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[目的]基于超高效液相色谱–四极杆飞行时间–质谱（UHPLC–QTOF–MS）技术分析五倍子中单宁成分,建立一种有效的五倍子单宁成分测定方法,并解析单宁的裂解规律。[方法]使用高温和超声波辅助方法提取五倍子中的酚类化合物,基于二级质谱推定化合物的裂解途径。[结果]共鉴定到20种化合物,包含14种没食子单宁、3种酚酸、2种没食子酸酯和1种黄烷醇。以高温121℃为提取条件,均未鉴定到分子质量高于1 500 Da的没食子单宁,而在超声波辅助提取的五倍子水提取液中,成功地检测到1–O–没食子酰基葡萄糖至14–O–没食子酰基葡萄糖,其中,超声功率1 500 W,提取温度65℃条件下,鉴定到更多的没食子单宁异构体。MS/MS图谱显示,五倍子单宁主要通过没食子酸、没食子酰基、糖苷、水、羧基的损失进行裂解。[结论]本研究证明,超声波辅助提取条件下,应用UHPLC–QTOF–MS技术能够全面高效地分析五倍子中的单宁成分,本研究为富含单宁的植物的化学成分研究提供参考依据。 相似文献
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Okumu Gordon Wanyama Kei Sawata Takuro Hirai Akio Koizumi Yoshihisa Sasaki 《Journal of Wood Science》2012,58(4):315-321
In this study, an experimental study was conducted on the nailed timber–plywood–timber joints extended from the standard wall–floor joints of wooden light frame constructions, where the bottom plates of shear walls are nailed to the floors consisting of joists and floor sheathings nailed to them. The principal conclusions are as follows: The allowable lateral resistance of the nailed timber–plywood–timber joints can roundly be estimated by neglecting the plywood panels if their densities are higher than those of the timber main-members and they are fastened effectively onto the timber main-members. The stiffness of the timber–plywood–timber joints is less than that of the control timber–timber joints, which is improved by increasing the number of nails used to fasten the plywood panels onto the timber main-members. The stiffness of the joints whose floor sheathings are glued onto the joists is equivalent to the control timber–timber joints. The timber–plywood–timber joints with appropriate specifications have greater energy capacity until the failure than that of the control timber–timber joints. This ensures their energy capacity, which is important in dynamic resistance, to be equivalent to the control timber–timber joints. 相似文献
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Ida Poljanšek Blaž Likozar Nataša Čuk Matjaž Kunaver 《Wood Science and Technology》2013,47(2):395-409
The objective of this research was to investigate the effect of liquefied wood (LW) on the cure kinetics and network properties of melamine–urea–formaldehyde (MUF) resins by differential scanning calorimetry. The MUF/LW compounds exhibited two distinct cross-linking processes. It can be assumed that there did not appear to be a coreaction of the MUF with the LW. The overall apparent activation energies (E a) of the curing reactions were calculated using the Kissinger equation. An nth-order kinetic model was used to describe the cross-linking of MUF/LW compounds, of various compositions, cured at different heating rates. The E a values for the cross-linking process of the MUF/LW compounds predominantly tended to be approximately 80 and 71 kJ mol?1 for MUF and LW, respectively. The apparent reaction orders of the MUF cross-linking process of the MUF/LW compounds were in the range 1–2, whereas the n values of the LW were approximately unity or less, which hints to there being a more complex mechanism of this process. 相似文献
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A novel and simple electroless Ni–Cu–P plating process was used for preparing corrosion-resistant and electromagnetic interference shielding wood-based composite. The effects of CuSO4·5H2O concentration, pH value in the plating solution and operation temperature on the metal deposition, surface resistivity, chemical composition, corrosion resistance and surface morphology of the composite were investigated. The surface morphologies were observed by using scanning electron microscopy and the chemical compositions were analyzed by X-ray energy dispersive spectrometer. The electromagnetic shielding effectiveness (ESE) was measured by spectrum analyzer. The corrosion resistance was evaluated by potentiodynamic corrosion measurement. The results show that metal deposition increases with pH value and temperature increase; however, it decreases with CuSO4·5H2O concentration increase. The corrosion resistance of the plated Ni–Cu–P coatings obviously depends on the total content of Cu and P in the coating. Higher total content of Cu and P leads to higher corrosion resistance. The optimum conditions are as follows: CuSO4·5H2O concentration of 1.0 g/L, pH value of 9.5, and operation temperature of 90 °C. The obtained coating contains 77.41 % Ni, 8.96 % Cu, and 13.63 % P. The wood-based composite exhibits higher corrosion resistance and ESE of around 60 dB in frequencies ranging from 9 kHz to 1.5 GHz. In this paper, a promising process for corrosion-resistant and electromagnetic shielding wood-based composites was developed. 相似文献
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Andrea Balázs Magdolna Tóth Balázs Blazics Éva Héthelyi Szabolcs Szarka Emese Ficsor Gitta Ficzek Éva Lemberkovics Anna Blázovics 《Fitoterapia》2012
Three red-fleshed apple cultivars (Malus ‘Geneva’: GFV-03, Hungarian hybrid: GFV-04, Malus pumila Niedwetzkyana: GFV-05) were investigated for their chemical composition by sHS–SPME–GC–MS and HPLC–DAD–MS/MS analytical techniques. 相似文献
