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1.
S. Chow 《Wood Science and Technology》1994,28(3):189-198
Summary Thermal movement of wood and wood composites was studied and compared with that of random and oriented phenolic foams. Cell orientation was a dominate factor determining the thermal response of these structures. In dried wood, thermal movement in the direction parallel to the cells (longitudinal) decreased in dimension during heating while the radial and tangential directions expanded under similar heating condition. Oriented foams showed more restraint in thermal movement in the parallel to orientation direction. These findings indicate constraining forces act on the direction parallel to the cells while more flexibility exists in perpendicular directions. Wood element size and orientation and the manufacturing process also influence the thermal response in wood composites. The experimental results also revealed the potential fire hazard of waferboard type of composites. 相似文献
2.
Predetermination of growth ring wood quality was a frontier. By the method of growth ring wood quality analysis, correlation
ship of variation between the wood quality and ecological condition of forest growth is explained with the theory of quantification.
According to index of quantification model, the variation of forests growth and wood quality is forecasted.This paper discribed
the correlationship between branch wood and stem wood of growth ring wood quality, according to quantification index to infer
the stemwood quality by the branchwood quality predeterminning stemwood quality, this lead to a new way for wood quality predetermination. 相似文献
3.
Sedric Pankras Paul A. Cooper Lucie Coudert Jean-Francois Blais Guy Mercier 《Wood Science and Technology》2014,48(2):393-409
Remediation of copper-based alkaline copper quat (ACQ) and micronized copper quat (MCQ) wood-preservative-treated weathered southern pine mulch samples by monoethanolamine (Mea) extraction was studied. The potential reuse of Mea extract in ACQ wood preservative application was also evaluated. Continuous column extraction of copper-preservative-treated samples for 32 h, using 12 % Mea removed 66–86 % (between top and bottom of the column) and 65–80 % of Cu, respectively, from ACQ- and MCQ-treated wood. Mea extracts of treated wood could be reused in ACQ-treating solutions that met the American Wood Protection Association standard specifications for ACQ wood preservatives. This was achieved either by mixing the extract with industrial Cu–Mea solution at 1:4 ratio or by adding cupric acetate salt directly into the Mea extract. ACQ-treating solutions reformulated using Mea extracts of ACQ- and MCQ-treated wood performed similarly to wood treated with industrial ACQ solution and freshly prepared solution using cupric acetate. All treated wood had similar penetrations of Cu in wood during preservative treatment, Cu leaching from the treated wood in contact with water, corrosion of nails in contact with treated wood, and ability to protect wood from mold growth. 相似文献
4.
F. C. Beall 《Wood Science and Technology》1971,5(3):159-175
Summary The prolysis of cellulose, hemicelluloses, lignin preparations, and wood was studied by differential calorimetric analysis (DCA) for the range of 25° to 800° C. The test samples included powdered and filter paper celluloses; hardwood xylan; softwood galactoglucomannans, compression wood galactan, and arabinogalactan; a synthetic (DHP), sulfuric acid, Björkman, Brownell, and cellulase lignins; and unextracted and extracted hardwoods and softwoods. Heats of reaction were determined from the DCA thermal transition areas. Distinct differences were found between the thermograms of each hemicellulose and lignin sample. Although wood species could not be separated thermally, hardwood and softwood thermograms differed because of the hemicellulose degradation pattern.Trade names and company names are included for the benefit of the reader and do not imply any endorsement or preferential treatment of the product by the U.S. Department of Agriculture.Formerly Research Technologist, Forest Products Laboratory, Forest Service, U.S. Department of Agriculture. The Laboratory is maintained at Madison, Wis. 53705, in cooperation with the University of Wisconsin. Present address: The Pennsylvania State University, University Park, Pennsylvania 16802. 相似文献
5.
