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1.
Abstract

A study was conducted to investigate the chemical speciation of added cadmium (Cd) and lead (Pb) and their availability as influenced by fresh organic matter (OM) and sodium chloride (NaCl) in three agricultural soils. The soils were treated with 20 mg Cd/kg as cadmium nitrate [Cd(NO3)2 · 4H2O], 150 mg Pb/kg as lead nitrate [Pb(NO3)2], 20 g/kg alfalfa powder, and 50 mmol/kg of NaCl and then incubated for 3 months at 60% water‐holding capacity (WHC) and constant temperature (25 °C). Subsamples were taken after 1, 3, 6, and 12 weeks of incubation, and electrical conductivity (EC), pH, dissolved organic carbon (DOC), and concentrations of cations and anions were determined in the 1:2.5 soil/water extract. Available Cd and Pb were determined in 0.05 M ethylenediaminetetraacetic acid (EDTA) extract. Concentrations of organic and inorganic species of Cd and Pb in soil solution were also predicted using Visual Minteq speciation program. The most prevalent species of dissolved Pb and Cd in the soils were Pb‐DOC and Cd2+ species, respectively. Salinity application increased the available and soluble Cd significantly in the acid and calcareous soils. It, however, had little effect on soluble Pb and no effect on available Pb. Organic‐matter application decreased availability of added Pb significantly in all soils. In contrast, it raised soluble Pb in all soils except for the acid one and approximated gradually to the added Pb with time. Impact of OM on available Cd was somewhat similar to that of Pb. Soluble Cd increased by OM application in the calcareous soil, whereas it decreased initially and then increased with time in the other soils.  相似文献   

2.
The aim of this article is the determination of uranium accumulation in plants tissue in shoots and roots of corn—maize (Zea mays), grown on two types of soils, pseudogley and chernozem, together with its phytotoxic effect on the plant growth and development. The soils was contaminated with different rates (10 to 1,000 mg U(VI) kg?1) of uranyl nitrate (UO2(NO3)2·6H2O). Vegetative tests performed with maize indicated uranium phytotoxic effect on plant height, yield, and germination of seeds. This effect was stronger on the plants grown on pseudogley in comparison with those grown on chernozem. Soil properties determined the tolerance and accumulation of U in plants. A linear dependence between the content of uranium in soil and in plants tissue, including maximal content of 1,000 mg U?kg?1, indicates that maize could be used for phytoremediation of uranium-contaminated soils.  相似文献   

3.
Abstract

Denitrification products nitrous oxide ((N2O) and nitrogen (N2)) were measured in three flooded soils (paddy soil from Vietnam, PV; mangrove soil from Vietnam, MV; paddy soil from Japan, PJ) with different nitrate (NO3–) concentrations. Closed incubation experiments were conducted in 100-mL bottles for 7 d at 25°C. Each bottle contained 2 g of air-dried soil and 25 mL solution with NO3– (concentration 0, 5 or 10 mg N L?1) with or without acetylene (C2H2). The N2O + N2 emissions were estimated by the C2H2 inhibition method. Results showed that N2O + N2 emissions for 7 d were positively correlated with those of NO3– removal from solution with C2H2 (R2 = 0.9872), indicating that most removed NO3– was transformed to N2O and N2 by denitrification. In PJ soil, N2O and N2 emissions were increased significantly (P < 0.05) by the addition of greater NO3– concentrations. However, N2O and N2 emissions from PV and MV soils were increased by the addition of 0 to 5 mg N L?1, but not by 5 to 10 mg N L?1. At 10 mg N L?1, N2 emissions for 7 d were greater in PJ soil (pH 7.0) than in PV (pH 5.8) or MV (pH 4.3) soils, while N2O emissions were higher in PV and MV soils than in PJ soil. In MV soil, N2O was the main product throughout the experiment. In conclusion, NO3– concentration and soil pH affected N2O and N2 emissions from three flooded soils.  相似文献   

