首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
ABSTRACT

Composites formed from wood fibers and man-made cellulosic fibers in PLA (polylactic acid) matrix, manufactured using sheet forming technique and hot pressing, are studied. The composites have very low density (due to high porosity) and rather good elastic modulus and tensile strength. As expected, these properties for the four types of wood fiber composites studied here improve with increasing weight fraction of fibers, even if porosity is also increasing. On the contrary, for man-made cellulosic fiber composites with circular fiber cross-section, the increasing fiber weight fraction (accompanied by increasing void content) has detrimental effect on stiffness and strength. The differences in behavior are discussed attributing them to fiber/ fiber interaction in wood fiber composites which does not happen in man-made fiber composites, and by rather weak fiber/matrix interface for man-made fibers leading to macro-crack formation in large porosity regions.  相似文献   

2.
Chemical components are the main factors affecting the mechanical properties of wood fibers. Lignin is one of the main components of wood cell walls and has a critical effect on the mechanical properties of paper pulp and wood fiber based composites. In this study, we carried out tensile tests on single mature latewood tracheids of Chinese fir (Cunninghamia lanciolata (Lamb.) Hook.), using three different delignified treatment methods to obtain different amounts of lignin. We applied single fiber tests to study the effect of the amount of lignin on mechanical tensile properties of single wood fibers at the cellular level. The results show that in their dry state, the modulus of elasticity of single fibers decreased with the reduction in the amount of lignin; even their absolute values were not high. The amount of lignin affects the tensile strength and elongation of single fibers considerably. Tensile strength and elongation of single fibers increase with a reduction in the amount of lignin.  相似文献   

3.
木纤维PP/PE共混物复合材料的流变和力学性能(英文)   总被引:2,自引:0,他引:2  
For evaluation of the rheological and mechanical properties of highly filled wood plastic composites (WPCs), polypropylene/polyethylene (PP/PE) blends were grafted with maleic anhydride (MAH) to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region (〈0.1%). The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.  相似文献   

4.
Abstract

This study focuses on the water absorption and mechanical properties of composites made from softwood sawdust and plastics, such as virgin and recycled polypropylene and polylactic acid (PLA). The composites were processed by extrusion, and their properties were investigated by a water immersion test, mechanical tests and a cyclic test for moisture resistance. Scanning electron microscopy was used to study the morphology of the fracture surfaces of the composites. The composites made with recycled polypropylene had the lowest water absorption and thickness swelling of the studied composites. The PLA composites made with heat-treated sawdust showed the highest flexural strength. Of the polypropylene based composites, virgin polypropylene resulted in composites with higher flexural strength. The Charpy impact strength of the composites was found to have an inverse trend compared to flexural strength. Cyclic treatment of the studied composites resulted in 20–60% loss of flexural strength, depending on type of composite.  相似文献   

5.
为探索纳米CaCO3对增强生物可降解复合材料力学性能的影响,采用混炼、注射成型工艺制备纳米CaCO3改性木纤维/聚乳酸复合材料,研究了纳米粒子添加量(1wt%,2wt%,3wt%,4wt%)及粒子预处理(偶联剂,硬脂酸,偶联剂-硬脂酸)对材料拉伸性能与冲击性能的影响。随着CaCO3添加量增加,复合材料力学强度先增大后减小,质量分数2%时材料拉伸强度和冲击强度分别提高8%与20%,粒子的增韧效果明显。预处理不仅能增强木纤维与聚乳酸的结合,也提高了纳米粒子分散性,增强材料整体力学性能。纳米粒子在聚合物基体中的分散性及其与聚合物界面结合是影响材料性能的关键。  相似文献   