K. Weggler M. Dobbertin E. Jüngling E. Kaufmann E. Thürig 《European Journal of Forest Research》2012,131(5):1423-1438
Requirements for emission reporting under the Kyoto protocol demand an estimate of the dead wood carbon pool in forests. The volume of dead wood consists of coarse woody debris, smaller woody debris and dead roots. The measurement of dead wood volume was included in the most recent National Forest Inventory in Switzerland. To convert dead wood volume into carbon two conversion factors are required: (a) carbon (C) concentration and (b) wood density. So far internationally accepted default values for C concentration (50%) and for wood density (density of alive trees) were used as default values to estimate dead wood carbon, since local measurements were lacking. However, in a field study at 34 sites in Switzerland, the C concentration and density of CWD from Picea abies and Fagus sylvatica of four decay classes were measured recently. The results showed that C concentration in CWD differed significantly between species but did not change due to decay class. The density of CWD decreased significantly with an increase in decay class and it also differed between species. The decrease in CWD density was more pronounced for F. sylvatica than for P. abies. We assessed correlations between climate attributes and CWD density using regression analysis. The modeled densities and measured C concentrations were then expanded with the help of CWD volume data from the NFI3. Spruce CWD and thus spruce CWD carbon is much more abundant in Swiss forests than beech CWD carbon. The majority of spruce CWD is located in the Alps and Pre-Alps. The CWD volume from P. abies was 10 times higher than that from F. sylvatica. Thus, changes in conversion factors for P. abies CWD affected the overall estimate of dead wood carbon in Swiss forests much more than changes in conversion factors for F. sylvatica CWD. Current improvements in CWD conversion factors decreased the estimated amount of spruce CWD carbon by 23.1% and that of beech by 47.6%. The estimated amount of CWD carbon in Swiss forests is decreased by 31%. Since improved estimation methods are currently not applied to smaller woody debris and dead root material, the estimated amount of dead wood carbon is only reduced by 15%. Improving conversion factors for all dead wood fractions would presumably decrease the amount of dead wood carbon by additional 16%. 相似文献
6.
7.
Summary The wood, composed of alternate earlywood and latewood lamellae, forms a statically indeterminate system with two redundants. The redundant forces are the shearing forces arising at the edge of the boundary between earlywood and latewood in the longitudinal and in the tangential directions of wood. By determining the redundant forces according to the theory of statically indeterminate systems, we know the state of stress and the state of detormation of the wood element and thus can determine its shrinkage and stresses in the longitudinal, tangential and radial directions.
Zusammenfassung Holz ist aus Früh-und Spätholzlamellen aufgebaut und bildet damit ein statisch unbestimmtes System mit zwei statisch unbestimmten Größen. Diese statisch unbestimmten Größen sind die Scherkräfte, die in longitudinaler und tangentialer Richtung an den Kanten der Grenzschicht zwischen Früh-und Spätholz entstehen. Bestimmt man die statisch unbestimmten größen nach der Theorie der statisch unbestimmten Systeme, so kennt man den Spannungs-und Verformungszustand der Gefügeteile des Holzes und ist damit in der Lage, scine Schwindung und Schwindspannungen in longitudinaler, tangentialer und radialer Richtung zu berechnen.相似文献
8.
A trial set-up with methods for sampling, treatment and analysis of small wood chips are presented in this paper, to determine important wood and fibre properties, like basic density, dry density, volume swelling of wood, Kraft pulp yield, fibre length, fibre coarseness, fibre width, lumen width and fibre wall thickness. The required time for one sample is about 1.5 man-hour, but this requires relatively larger series and trained personnel. Acceptable measurement accuracy is achieved when the volume of the wood sample is at least 1.5 ml, except that of wood volume swelling. To gain acceptable measurement accuracy for volume swelling, the wood volume should be increased to at least 3 ml, and preferably more than 5–6 ml per sample. The level of pulp yield and wood density do not show a significant effect on the measurement accuracy for fibre cross-section dimensions. Fibre coarseness, on the other hand, has a significant influence on these accuracies. A double measurement of fibre coarseness will improve the accuracy to an acceptable level. The method presented here may, together with information about trees and growth locations, form the basis for greater insight into the mechanisms involved in development of wood and fibre properties in trees, which in turn may provide better control and utilisation of wood for pulp and paper production.Abbreviations CWD cell wall density in dry wood=1500 kg/m3 - Ww dry weight of wood (kg) - Vmax green (wet) volume of wood (m3) - Vmin dry volume of wood (m3) - BD basic wood density (kg/m3) - DD dry wood density (kg/m3) - VS maximum volume swelling of wood (%) - Wp dry weight of pulp (kg) - PY pulp yield (%) - C fibre coarseness, the average weight of a unit length of fibre (g/m) - CL average chip length (mm) - CWT average cell wall thickness (m) - FW average fibre width (m) - l average native fibre length in solid wood - L chip length - lc average fibre length in wood chip (mm) - Lc length-weighted fibre length in wood chip (mm) - lw native average fibre length in wood (mm) - Lw native length-weighted fibre length in wood (mm) - LW average lumen width (m) - llw average native fibre length, length weighted, in wood - X average fibre length in chip - Xlw average fibre length, length weighted, in chip 相似文献
9.
