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1.
A simple model to predict soil water components and the CO2 release for peat soils is presented. It can be used to determine plant water uptake and the CO2 release as a result of peat mineralization for different types of peat soils, various climate conditions, and groundwater levels. The model considers the thickness of the root zone, its hydraulic characteristics (pF, Ku), the groundwater depth and a soil‐specific function to predict the CO2 release as a result of peat mineralization. The latter is a mathematical function considering soil temperature and soil matric potential. It is based on measurements from soil cores at varying temperatures and soil water contents using a respiricond equipment. Data was analyzed using nonlinear multiple regression analysis. As a result, CO2 release equations were gained and incorporated into a soil water simulation model. Groundwater lysimeter measurements were used for model calibration of soil water components, CO2 release was adapted according long‐term lysimeter data of Mundel (1976). Peat soils have a negative water balance for groundwater depth conditions up to 80—100 cm below surface. Results demonstrate the necessity of a high soil water content i.e. shallow groundwater to avoid peat mineralization and soil degradation. CO2 losses increase with the thickness of the rooted soil zone and decreases with the degree of soil degradation. Especially the combination of deep groundwater level and high water balance deficits during the vegetation period leads to tremendous CO2 losses.  相似文献   

2.
The rate of oxidation of peat soils is highly seasonal and varies with temperature and soil moisture content. Large variations in soil moisture content result in wet–dry cycles that can enhance peat degradation. Water‐table management plays a crucial role in controlling and damping the effect of these environmental factors. However, maintaining high ditch water levels in fields bounded by ditches does not guarantee a high field groundwater level. The effect of installing subsurface irrigation at different spacings on water table elevation was studied in a low‐lying peat grassland. The water table elevation data were compared against values predicted with a water balance model. In addition, greenhouse experiments were carried out on undisturbed soil core samples collected from the peat grassland as well as a low‐lying peatland under intensive arable faming to measure CO2 evolution under different water regimes. The field data from the peat grassland suggest that sub‐irrigation spacing as low as 10 m is necessary during summer periods to maintain groundwater levels similar to those in the ditches. Over the same period of observation, the difference in water level between the ditches and the non‐irrigated fields is as high as 0.7 m. Modelled outputs are in good correlation with the field observations, and demonstrate that simple water balance models can provide an effective tool to study the effect of water management practices and potential changes in subsurface conditions, climate and land use on water‐table levels. The measurement of CO2 emission from undisturbed peat soil columns shows that the rate of oxidation of soil organic matter from peat soils is highly seasonal and that drainage exacerbates the rate of peat mineralization.  相似文献   

3.
Forty percentage of UK peatlands have been drained for agricultural use, which has caused serious peat wastage and associated greenhouse gas emissions (carbon dioxide (CO2) and methane (CH4)). In this study, we evaluated potential trade-offs between water-table management practices for minimizing peat wastage and greenhouse gas emissions, while seeking to sustain romaine lettuce production: one of the most economically relevant crop in the East Anglian Fenlands. In a controlled environment experiment, we measured lettuce yield, CO2, CH4 fluxes and dissolved organic carbon (DOC) released from an agricultural fen soil at two temperatures (ambient and +2°C) and three water-table levels (−30 cm, −40 cm and −50 cm below the surface). We showed that increasing the water table from the currently used field level of −50 cm to −40 cm and −30 cm reduced CO2 emissions, did not affect CH4 fluxes, but significantly reduced yield and increased DOC leaching. Warming of 2°C increased both lettuce yield (fresh leaf biomass) and peat decomposition through the loss of carbon as CO2 and DOC. However, there was no difference in the dry leaf biomass between the intermediate (−40 cm) and the low (−50 cm) water table, suggesting that romaine lettuce grown at this higher water level should have similar energetic value as the crop cultivated at −50 cm, representing a possible compromise to decrease peat oxidation and maintain agricultural production.  相似文献   

