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1.
Taekyeong Kim Jongsuc Jung Kyungjin Jang Seokhan Yoon Mikyung Kim 《Fibers and Polymers》2009,10(2):148-153
A series of new monoazo yellow dyes having different alkyl substituents was synthesized to dye unmodified polypropylene fiber.
Color hue of the dyes exhibited light yellow with very high chroma enough to use as yellow primary color dyes. The affinity
of the dyes onto unmodified polypropylene was increased with the increase of the length of alkyl substituents. Therefore,
the hexyl-substituted dye having the longest alkyl group in this experiment showed very high color strength of dyeings with
K/S value of over 26 at maximum absorption wavelength. The color fastnesses to washing, rubbing and light were also improved
significantly for the longer alkyl substituted dyes, so that the hexyl-substituted dye exhibited a rating higher than 4∼5
for all kinds of fastnesses. 相似文献
2.
Following the previous studies regarding blue and yellow dyes, a series of new red dyes having different length of alkyl substituents
on the same chromophore were synthesized in order to dye unmodified polypropylene fiber. The affinity of the dyes onto unmodified
polypropylene fiber was increased with the increase of the length of alkyl substituents. Therefore, the longest hexyl-substituted
dye showed very deep shade of dyeing with K/S value of around 30 at maximum absorption wavelength. Within the range below 2 % o.w.f., the exhaustion (%) showed more than
80 %. The color fastnesses to washing, rubbing, and light of the dyeings were also improved greater for the dyes having longer
alkyl substituents than the shorter ones. Since color hue of the dyes exhibited very strong red, they could be considered
to be used as the primary red color dyes for unmodified polypropylene fibers. 相似文献
3.
A new series of magenta dyes having different length of alkyl substituents was synthesized to dye unmodified polypropylene (PP) and ultra-high molecular weight polyethylene (UHMWPE) fiber. It could be concluded that the affinity of the dyes onto unmodified PP and UHMWPE fibers was increased with the increase of the length of alkyl substituents. The optimum length of alkyl group was determined as the longest dodecyl-substituted dye in this study. Their absorption spectra appeared almost the same at visible range, which meant that the length of alkyl substituents did not affect the color appearance of the dyes. The color fastness properties of the dyeings to washing, rubbing and light were good enough for commercialization. 相似文献
4.
UHMWPE fibers were dyed with yellow and red dyes having different length of alkyl substituents on monoazo chromophores. The dyeability was investigated at various conditions and fastness of the dyeings was examined. As the length of alkyl substituents increased, the dyeability toward UHMWPE fibers tends to be improved gradually up to propyl or butyl groups and then decreased for the longer alkyl substituents. Color strength of the fabrics was increased with the increase of dyeing temperature from 100 to 130 °C. From the dyeing rate, equilibrium dyeing at 130 °C was achieved at 2～3 h. The color fastnesses to washing, rubbing, and light of the dyeings were good showing higher than 4 ratings except for light fastness of the red dye. 相似文献
5.
A new series of anthraquinoid red dyes were synthesized with 1-amino-2-bromo-4-hydroxyanthraquinone and nalkylphenols to dye UHMWPE fibers with high light fastness. Their dyeability was examined depending on the length of alkyl chains. As the length of alkyl substituents increases, the dyeability toward UHMWPE fibers improves rapidly from methyl to ethyl substituents and maintains almost same level of color strength, and then decreases from heptyl to octyl groups. The color strength of dyeings increased dramatically with the increase of dyeing temperature from 100 °C to 130 °C. The maximum build-up was shown at around 5 % owf dye amount. From the dyeing rate, equilibrium dyeing was achieved at around 5 h at 130 °C. All kinds of fastnesses were good enough showing higher than ratings 4-5 to washing and rubbing for the longer alkyl substituents. Especially, much improvement was achieved in light fastness showing ratings 4, which was higher than ratings 2 of the previous study. 相似文献
6.