Summary A titration procedure was used to confirm carbon dioxide evolution from wood treated with solutions containing chromic acid and to quantify the effects of species (red pine vs soft maple), solution concentration and reaction temperature on the rate and amount of CO2 evolved. Small blocks or chips were vacuum treated with either chromated copper arsenate (CCA) wood preservative or chromic acid solutions and the release of CO2 monitored until the reaction was complete. Significant volumes of CO2 were measured. This is attributed to the oxidation and subsequent decarboxylation of primary hydroxyl groups on wood constituents. The ratio of moles of CO2 produced to moles of chromium added to the wood ranged from about 0.07 to 0.24 depending on the wood species, solution properties and fixation conditions. This accounted for from 9 to 32% of the total oxidation potential of the hexavalent chromium applied. The relative amounts of CO2 produced were higher for maple than for red pine. The rate of CO2 evolution was also higher in the maple samples, consistent with the higher rate of chromium reduction in soft maple compared to red pine. The amount of C02 produced was approximately proportional to the amount of hexavalent chromium in the CCA treating solution although the ratio of CO2 produced to chromium added to the wood increased slightly with increasing solution concentration. The relative amounts of CO2 produced increased with increasing fixation temperature over the 50–90 °C range in both species. The rate of CO2 evolution was accelerated as the fixation temperature was increased. The rates and amounts of CO2 produced were similar for CCA and Cr03 treatments containing the same concentration of chromic acid. Copper and arsenic components of the CCA solution did not appear to have any effect on the decarboxylation reaction.We gratefully acknowledge the financial support of the Natural Sciences and Engineering Research Council of Canada, Natural Resources Canada;, LPB Poles Inc., Masson Quebec, Timber Specialties Ltd., Campbellville Ontario and Guelph Utility Pole Co. Ltd., Guelph Ont. for this study. 相似文献
10.
Modelling moisture-related mechanical properties of wood Part I: Properties of the wood constituents
I. D. Cave 《Wood Science and Technology》1978,12(1):75-86
Summary By starting with simple concepts of the molecular structure and building up through the various levels of organisation in the wood cell wall it is possible to construct a model that simultaneously predicts the variation with moisture content change of both the longitudinal Young's modulus and longitudinal shrinkage of wood. To do this it is first necessary to define the stiffness and swelling characteristics of the lignin, hemicellulose and cellulose constituents of the wood as moisture content changes. It is suggested here that it is the bound fraction of the sorbed water that is responsible for the changes in swelling stress as well as for change in stiffness in the lignin and hemicellulose. The magnitudes of the stiffness of each of the constituents appear to be quite closely circumscribed by experimental values for longitudinal Young's modulus and shrinkage of wood and it is apparent that the stiffness characteristics of the in situ constituents are compatible with available experimental evidence for extracted lignin and hemicellulose and for native cellulose. 相似文献
11.
Diffusion and the drying of wood 总被引：5，自引：0，他引：5
G. Bramhall 《Wood Science and Technology》1995,29(3):209-215
Summary Fick's laws, stating that diffusion rate is proportional to the concentration gradient, have traditionally been used to describe the drying of wood. The author contends that they have been used inappropriately, since according to Fick's laws the rate varies as the concentration gradient of diffusing molecules, whereas many wood scientists use the concentration gradient of non-diffusing molecules —the bound water. When the temperature-dependent component of the diffusion coefficient is combined with the concentration gradient of diffusing molecules, the resulting driving force is proportional to the vapour pressure, and the diffusion coefficient is independent of temperature. 相似文献
12.
Georgiana Daian Alexander Taube Amikam Birnboim Mihai Daian Yury Shramkov 《Wood Science and Technology》2006,40(3):237-246
A method for calculating the complex dielectric permittivity of an anisotropic wood structure at microwave frequencies is
presented. A numerical model for describing the 3D wood structure containing fibers, rays, vessels and cracks with changeable
dimensions and material composition is built. This model is introduced into an efficient solver that calculates the effective
dielectric constant of any 3D structure of dielectric materials. Using our numerical model we succeeded in theoretically reproducing
the results of recent measurements of the dielectric permittivity of wood, in various directions and various moisture contents.