4.
In this study spatial and temporal relations between denitrification rates and groundwater levels were assessed for intensively managed grassland on peat soil where groundwater levels fluctuated between 0 and 1 m below the soil surface. Denitrification rates were measured every 3–4 weeks using the C2H2 inhibition technique for 2 years (2000–2002). Soil samples were taken every 10 cm until the groundwater level was reached. Annual N losses through denitrification averaged 87 kg N ha-1 of which almost 70% originated from soil layers deeper than 20 cm below the soil surface. N losses through denitrification accounted for 16% of the N surplus at farm-level (including mineralization of peat), making it a key-process for the N efficiency of the present dairy farm. Potential denitrification rates exceeded actual denitrification rates at all depths, indicating that organic C was not limiting actual denitrification rates in this soil. The groundwater level appeared to determine the distribution of denitrification rates with depth. Our results were explained by the ample availability of an energy source (degradable C) throughout the soil profile of the peat soil.This revised version was published online November 2003 with corrections to Figure 4 and in February 2004 with corrections to Figure 2.  相似文献   

5.
Actual evapotranspiration and net groundwater recharge (drainage minus capillary rise) as a function of climate, soil properties, land use and groundwater depth were determined for a 15-year period in the region north of Hannover, West-Germany. Calculations were done using a simulation model calibrated for cropland, grassland and coniferous forest. Results of a sensitivity study showed, that the influence of climatic factors on actual evapotranspiration and net groundwater recharge increases with the amount of plant available water during the vegetation period. Under similar climatic conditions, evapotranspiration and groundwater recharge mainly depend on the two basic soil-physical relations between. – soil water content and suction and – soil hydraulic conductivity and suction. For same groundwater depths, evapotranspiration rises with increasing plant available water in the rootzone, whereas groundwater recharge decreases.  相似文献   

6.
Agricultural peat soils in the Sacramento-San Joaquin Delta, California have been identified as an important source of dissolved organic carbon (DOC) and trihalomethane precursors in waters exported for drinking. The objectives of this study were to examine the primary sources of DOC from soil profiles (surface vs. subsurface), factors (temperature, soil water content and wet-dry cycles) controlling DOC production, and the relationship between C mineralization and DOC concentration in cultivated peat soils. Surface and subsurface peat soils were incubated for 60 d under a range of temperature (10, 20, and 30 °C) and soil water contents (0.3-10.0 g-water g-soil−1). Both CO2-C and DOC were monitored during the incubation period. Results showed that significant amount of DOC was produced only in the surface soil under constantly flooded conditions or flooding/non-flooding cycles. The DOC production was independent of temperature and soil water content under non-flooded condition, although CO2 evolution was highly correlated with these parameters. Aromatic carbon and hydrophobic acid contents in surface DOC were increased with wetter incubation treatments. In addition, positive linear correlations (r2=0.87) between CO2-C mineralization rate and DOC concentration were observed in the surface soil, but negative linear correlations (r2=0.70) were observed in the subsurface soil. Results imply that mineralization of soil organic carbon by microbes prevailed in the subsurface soil. A conceptual model using a kinetic approach is proposed to describe the relationships between CO2-C mineralization rate and DOC concentration in these soils.  相似文献   

7.
The ecosystem fluxes of mass and energy were quantified for a riparian cottonwood (Populus fremontii S. Watson) stand, and the daily and seasonal courses of evapotranspiration, CO2 flux, and canopy conductance were described, using eddy covariance. The ecosystem-level evapotranspiration results are consistent with those of other riparian studies; high vapor pressure deficit and increased groundwater depth resulted in reduced canopy conductance, and the annual cumulative evapotranspiration of 1095 mm was more than double the magnitude of precipitation. In addition, the cottonwood forest was a strong sink of CO2, absorbing 310 g C m−2 from the atmosphere in the first 365 days of the study. On weekly to annual time scales, hydrology was strongly linked with the net atmosphere-ecosystem exchange of CO2, with ecosystem productivity greatest when groundwater depth was ∼2 m below the ground surface. Increases in groundwater depth beyond the depth of 2 m corresponded with decreased CO2 uptake and evapotranspiration. Saturated soils caused by flooding and shallow groundwater depths also resulted in reduced ecosystem fluxes of CO2 and water.  相似文献   