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Waste paper could potentially be used as raw material for fiber- or particle-based composites without resorting, deinking and decontamination required for paper manufacturing. The objective of this study was the evaluation of one-layer boards made of various ratios (0:100,15:85, 25:75, 50:50, 75:25 and 100:0) of waste paper flakes to wood particles mixtures (wt:wt). Three types of waste paper (newspaper, office paper and magazine paper) in pure form or mixed all together were used for board manufacture. PMDI resin at three different levels of 5, 8 and 10% without or with the addition of various amounts of wax (0.7, 1.0, 1.5 and 2.0%) were applied. The participation of waste paper flakes in boards made their appearance more attractive than ordinary particleboards and fiberboards made of wood. In contrast to internal bond, screw-holding strength and thickness swelling, properties that deteriorated substantially as the waste paper percentage increased, the bending strength was only slightly affected. By increasing the resin content all properties of boards and particularly internal bond and thickness swelling were improved. The addition of wax reduced considerably the thickness swelling of boards containing waste paper; however, even at a 2.0% level, it remained greater than the maximum permitted value specified by the relevant standard. Among the three types of waste paper tested, newspaper proved to be the most appropriate for board manufacture, and magazine paper the least appropriate. With the exception of screw-holding strength, the substitution of wood particles by mixed waste paper flakes in amounts up to 50% resulted in acceptable mechanical properties for specific applications in interior uses. 相似文献
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To verify master curves obtained based on time–temperature superposition principle for wood–plastic composites (WPCs), a 220-day long-term creep test was conducted under an unconditioned environment. In this study, WPCs were made by extrusion with various formulations; using mountain pine beetle-attacked lodgepole pine flour and high-density polyethylene as raw materials, as well as maleated polypropylene as coupling agent. The results showed that the effect of naturally elevated temperature during the summer months caused additional increases in creep strain. The information obtained from the conventional creep study method may be insufficient to reflect the practical application. Comparisons between long-term data and the master curves showed that the master curves tended to overestimate the real creep strain of large specimens and that the deviation increased with time. The prediction of the master curve agreed more reasonably with the long-term data for coupled WPC products, whereas the master curves showed considerable overestimation for the uncoupled ones. In general, the master curves cannot precisely predict the long-term creep strain, but merely provide conservative estimations. 相似文献
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E. Kristofer Gamstedt Thomas K. Bader Karin de Borst 《Wood Science and Technology》2013,47(1):183-202
Mixed numerical–experimental methods are increasingly used in various disciplines in materials science, recently also in wood micromechanics. Having a relatively irregular microstructure, direct interpretation of mechanical tests is not always possible since structurally specific properties are quantified rather than general material properties. The advent of combined numerical–experimental methods unlocks possibilities for a more accurate experimental characterization. A number of examples of mixed methods pertaining to both emerging experimental techniques and physical phenomena are presented: nano-indentation, moisture transport, digital-image correlation, dimensional instability and fracture of wood-based materials. Successful examples from other classes of materials are also presented, in an attempt to provide some ideas potentially useful in wood mechanics. Some general pit-falls in parameter estimation from experimental results are also outlined. 相似文献
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A conductive and corrosion-resistant wood-based composite was obtained via electroless Ni–W–P plating on birch veneers. The W content of the Ni–W–P coatings obtained under different Na2WO4 concentrations in the plating bath was analyzed. The crystal structure, surface morphology, electrical resistivity, electromagnetic shielding effectiveness, surface wettability, adhesive strength and corrosion resistance of the composite were investigated. Energy-dispersive spectroscopy and X-ray photoelectron spectroscopy results showed that the coating consisted mainly of Ni0, Mo0 and P0 doped with little of their oxides. X-ray diffractometry analysis suggested the obtained coatings contained a nanocrystalline structure. Scanning electron microscopy images showed that the veneer surfaces were covered with uniform and continuous coatings. Birch veneers plated with Ni–W–P alloy exhibited good electrical conductivity with surface resistivity below 200 mΩ/cm2 and shielding effectiveness above 35 dB from 9 kHz to 1.5 GHz. Ni–W–P films firmly adhered to the wood surface. Water contact angle of the composite reached about 130° indicating the hydrophobic surface. The Ni–W–P-plated veneers showed excellent corrosion resistance due to the polarization resistance above 3.1 kΩ/cm2. This study further provides a new method for fabricating multifunctional wood-based composites. 相似文献
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David Janik Dusan Adam Tomas Vrska Libor Hort Pavel Unar Kamil Kral Pavel Samonil David Horal 《European Journal of Forest Research》2008,127(4):337-345
The paper deals with the issue of the spontaneous development of Central-European floodplain forests. The research object
was the Cahnov–Soutok National Nature Reserve situated on the confluence of Dyje R. and Morava R. in the Czecho–Slovak-Austrian
borderland area. This locality has been left to spontaneous development since the beginning of the 1930s. In the years 1973,
