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1.
The influence of pH was examined, over the range from 6 to 14, on the amounts of p-hydroxybenzoic, vanillic, p-coumaric, ferulic and syringic acids, p-hydroxybenzaldehyde and vanillin, extracted from four soils and associated roots or leaf litter. Adjustment of pH was obtained by the addition of graded amounts of Ca(OH)2 to water or by 2 m NaOH. The roots associated with three of the soils were from permanent pasture, perennial ryegrass and red clover, while the leaf litter associated with the fourth soil was from beech.The amounts of each phenolic compound extracted increased continuously with increasing pH, from a “threshold” value which varied between pH 7.5 and 10.5. The amounts extracted by water alone from the soil under permanent pasture, at pH 5.8, were equivalent to concentrations in the soil solution ranging from 1.4 μm for p-hydroxybenzoic acid to < 10 nm for ferulie acid. Amounts of up to 2000 times greater than these were extracted by 2 m NaOH. Similar effects of extractant pH were found with the other soils.Comparisons of the amounts of the phenolic compounds extracted from the soils, with the amounts extracted from the associated roots or leaf litter, suggested that substantial proportions of the soil phenolic compounds were either derived from organic residues more than 4 yr old or were the result of microbial synthesis. 相似文献
2.
Saadatullah?Malghani Elisabeth?Jüschke Julia?Baumert Angelika?Thuille Markus?Antonietti Susan?Trumbore Gerd?Gleixner
Soil amendment with hydrochar produced by hydrothermal carbonization of biomass is suggested as a simple, cheap, and effective method for increasing soil C. We traced C derived from corn silage hydrochar (δ13C of ?13?‰) added to “coarse” and “fine” textured soils (δ13C of ?27?‰ for native soil C (SOC)) over two cropping seasons. Respiration rates increased in both soils (p?<?0.001) following hydrochar addition, and most of this extra respiration was derived from hydrochar C. Dissolved losses accounted for ~5 % of added hydrochar C (p?<?0.001). After 1 year, 33?±?8 % of the added hydrochar C was lost from both soils. Decomposition rates for the roughly two thirds of hydrochar that remained were very low, with half-life for less estimated at 19 years. In addition, hydrochar-amended soils preserved 15?±?4 % more native SOC compared to controls (negative priming). Hydrochar negatively affected plant height (p?<?0.01) and biomass (p?<?0.05) in the first but not the second crop grown on both soils. Our results confirm previous laboratory studies showing that initially, hydrochar decomposes rapidly and limits plant growth. However, the negative priming effect and persistence of added hydrochar C after 1 year highlight its soil C sequestration potential, at least on decadal timescales. 相似文献
3.
《Communications in Soil Science and Plant Analysis》2012,43(5-6):757-772
Abstract Soil samples from different land use systems were collected before cropping (in spring) and after harvest (in fall) for organic phosphorus (P) extractions by 0.4M sodium hydroxide (NaOH) and characterization by 31P nuclear magnetic resonance spectroscopy. To prevent hydrolysis of organic P compounds prior to sample concentration, NaOH was removed from the NaOH soil extracts using a G‐25 Sephadex column. The 31P NMR spectra in the NaOH soil extracts showed the presence of glucose‐6 phosphate (up to 64%), glycerophosphate (up to 45%), nucleoside monophosphates (up to 91%), and polynucleotides (up to 58%) as the major forms of organic P in soils. The relative concentration of nucleoside monophosphates and polynucleotides decreased in some of the soils after harvest. The 31P NMR spectra of the extracts also revealed the presence of phosphoenolpyruvates, a previously unreported form of soil organic P. 相似文献
4.
Naoharu Mizuno Hozumi Yoshida Masami Nanzyo Toshiaki Tadano 《Soil Science and Plant Nutrition》2013,59(3):289-295
Potato common scab induced by Streptomyces scabies is a serious constraint for potato-producing farmers and the incidence of potato scab depends on the soil chemical properties. We examined the chemical characteristics of conducive and suppressive soils to potato common scab with reference to the chemical properties of nonallophanic Andosols, recently incorporated into the classification system of cultivated soils in Japan. Allophanic Andosols with a ratio of pyrophosphate-extractable aluminum (Alp) to oxalate-extractable aluminum (Alo) of less than 0.3–0.4 were “conducive” soils with a high allophane content of more than 3%. On the other hand, nonallophanic Andosols with a Alp/Ala ratio higher than this critical value were “suppressive” soils, and their allophane content was less than 2%. The concentration of water-soluble aluminum (AI) was also a useful index for separating conducive from suppressive soils as well as the Alp/Ala value and allophane content. The suppressive soils showed a much higher concentration of water-soluble Al at pH 4.5 to 5.5 than the conducive soils. The high concentration of water-soluble Al may be responsible for the control of the incidence of potato common scab in Andosols. 相似文献
5.