8.
黄土高原水土流失严重,生态环境脆弱,水资源短缺,地下水对保障区域社会经济发展和维持生态系统平衡具有重要意义,而该区的地下水转化和补给机制尚不明确。为探究黄土高原水蚀风蚀交错区土壤剖面深层水分运动及降水对浅层地下水补给的可能性,利用六道沟小流域分布的粗质地风沙土样地2013—2016年土壤剖面0~600 cm含水量数据,运用HYDRUS-1D模型对各土层水力参数进行反演和验证,并用于模拟样地土壤深剖面0~1 500 cm水分运移过程。结果显示,在平水年2014年(439 mm)和干旱年2015年(371 mm),0~600 cm土壤含水量生长季末与生长季初持平或略有亏缺;降水充沛年2013年(669 mm)和2016年(704 mm)土壤含水量生长季末远高于生长季初,降水入渗深度超过观测深度(600 cm)。深剖面水分运动模拟显示,2014年和2015年剖面含水量变化不明显,水分向深层运移微弱缓慢;但是,2013年和2016年降水可分别入渗运移至1 100 cm和1 200 cm深度,远超过样地上生长的旱柳根系区域,可能补给浅层地下水。在4年模拟期间,平均土壤蒸发为14.87 cm·a-1,平均植物蒸腾为33.70 cm·a-1,土壤水分主要以植物蒸腾形式损耗。在2个丰水年,得益于较充足的降水和粗质地风沙土壤的高入渗率,降水大量转化为土壤水快速向下入渗运移,模拟显示当年生长季末降水最深运移至1 200 cm,至年末已超过模拟深度(1 500 cm),水分继续运移可能补给浅层地下水。相关研究结果为黄土高原水蚀风蚀交错区地下水来源和补给机制提供理论依据。  相似文献   

9.
Peatlands are common in many parts of the world. Draining and other changes in the use of peatlands increase atmospheric CO2 concentration. If we are to make reliable quantitative predictions of that effect, we need good information on the CO2 emission rates from peatlands. The present study uses two different methods for predicting CO2‐C release of peatland soils: (i) a 40‐year field investigation of balancing organic carbon stocks and (ii) short‐term CO2‐C release rates from laboratory experiments. To estimate long‐term losses of peat, and its resulting C input to the atmosphere, we combined highly detailed maps of surface topography and its changes, and the organic C contents and bulk densities of a drained peatland from different years. Short‐term CO2‐C release rates were measured in the laboratory by incubating soil samples from several soil horizons at various temperatures and soil moistures. We then derived nonlinear CO2‐C production functions, which we incorporated into a numerical simulation model (HYDRUS). Using HYDRUS, we calculated daily soil water components and CO2‐release for (i) real‐climate data from 1950 to 2003 and (ii) a climate scenario extending to 2050, including an increase in temperature of 2°C and 20% less rainfall during the summer half year, i.e. from April to September inclusive. From our field measurements, we found a mean annual decrease of 0.7 cm in the thickness of the peat. Large losses (> 1.5 cm year?1) occurred only during periods when groundwater levels were low (i.e. a deep water‐table). The annual CO2‐C release results in a mean loss from the peat of about 700 g CO2‐C m?2, mostly as a direct contribution to the atmosphere. Both methods produced very similar results. The model scenarios demonstrated that CO2‐C loss is mainly controlled by the groundwater (i.e. water‐table) depth, which controls subsurface aeration. A local climate scenario estimated a c. 5% increase of CO2‐C losses within the next 50 years.  相似文献   

10.
An incubation experiment was carried out to test the effects of biogenic municipal waste (compost I) and shrub/grass (compost II) composts in comparison to peat on respiration and microbial biomass in soil. The amounts of these three substrates added were linearly increased in the range of field application rates (0.5%, 1.0%, 1.5%, 2.0%). The sum of CO2 evolved during the incubation was markedly raised by the three substrates and increased with the rate of substrate concentration. However, the percentage of substrate mineralized to CO2 decreased with the addition rate from 103 to 56% for compost I, from 81 to 56% for compost II, and from 21 to 8% for peat. During the first 25 days of incubation, compost I enlarged the biomass C content, which remained constant until the end. In contrast, compost II did not raise biomass C initially. But at the end of the incubation, the biomass C content of all 4 compost II treatments almost reached the level of the respective compost I treatment. The increase was significantly larger the more of the two composts was added. In contrast to the two composts, the addition of peat did not have any significant effect on microbial biomass C. The average qCO2 values at day 25 declined in the order compost I > compost II > peat, at day 92 the order was changed to compost II > peat > compost 1. This change in the order was caused by a significant decrease in qCO2 values of the compost I treatments, a significant increase in qCO2 values of the peat treatments and constant qCO2 values in the compost II treatments.  相似文献   