4.
This study developed a new adsorbent, specifically activated carbon-loaded silver nanoparticles (AgNPs-AC) by coating the silver nanoparticles (AgNPs) onto activated carbon (AC). The obtained AgNPs-AC were characterized by scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), Fourier transform infrared spectroscopy (FTIR), and Brunauer-Emmett-Teller (BET). The ability of AgNPs-AC to remove methylene blue (MB) was evaluated using different experimental factors, these being pH solution, contact time, adsorbent dose, and initial MB concentration. Results indicated that the highest adsorption capacity of MB onto AgNPs-AC was obtained when the AC was loaded onto AgNPs at the impregnation ratio of 0.5% w/w for AC and AgNPs. The best conditions in which AgNPs-AC could remove MB were as follows: pH 10, contact time lasting 120 min, and adsorbent dose being 250 mg/25 mL solution. In this scenario, the maximum adsorption capacity of MB onto AgNPs-AC was 172.22 mg/g. The adsorption isothermal equilibrium was well described by the Langmuir, Freundlich and Sips models. The Sips equations had the highest correlation coefficient value (R2?=?0.935). The pseudo-first-order and pseudo-second-order kinetic models agree well with the dynamic behavior of the adsorption of dye MB on AgNPs-AC.  相似文献   

5.
The potential competitive effect of background electrolytes (Na2HPO4 ·2H2O, NaHCO3, Na2SO4 and NaCl solutions) on arsenate adsorption onto synthetic 2-line ferrihydrite has been studied by means of kinetic batch experiments conducted at pH values from 4.0 to 10.0 and at anionic concentrations of 0.01 and 0.1 M. The results indicate that the adsorptive capacity of ferrihydrite for arsenate decreases strongly in the presence of phosphate species at pH in the range of 4–10 and in the presence of bicarbonate at pH 8.3 as a consequence of their competitive effect. Analogously to phosphate, a surface interaction of inner-sphere type between ferrihydrite and bicarbonate is suggested. Chloride has negligible effects on arsenate adsorption processes, confirming it as an outer-sphere ion that does not compete with the inner-sphere binding peculiar to arsenate onto ferrihydrite. Sulphate exhibits an intermediate behaviour; at 0.01 M concentration, the competitive effect of sulphate is similar to that of chloride, whereas at 0.1 M concentration sulphate shows a moderate influence on arsenate adsorption. The results of the kinetic studies can be summarised by the following order of competitive capacity: phosphate?>?carbonate?>?sulphate?>?chloride. The process of arsenate adsorption follows pseudo-second order kinetics and the reaction half-time notably increases in the presence of strong competitor anions such as phosphate and carbonate with respect to an ineffective competitor anion such as chloride. Modelling of arsenate adsorption with PHREEQC, according to the Generalized Two-Layer Model, confirms that the pH effect is notably less important than the competitive effect of carbonate species in determining the amount of arsenate adsorbed onto ferrihydrite at pH 8.3 in 0.1 M NaHCO3 solution, whereas the model greatly underestimates the competitive effect of carbonate species at pH 8.3 in 0.01 M NaHCO3 solution. The results of the batch experiments in 0.1 M NaHCO3 solution are substantiated by XPS analyses of ferrihydrite after immersion in the same solution, both with and without dissolved arsenate. XPS confirms the interaction between ferrihydrite surface and arsenate; the binding energy of As3d shifts towards higher binding energies after adsorption with respect to the pure compound Na2HAsO4·7H2O taken as reference standard. In presence of carbonate species, the As3d binding energy is found at intermediate values. XPS quantitative analysis shows a depletion of arsenate on ferrihydrite surface, providing further evidence of the competition of the two species (i.e. arsenate and bicarbonate) for the ferrihydrite adsorption sites. Important environmental implications concerning arsenic mobility, as well as possible application in various fields (e.g. irrigation agriculture, soil decontamination, water treatment), might derive from these findings.  相似文献   

