium fastest during adsorption. Differences in adsorption and desorption kinetics between soils could not be related to soil pH, organic carbon content or cropping and manuring history. Comparisons of unlimed and limed soils suggested that no simnazine was lost by acid hydrolysis during the experiments.
Adsorption et désorption de la simazine par quelques sols de Rothamsted  相似文献   

16.
Summary. When columns of three soil types were perfused with a microbial medium containing 5·7 and 26·9 ppm 14COOH-labelled chloramben, there was a rapid decrease in the 14C activity remaining in solution, attributable to soil adsorption. Soil pH and organic matter content were the primary factors controlling chloramben adsorption. Soil pH may enhance adsorption through its effect on the number of soil anion exchange sites, and sites for polyvalent cation bridging and H bonding. Following adsorption, liver decreases in solution 14C-chloramben activity were attributed to degradation; 14CO2 evolved during perfusion amounted to 25–30% of the total decrease in 14C-chloramben from solution. It was concluded that more than 90% of the 14C-activity remaining in solution could be attributed to intact chloramben. Thus, decarboxylation appeared to be the primary mechanism of chloramben degradation in soils. Lag phases observed during degradation and subsequent investigations with re-amended solutions implicated the soil microflora; even at chloramben concentrations of 26.9 ppm no toxic effect on the chloramben-degrading micro-organisms was apparent.
Dégradation du chlorambène [amibène) dans le sol  相似文献   

17.
R. J. HANCE 《Weed Research》1969,9(2):108-113
Summary. Model adsorbents were prepared by treating cellulose phosphate powder with a series of alkyltrimethylammonium compounds in which the size of the alkyl group was varied from C8to C18. The adsorption of linuron, atrazine and EPTC by these materials was found to increase logarithmically with increasing chain length. The extent of the adsorption was large compared with the adsorption of these herbicides by a humic acid and by a preparation made by removing the bulk of the inorganic constituents of a peat soil with a mixture of HCl and HF. Since soil organic matter is thought to contain alkyl groups, it is concluded that the possible influence of such groups should be considered in any discussion of the mechanisms involved in the adsorption of organic molecules by soils.
Adsorption du linuron, de I'atrazine de l'EPTC par des adsorbants de la série aliphatique et des préparations organiques de sol  相似文献   

18.

The behavior in competitive adsorption-desorption reactions of Cu and Zn was studied in four calcareous soils. Cu and Zn were added to the soil by Cu, Zn, and Cu+Zn sulfate solutions in a CaSO4 background. Soil sorption of these cations was described by equilibrium isotherms that fitted either Freundlich- or Langmuir type equations, although Cu desorption data fitted only Freundlich isotherms. Cu and Zn competition was quantified by distribution coefficients, Kd, relating cation distribution between soil and solute and by the competitive Langmuir equation. The competitive Langmuir equation was the better suited to describe the Cu-Zn competitive adsorption in these soils. Distribution coefficients presented lower values when both cations were present, decreasing when the Cu and Zn concentration in solution increased (decreasing soil affinity for these cations), thereby increasing their mobility through the soil. However, the distribution coefficient of specifically adsorbed Cu in equilibrium with cations extracted by a Mg (NO) solution increased with Cu concentration. Cu adsorption was more depres 3 se 2 d by Zn than Zn adsorption by Cu. The different behavior of Cu and Zn seems dependent on the percentage Ca (CO) and, to a lesser degree, on Cu and Zn organic matter complexes, free iro 3 n 2 content, and surface precipitation on oxides and carbonates.  相似文献   

19.
Summary. Some investigations were carried out on the adsorption of paraquat by a range of organic materials which included an organic soil, various humic fractions from that soil, model polymers prepared by the oxidative coupling of benzoquinone, the ion exchange resins Zeo-Karb 216 and 226, and Amberlite XAD-2. The time required for the adsorption process to reach equilibrium ranged from about 3 h (for the soil and humic preparations) to about 48 h (for the more highly cross-linked materials). Adsorption by Amberlite XAD-2, a cross-linked polystyrene resin, was very small, presumably because it lacked ion-exchange sites.
The results suggested that particle diffusion control was operating and the different equilibrium times reflected different degrees of molecular complexity within the adsorbents.
Temperature, within the 20°–70°C range, did not affect the adsorption equilibrium, and this is indirect evidence for ion exchange as the primary adsorption mechanism. No evidence was found for decomposition of paraquat in the adsorption systems studied.
Quelques interactions physico-chimiques du paraquat avec des inatéaux de sol organique et des composes modéles I. Effets de la température, du temps et de la dégradation sur I'adsorption du paraquat  相似文献   

20.
Activity, adsorption, and mobility of emulsifiable concentrate (EC) and microencapsulated (ME) formulations of alachlor and acetochlor as well as of metolachlor, S-metolachlor, dimethenamid and flufenacet were studied. Petri-dish bioassay, based on root response of oats ( Avena sativa L.), was used for their activity in sand and in a silty clay loam soil, and for determination of herbicide concentrations in soil solution (not adsorbed) and in column leachates of the adsorption and mobility studies respectively. Flufenacet and both acetochlor formulations showed the highest activity in both soils and ME-alachlor and metolachlor the lowest; the activity of dimethenamid, EC-alachlor and S-metolachlor was intermediate. Activity of both formulations of alachlor and acetochlor decreased with increasing organic matter content, but alachlor activity was reduced more than that of acetochlor. Lower amounts of dimethenamid and S-metolachlor were adsorbed by soil compared with the other herbicides and, consequently, greater amounts of these two herbicides were leached through that soil. None of the herbicides tested was detected below 30 cm. Less alachlor and acetochlor were biologically available in soil solution after their application as ME-formulations and, therefore, lower amounts of both ME-alachlor and ME-acetochlor were leached through the soil compared with those applied as EC-formulations.  相似文献   

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