11.
Variations in sulphate (SO4 2-) concentration of porewater and net SO4 2- mobilization were related to differences in water level fluctuations during wet and dry summers in two conifer swamps located in catchments which differed in till depth and seasonality of groundwater flow. Sulphate depletion at the surface and in 20 cm porewater coincided with anoxia and occurred mainly during the summer when water levels were near the peat surface and water flow rates were low in both catchments. There was an inverse relationship between net SO4 2- mobilization and water level elevation relative to the peat surface, explaining variation in SO4 2- dynamics between the swamps during summer drought periods. Aeration of peat to 40 cm and a large net SO4 2- mobilization (10–70 mg SO4 2- m-2 d-1) occurred during a dry summer in which the water level dropped to 60 cm below the surface in the swamp receiving ephemeral groundwater inputs from shallow tills within the catchment. This resulted in high SO4 2- concentrations in the surface water and porewater (30–50 mg L-1), and elevated SO4 2- concentrations remained through the fall and winter. In contrast, within the swamp located in the catchment with greater till depth (> 1 m), continuous groundwater inputs maintained surface saturation during the dry summer, and SO4 2- mobilization and concentrations of SO4 2- in the pore water during the following fall did not increase. Susceptibility to large water table drawdown and mobilization of accumulated SO4 2- is influenced by the occurrence of ephemeral vs. continuous groundwater inputs to valley swamps during dry summer periods in the Canadian Shield landscape. This study reveals that extrapolation of results of SO4 2- cycling from one wetland to another requires knowledge of the hydrogeology of the catchment in which the wetlands are located.  相似文献   

12.
Laboratory columns (80 cm long, 10 cm diameter) of peat were constructed from samples collected from a subarctic fen, a temperate bog and a temperate swamp. Temperature and water table position were manipulated to establish their influence on emissions of CO2 and CH4 from the columns. A factorial design experiment revealed significant (P < 0.05) differences in emission of these gases related to peat type, temperature and water table position, as well as an interaction between temperature and water table. Emissions of CO2 and CH4 at 23°C were an average of 2.4 and 6.6 times larger, respectively, than those at 10°C. Compared to emissions when the columns were saturated, water table at a depth of 40 cm increased CO2 fluxes by an average of 4.3 times and decreased CH4 emissions by an average of 5.0 times. There were significant temporal variations in gas emissions during the 6-week experiment, presumably related to variations in microbial populations and substrate availability. Using columns with static water table depths of 0, 10, 20, 40 and 60 cm, CO2 emissions showed a positive, linear relation with depth, whereas CH4 emissions revealed a negative, logarithmic relation with depth. Lowering and then raising the water table from the peat surface to a depth of 50 cm revealed weak evidence of hysteresis in CO2 emissions between the falling and rising water table limbs. Hysteresis (falling > rising limb) was very pronounced for CH4 emissions, attributed to a release of CH4 stored in porewater and a lag in the development of anaerobic conditions and methanogenesis on the rising limb. Decreases in atmospheric pressure were correlated with abnormally large emissions of CO2 and CH4 on the falling limb. Peat slurries incubated in flasks revealed few differences between the three peat types in the rates of CO2 production under aerobic and anaerobic conditions. There were, however, major differences between peat types in the rates of CH4 consumption under aerobic incubation conditions and CH4 production under anaerobic conditions (bog > fen > swamp), which explain the differences in response of the peat types in the column experiment.  相似文献   