《Communications in Soil Science and Plant Analysis》2012,43(13-14):1453-1477
Abstract Differences were studied in humic (HA) and fulvic acid (FA) extracted from soils and streams in South Georgia by the Amberlite XAD‐8 resin and conventional NaOH method. Characterization analysis was performed by liquid 13C NMR, infrared (IR) spectroscopy, scanning electron microscopy (SEM), and chemical analysis. The NMR spectra indicated that the resin method yielded black water HA and FA with spectroscopic, chemical and elemental characteristics different from those isolated by the conventional NaOH method. Humic acids from both the resin and conventional NaOH methods were composed of aliphatic, aromatics and carboxyl groups, but the “resin”; HA contained more aliphatic groups. These differences were also noticed between the FA fractions obtained by the two methods. The differences corresponded to differences in IR spectra. The IR spectrum of “resin”; FA exhibited only a weak shoulder at 1625/cm for the COO”; stretching vibration, in contrast to that of FA isolated by the conventional NaOH procedure. Apparently, the high aliphatic‐CH3 group content has blocked the vibration above, as evidenced by methylation of HA. Fulvic acid extracted by the resin method was also higher in total acidity, but considerably lower in N content than FA obtained by the conventional NaOH method. Both methods yielded black water FA which was less aromatic in nature than black water HA, or soil FA. 相似文献
6.
《Geoderma》2006,130(1-2):176-189
The distribution and form of P in soil is central to the sustainability of agricultural practice. This study used sequential fractionation and 31P nuclear magnetic resonance spectroscopy (31P NMR) of NaOH–EDTA extracts to examine the influence of pastoral, native (undisturbed) and forest land use on soil P forms in 5 contrasting soils ranging from a Regosol to a Rendzina in Otago, New Zealand. Climatic factors likely to influence soil P distribution were negated by careful site selection. Together with a decrease in soil organic C (31%), total P decreased in forested soils (mean=674 mg kg−1) compared to native soils (mean=784 mg kg−1). In contrast, the ratio of inorganic to organic P increased (10%) probably due to mineralization of organic P in forest soils, while for pasture soils, accumulation of P in inorganic forms due to P inputs via fertilisers and animal dung was to blame. Investigation of the organic P forms in NaOH–EDTA extracts of each land use by 31P NMR indicated that diesters were greatest in the native soil (4–12% of total P in spectra), and declined as a proportion of total P in pasture soils and more so in forest soils. This was reflected in a decline of the diester to monoester ratio. However, the ratio was generally greater in forest than pasture soils and attributed to the labile nature of diesters, mineralization of monoesters in forest soils, and an increase in monoesters in pasture soils from inositol phosphates in plant debris. This effect was pronounced in the Regosol due to sandy texture and the preferential accumulation of plant debris in coarse particle size fractions. Due to the depletion of soil P reserves, forest soils in the area should be followed by pasture and well managed fertiliser additions before replanting. 相似文献
7.
Differences in the properties of soil organic matter as a result of differing soil managements The organic matter of 62 soil samples from 20 farms was analyzed by the following methods: total organic C, “light” C (density < 2 g/ml) and C content and Q 4/6 of extracts obtained with NaF and NaOH solutions under different conditions. The soil samples were obtained from 10 pairs of adjacent plots; in each pair one of the plots was under “conventional”, the other under “bio-dynamic” management. The results obtained by the different laboratory methods evidenced more or less clearly the different managements. C extracted by shaking the soil with 0,5 % NaOH was most significant in that respect. The results as a whole are coherent in showing that in the soils under bio-dynamic treatment of higher content of the more easily decomposable fractions of the organic matter as compared with the soils under conventional treatment can be detected by rather simple means. 相似文献
8.
