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1.
Effect of different substances on the resistance of penetration of soil pastes A preliminary study was carried out to test for to what extent the molecular forces of a soil may be influenced. Soil pastes treated with Alginure', Ca(OH)2, NaCl, KCl, organic matter, or ferrihydrite, were prepared from topsoil samples of two eroded Typic Hapludalfs derived from loess (Ap within the Al and Bt horizon, resp.). Following airdrying and breaking the pastes, the penetration resistance of 8–12 mm aggregates was measured at 4 different applied water suctions. These resistances to penetration are correlated with the applied water suction by lg(resistance) = ?a+b*(suction) and with the aggregate water content by lg(resistance) = a-b*lg(water content). The resistances to penetration of the Bt-pastes are constantly higher than those of the Al-pastes. If any change due to treatment occurred, adding a substance decreased the resistance to penetration of the Bt-pastes whereas those of the Al-pastes were increased. As differences due to parent material and treatments occured at >10kPa and >30kPa applied water suction, resp., it is assumed that they essentially effect the surface tension of the soil water, which on its part influences the force of cohesion of the water menisci. This force of cohesion affects the degree of aggregation and thereby among others the resistance to penetration of a soil.  相似文献   

2.
A method to determine oxygen partial pressure and oxygen diffusion in single soil aggregates as a function of soil moisture tension Anaerobic zones occur even in unsaturated soils of silty or clayey texture, that are aerated sufficiently in their macropore system. These zones can be related to the inner parts of soil aggregates. To describe the oxygen balances in soils it is necessary to measure not only in soil profiles but as well in single soil aggregates within a range of soil matrix potentials. Therefore oxygen partial pressure in single soil aggregates of different texture was measured continuously as a function of soil matrix potential. For that purpose we developed an oxygen sensitive microelectrode with a tip diameter of 0.5 mm, that is sturdy enough to measure even in sandy soils. One microtensiometer (diameter of the tip < 0.5 mm) and one oxygen microelectrode were placed in water saturated soil aggregates. Soil water potential and oxygen partial pressure were measured continuously during soil drying. The results show an aeration of primarily anoxic soil aggregates at different soil matrix potentials due to different texture and structure. The clayey polyhedral aggregates of the Vertisol were aerated at significantly lower soil matrix potentials than the loamy prisms of the Fluvisol. These show higher values of oxygen partial pressure even at soil water potentials less than 150 hPa. In the aggregates of the Vertisol, that have a fine texture, values of rel. aparent diffusion Ds/Do were in the range of 1 · 10?3 at soil water potentials < ?  相似文献   

3.
H.H. Becher 《Geoderma》1978,21(2):105-118
Penetration resistance was measured with probes 1.5 and 0.55 mm in diameter on relatively small cores and aggregates from horizons of a Pelosol (Chromudert) profile (a soil with 55–65% clay) at moisture tensions ranging from 0 to 600 cm H2O. The resistance was highly correlated with moisture tension and with water content. At a moisture tension of about 450 cm H2O, resistance to penetration was as high as 25 kp/cm2, a value that severely restricts root growth. That correlation was more evident with aggregate than with core samples. Resistance to penetration of the aggregates differed from that of the core samples with the ratio of friction to the cross section.Resistance to penetration by the probes is also negatively correlated with amounts of organic matter in the samples. This correlation suggests maintenance and increasing levels of organic matter as measures to lower penetration resistance in horizons of Pelosols.  相似文献   

4.
Aggregate hierarchy and porosity changes in aggregate beds as a consequence of wetting–drying cycles were studied in two Andisols and one Mollisol from Chile, collected at two depths. Bulk density and indirect tensile strength were measured in aggregates of different sizes. Aggregate beds were prepared in cylinders with two size classes. Six wetting–drying cycles between 0 and –60 hPa were applied. Bulk density (Db) of soil matrix was controlled after each cycle, and the macroporosity was calculated. A repellency index was measured in one of the Andisols. In addition, also the air permeability was measured after the sixth cycle. It could be proofed, that the aggregate strength is an appropriate parameter to evaluate the aggregate hierarchy, and this parameter is also more sensitive than aggregate Db to discriminate between the effects of land‐use intensity. Aggregate strength is furthermore well correlated with changes in pore water pressure and can be applied to relate strength values with aggregate development level. Only if the predrying exceeds pF > 3.0, aggregate strength correlates with Db. The more pronounced is the land‐use, the higher is the increase of Db values for aggregate beds. The decrease of coarse porosity during wetting–drying cycles can be explained by mass differences between saturated and equilibrated water conditions that considers the water around aggregates and within the contact area. Nevertheless, the relation of relative macroporosity change, calculated by Pexped where Dagg is the Db measured by clod method, and the relative Db change, is useful to explain possible presence of coarse pores inside the aggregates. The newly formed porosity prevents the water repellency, but after six cycles of drying, the repellency index increased in the topsoil while we could detect a decrease in the subsoil samples (under defined conditions in the laboratory) which we assume to be caused by microbial activity. The approaching of aggregates by drying cycles generates in Andisols a reduced area to air fluxes, with low values of air permeability.  相似文献   