6.
Agrichemical spills and discharges to soil can cause point-source contamination of surface and ground waters. When high contaminant concentrations inhibit natural attenuation in soils, chemical treatments can be used to promote degradation and allow application of treated soils to agricultural lands. This approach was used to remediate soil containing >650 mg atrazine, >170 mg metolachlor and >18,000 mg nitrate kg?1. Results indicated a decrease in metolachlor concentration to <1 mg kg?1 within 95 days of chemical treatment with zerovalent iron (Fe0, 5% w/w) and aluminum sulfate (Al2(SO4)3, 2% w/w) but after one year >150 mg atrazine and >7000 mg nitrate kg?1 remained. Laboratory experiments confirmed that subsequent additions of sucrose (table sugar) to the chemically pretreated soil promoted further reductions in atrazine and nitrate concentrations. Field-scale results showed that adding 5% (w/w) sucrose to windrowed and pretreated soil significantly reduced atrazine (<38 mg kg?1) and nitrate (<2,100 mg kg?1) concentrations and allowed for land application of the treated soil. These results provide evidence that zerovalent iron in combination with Al2(SO4)3 and sucrose can be used for on-site, field-scale treatment of pesticide- and nitrate-contaminated soil.  相似文献   

7.
This study was conducted to evaluate the redistribution of the heavy metals Cd, Cu, Pb, Ni, and Zn among different soil fractions by N fertilizers. In a lab experiment, soil columns were leached with distilled water, KNO3, NaNO3, NH4NO3, or Ca(NO3)2 · 4H2O. After leaching, soil samples were sequentially extracted for exchangeable (EXCH), carbonate (CARB), organic‐matter (OM), Mn oxide (MNO), Fe oxide (FEO), and residual (RES) fractions. Distilled water significantly increased the concentrations of Cd and Ni in EXCH fraction, while concentration of Cu and Zn did not change significantly. Application of KNO3, NaNO3, NH4NO3, or Ca(NO3)2 · 4H2O significantly increased the concentrations of Cd and Zn in EXCH fraction, while concentration of Pb and Ni was decreased. Application of all fertilizers caused an increase of Cu in the OM fraction. Moreover, leaching with these solutions significantly increased Cd [except in Ca(NO3)2 · 4H2O], Cu, and Zn concentrations in the CARB fraction, while Pb and Ni concentrations were decreased. With application of all leaching solutions, Zn in the EXCH, CARB, FEO, and MNO fractions was significantly increased, while Zn in the OM fraction did not change. The mobility index indicated that Ca(NO3)2 · 4H2O increased the mobility of Cd, Cu, and Zn in the soil, whereas NaNO3 decreased the mobility of Pb and Ni in the soil. The mobility index of Pb decreased by all leaching solutions. Thus, these results suggest that applying N fertilizers may change heavy‐metal fractions in contaminated calcareous soil and possibly enhance metal mobility and that N‐fertilization management therefore may need modification.  相似文献   

8.
Abstract

A pot experiment was conducted to investigate the effects of three soluble zinc (Zn) fertilizers on cadmium (Cd) concentrations in two genotypes of maize (Zea mays): Jidan 209 and Changdan 374. Zinc fertilizers were added to soil at four levels: 0, 80, 160, and 240 mg kg?1 soil as nitrate [Zn(NO3)2], chloride (ZnCl2), and sulfate (ZnSO4). Cadmium nitrate [Cd(NO3)2] was added to all the treatments at a uniform rate equivalent to 10 mg kg?1 soil. The biomass of maize plants was increased with the application of three zinc fertilizers, of which Zn(NO3)2 yielded more than others. Under ZnCl2 treatment, plant growth was promoted at the lower level and depressed at the higher one. All the three fertilizers decreased Cd concentration in shoots in comparison with treatments without Zn, but there were variations with different forms, especially in plants treated with Zn(NO3)2, which had the minimal value. The orders of average Cd concentration in shoots with different zinc fertilizers were ZnSO4>ZnCl2>Zn(NO3)2 for Jidan 209 and ZnCl2>ZnSO4>Zn(NO3)2 for Changdan 374, respectively (P<0.001). There was no significant difference between ZnSO4 and ZnCl2 treatments. The lowest Cd concentration in shoots was found in the 80‐mg‐kg?1 soil or 160‐mg‐kg?1 soil treatment. Cadmium concentration in roots in the presence of ZnCl2 was the lowest and under ZnSO4 the highest. The mechanism involved needs to be studied to elucidate the characteristics of complexation of Cl? and SO4 2? with Cd in plants and their influence on transfer from roots to shoots.  相似文献   