The solubility and forms of phosphorus (P) were investigated in manures from chicken and pigs, eight whole soil samples and
clay-, silt-, and sand-size separates from an arable and a grassland soil. Total P (Pt) in liquid pig manure (16.2 g kg–1) and dry chicken manure (26.2 g kg–1) was distributed between residual P (39–41% Pt), H2SO4–P (17–27% Pt), labile resin- and NaHCO3–P (24–39% Pt), and NaOH-P (3–10% Pt). Most soils had larger proportions of NaOH-P and residual P, indicating reactions of manure-derived P compounds with pedogenic
oxides and humic substances. Clay-size separates had the highest P-concentrations in all fractions and were particularly enriched
in exchangeable and labile P forms. Solution 31P-nuclear magnetic resonance (NMR) spectra of 0.5 M NaOH extracts from manures and some soil samples showed greater signal intensities for orthophosphate and monoester P than
0.1 M NaOH extracts. This can be explained by alkaline hydrolysis phosphate diesters at higher NaOH concentrations and/or by preferential
extraction of diesters at lower concentrations. The 31P-NMR spectra showed differences between the two manures and confirmed that increasing proportions of ester-P can be expected
if they are spread to soils. The NaOH extracts of soil samples were characterized by large proportions of orthophosphate-P
(mean 77% of assigned P compounds), which seemed to be slightly enriched in clay fractions whereas the extracts from silt
contained more ester-P. Sequential extractions and 31P-NMR spectroscopy both showed that these excessively manured soils are likely to lose large amounts of P.
Received: 15 July 1996 相似文献
9.
V. S. Anisimov I. V. Kochetkov D. V. Dikarev L. N. Anisimova Yu. N. Korneev L. M. Frigidova 《Eurasian Soil Science》2016,49(8):868-878
The relationship between the main physicochemical properties of soils and the accumulation of natural Zn and 65Zn radionuclide has been studied, and the capacity of soils to limit the mobility of the element in the soil–plant system has been assessed. The contribution of each of the selected soil state parameters to the accumulation of zinc by barley has been determined, and the soil state parameters have been ranked. It has been found that the largest contributions to the variation of the resulting parameter (65Zn accumulation coefficient, Ka) are made by mobile Fe (25%), free carbonates (21%), and acid-soluble Zn (18%). The largest contributions to the ZnacKa are made by free carbonates (13%) and mobile Fe (8%). The contributions of physical clay and organic carbon in soils and qualitative composition of humic substances are almost similar (4% for each). No differences in the inactivating capacity of different soils (soddy-podzolic soils, gray forest soils, and chernozems) for 65Zn are observed. This is related to the fact that the transfer of 65Zn to plants is statistically significantly controlled by the contents of free carbonates, mobile iron, and potentially plantavailable forms of stable natural Zn (carrier of 65Zn) rather than the quantitative and qualitative composition of organic matter and the degree of dispersion of mineral particles. The analysis of the ZnacKa/65Zn Ka ratios has shown that the share of plant-available Zn in the acid-soluble form of the metal (1 M HCl) is 0.61 on the average for the studied soils, and its share in the total Zn content in the soils is only 0.14. 相似文献
10.
Stylianos Liodakis Magdalini Tsoukala Georgios Katsigiannis 《Water, air, and soil pollution》2009,201(1-4):99-107
For bioremediation of copper-contaminated soils, it is essential to understand copper adsorption and chemical forms in soils related to microbes. In this study, a Penicillium strain, which can tolerate high copper concentrations up to 150 mmol l?1 Cu2+, was isolated from a copper mining area. The objective was to study effects of this fungus on copper adsorptions in solutions and chemical forms in soils. Results from lab experiments showed the maximum biosorptions occurred at 360 min with 6.15 and 15.08 mg g?1 biomass from the media with Cu2+ of 50 and 500 mg l?1, respectively. The copper was quickly adsorbed by the fungus within the contact time of the first 60 min. To characterize the adsorption process of copper, four types of kinetics models were used to fit the copper adsorption data vs. time. Among the kinetics models, the two-constant equation gave the best results, as indicated by the high coefficients of determination (R 2?=?0.89) and high significance (p?<?0.01). The addition of the fungal strain to autoclaved soil facilitated increases in concentrations of acid-soluble copper, copper bound to oxides, and of copper bound to organic matter (p?<?0.05). However, the inoculation of Penicillium sp. A1 led to a decrease of water-soluble copper in the soil. The results suggested that Penicillium sp. A1 has the potential for bioremediation of copper-contaminated soils. 相似文献
11.