5.
Measuring resistance to penetration on single soil aggregates This paper describes an improved procedure for measuring resistance to penetration. Single, partly encased aggregates of 20–50 mm diameter are slowly (3.65 mm/min) penetrated by a fine (0.5 mm, 10°) penetrometer probe at several predefined locations along at least one transect on that aggregate. Using the depth depending values of forces to penetration and shaft friction for each penetration, resistance to penetration along the penetration path and, from several of those, the distribution of resistance to penetration within that aggregate is calculated.  相似文献   

6.
Soil wettability is especially important for rainfed agriculture in climates with a dry period during the growing season. The effect of aggregate structure and soil organic C content on wettability of soil aggregates was determined for grassland (grass) and tilled fields (tillage). Soil organic C, plastic limit, aggregate total porosity, and wettability at 100 mm (rapid wetting) and 300 mm (slow wetting) water tension were measured on soil at 0–0.2 m depth. Natural aggregates from tillage and grass were compared to soil pellets formed by remolding aggregates. At both tensions, wettability of grass aggregates was significantly greater than that of tillage aggregates (P ≤ 0.001). Pellets were significantly less wettable than natural aggregates at 300 mm tension and during the initial wetting at 100 mm tension, but became significantly more wettable with time at 100 mm tension. Cumulative water uptake during 60 min exceeded the initial total porosity of pellets and natural tillage aggregates, suggesting incipient failure (formation of microcracks) during fast wetting. Grass aggregates contained twice as much organic C as tillage aggregates (26 g kg−1 versus 13 g kg−1). Organic C was linearly and positively related to plastic limit, total porosity, and the wettability of natural aggregates at 300 mm tension. At 100 mm tension, organic C was negatively related to wettability of natural aggregates under grass, but unrelated to wettability under tillage. Aggregate wettability was positively related to organic carbon content, except when the arrangement of soil constituents reduced or prevented incipient failure and soil dispersion during rapid wetting resulted in cumulative water uptake (60 min) similar to initial aggregate total porosity. Organic C increased wettability of grass aggregates when compared to tillage aggregates and also stabilized natural aggregates during fast wetting (100 mm tension). Both soil organic C content and aggregate structure were key factors controlling aggregate stability and wettability.  相似文献   

7.
The location of soil organic matter (SOM) within the soil matrix is considered a major factor determining its turnover, but quantitative information about the effects of land cover and land use on the distribution of SOM at the soil aggregate level is rare. We analyzed the effect of land cover/land use (spruce forest, grassland, wheat and maize) on the distribution of free particulate organic matter (POM) with a density <1.6 g cm−3 (free POM<1.6), occluded particulate organic matter with densities <1.6 g cm−3 (occluded POM<1.6) and 1.6-2.0 g cm−3 (occluded POM1.6-2.0) and mineral-associated SOM (>2.0 g cm−3) in size classes of slaking-resistant aggregates (53-250, 250-1000, 1000-2000, >2000 μm) and in the sieve fraction <53 μm from silty soils by applying a combined aggregate size and density fractionation procedure. We also determined the turnover time of soil organic carbon (SOC) fractions at the aggregate level in the soil of the maize site using the 13C/12C isotope ratio. SOM contents were higher in the grassland soil aggregates than in those of the arable soils mainly because of greater contents of mineral-associated SOM. The contribution of occluded POM to total SOC in the A horizon aggregates was greater in the spruce soil (23-44%) than in the grassland (11%) and arable soils (19%). The mass and carbon content of both the free and occluded POM fractions were greater in the forest soil than in the grassland and arable soils. In all soils, the C/N ratios of soil fractions within each aggregate size class decreased in the following order: free POM<1.6>occluded POM<1.6-2.0>mineral-associated SOM. The mean age of SOC associated with the <53 μm mineral fraction of water-stable aggregates in the Ap horizon of the maize site varied between 63 and 69 yr in aggregates >250 μm, 76 yr in the 53-250 μm aggregate class, and 102 yr in the sieve fraction <53 μm. The mean age of SOC in the occluded POM increased with decreasing aggregate size from 20 to 30 yr in aggregates >1000 μm to 66 yr in aggregates <53 μm. Free POM had the most rapid rates of C-turnover, with residence times ranging from 10 yr in the fraction >2000 μm to 42 yr in the fraction 53-250 μm. Results indicated that SOM in slaking-resistant aggregates was not a homogeneous pool, but consisted of size/density fractions exhibiting different composition and stability. The properties of these fractions were influenced by the aggregate size. Land cover/land use were important factors controlling the amount and composition of SOM fractions at the aggregate level.  相似文献   