9.
Hydroponics culture generates large amounts of wastewater that are highly concentrated in nitrate and phosphorus but contains almost no organic carbon. Constructed wetlands (CWs) have been proposed to treat this type of effluent, but little is known about the performance of these systems in treating hydroponic wastewater. In addition, obtaining satisfactory winter performances from CWs operated in cold climates remains a challenge, as biological pathways are often slowed down or inhibited. The main objective of this study was to assess the effect of plant species (Typha sp., Phragmites australis, and Phalaris arundinacea) and the addition of organic carbon on nutrient removal in winter. The experimental setup consisted of 16 subsurface flow CW mesocosms (1 m2, HRT of 3 days) fed with 30 L?d1 of synthetic hydroponics wastewater, with half of the mesocosms fed with an additional source of organic carbon (sucrose). Carbon addition had a significant impact on nitrate and phosphate removal, with removal means of 4.9 g m-2?d-1 of NO3-N and 0.5 g m-2 d-1 of PO4-P. Planted mesocosms were generally more efficient than unplanted controls. Furthermore, we found significant differences among plant treatments for NO3-N (highest removal with P. arundinacea) and COD (highest removal with P. australis/Typha sp.). Overall, planted wetlands with added organic carbon represent the best combination to treat hydroponics wastewater during the winter.  相似文献   

10.
几株高效溶磷菌株对不同磷源溶磷活力的比较   总被引：3，自引：0，他引：3  
在液体培养条件下，研究了4株溶磷菌株(Bmp5、Bmp6、Bmp7和Fmp9)对不同磷源溶解能力的差异并与荧光假单孢菌As1.867和巨大芽孢杆菌As1.223进行了比较，探讨了菌株组合培养对溶磷活力的影响。结果表明，4株菌株对磷酸钙、磷酸铝、磷酸氢钙溶解能力明显高于磷酸铁和卵磷脂。以磷酸钙为磷源时，Fmp9的溶磷量比As1.867和As1.223分别高出约92%和48%；而以磷酸铝为磷源时，As1.223的溶磷量明显高于其他菌株；在磷酸氢钙为磷源的条件下，Bmp6为优势菌株，溶磷量高达785.51mg/L。对比研究发现，Bmp5、Bmp6、Bmp7及Fmp9的优势磷源分别为卵磷脂、磷酸氢钙、磷酸铝和磷酸钙。组合培养表明，Bmp5+Fmp9和Bmp6+Fmp9较单株菌的溶磷量有所增加，为较好的组合。试验得到的溶磷微生物配方已经应用于生物复合肥料的研究，并进行了盆栽实验，得到了较好的效果。该研究可为土壤生物肥料工业的微生物学研究提供借鉴。  相似文献   