UHMWPE fibers were dyed with a series of anthrquinoid blue dyes having different length of alkyl substituents at general dyeing
condition. The dyeability was investigated at various conditions and fastness of the dyeings was examined. As the length of
alkyl substituents increased, the dyeability toward UHMWPE fibers tends to be improved gradually. Color strength of the fabrics
was increased with the increase of dyeing temperature from 100 to 130 °C. From the dyeing rate, equilibrium dyeing at 130°C
was achieved at 2–3 h. The tensile strength of UHMWPE fibers after dyeing at 130 °C for 1 h was maintained at a level of 95
% of untreated fiber. However, at prolonged dyeing time at 130 °C, the tensile strength was significantly decreased to a practically
unacceptable level. The color fastnesses to washing, rubbing and light of the dyeings were very good showing higher than 4
ratings. 相似文献
7.
Dyeing and color fastness properties of a reactive disperse dye containing an acetoxyethylsulphone group on PET, Nylon, silk
and N/P fabrics were examined. The reactive disperse dye exhibited almost the same dyeing properties on PET fabric as a conventional
disperse dye except the level of dye uptake. The most appropriate pH and dyeing temperature for the dyeing of Nylon fabric
were 7 and 100°C respectively. The build-up on Nylon fabric was good and various color fastnesses were good to excellent due
to the formation of the covalent bond. Application of the reactive disperse dye on silk fabric at pH 9 and 80°C yielded optimum
color strength. The rate of dyeing on Nylon fabric was faster than that on PET fabric when both fabrics were dyed simultaneously
in a dye bath, accordingly color strength of the dyed Nylon was higher. The reactive disperse dye can be applied for one-step
and one-bath dyeing of N/P mixture fabric with good color fastness. 相似文献
8.
The synthesis of a series of phthalimide based azo disperse dyes and their spectral properties were investigated. The azo
dyes containing phthalimide and N-methyl phthalimide structure in diazo component were synthesized in order to compare their spectral properties. The synthesized
dyes developed the color of yellow to violet and the N-substitution of the phthalimide gave a bathochromic effect on the color change. Most of the synthesized dyes exhibit negative
solvatochromism so that the absorption band of dyes moves toward shorter wavelengths as the polarity of the solvent increases.
In the case of halochromic effect, the bathochromic shift decreased steadily with the general electron donating capacity of
the substituents in the coupling component, and became negative especially when more powerful electron donating groups are
present in the coupling components ring. 相似文献
9.
The dyeing and color fastness properties of two reactive-disperse dyes containing a sulfatoethylsulfone group on nylon, PET
and N/P mixture fabrics were examined. The rate of dyeing on nylon fabric was greatly dependent upon dye bath pH. The final
dye uptakes at all pH, however, were as high as 97 %. Color strength of the dyed nylon fabric linearly increased up to 0.5
%owf and then slowed down over 1 %owf dyeing. Washing and rubbing fastness of the dyed nylon fabric were excellent, but grade
of light fastness was moderate. Dyeability of the reactive-disperse dyes on PET fabric was not much affected by pH, and K/S
values of PET fabric dyed at pH 5–8 were lower than those of nylon fabric at all pH examined. Buildup and color fastnesses
properties on PET fabric showed the same tendency with nylon fabric. The rate of dyeing of the reactive-disperse dyes on nylon
fabric was faster than on PET fabric when both fabrics were dyed simultaneously in the same dye pot, resulting in higher color
strength of nylon than PET. The reactive-disperse dyes were found to be adequate to the one-bath, one-step dyeing of N/P mixture
fabric when applied at pH 5 and 120 °C. 相似文献
10.
The dyeing properties of hydrophobic polypropylene fibers using cationic dyes were investigated to improve dyeability by electron
beam irradiation and sulfonic acid incorporation. The color strength of polypropylene fibers after irradiation was examined
according to the dyeing conditions including the pH of the dyebath, absorbed doses, and the introduction of a functional group
to the fiber substrate. The best dyeing result was obtained when polypropylene fibers incorporated by sulfonic acid group
after electron beam irradiation were dyed with cationic dyes at alkaline conditions and 30∼75 kGy irradiation ranges. 相似文献
11.