8.
Influence of organic amendments on soil physical properties The effect of applying crop residues additionally to fertilzers or farmyard manure on soil structure was studied in Upper Bavaria. Crop residues were applied each year for 13 years before sampling. The Aquic Hapludalf, derived from loess underlain by Tertiary fine sand, was cropped with vegetables. Resistance to penetration, saturated hydraulic conductivity (kf), pore size distribution, and aggregate stability (AS) were determined. The application of residues and/or manure increased the organic matter content of the top soil, resulting in increases in AS and kf. However, both of these parameters were higher following residue application rather than that of manure. Only the application of residues improved the plant available water capacity by about 10 mm within 70 cm depth of soil profile. The other properties were not significantly affected, probably because they were also influenced by the weather and soil management practices. The values for these properties must therefore be considered as only momentary.  相似文献   

9.
Soil aggregation is influenced by the tillage system used, which in turn affects the amount of C and N in the different aggregate fractions. This study assessed the impact of different tillage systems on soil aggregates by measuring the aggregate stability, the organic carbon (Corg) and the total nitrogen (Ntot) contents within different aggregate fractions, and their release of dissolved organic carbon (DOC). Soil samples were collected from the top 0 to 10 cm of a long-term tillage experiment at Fuchsenbigl (Marchfeld, Austria) where conventional tillage (CT), reduced tillage (RT), and minimum tillage (MT) treatments were applied to a Chernozem fine sandy loam. The stable aggregates (1000–2000 μm) were subject to dispersion by the soil aggregate stability (SAS or wet sieving) method after Kemper and Rosenau (1986), and the ultrasonic method of Mayer et al. (2002). Chemical analysis of the soil was obtained for the aggregate fractions 630–1000, 250–630 and 63–250 μm gathered from the ultrasonic method. Using the SAS method, CT and RT had the least amounts of stable aggregates (18.2% and 18.9%, respectively), whereas MT had twice as much stable aggregates (37.6%). Using the ultrasonic method, MT also had the highest amount of water stable aggregates in all three fractions (1.5%, 3.7%, and 35%, respectively), followed by RT (1%, 2.3%, 32.3%), and CT (0.8%, 1.7%, 29.1%). For comparison, a reference soil, EUROSOIL 7 (ES-7) was also analysed (40%, 6.7%, and 12.1%). The highest amounts of Corg and Ntot were measured under MT in all three fractions, with 8.9%, 3.8%, and 1.3% for Corg, and 0.4%, 0.3%, and 0.1% for Ntot. Apart from the fraction 630–1000 μm, the aggregates of RT and CT contained <50% of the Corg and Ntot values of MT. The C/N ratio was least favourable for CT (42.6) in the aggregate fraction 630–1000 μm. The DOC release from stable aggregates after 10 min of ultrasonic dispersion was highest from MT soil (86.7 mg l−1). The values for RT and CT were 21% and 25% below this value. The results demonstrate that tillage type influences both aggregate stability and aggregate chemical composition. This research confirms that CT interferes more with the natural soil properties than RT and MT. Furthermore, MT has the highest potential to sequester C and N in this agriculturally used soil.  相似文献   