11.
In this study, a process has been proposed whereby the sulfide required for autotrophic denitrification is supplied by reducing the sulfate of influent water without the need to add an external sulfide source. The molar ratio of nitrate-to-sulfide was maintained at 1.6. The proposed system was operated continuously for 6 months, including two anoxic and anaerobic reactors with upward flow. The results indicate that the average amount of nitrate declined by 74%. The pH of 7–8 was more effective than a pH of 6 in removing the nitrate. As the hydraulic retention time was prolonged from 1.5 to 3 and was further prolonged to 5 h, the system efficiency was enhanced by removing the nitrate. An alkalinity consumption rate of 1.15 mg (as CaCO3) per mg of removed NO3 ?-N was achieved. In the effluent water, the increased sulfate was 6.7 mg per mg of removed NO? 3-N, while the hardness was diminished by 2.85 mg (as CaCO3).  相似文献   

12.
In vitro, high nitrate (NO3 ?) concentrations significantly inhibit N2O reductase activity. However, little information is available on the in situ temporal effects of excessive N fertilization on soil N2O reductase activity and the regulation of the N2O/(N2 + N2O) product ratio in agricultural soil. This study examined the monthly in situ dynamics of NO3 ? concentration, N2O reductase activity, and N2O/(N2 + N2O) product ratio for 2 years in loamy soil that had received either continuous N fertilizer at 400 kg N ha?1 year?1 for 15 years (N400) or no N fertilizers (CK). N2O reductase activity was significantly lower under the N400 treatment than under the CK and correlated negatively with soil NO3 ? concentration. The decrease in N2O reductase activity resulted in the N2O/(N2 + N2O) product ratio increasing. These results demonstrate that excessive N fertilization has the potential to increase N2O emissions by reducing N2O reductase activity in soils. These results highlight the need for N2O mitigation options to embrace the reduction of soil NO3 ? concentrations.  相似文献   

13.
Molecular nitrogen (N2) and nitrous oxide (N2O) generated by denitrification increase N losses in the soil–plant system. This study aimed to quantify N2 and N2O from potassium nitrate (K15NO3) applied to soils with different textures and moisture contents in the absence and presence of a source of carbon (C) using the 15N tracer method. In the three soils used (sandy texture (ST), sandy clay loam texture (SCLT), and clayey texture (CT)), three moisture contents were evaluated (40%, 60%, and 80% of the water holding capacity (WHC)) with (D+) and without (D?) dextrose added. The treatments received 100 mg N kg?1 (KNO3 with 23.24 atom% 15N). N2 emissions occurred in all of the treatments, but N2O emissions only occurred in the D+ treatment, showing increases with increasing moisture content. SCLT with 80% WHC in the D+ treatment exhibited the highest accumulated N emission (48.26 mg kg?1). The 15N balance suggested trapping of the gases in the soil.  相似文献   

14.
A 56-day aerobic incubation experiment was performed with 15-nitrogen (N) tracer techniques after application of wheat straw to investigate nitrate-N (NO3-N) immobilization in a typical intensively managed calcareous Fluvaquent soil. The dynamics of concentration and isotopic abundance of soil N pools and nitrous oxide (N2O) emission were determined. As the amount of straw increased, the concentration and isotopic abundance of total soil organic N and newly formed labeled particulate organic matter (POM-N) increased while NO3-N decreased. When 15NO3-N was applied combined with a large amount of straw at 5000 mg carbon (C) kg?1 only 1.1 ± 0.4 mg kg?1 NO3-N remained on day 56. The soil microbial biomass N (SMBN) concentration and newly formed labeled SMBN increased significantly (P < 0.05) with increasing amount of straw. Total N2O-N emissions were at levels of only micrograms kg?1 soil. The results indicate that application of straw can promote the immobilization of excessive nitrate with little emission of N2O.  相似文献   