Phosphorus in soils is found to be present in organic combinations, inorganic form or in adsorted form on clay complex. Different forms of soil phosphorus have different solubilities and consequent availability in soils. A knowledge about the content and types of soil phosphorus enables one to understand the organic behaviour and predict the response of added phosphatic material to crops (Parker 1953). The form in which phosphorus is present in soil is directly related to pH and CaCO3 in the soil as well as the intensity of the development of the soil. Williams (1950) has found that in calcareous soils of South Australja most of the phosphorus was in combination with calcium, whereas in acid soils it forms compounds with alumina and iron. Hibbard (1931) concluded that in alkaline and calcareous soils, phosphorus exists mostly in the form of hydroxyapatite, chloroapatite, and the like. Kanwar and Grewal (1959) studied fractionation of phosphorus in Punjab soils and reported that differences in the nature and amounts of the phosphorus present in acid and alkaline soils of the State explain the causes of different phosphatic fertilizer responses to the crops. A similar report has been given by Goel and Agarwal (1959) who studied the fractionation of phosphorus in Kanpur soils and concluded that the mature soils are rich in iron and aluminium bound phosphorus and respond better to phosphatic fertilizer than the immature soils rich in Ca2+ and Mg2+ bound phosphorus. Chai Moo Cnoo and Caldwell (1959) reported that Fe3+ and Al3+ bound phosphorus was abundant in acid soils while Ca2+ and Mg2+ bound phosphorus content in alkaline soils, and organic phosphorus agreed, in general, with the content of organic matter, with some deviations. 相似文献
12.
Jes Leisgaard Poulsen Anne Louise Gimsing Barbara Ann Halkier Nanna Bjarnholt Hans Christian Bruun Hansen 《Soil biology & biochemistry》2008,40(1):135-141
Plants produce many secondary metabolites that are used as a defense against herbivores, pests and pathogens. Among them are the glucosinolates (GSLs) that are produced by plants of the Brassicales order. Upon enzymatic hydrolysis, GSLs are transformed to primarily isothiocyanates (ITCs) and nitriles. ITCs are toxic compounds with the potential to be used as biofumigants for the control of soil-borne pests. In this study, mineralization kinetics of benzyl GSL and benzyl ITC in a sandy and a clayey soil at 8–9 °C were investigated. Mineralization of 14C-benzyl GSL, which was de novo synthesized and purified from transgenic Arabidopsis thaliana after administering l-[U-14C]phenylalanine, showed that 40–50% was mineralized after 60 days. Mineralization of 14C-benzyl ITC produced by enzymatic hydrolysis of the 14C-benzyl GSL resulted in mineralization of 35–50% after 45 days. The ITC or a metabolite of ITC was rate limiting for mineralization of ITC during the first 10–15 days in incubations with subsoils. This effect may be attributed to toxicity of the ITC or an ITC metabolite, or that a lag phase was required for the relevant degraders to grow. Although the compounds are of natural origin and thus “known” to microbial degraders the extent of mineralization was not higher than for synthetic compounds like pesticides. After termination of the mineralization experiments, the soils were extracted with water, ethyl acetate and 4 M NaOH, respectively. These extractions indicated that a large amount of the applied 14C-labeled benzyl GSL and benzyl ITC was incorporated in organic fractions with low bioavailability. 相似文献
13.
We investigated the effects of land uses on P distribution and availability in selected calcareous soils under different management practices. KCl‐P (labile P), NaOH‐P (Fe‐Al‐bound P), HCl‐P (Ca‐bound P), and residual P (Res‐P) fractions at 0–30 cm depth were determined for soils planted to garlic, orchard, pasture, potato, leafy vegetables, and wheat. Trends in P distribution between chemical fractions were similar between land uses. Ca‐bound P was the most abundant P fraction in the soils, constituting between 61% and 78% of the total P, whereas P associated with labile was less abundant (< 2%). Soils under leafy vegetables and wheat along with pasture presented the highest and lowest values in all fractions of P, respectively. Labile P generally was highest for leafy vegetables and potato. Labile P and Fe‐Al‐bound P comprised < 1.4% and 8% of total P, respectively. Residual P ranged from ≈ 14% (potato and garlic) to 31% (pasture). Long‐term fertilization increased P allocation to inorganic fractions, as Ca‐bound P contained 78% of total P for potato and garlic and 74% for leafy vegetables but 61% for pasture. A strong positive correlation between labile P and Fe‐Al‐bound P (r = 0.534, p < 0.01), labile P and Ca‐bound P (r = 0.574, p < 0.01), Ca‐bound P and Fe‐Al‐bound P (r = 0.504, p < 0.01), Olsen‐P and CaCl2‐P (r = 0.821, p < 0.01) was found. Principal‐component analysis showed that the first four components accounted for most of the variation, 32.5%, 16.9%, 12.9%, and 7.9% of total variation, respectively. 相似文献
14.