6.
Abstract

This study investigated the effects of organoclay platelet contents (0, 3 and 5 wt%) and polypropylene type (virgin and recycled) on the mechanical properties of polypropylene/wood flour composites. Composite samples were made by melt compounding and consequent injection moulding. The tensile, flexural and impact properties of resultant composites were determined. X-ray diffraction (XRD) analysis of composites with 3 and 5% nanoclay content was also conducted. The results indicated that tensile and flexural properties of the composites increased with the addition of nanoclay particles up to 3 wt% and decreased thereafter. The impact strength of the composites, however, decreased with the incorporation of nanoclay. The mechanical properties of the recycled polypropylene-based nanocomposites were statistically comparable with those based on virgin polypropylene. XRD analysis revealed that the degree of intercalation in the nanocomposites containing 3% nanoclay was higher than in those containing 5%. Based on these results, it can be concluded that recycled polypropylene could be used instead of virgin polypropylene in the production of value-added products with no significant adverse effects on the mechanical properties.  相似文献   

7.
The effect of wood species (Chinese fir and Poplar), wood fiber content (10%, 25%, 40%) and wood fiber sizes (16 to 32 mesh, 32-65 mesh, above 65 mesh) on the properties of the wood fiber-Polypropylene composites were studied in this paper. The results indicate that the effect of wood fiber content and size in composite were more important than that of chosen wood species. Compared with polypropylene without wood fiber, the flexural strength of the composites increased when adding wood fiber into polypropylene, but the tensile and unnotched charpy impact strength decreased. And the above strength decreased with the wood fiber content increasing. When the wood fiber size becoming smaller (in higher mesh), the strength increased. In the comparison of wood species, the properties of composite using Chinese fir wood were better than that of Poplar, but not significant. The dynamic mechanical properties of the composites and PP were also tested and analyzed in this paper.  相似文献   

8.
Kenaf fibers have excellent properties and possess the potential to be outstanding reinforcing fillers in cement. The grafting of acrylamide to kenaf fibers is important in improving the compatibility between the fibers and the cement. Acrylamide was grafted onto kenaf fibers using gamma-ray radiation. The radiation dose ranged from 20 to 100 kGy, and the dose rate was 10 kGy/h. The degree of grafting increased with increased radiation doses. FT-IR analysis revealed an increase in amide content after gamma-ray-radiation-induced grafting, further evincing the attachment of acrylamide to the kenaf fibers. SEM images showed evidence of acrylamide grafting to the fiber surface. Contact angle measurements on individual fibers taken before and after grafting demonstrated changes in wettability. The mechanical properties of the gamma-ray-grafted kenaf fiber–cement composites were superior to those of the ungrafted kenaf fiber–cement specimens.  相似文献   

9.
In order to reduce the density of wood-based composites without causing a deterioration of their mechanical properties, we studied the process of manufacturing wood-based composites. A combination of polymer foaming technology and flat hot-pressing technology was used. The microscopic structure of the various wood-based composites was analyzed with a scanning electron microscope (SEM). Modulus of rupture (MOR), modulus of elasticity (MOE), impact strength, and thickness expansion rate of water sorption (TS) were all measured. The results showed that fibers loosely interweave, and fibers had been connected by micropore. They also showed that spaces between fibers had big micropore structure. MOR, MOE and impact strength were the highest among three levels of ratio. When the total content of resin and foaming agent were 20% by weight, TS was higher. A hot-pressing temperature of 120°C was optimal. At the low temperatures of 80°C, the foaming process was uncompleted. At a higher temperature, micropores burst at a certain pressure. Based on the variance analysis and maximum difference analysis, a significance test shows that the optimum conditions for the total content of resin and foaming agent is 20% by weight, with a hot pressing temperature of 120°C for 15 min. Under these conditions, the properties of wood-based foaming composites all achieved the industry standard. __________ Translated from Journal of Beijing Forestry University, 2007, 29(3): 154–158 [译自: 北京林业大学学报]  相似文献   