15.
氮肥对镉在土壤-芥菜系统中迁移转化的影响   总被引：6，自引：0，他引：6  
以芥菜为研究对象, 采用盆栽试验, 探讨了不同用量的5种氮肥对污染农田土壤中镉(Cd)在土壤–根系–地上部迁移累积的影响。结果表明: 5种氮肥均促进了芥菜根系对Cd的吸收, 且根系Cd含量随施氮量的增加而增加; 但根系吸收转运Cd的能力随氮肥施用量的增加呈先降后增的变化趋势。在≤200 mg(N)·kg-1(土)的施氮水平下, CO(NH2)2和Ca(NO3)2处理能显著降低芥菜地上部Cd含量, 降低幅度分别为13%~29%和24%~30%。在施氮量相同的条件下, NH4Cl和(NH4)2SO4显著降低了土壤pH, 增加了土壤DTPA-Cd含量, 促进了芥菜对Cd的吸收。本试验条件下, 200 mg(N)·kg-1(土)的CO(NH2)2在增加芥菜产量和降低芥菜地上部Cd含量等方面优于其他氮肥处理。  相似文献   

16.
Abstract

Nitrite (NO2 ?‐N) toxicity symptoms have been observed on lettuce (Lactuca sativa) at various locations in California. The objective was to evaluate the symptoms of ammonium (NH4 +‐N) and nitrite (NO2 ?‐N) toxicity on Sundevil iceberg lettuce and Paragon romaine lettuce and to determine lettuce growth and biomass production under different levels of NO2 ?‐N. Hydroponic studies under greenhouse conditions were conducted using nutrient solutions containing nitrate (NO3 ?‐N) and two other forms of nitrogen (NO2 ?‐N and NH4 +‐N) applied at a constant concentration (50 mg NL?1) or using different NO2 ?‐N levels (0, 5, 10, 20, 30, and 40 mg N L?1) and a constant NO3 ?‐N level (30 mg N L?1). Crown discoloration (brownish color) was observed for lettuce grown in both NO2 ?‐N and NH4 +‐N solutions approximately 3 weeks after transplanting into the hydroponic systems. Lettuce grown in NO3 ?‐N solution produced larger biomass and greater number of leaves per plant than lettuce grown in NO2 ?‐N or NH4 +‐N solutions. Increasing the concentration of NO2 ?‐N suppressed plant height, fresh and dry biomass yield, and number of leaves and increased the root vascular discoloration. Lettuce growth was reduced more than 50% at NO2 ?‐N concentrations greater than 30 mg N L?1. Even at 5 mg NO2 ?‐N L?1, growth was reduced 14 and 24% for romaine and iceberg lettuce, respectively, relative to that obtained in nitrate solution. Although concentrations between 5 and 40 mg NO2 ?‐N L ?1 reduced dry biomass similarly for both lettuce types, toxicity symptoms were more severe in iceberg lettuce than in romaine.  相似文献   

17.
This study investigated general physicochemical properties of tea garden soils at the alluvial plain of Cong River in Tan Cuong commune, Vietnam. Four gardens were selected as study sites on three transect lines established perpendicularly to the river. Soil samples were collected from the surface (0–10 cm) and subsurface (20–30 cm). Soil texture classes varied from sandy loam to light clay, which was affected by different terrains along the transect lines as well as severe disturbance such as terracing and earth excavation. The levels of total C and total N were correlated with increasing garden age, suggesting the replenishment of soil organic matter pool by the addition of plant residue and manure. Meanwhile, the soils showed strongly acidic nature with the average pH(H2O) of 3.7 at the surface and 3.9 at the subsurface. The effective cation exchange capacity (ECEC) was low at 4.7 and 4.9 cmolc kg?1, respectively, and dominated by exchangeable Al3+. Soil acidification was exacerbated with increasing garden age. However, a relatively large saturation of exchangeable calcium (Ca2+), potassium (K+), and magnesium (Mg2+) on the ECEC was found in the surface soils. The levels of available P were high, occasionally exceeding 1000 and 500 mg kg?1 at the surface and subsurface, respectively. In spite of strongly acidic condition, ammonium (NH4-N) applied as fertilizer was converted to nitrate (NO3-N) to move down to deeper layers. The levels of the bases, P, and mineral N seem to be principally determined by management practices. Significant portion of these nutrients was likely to exist in water soluble forms without adsorption onto soils. It should be required to develop proper schemes and to educate the owners for adequate fertilizer managements.  相似文献   