The dyeing and color fastness properties of three reactive-disperse dyes containing a sulphatoethylsulphone group on Nylon,
cotton and N/C mixture fabrics were examined. Reduction-clearing was more effective in removing the unfixed dyes than soaping
since the reactive-disperse dye became hydrophobic during dyeing process. Nylon was dyed well with three reactive-disperse
dyes at pH 5∼8 and difference in chemical structure between dyes did not affect the final color strength of the dyed Nylon
fiber, but their build-up properties on Nylon were not so good. The color strength of the dyed cotton was not as high as that
of Nylon. The color strength of cotton increased by lowering dyeing temperature when the reactive-disperse dyes having hydroxy
group were used. Nylon absorbed more dye molecules than cotton in simultaneous dyeing, the color difference between Nylon
and cotton could be reduced as the dyeing temperature decreased. N/C mixture fabric was dyed well at 60 °C with the reactive-disperse
dyes having hydroxyl group when applied at pH 7 and 60 °C, and their build-up properties were good. It was also found that
washing fastness and rubbing fastness of dyed Nylon, cotton and N/C fabrics with the reactive-disperse dyes were excellent,
while light fastness was moderate. 相似文献
12.
Dispersant-free PTT dyeing of temporarily solubilized azo disperse dyes based on pyridone moiety which contain β-sulfatoethylsulfonyl
group was investigated. The dyes were successfully applied to PTT without the use of dispersants. The color yields of the
dyes on PTT fabric were dependent on dyeing pH as well as dyeing temperature. The optimum results were obtained at pH 5–6
and 110 °C. The dyes showed alkali-clearing property and exhibited good to excellent fastness on the PTT fabric. The COD levels
of the dyeing effluent from the temporarily solubilized disperse dyes were much smaller than those from commercial disperse
dye. 相似文献
13.
Seyed Majid Ghoreishian Laleh Maleknia Hamid Mirzapour Mohammad Norouzi 《Fibers and Polymers》2013,14(2):201-207
The use of non-toxic and eco-friendly natural dyes on textiles has received much attention due to the increased environmental awareness in order to avoid some hazardous synthetic dyes. In the present study, an eco-friendly approach was developed to impart color and antibacterial properties to silk fabrics dyed with turmeric extract as a non-toxic natural colorant. The natural colorant was extracted from Curcuma Longa rhizome. Copper sulfate, ferrous sulfate and potassium aluminium sulfate were applied in a pre-metallization process as mordanting agents. Antibacterial properties of treated fabrics were evaluated against common pathogenic bacteria, Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative). The effects of dye concentration and mordant types on the obtained color hues, antibacterial efficiency and color fastness of the fabrics were investigated. The results indicated that mordanted and dyed fabrics possessed desirable antibacterial properties. Complete antibacterial activity of the treated fabrics was obtained with 3 %owf (on weight of the fabric) copper sulfate. It was also shown that increasing the dye concentration could lead to a more efficient antibacterial activity on the mordanted dyed fabrics. An optimum level of the antibacterial activity was observed in the sample treated with 30 %owf of turmeric. Furthermore, the results of CIE L*, a*, b* values, FTIR, washing, light and rubbing fastnesses of the dyed fabrics were reported. The mordanted dyed silk fabrics exhibited desirable color fastness properties. These studies proved a direct relationship between the degree of antibacterial activity of the fabrics treated with turmeric and the metals ion concentration. 相似文献
14.
Moosa Sadeghi Kiakhani Mokhtar Arami Kamaladin Gharanjig Javad Mokhtari Niyaz Mohammad Mahmoodi 《Fibers and Polymers》2009,10(4):446-451
A series of novel monoazo disperse dyes based on N-carboxylic acid-1,8-naphthalimides have been synthesized via 4-(4-amino-1,8-naphthalimido) butanoic acid as diazo components
and various couplers. The synthesized dyes were characterized with elemental analysis, differential scanning colorimetry,
Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, and UV-visible spectroscopic techniques. The molar
extinction coefficient, wavelength maxima, and solvatochromism effect were obtained using chloroform, acetone, and N,N-dimethyl formamide as solvent. The results showed that the synthesized dyes had molar extinction coefficient of 20908 to
38939 l mol−1 cm−1, wavelength maxima of 409–549 nm, and positive solvatochromism by changing solvent from chloroform to N,N-dimethyl formamide. The synthesized dyes were applied on poly(ethylene terephthalate) using high temperature method. Dyes
1 and 2 showed high build-up properties on poly(ethylene terephthalate), whereas dyes 3 and 4 offered medium build-up. All
the dyes offered excellent heat fastness, good wash and rubbing fastnesses on poly(ethylene terephthalate) fabrics. The hydrolysis
of the synthesized dyes in alkali media indicated that the presence of a carboxylic acid group within the dye molecules provides
alkali-clearable potential. 相似文献
15.