10.
High-density polyethylene (HDPE), bagasse fibers treated by four pulping processes (AS-AQ (alkaline sulfite anthraquinone), SODA-AQ (soda anthraquinone), MEA (monoethanolamine) and chemical–mechanical pulping (CMP)), three levels of nano-SiO2 (0, 2, and 5?wt%), and maleic anhydride polyethylene as coupling agent were used to produce pulp–plastic composites (PPCs) by injection molding. The physical and mechanical properties of corresponding composites were evaluated according to ASTM standards. The results showed that compared to untreated bagasse/HDPE composite, the addition of bagasse pulp fibers increased significantly the mechanical properties such as tensile strength and modulus, flexural strength and modulus, and hardness. The chemical pulps-reinforced composites showed better mechanical strengths than that of CMP-reinforced composites, but in some properties, CMP pulp composites have comparable results to the chemical pulp-reinforced composites. Natural fibers (untreated and treated) increased water absorption and thickness swelling of composites compared to pure HDPE. The addition of nano-SiO2 particles showed both increasing and decreasing trends on physical and mechanical properties ofPPCs.  相似文献   

11.
织物增强聚合物(TRP)因其具有优异的机械性能而被广泛应用于汽车、建筑等领域。传统TRP材料通常以玻璃纤维、碳纤维作为增强体,由于成本高及不可降解等问题限制了发展和应用。本研究采用可生物降解的天然黄麻纤维为增强体,以乙烯酯为基体树脂,采用模压工艺制备双层黄麻织物增强乙烯酯树脂复合材料。考察经纱和纬纱的取向对复合材料密度、孔隙率及力学性能的影响。通过调整黄麻织物的纱线角度(0°,30°,45°,60°和90°),研究经纬纱角度对复合材料性能的影响,采用的模压成型工艺是80℃、7 MPa条件下压制2.5 h。为了考察模压温度的影响,将纱线角度为60°的试样在40℃的低温条件下(其余条件不变)压制成型。结果表明:与纯乙烯酯相比,黄麻纤维具有一定的增强作用,复合材料的弯曲强度和冲击强度分别提高24.77%和39.83%,拉伸性能降低30.52%。扫描电子显微镜结果显示,复合材料力学强度的提高与纱线间的孔隙分布有关。在研究范围内,经纬纱定向对复合材料的冲击强度影响比较显著。低温(40℃)条件下,制备的定向角为60°时的黄麻纤维增强乙烯基酯复合材料的各项力学性能达到最佳。  相似文献   

12.
Wood flour (WF) and polypropylene (PP) composites (WF/PP) were compatibilized by m-isopropenyl-α,α-dimethylbenzyl isocyanate grafted polypropylene (m-TMI-g-PP). The effect of wood flour, m-TMI-g-PP contents on the rheology, dynamic mechanical analysis (DMA), mechanical properties, as well as the morphology of the composites were investigated and discussed. Rheology, DMA results showed that m-TMI-g-PP was an effective compatibilizer for WF/PP composites. The shear modulus (G′) and complex viscosity (η*) of the composites were increased, which implied that the composites probably withstood pronounced shear forces, resulting from strong adhesion at the interface between the matrix PP and WF. The mechanical test indicated that the tensile strength and the flexural strength of the composites were improved with increasing content of m-TMI-g-PP. From the properties tests, the optimum loading of WF in WF/m-TMI-g-PP/PP was found to be 40%, and the optimum loading of m-TMI-g-PP was 6%. Property enhancement is attributed to improved wetting and interactions between the PP matrix and WF, which is supported by scanning electron microscopy analysis.  相似文献   

13.
The aim of this study is to investigate the properties of CaCO3 in situ treated bamboo pulp fiber (BPF) composites that have been filled with epoxy resin by means of vacuum-assisted resin infusion (VARI). Un-treated and treated BPF were processed at a pressure of 0.24 MPa into BPF preforms. VARI was used to infuse epoxy resin through the BPF preforms to make BPF composites. The flexural properties, impact property, and thermal properties of the BPF composites were analyzed. CaCO3 with the loading of 30 wt% affects the performance of the composites. The flexural strength did not decrease and modulus of the treated BPF composites increased by 9.38%, while the impact strength decreased by 50.98%, compared to the control sample. Dynamic mechanical analysis revealed the maximum elastic moduli of the treated specimens increased by 1.19 times in the temperature range of ?20 to 120 °C. The thermal decomposition temperature of the composites was influenced by the effect of the crystal field and size effect of CaCO3.  相似文献   