13.
Drying and rewetting to a variable extent influence the C gas exchange between peat soils and the atmosphere. We incubated a decomposed and compacted fen peat and investigated in two experiments 1) the vertical distribution of CO2 and CH4 production rates and their response to drying and 2) the effects of temperature, drying intensity and duration on CO2 production rates and on CH4 production recovery after rewetting. Surface peat down to 5 cm contributed up to 67% (CO2) and above 80% (CH4) of the depth-aggregated (50 cm) production. As CO2 production sharply decreased with depth water table fluctuations in deeper peat layers are thus not expected to cause a substantial increase in soil respiration in this site. Compared to anaerobic water saturated conditions drying increased peat CO2 production by a factor between 1.4 and 2.1. Regarding the effects of the studied factors, warmer conditions increased and prolonged drying duration decreased CO2 production whereas the soil moisture level had little influence. No significant interactions among factors were found. Short dry events under warmer conditions are likely to result in greatest peaks of CO2 production rates. Upon rewetting, CH4 production was monitored over time and the recovery was standardized to pre-drying levels to compare the treatment effects. Methane production increased non-linearly over time and all factors (temperature, drying intensity and duration) influenced the pattern of post-drying CH4 production. Peat undergoing more intense and longer drying events required a longer lag time before substantial CH4 production occurred and warmer conditions appeared to speed up the process.  相似文献   

14.
Statistical analysis of a vast body of data collected during five field seasons (2011–2015) was performed to characterize the biological activity of soils in the northern taiga ecosystems of Western Siberia. Automorphic forest soils, hydromorphic (oligotrophic bog) soils, and semihydromorphic (flat-topped and large peat mounds) soils were characterized. Statistically significant differences of average levels of CO2 emission from the soils were identified at the ecosystem level. The CO2 emission from podzols of automorphic forest ecosystems at the peak of the growing season (205 ± 30 to 410 ± 40 mg CO2/(m2 h)) was significantly higher than the emission from semihydromorphic soils of peat mounds (70 ± 20 to 116 ± 10 mg CO2/(m2 h)). The presence and depth of permafrost was a significant factor that affected ecosystem diversity and biological activity of northern taiga soils. Statistically significant differences in the total, labile, and microbial carbon pools were observed for the studied soils. Labile and microbial carbon pools in the organic layer (10 cm) of forest podzols amounted to 0.19 and 0.66 t/ha, respectively; those in the organic layer (40 cm) of peat cryozems of flat-topped peat mounds reached 1.24 and 3.20 t/ha, and those in the oligotrophic peat soils (50 cm) of large peat mounds were 2.76 and 1.35 t/ha, respectively. The portion of microbial carbon in the total carbon pool (Cmicr/Ctot, %) varied significantly; according to the values of this index, the soils were arranged into the following sequence: oligotrophic peat soil < peat cryozem < podzol.  相似文献   

15.
The microbial activity and bacterial community structure were investigated in two types of peat soil in a temperate marsh. The first, a drained grassland fen soil, has a neutral pH with partially degraded peat in the upper oxic soil horizons (16% soil organic carbon). The second, a bog soil, was sampled in a swampy forest and has a very high soil organic carbon content (45%), a low pH (4.5), and has occasional anoxic conditions in the upper soil horizons due to the high water table level. The microbial activity in the two soils was measured as the basal and substrate-induced respiration (SIR). Unexpectedly, the SIR (μl CO2 g−1 dry soil) was higher in the bog than in the fen soil, but lower when CO2 production was expressed per volume of soil. This may be explained by the notable difference in the bulk densities of the two soils. The bacterial communities were assessed by terminal restriction fragment length polymorphism (T-RFLP) profiling of 16S rRNA genes and indicated differences between the two soils. The differences were determined by the soil characteristics rather than the season in which the soil was sampled. The 16S rRNA gene libraries, constructed from the two soils, revealed high proportions of sequences assigned to the Acidobacteria phylum. Each library contained a distinct set of phylogenetic subgroups of this important group of bacteria.  相似文献   