10.
Previous soil and spring water analyses in small catchments revealed low pH values in the spring water during high discharge events. This paper analyses the potential which small scale heterogeneity of soil acidity may have to explain decreasing spring water pH as a result of high discharge. Soil aggregates were collected from a C‐horizon of a Spodosol in the Fichtelgebirge. Exchangeable cations and soil solution were examined on both samples from the surfaces and the cores of aggregates which were obtained by a mechanical separation procedure. The Reuss‐Johnson soil chemical equilibrium model was used to predict soil and spring water pH values as a function of acidic input and soil air CO2 concentration in equilibrium with both aggregate fractions. Ranges of acidic input from 160—570 μeq L−1 and soil air CO2 concentrations from 0.1 to 3 Vol. % were considered. The model predicted spring water pH values from 5.0 to 5.3 for the acidic aggregate surface samples (base saturation = 12.5%) and from 6.8 to 7.2 for the aggregate core samples (base saturation = 32.1%). The results suggest that small scale acidity gradients may expand the range of predictable spring water pH values. However, very low pH values (<5) still need additional explanation.  相似文献   

11.
On the bulk density of aggregates and its possible impact on the movement of soil solutions The bulk densities of the aggregate fractions 15-18 mm, 10-15 mm, 5-10 mm, and 3-5 mm from a Typic Hapludalf, an Aquic Hapludalf, and a Typic Chromudert, all used as cropland and grassland, and that of aggregates of the 3-5 mm fraction from a Typic Dystrochrept used for a farm manure and crop residue trial, lay between 1.8 and 2.0 g/cm3. Sampling was done down to depths of 85 cm, 70 cm, 55 cm, and 80 cm. respectively. The bulk density values increase in most cases with decreasing aggregate size and indicate the aggregate pore volumes to generally range from 25 to 35% b.v. This means that either soil aggregates often contain only fine pores or that fine and medium pores also act as inter-aggregate pores. As a consequence, movement and exchange of soil water and soil solution between inter- and intra-aggregate pores is severely restricted.  相似文献   

12.
The influence of soil structure on penetration resistance Penetration resistance depends strongly on the soil structure. However, because roots may either penetrate aggregates or grow around them, the value determined for the bulk soil can only be used as a first approximation. If e.g. unconfined aggregates are penetrated, the penetration resistance increases with increasing size. If however, the aggregates are confined by being embedded in gypsum then the penetration resistance is higher but is independent of aggregate size. Thus, the outer skin is stronger than the inner part of the aggregates. When single prisms are penetrated horizontally, then the penetration resistance is smaller than the resistance to vertical penetration. On the other hand, for polyhedral structure the penetration resistance is of the same order of magnitude in both directions.  相似文献   

13.
The impact of fertilizer application on soil aggregate stability is of increasing interest to soil scientists. Aggregate water stability depends primarily on soil organic matter. We studied silty loam and loamy sand aggregates from three long‐term fertilizer treatments (control, pig manure and NPK) which significantly altered the quantity of organic matter. A new approach to examining aggregate stability was used: soil aggregates were immersed in methanol‐water solutions with methanol at 0, 20, 40 and 60% concentration (C), and non‐disrupted aggregates were separated after 30 minutes. The aggregate resistance R(C) against each solution was taken as the percentage of stable aggregates. Overall resistance of the aggregates was taken as the Rtot parameter given by the product of four R(C) values. The R(C) values of all aggregates were positively correlated with C. The R(60) values were independent of the applied fertilizer. The R(0) value for silty loam aggregates ranged from 28% (pig manure) to 7% (NPK), while that for loamy sand equalled 7–9% in all cases. The R(20) values were most effective at differentiating the soils and the fertilizer treatments. However, the Rtot value was a better indicator of aggregate stability. Greater differences in stabilities of aggregates were noted in loamy sand. Mineral fertilizer application seemed to decrease aggregate resistance in both soils. Total organic carbon and nitrogen content in all non‐disrupted aggregates were negatively correlated with methanol concentration (C) of the solution applied for aggregate separation. The largest decrease was for the pig manure treatment, and the smallest was for the control. Porosity and pore size distributions of the aggregates were derived from micro‐tomography and approximated to lognormal pore size distributions. Larger porosities and pores were found in water‐stable aggregates than in methanol‐stable aggregates. It seems that the dominant mechanisms for aggregate instability during fast wetting were not related only to the pore air compression, but to weakening of attractive forces between aggregate particles by water.  相似文献   