18.
Field experiments were conducted to study the effects of summer green-manuring crops and zinc (Zn) fertilization on the productivity and economics of Basmati rice. Sesbania aculeata summer green-manuring crop residue incorporation (SGMI) gave highest values of all the growth and yield attributes, grain and straw yield, viz. 3.58, 3.69 t ha?1 and 16.14, 16.25 t ha?1 of Basmati rice in 2008 and 2009. Among the Zn fertilization treatments, application of 2.0% Zn-enriched urea (ZEU) as ZnSO4 · H2O significantly influenced yield attributes and yield of Basmati rice during both years, and the increase in grain yield was 38.5 and 40.0% over absolute control (no N and no Zn) and 11.9 and 13.6% over control (only N) in both years of study. However, 2.0% ZEU (ZnO) was very close in terms of yield attributes and grain, straw yields of Basmati rice. As regards to the economics of Basmati rice, SGMI and 2.0% ZEU (ZnSO4 · H2O) Zn fertilization treatments gave the highest gross (SGMI, 85,985 and 91,582 INR ha?1; 2.0% ZEU, 89,837 and 59,851 INR ha?1) and net (SGMI, 56,997 and 61,445 INR ha?1; 2.0% ZEU, 59,851 and 64,442 INR ha?1) returns, respectively, compared with incorporation of the remaining summer green manuring residue and Zn fertilization treatments in 2008 and 2009. A significantly higher benefit:cost ratio was recorded with SGMI and 2.0% ZEU (ZnSO4 · H2O). Overall, Sesbania aculeata green manuring and 2.0% ZEU (ZnSO4 · H2O) are excellent sources of N and Zn for improved productivity of Basmati rice.  相似文献   

19.
Batch adsorption experiments were conducted to assess the effects of pH and ionic strength (I) on cadmium (Cd) adsorption by two Brazilian Oxisols. Adsorption envelopes were constructed through soil sample reactions with 0.01, 0.1, and 1 mol L?1 calcium nitrate [Ca(NO3)2] solutions containing 5 mg L?1 of Cd, with an increasing pH value from 3 to 8. The adsorption increased drastically with increasing pH, varying from 20 to 90% in a narrow pH range (4–6 in topsoil and 5–6 in subsoil). Gibbs energy (ΔG) for Cd adsorption was negative, and the phenomenon became more thermodynamically spontaneous with an increase in pH. Under the standard 0.01 mol L?1 I and at pH close to natural, the ΔG values ranged from ?796 to ?3427 J mol?1. No effect of I was observed on the ΔG values for Cd adsorption at pH values less than 6. At values greater than pH 6, sharp changes in the Cd adsorption pattern were observed on subsoil samples. The only soil attribute significantly correlated with the spontaneity of Cd adsorption was the effective cation exchange capacity, ECEC (r = 0.97; p < 0.1).  相似文献   

20.
本试验研究了一种合成水钠锰矿对Mn2+的持留机理和Mn2+被吸附后的去向,并进一步探讨了三种锰盐溶液(MnSO4,MN(NO3)2和MnCl2)对水钠锰矿晶体结构变化的影响。.试验结果表明,水钠锰矿对MN2+离子的吸附包括专性吸附和非专性吸附。随着吸附后的老化过程,吸附在矿物表面的锰逐渐扩散到晶格内,其置换性随之降低。.在MnSO4,Mn(NO3)2和MnCl2溶液中,水钠锰矿最终转化成六方锰矿(Nsutite),一种比水钠锰矿更稳定,结晶更好的晶体。MnSO4溶液在加入水钠锰矿后pH值比其它两种溶液高,除生成六方锰矿外还形成大量拉锰矿(Ramsdellite)。随着生成新矿物的老化,最初被吸附的Mn被固定在晶格内而失去其置换性和生物有效性。  相似文献   

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