The qualitative agreement is realistic, reproducing all the trends of the changes in ɛ as the direction of the electric field
and the moisture content are varied. The quantitative agreement is practical and reliable for engineering calculations with
an average deviation of ±10% in ɛ′ and ±5% in ɛ′′. As microwave processing of wood involves internal temperatures as high
as 150°C and pressures of up to 5 atm, the dielectric properties of wood were also calculated with the same numerical model
by simulating high internal temperature and pressure. A comparison between the calculated and measured values shows once again
how accurate the model reproduces the empirical study. 相似文献
13.
通过适当的化学改性反应如酯化、醚化等,可以使木材转化为热塑性高分子材料。这些热塑性材料可单独或与合成高聚物按比例混合热压加工成型为各种板材或其他成型产品,这对扩大木材的加工利用途径、充分利用木材加工剩余物、提高木材利用率等都具有十分重要的意义。本文介绍了酯化、醚化木材的主要方法,产品的特点,以及今后木材及纤维素酯化、醚化的发展方向。 相似文献
14.
We investigated the relationship between the crystal lattice strain and the piezoelectric response in Japanese cypress (Chamaecyparis obtusa Endl.) wood fibers subjected to tension stress in the fiber direction. As a result, the piezoelectric voltage was very sensitive to the mechanical behavior (deformation) of the wood crystalline regions obtained from the x-ray stress measurement. Thus, by investigating the behavior of piezoelectric voltage, it was possible to simply estimate the mechanical behavior of the crystalline regions in the wood. 相似文献
15.
16.
Swelling of wood 总被引：1，自引：0，他引：1
Summary The rate and maximum swelling of several North American wood species in water have been obtained with a computer interfaced linear variable displacement transformer. Since wood swells extremely fast in water even at room temperature, this apparatus made it possible for the first time, to obtain accurate rate data on the swelling of wood in water. The strict linear dependence of swelling on the temperature suggests a chemical mechanism. The activation energies obtained from Arrhenius plots ranged from 32.2 KJ/mole for sitka spruce to 47.6 KJ/mole for sugar maple. Although the two hardwoods exhibited greater maximum tangential swelling compared with the two softwoods, the maximum swelling appears to be correlated with the wood density. Generally both the rate and maximum swelling of the woods were increased by removal of extractives and the activation energies were reduced. 相似文献
17.
18.
Summary Thermodynamic work of adhesion, contact angle, wettability and acid-base contributions of the wetting of four North American wood species were determined using the Wilhelmy technique. The wetting angles with water varied from 60° for Sitka spruce to 74° for Douglas-fir. The wood surfaces had a strong acidic character since the greatest interactions for all the wood species occurred with formamide (basic probe) while lesser interactions were obtained with ethylene glycol (acidic probe). In addition, dispersive and polar surface free energies of wood,
d
s
and
p
s
respectively, were determined using Wu's simultaneous equations. In general, 75 to 80% of the total surface free energy of wood was due to dispersion forces. Specific wettabilities of wood and advancing contact angles in thirty various organic liquids were also evaluated. 相似文献
19.
Fred E. Dickinson 《Wood Science and Technology》1976,10(2):73-77
Summary As the world's supply of non-renewable resources becomes increasingly critical, wood with its many attributes, but also with some inherent problems, has the opportunity of playing a more and more important role in meeting a wide variety of man's needs. Research and the development and utilization of research findings will be most important in determining how well wood fares in the years ahead. Those involved in the research effort must be aware of the need to select problems which if successful solutions are found can aid wood in better meeting man's needs. Also, there need be the recognition that the solution will only find use, if in addition to the problem being deemed of importance, both technical and economic feasibility to a significant degree can be demonstrated. The industrial rather than the scientific community is the final judge.Paper presented at the IAWS International Conference, September 9–11, 1975, in Banská Bystrica, Czechoslowakia. 相似文献
20.
Summary Wet cross-sections up to several centimetres thick of young trees show marked translucency. Various research applications are suggested by the observation of this phenomenon. 相似文献