14.
A soil with double porosity is modelled as a collection of aggregated particles, in which a single aggregate is made up of discrete particles bonded together. Separate fractal distributions for pore sizes around and within aggregates are defined. The particle size distribution of the double porosity soil is also modelled using a fractal distribution, which may have a fractal dimension very different to those defining the pore sizes. The surface areas of the particles and the pores within the aggregates are assumed to be equal, enabling an expression linking two fractal dimensions to be defined. It is necessary to introduce ratios between maximum and minimum particle and pore sizes into the expression. A theoretical soil‐water characteristic curve is then derived for a double porosity soil. The curve, and the underlying assumptions regarding the distributions of pore and particle sizes, showed good agreement with experimental data for a range of soils having double porosity. A discontinuity is observed in the soil‐water characteristic curve at a second air entry value related to the maximum pore size within the aggregates, a feature also observed in experimentally obtained soil‐water characteristic curves for double porosity soils.  相似文献   

15.
The contribution of rock fragments to the soil available water content (SAWC) of stony soil has been quantified by measurements of bulk density and gravimetric water content at different water potentials on rock fragments of different lithologies: flints, cherts, chalks, gaizes and limestones. More than 1000 pebbles (2 cm < equivalent diameter of the rock fragment < 5 cm) have been sampled in stony soils developed from each of the five lithologies. We demonstrated that the water content at saturation of the studied pebbles was equal to the water content at −100 hPa and to the water content at field capacity. A linear relationship between the water content at −100 hPa and at −15,840 hPa enabled to derive a simple pedotransfer function to determine the available water content of the rock fragments. We also proposed a second simple pedotransfer function, which expresses the available water content from the dry bulk density of the rock fragments only. A simulation at the horizon scale for a loamy-clay stony horizon showed that the SAWC could be strongly misjudged when the rock fragments were not taken into account: for a stony horizon containing 30% of pebbles, the SAWC is underestimated by 5% for chert pebbles and by 33% for chalk pebbles.  相似文献   

16.
An experiment was conducted to determine the effect of four tillage systems (moldboard plow, chisel plow, Paraplow and no-till) on soil aggregate shear strength and bulk density. Two soils, a Canisteo clay loam (fine-loamy, mixed (calcareous), mesic, Typic Haplaquoll) and a Haig silt loam (fine, montmorillonitic, mesic, Typic Argiaquoll) were used in this study. Soil samples were collected from the 0.075–0.15-m-depth increment in 1983 and the 0.075–0.15- and 0.225–0.30-m-depth increments in 1985. Shear strength of soil aggregates 0.02–0.03 m in diameter was measured by a fall-cone penetrometer and bulk density of the same aggregates was measured by gamma-ray attenuation. Aggregates were tested at soil water matric potentials (ψm) of −0.2, −1.1 and −4.0 kPa in 1983 and at ψm of −0.2, −1.1, −4.0 and −7.9 kPa in 1985. Tillage for the 1983 growing season was conducted under very wet conditions, whereas tillage for the 1985 growing season was conducted under much drier conditions. Samples collected in 1983 showed little tillage effect on shear strength or bulk density. In 1985, tillage had an effect on shear strength and bulk density for the Haig soil, but not for the Canisteo soil. Much of the tillage effect on soil aggregate shear strength could be explained by tillage-induced changes in the aggregate bulk density. As bulk density decreased, soil aggregate shear strength decreased.Sampling depth had no effect on soil aggregate shear strength or bulk density. Matric potential had an effect on soil aggregate shear strength and bulk density. As matric potential decreased, both shear strength and bulk density increased.  相似文献   

17.
长期施肥对中国亚热带水稻土土壤稳定性和机械属性的影响   总被引:12,自引:0,他引:12  
LI Jiang-Tao  ZHANG Bin 《土壤圈》2007,17(5):568-579
Wet stability, penetration resistance (PR), and tensile strength (TS) of paddy soils under a fertilization experiment for 22 years were determined to elucidate the function of soil organic matter in paddy soil stabilization. The treatments included no fertilization (CK), normal chemical fertilization (NPK), double the NPK application rates (2NPK), and NPK mixed with organic manure (NPK+OM). Compared with CK, Fertilization increased soil organic carbon (SOC) and soil porosity. The results of soil aggregate fragmentation degree (SAFD) showed that fast wetting by water was the key fragmentation mechanism. Among the treatments, the NPK+OM treatment had the largest size of water-stable aggregates and greatest normal mean weight diameter (NMWD) (P ≤ 0.05), but the lowest PR and TS in both cultivated horizon (Ap) and plow pan. The CK and 2NPK treatments were measured with PR 〉 2.0 MPa and friability index 〈 0.20, respectively, in the Ap horizon, suggesting that the soils was mechanically unfavourable to root growth and tillage. In the plow pan, the fertilization treatments had greater TS and PR than in CK. TS and PR of the tested soil aggregates were negatively correlated to SOC content and soil porosity. This study suggested that chemical fertilization could cause deterioration of mechanical properties while application of organic manure could improve soil stability and mechanical properties.  相似文献   