P. V. Koroleva D. I. Rukhovich A. D. Rukhovich D. D. Rukhovich A. L. Kulyanitsa A. V. Trubnikov N. V. Kalinina M. S. Simakova 《Eurasian Soil Science》2018,51(9):1021-1033
A classical soil line (SL) in the RED–NIR spectral space is specified by two coefficients “a” and “b.” In this form, it does not characterize soil types and subtypes. A multitemporal soil line (MSL) represents the major axis of the ellipse describing all possible pairs of RED–NIR values characterizing a bare soil surface for a given pixel of remote sensing images. The MSL in the RED–NIR spectral space is specified by several (N) coefficients. The resulting N-dimensional space of MSL coefficients makes it possible to give unique characteristics for each type and subtype of soils in the following zonal soil sequence: soddy-podzolic soils, light gray forest soils, gray forest soils, dark gray forest soils, podzolized chernozems, and leached chernozems. The analysis of variance allows us to state that the soils of this sequence significantly differ from one another in the characteristic sets of MSL coefficients. In other words, these coefficients characterize soil types and subtypes, and the MSL can be considered an empirical soil line (ESL) of the given type and subtype of soil. A classical SL is an integrity of ESLs of different soils within the given scene of remote sensing data. 相似文献
15.
The effects of 10 urease inhibitors on nitrification in soils were studied by determining the effects of 10 and 50 parts/106 (soil basis) of each inhibitor on the amounts of nitrate and nitrite produced when soils treated with ammonium sulfate (200 μg of ammonium N/g of soil) were incubated (30°C) under aerobic conditions for 14 days. The urease inhibitors used (catechol. hydroquinone, p-benzoquinone, 2,3-dimethyl-p-benzoquinone, 2,5-dimethyl-p-benzoquinone. 2,6-dimethyl-p-benzoquinone. 2,5-dichloro-p-benzoquinone, 2,6-dichloro-p-benzoquinone. sodium p-chloromercuribenzoate, and phenylmercuric acetate) were those found most effective in previous work to evaluate more than 130 compounds as soil urease inhibitors. Their effects on nitrification were compared with those of three compounds patented as soil nitrification inhibitors (N-Serve. AM. and ST).Most of the urease inhibitors studied had little effect on nitrification when applied at the rate of 10 μg/g of soil. but had marked inhibitory effects when applied at the rate of 50 μg/g of soil. None inhibited nitrification as effectively as N-Serve. but phenylmercuric acetate inhibited nitrification more effectively than did AM or ST when applied at the rate of 10 μg/g of soil. Phenylmercuric acetate, 2,5-dimethyl-p-benzoquinone, and 2,6-dimethyl-p-benzoquinone had very marked effects on nitrification when applied at the rate of 50 μg/g of soil. 相似文献
16.
Phosphorus forms and dynamics as influenced by land use changes in the sub-humid Ethiopian highlands
《Geoderma》2002,105(1-2):21-48
In undisturbed tropical forest ecosystems, the phosphorus (P) cycle is essentially “closed” with minimal short-term losses or gains of P. The forms and dynamics of soil P, however, can be greatly affected by land use changes, which often involve changes in vegetation cover, biomass production and nutrient cycling in the ecosystem. Sequential extraction and 31P nuclear magnetic resonance (NMR) spectroscopy were used to investigate the influence of land use changes on the amount and structural composition of P in the sub-humid highlands of southern Ethiopia. Samples were collected from surface soils (0–10 cm) of natural forest, tea plantations and cultivated fields (25 years) at Wushwush and from Podocarpus dominated natural forest, Cupressus plantations and cultivated fields (30 years) at Munesa sites. Significantly lower (P<0.05) amounts of total P were found following clear-cutting and long-term cultivation (31% and 39%), and establishment of plantations (21% and 22%) at Wushwush and Munesa, respectively. The largest depletion of sodium bicarbonate-extractable organic P (NaHCO3–Po) (74% and 77%) and sodium hydroxide-extractable Po (NaOH–Po) (67% and 67%) due to cultivation occurred in the sand, followed by the silt (52% and 56%, NaHCO3–Po and 32% and 53%, NaOH–Po) and the clay (33% and 42%, NaHCO3–Po and 28% and 35%, NaOH–Po) size separates from the two sites, respectively. 31P NMR spectroscopy revealed that orthophosphate monoesters were the major organic P compounds (27–66%) followed by orthophosphate diesters (9–27%) and teichoic acids (7–11%). Unknown organic P species accounted for 3–8% (unknown A) and 3–5% (unknown B), whereas phosphonates made up 2–3%. The proportion of diester-P decreased in the order: natural forests (24% and 27%)>plantations (15% and 13%)>cultivated fields (10% and 9%) at Wushwush and Munesa, respectively. The percentages of teichoic acid, unknown A, unknown B and phosphonates also decreased, whereas the proportions of orthophosphate monoesters increased following land use changes. Greater decline in proportions of diester-P and teichoic acids were found in the silt than in the clay size separates, which may be attributed to stabilization of microbially derived organic P structures by closer association with clay minerals and/or sesquioxides. The results of sequential extraction and 31P NMR spectroscopy indicate that continuous cultivation with little or no P input not only decreased the amount, but also influenced the structural composition and bioavailability of P in these tropical soils. Thus measures have to be designed for replenishment and subsequent maintenance of soil P stocks, to ensure sustainable crop production in sub-humid highland agroecosystems of southern Ethiopia. 相似文献
17.