1994 and 2006, the surveyed site was subjected to the measurement of standing and lying, live and dead trees reaching a diameter
at breast height of 10 cm and the whole area regeneration of woody species. The work objective is to describe the most pronounced
trends in tree layer changes having occurred in the period of study and to capture changes in the total tree volume and production
of dendromass during the disintegration of the old grazing oak layer. The survey into the near-natural floodplain forest of
Cahnov–Soutok showed that (1) the most significant trend is a decreased representation of Quercus robur in all monitored indicators and conversely an expanding representation of Acer campestre, Carpinus betulus and Tilia cordata and (2) that the floodplain forest ecosystem demonstrates a high-level stability in the total volume of tree biomass with
an essential change in the tree species composition, spatial structure and average stem volume of individual trees. 相似文献
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《Forest Ecology and Management》1998,106(1):9-18
Dendroecological techniques were used to examine the disturbance history and patterns of species recruitment in an old-growth Quercus rubra L. (northern red oak)–Acer saccharum Marsh. (sugar maple)–Tilia americana L. (basswood) forest on a steep, talus slope in eastern West Virginia. The forest was uneven-aged as were the populations of red oak. Sugar maple dominated the sapling layer, which comprised little or no basswood and red oak. A compilation of major and moderate releases (indicative of disturbance) in 25 cores revealed single or multiple release events in every decade from 1870–1990. The high elevation of the forest coupled with a fertile sub-soil beneath the talus ameliorated the outwardly harsh conditions of the site, allowing for the domination of typically mesophytic, nutrient demanding tree species. We observed several fire scarred trees as well as extensive small-scale blow-down throughout the forest. Frequent disturbance events were probably crucial to the co-existence and continuous canopy recruitment of the relatively light demanding red oak with highly shade tolerant sugar maple and basswood. The strong successional replacement tendencies of red oak by northern hardwoods noted elsewhere in the eastern US may be less apparent on high elevation, rocky sites in the central Appalachians. Thus, this is a unique case study of long-term red oak domination with later successional species in an old-growth forest. 相似文献
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In a survey of the Bore–Anferara–Wadera forest to study the vegetation structure and regeneration status of woody plant species, 112 quadrats were systematically sampled along altitudinal transects to collect vegetation data. Nested sample plots of 30 m × 30 m and 5 m × 5 m were laid for collecting data on abundance and some variables of tree and shrub size. The regeneration status of woody species was assessed by counting all seedlings within the main sample plot. Woody plant species taller than or equal to 3 m were counted and their height and DBH measured. Density, frequency, basal area and importance value(IV) of woody plant species were computed. A total of 136 vascular plant species belonging to119 genera and 63 families were recorded. The overall Shannon—Wiener diversity value was 3.84 and evenness was 0.78. Total density of trees and shrubs with DBH >2 cm was 1047 ha-1. Size class distribution of woody species across different DBH and height classes indicated a relatively high proportion of individuals at lower classes,suggesting impacts of past anthropogenic disturbances.Analysis of population structure and regeneration status of the forest revealed various patterns of population dynamics where some species were represented by only a few mature plants, suggesting that they are on the verge of local extinction and that immediate conservation measures should be taken. The results highlight the need for joint management and conservation measures by the government, local people and other stakeholders to abate the rapid rate of deforestation and promote sustainable utilization of the forest resources in this forest in southern Ethiopia. 相似文献
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《Forest Ecology and Management》2004,199(1):165-173
Severe storm damage has been a recurring problem to the Swedish forestry sector since, at least, the start of the19th century. This short communication presents a regionally resolved time-series of storm damage in Swedish forests during the last century. Data on storm damage have been gathered from the National Board of Forestry, the Regional Forestry Boards and scientific reports.Storm damage in Swedish forests seems to have increased during the century with a peak around the 1980s. In total 110 million m3 forest were destroyed by 77 recorded wind storms, with the severe storms in 1954 and 1969 accounting for 49% of the total damage. Reported damage in southern Sweden was normalised against the area of productive forest with trees older than 40 years, for inter annual comparisons. The geostrophic wind was used to describe the regional wind direction during the storm events. Most damage occurred during NNW to SW winds, and by winds from NNE. Apart from a possible shift in storm intensity and frequency, the increase in storm damaged trees can be attributed to changes in regeneration and thinning regimes, variations in storm damage reporting system, increase in forest cover and various damage to root architecture. 相似文献