14.
Binderless fiberboards with densities of 0.3 and 0.5 g/cm3 were developed from kenaf core material using the conventional dry-manufacturing process. The effects of steam pressure (0.4–0.8 MPa) and cooking time (10–30 min) in the refining process, fiber moisture content (MC) (10%, 30%), and hot-pressing time (3–10 min) on the board properties were investigated. The results showed that kenaf core binderless fiberboards manufactured with high steam pressure and long cooking time during the refining process had high internal bond (IB) strength, low thickness swelling (TS), but low bending strength values. The binderless fiberboards made from 30% MC fibers showed better mechanical and dimensional properties than those from air-dried fibers. Hot-pressing time was found to have little effect on the IB value of the binderless board at the refining conditions of 0.8 MPa/20 min, but longer pressing time resulted in lower TS. At a density of 0.5 g/cm3, binderless fiberboard with the refining conditions of 0.8 MPa/20 min recorded a modulus of rupture (MOR) of 12 MPa, modulus of elasticity (MOE) of 1.7 GPa, IB of 0.43 MPa, and 12% TS under the optimum board manufacturing conditions. Part of this article was presented at the 54th Annual Meeting of the Japan Wood Research Society, Hokkaido, August 3–5, 2004  相似文献   

15.
Kevlar fiber (KF) is a synthesized product with strong mechanical properties. We used KF as a reinforcement to improve the mechanical properties of wood-flour/polypropylene (WF/PP) composites. KF was pretreated with NaOH to improve its compatibility with the thermoplastic matrix. Maleated polypropylene (MAPP) was used as a coupling agent to improve the interfacial adhesion between KF, WF, and PP. Incorporation of KF improved the mechanical properties of WF/PP composites. Treatment of KF with NaOH resulted in further improvement in mechanical strength. Addition of 3% MAPP and 2% hydrolyzed KF (HKF) led to an increment of 93.8% in unnotched impact strength, 17.7% in notched impact strength, 86.8% in flexure strength, 50.8% in flexure modulus, and 94.1% in tensile strength compared to traditional WF/PP composites. Scanning electron microscopy of the cryoractured section of WF/PP showed that the HKF surface was rougher than the virgin KF, and the KF was randomly distributed in the composites, which might cause a mechanical interlocking between KF and polypropylene molecules in the composites.  相似文献   

16.
Although wood/cellulose-plastic composites (WPC) of low wood/cellulose content have been more accepted worldwide and are promoted as low-maintenance, high-durability building products, composites containing high wood/cellulose content are not yet developed on an industrial scale. In this study, flow properties, mechanical properties, and water absorption properties of the compounds of cellulose microfiber/polypropylene (PP) and maleic anhydride-grafted polypropylene (MAPP) were investigated to understand effects of the high cellulose content and the dimensions of the cellulose microfiber. The molding processes studied included compression, injection, and extrusion. It was found that fluidity is not only dependent on resin content but also on the dimension of the filler; fluidity of the compound declined with increased fiber length with the same resin content. Dispersion of the composite was monitored by charge-coupled device (CCD) microscope. Increasing the plastic content in the cellulose-plastic formulation improved the strength of mold in addition to the bond development between resin and filler, and the tangle of fibers. The processing mode affected the physicomechanical properties of the cellulosic plastic. Compression-molded samples exhibited the lowest modulus of rupture (MOR) and modulus of elasticity (MOE) and the highest water absorption, while samples that were injection-molded exhibited the highest MOR (70 MPa) and MOE (7 GPa) and low water absorption (2%).  相似文献   