18.
Biao Fan Yuechun Zhao Ganhui Mo Weijuan Ma Junqin Wu 《Journal of Soils and Sediments》2013,13(7):1232-1245
Purpose
2,2-Bis(p-chlorophenyl)-1,1,1-trichloroethane (DDT), one of the most widely used organochlorine pesticides in soil, was banned in the 1970s for agricultural use because of its detrimental impacts on wildlife and harmful effects on human health via the food chain. However, high levels of DDT are frequently detected in agricultural soils in China. Considering this situation, this study investigated the use of white rot fungi and laccase derived from white rot fungi to co-remediate DDT-contaminated soil.Materials and methods
A culture of white rot fungi was used to inoculate soil samples and also to extract laccase from. Soil was contaminated with four components of DDT (p,p′-DDE, o,p′-DDT, p,p′-DDD, and p,p′-DDT). Individual DDT components and the sum of the DDT components (p,p′-DDE, o,p′-DDT, p,p′-DDD, and p,p′-DDT—collectively referred to as DDTs) were both analyzed by GC at various stages during the incubation period. The efficacy of co-remediating DDT-contaminated soil using white rot fungi and laccase was tested by investigating how degradation varied with varying amounts of white rot fungi, sterilizing soil, temperature, soil pH, concentrations of DDT, and concentration of the heavy metal ion Cd2+.Results and discussion
“”It was concluded that the reduction of DDTs in soil using white rot fungi and laccase was higher than reduction using only white rot fungi or laccase by nearly 14 and 16 %, respectively. Five milliliters fungi per 15 g soil and 6 U laccase per gram soil were the optimal application rates for remediation, as shown by a reduction in DDTs of 66.82 %. The difference in the reduction of individual DDT components and DDTs between natural and sterilized soils was insignificant. The optimal temperature and pH in the study were 28 °C and 4.5, respectively. In addition, reduction of individual DDT components and DDTs increased with increasing concentrations of DDT and decreased with increasing concentrations of Cd2+.Conclusions
Compared with the remediation of DDT using only white rot fungi or laccase, the co-remediation of DDT using white rot fungi and laccase degraded DDT in soil more rapidly and efficiently; the highest reduction of DDTs was 66.82 %. 相似文献19.
The different forms of phosphorus in alkaline extracts of eight New Zealand topsoils, which are members of a climosequence, were characterized by 31P-nuclear magnetic resonance (NMR). A further two topsoils were used in an experiment to demonstrate that the NMR technique detected all of the P in the extracts. This direct method of estimating organic P in soil extracts enabled the different types and the relative amounts of P compounds to be estimated.Inorganic orthophosphate and orthophosphate monoesters were the major P components of the extracts from all soils, while all but the two driest soils also contained orthophosphate diesters. Only the high country and alpine soils, developed in a moist cool environment, contained phosphonates, a recently-discovered form of soil P of probable microbial origin.Across the climosequence of soils, the amount of orthophosphate diesters in the extracts was strongly and positively correlated with annual precipitation. This organic P fraction, together with phosphonates, could provide through mineralization a ready supply of “available” P in these mainly undisturbed tussock grassland ecosystems. 相似文献
20.
Nicolas Reynier Jean-François Blais Guy Mercier Simon Besner 《Journal of Soils and Sediments》2013,13(7):1189-1200