Six nano disperse dyes were prepared using corresponding O/W nanoemulsions which were obtained with sodium laurylsulphate
and caprylic triglyceride. The average particle size of the dyes prepared were in the range of 110–130 nm. Exhaust dyeing
using nano dyes resulted in low exhaustion yields of 17–26 % on regular polyester fiber and 28–38 % on ultramicrofiber polyester.
The observed low exhaustion yields of nano disperse dye can be explained by the solubilization of dye particles into surfactant
micelles as well as the high stability of the nanoemulsions, these might reduce the capacity of dye uptake onto the fibers.
However, higher K/S values of dyeings with nano dyes on ultramicrofiber sites compared to those on regular polyester sites
suggested their potential to be more efficient dyes for finer denier microfiber polyesters. 相似文献
16.
The objectives of this study were to evaluate color sensation for yellowish natural dye fabrics using magnitude estimation
to determine physical colorimetric factors significantly related to human sensibility by establishing power function in psychophysical
analysis. Fourteen different yellowish fabrics dyed with natural colorants were selected as stimuli. Subjective color sensations
including brightness, heaviness, softness, strength, warmth, activeness, classicalness, femininity, and pleasantness for each
stimulus were subjectively evaluated by using fixed magnitude estimation. As results, yellowish natural dye fabrics in general
seemed to evoke feeling of brightness, femininity, and pleasantness more strongly than that of heaviness and classicalness.
Most of color sensations were significantly related with more than one of physical color properties, which leads to establishing
reliable power functions between them. Color lightness, L* was found as a dominant physical attribute which affects subjective sensation such as brightness, femininity, and pleasantness.
Subjective activeness was explained by physical yellowness, b*, whereas both strength and classicalness were by color saturation, C* even though it described strength positively while it did classicalness negatively. In the power functions, these relationships
could be utilized to design color-sensible natural dye textiles. 相似文献
17.
Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It
was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration,
but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption, molar extinction
coefficient, and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling
component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree
of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradable dyes. 相似文献
18.
Reversible and stable photochromic plastic lenses were obtained using photochromic dyes that were mixed during the casting process of the lens. Photochromic lenses with blue, red, yellow, and gray dyes as well as different concentrations of blue dye were prepared. The initial colors and fading speeds of the different dyes and different concentrations were examined by measuring the transmittances of the colored and bleached lenses. The initial color increased slightly with increasing dye concentration but the contamination was not as severe as the commercial photochromic lens. The fading speed was measured by changing the concentration of the dye and it was independent of the dye concentration. The relative transmittance was found to be more convenient for comparing the photochromic properties than the absolute transmittance because it could be used regardless of the type of color and dye concentration. 相似文献
19.
Three vat dyes have been applied to regular viscose rayon and their dyeing and wash fastness properties were evaluated. Particle
size determination was undertaken to obtain information about the size of dye particles converted by a reducing agent, to
see if dye particle size has an affect on dyeing properties of regular viscose rayon. It is observed that viscose rayon exhibits
more dyeability with reducing agent concentrations between 5–7.5 g/l. Also, we found that the vat dyeing system is greatly affected by the particle size of the vat dye converted to leuco form
by a reducing agent. 相似文献
20.
Vanessa Pasquet Nemeshwaree Behary Anne Perwuelz Jalal Isaad 《Fibers and Polymers》2013,14(7):1141-1147
Development of water-soluble dyes for the dyeing of different textile fabrics is essential for the textile industry due to ecological and economical reasons. In this study, a series of new azoic dyes were prepared by diazotization reaction between the phenyl boronic acid and different aniline derivatives, and their dyeing capacity in aqueous solution was evaluated. The synthesized boronic azo dyes present good water solubility and can dye polyamide (nylon), wool, silk, and cellulose acetate fabrics. The effect of factors such as concentration of dye, dyeing temperature, and pH on the level of color strength (K/S) was studied. The dyeing results showed that higher color strength K/S (about 16) and fastness properties (about 4/5) with boronic acid dyes were achieved at higher temperatures avoiding the use of surface agents, mordants, and other polluting chemical additives. 相似文献