17.
Short carbon fibers, a reinforced material in wood veneer composites, were used to investigate the effects of fiber length and orientation of fibers on the elasticity of plywood. The technical feasibility, elasticity, and strength of the reinforced plywood with short carbon fiber were evaluated. In a short fiber reinforcement system, the fiber length does not directly influence the reinforcement in Cox's theory when the fiber length exceeded a certain length. When the length of short carbon fiber is beyond 3 mm, the high reinforced result was obtained in the experiment. However, if fiber length was too long, the reinforced result was less owing to the bridge between fibers and the increase of holes. The optimum fiber length must be considered. The orientation of fibers has a strong influence on the reinforcement. Unidirectional, perpendicular, and random orientation displayed different influence on the elasticity. Experimental results were discussed with Cox's method. Reinforced plywood with short carbon fibers in random orientation has a higher shear modulus and bending strength than the controls, in addition to other mechanical properties.  相似文献   

18.
The effects of using 100% black spruce (Picea mariana) bark fibers as core layer material accounting for up to 70% of the board and its resin content (between 6 and 10%) on the properties of three-layer medium-density fiberboard (MDF) were investigated using a full factorial experimental design with two independent variables and three levels. Five response variables, namely internal bond strength, modulus of rupture, modulus of elasticity, thickness swelling and water absorption were statistically analyzed using a response surface methodology and two-way analysis of variance. The effects of the proportion of core layer (bark fibers) and its resin content on panel properties were significant. All properties studied were positively affected by increasing core layer resin content. The effects of the proportion of core layer (bark fibers) on mechanical properties and water absorption were negative, but positive on thickness swelling. Simultaneous optimization of panel properties indicated that at a density of 850 kg/m3, a three-layer MDF with a core layer resin content of 6.5%, a face resin content of 12 and 60% of core layer proportion (spruce bark fibers) would satisfy the minimum requirements of ANSI standard for 130-grade MDF. Overall, black spruce bark, a major residue source in the Eastern Canada, should be considered as a supplemental furnish for the core layer materials of a three-layer MDF.  相似文献   

19.
ABSTRACT

High global production of medium-density fiberboard (MDF) in recent years could generate an equal quantity of waste MDF at the end of its service life, requiring recycling of waste MDF instead of landfilling or incineration. This study investigated effects of the addition of recycled fiber (RF) obtained from surface laminated MDFs with three different materials to the properties of three-layer recycled MDF (rMDF). Three types of surface laminates such as low-pressure laminate, polyethylene terephthalate, and polyester coating were hammer milled, and then went through a patent-pending fiber recovery system to obtain the resultant RFs that were added to the core layer of rMDF. These RFs at three contents (10, 20, and 30%) were blended with 12% of urea-formaldehyde (UF) resin prior to hot-pressing. Statistical analysis showed that the best internal bonding strength, modulus of rupture, and modulus of elasticity of rMDF panels were obtained for LPL-rMDF with a 20% RF content. Thickness swelling, water absorption, and formaldehyde emission of rMDF were reduced by increasing the RF content. These findings suggest that a minimum RF content of 20% can be replaced with virgin fibers for the rMDF manufacture, indicating the feasibility of recycling waste laminated MDF into three-layer rMDF.  相似文献   

20.
Binderless boards were prepared from steam-exploded fiber of oil palm(Elaeis guineensis Jacq.) frond at six levels of explosion conditions. Their properties were investigated and evaluated. The mechanical properties (i.e., modulus of rupture, modulus of elasticity, and internal bonding strength) of the boards increased linearly with increasing board density as the usual hardboard. The boards made from fibers treated under a steam explosion condition of 25 kgf/cm2 (steam pressure) and 5 min (digestion period) exhibited the maximum strength. These boards at a density of 1.2 g/cm3 met the requirement of S-20 grade of JIS A 5905 — 1994 (fiberboard). Thickness swelling of the boards ranged from 6% to 14% under the JIS A 5908 — 1994 (particleboard) test condition and showed no significant changes with increasing board density. The main bonding strength of the board is believed to be due to a ligninfurfural linkage. Considering the chemical components of oil palm frond, which is rich in hemicellulose, there seems to be a good possibility for producing binderless boards using steam-exploded fibers of oil palm frond.This study was presented in part at the 2nd International Wood Science Seminar, Serpong, Indonesia, November 1998  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号