18.
土壤理化性质异质性研究及其影响   总被引:2,自引:0,他引:2  
Structured soils are characterized by the presence of inter- and intra-aggregate pore systems and aggregates, which show varying chemical, physical, and biological properties depending on the aggregate type and land use system. How far these aspects also affect the ion exchange processes and to what extent the interaction between the carbon distribution and kind of organic substances affect the internal soil strength as well as hydraulic properties like wettability are still under discussion. Thus, the objective of this research was to clarify the effect of soil aggregation on physical and chemical properties of structured soils at two scales: homogenized material and single aggregates. Data obtained by sequentially peeling off soil aggregates layers revealed gradients in the chemical composition from the aggregate surface to the aggregate core. In aggregates from long term untreated forest soils we found lower amounts of carbon in the external layer, while in arable soils the differentiation was not pronounced. However, soil aggregates originating from these sites exhibited a higher concentration of microbial activity in the outer aggregate layer and declined towards the interior. Furthermore, soil depth and the vegetation type affected the wettability. Aggregate strength depended on water suction and differences in tillage treatments.  相似文献   

19.

Purpose

Soil aggregate mechanical characteristics can significantly affect soil strength and are important soil properties to predict soil erodibility. However, in most research, the aggregate mechanical strength is always measured under air-dried condition, and limited information is available about the mechanical strength of aggregates and soil blocks with different water contents. This study evaluated the effects of water content, bulk density, and aggregate size on mechanical properties of soil blocks and aggregates.

Materials and methods

Shear strength (τ) parameters (φ and c) of soil blocks in different states (undisturbed and remoulded) and tensile strength (TS) of aggregates were determined in the laboratory on two soils derived from Quaternary red clay (Q) and shale (S) with variations in water content, bulk density, and aggregate size.

Results and discussion

The results indicated that the φ values were higher in drier and denser soil and showed no obvious variation with varying aggregate size. The c values increased first and then decreased with increasing water content and decreasing aggregate size and increased with increasing bulk density. The water content corresponding to the rapid decrease of the c value appeared to be related to soil properties. Tensile strength increased with decreasing water content in all sizes of aggregates. It decreased with increasing aggregate size at a relative low water content (3.2–7.3 %), but increased with increasing aggregate size at a relative high water content (10.6–14.8 %). The effect of soil moisture on soil strength varied with soil states. Thus, water content, bulk density, and aggregate size have significant effects on the mechanical properties of the soil blocks and aggregates.

Conclusions

The result from this research may contribute to a better understanding of the soil erosion resistance of Aquults from the perspective of soil mechanics.
  相似文献   

20.
The migration of colloids in soils can enhance the leaching of strongly sorbing contaminants. We present a model for the simulation of colloid leaching from unsaturated, aggregated soil media under stationary flow. Transport in the intra-aggregate pores is simulated by convection–dispersion, and transport in the interaggregate pores, and a stagnant layer of water surrounding the aggregates, is simulated by diffusion. The model describes the release of colloids from soil aggregates, sorption and desorption processes at the air–water interfaces, and flocculation and subsequent straining from the flowing water. All three processes were simulated as functions of ionic strength. Transport of ions in intra-aggregate pores was simulated by Fickian diffusion. The model was calibrated against experimental results of colloid leaching from columns packed with natural soil aggregates. The aggregates were of two soils differing in organic matter content. On each soil a single calibrated parameter set could describe the experiments with the three ionic strengths. The parameters for release of colloids from the aggregate surface and the sorption properties of the air–water interface were different for the two soils. The key parameters for leaching were the thickness of the stagnant layer of water surrounding the aggregates, the mechanical dispersion, the maximum concentration of colloids at the surface of the aggregates, the sorption capacity and rate coefficient of the colloids at the air–water interface, and the colloid diffusion coefficient. Simulations were also done with two additional irrigation intensities at one ionic strength. Simulated leaching was greater than measured leaching at both irrigation intensities, but the diffusion-controlled release of colloids from the aggregates was simulated correctly.  相似文献   

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