16.
Recently, large areas of tropical peatland have been converted into agricultural fields. To be used for agricultural activities, peat soils need to be drained, limed and fertilized due to excess water, low nutrient content and high acidity. Water depth and amelioration have significant effects on greenhouse gas (GHG) production. Twenty-seven soil samples were collected from Jabiren, Central Kalimantan, Indonesia, in 2014 to examine the effect of water depth and amelioration on GHG emissions. Soil columns were formed in the peatland using polyvinyl chloride (PVC) pipe with a diameter of 21 cm and a length of 100 cm. The PVC pipe was inserted vertically into the soil to a depth of 100 cm and carefully pulled up with the soil inside after sealing the bottom. The treatments consisting of three static water depths (15, 35 and 55 cm from the soil surface) and three ameliorants (without ameliorant/control, biochar+compost and steel slag+compost) were arranged using a randomized block design with two factors and three replications. Fluxes of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) from the soil columns were measured weekly. There was a linear relationship between water depth and CO2 emissions. No significant difference was observed in the CH4 emissions in response to water depth and amelioration. The ameliorations influenced the CO2 and N2O emissions from the peat soil. The application of biochar+compost enhanced the CO2 and N2O emissions but reduced the CH4 emission. Moreover, the application of steel slag+compost increased the emissions of all three gases. The highest CO2 and N2O emissions occurred in response to the biochar+compost treatment followed by the steel slag-compost treatment and without ameliorant. Soil pH, redox potential (Eh) and temperature influenced the CO2, CH4 and N2O fluxes. Experiments for monitoring water depth and amelioration should be developed using peat soil as well as peat soil–crop systems.  相似文献   

17.
华北平原典型井灌区农田水循环过程研究回顾   总被引：1，自引：0，他引：1  
本文回顾了中国科学院栾城农业生态系统试验站在农田水分循环和水量转化方面的研究工作和进展。目前, 对于冬小麦-夏玉米农田的蒸散耗水量及其结构(植物蒸腾和土壤蒸发)有较详细的研究结果。全年总蒸散量多年平均870 mm, 每年亏缺的350 mm 左右需要靠提取地下水保证; 同位素分析结果显示土壤蒸发的深度在地表下20 cm 处, 而植物蒸腾耗水也主要是利用0~40 cm 土层的土壤水分。对于土壤深层渗漏量和地下水接受垂直补给的问题, 不同研究结果间仍然存在较大差异, 尚需更精细的试验来确定。对于区域水量平衡和地下水资源可持续性的评价和管理, 目前急需重点开展区域蒸散量的精确估算和模拟研究, 以及不同土地利用和不同农业种植方式的水量平衡与水分转化过程研究。  相似文献   

18.
A lysimeter method using undisturbed soil columns was used to investigate the effect of water table depth and soil properties on soil organic matter decomposition and greenhouse gas (GHG) emissions from cultivated peat soils. The study was carried out using cultivated organic soils from two locations in Sweden: Örke, a typical cultivated fen peat with low pH and high organic matter content and Majnegården, a more uncommon fen peat type with high pH and low organic matter content. Even though carbon and nitrogen contents differ greatly between the sites, carbon and nitrogen density are quite similar. A drilling method with minimal soil disturbance was used to collect 12 undisturbed soil monoliths (50 cm high, Ø29.5 cm) per site. They were sown with ryegrass (Lolium perenne) after the original vegetation was removed. The lysimeter design allowed the introduction of water at depth so as to maintain a constant water table at either 40 cm or 80 cm below the soil surface. CO2, CH4 and N2O emissions from the lysimeters were measured weekly and complemented with incubation experiments with small undisturbed soil cores subjected to different tensions (5, 40, 80 and 600 cm water column). CO2 emissions were greater from the treatment with the high water table level (40 cm) compared with the low level (80 cm). N2O emissions peaked in springtime and CH4 emissions were very low or negative. Estimated GHG emissions during one year were between 2.70 and 3.55 kg CO2 equivalents m−2. The results from the incubation experiment were in agreement with emissions results from the lysimeter experiments. We attribute the observed differences in GHG emissions between the soils to the contrasting dry matter liability and soil physical properties. The properties of the different soil layers will determine the effect of water table regulation. Lowering the water table without exposing new layers with easily decomposable material would have a limited effect on emission rates.  相似文献   

19.
The speciation of phosphorus (P) in native and degraded peat soils is an analytical challenge, and synchrotron‐based P K‐edge X‐ray absorption near‐edge structure (XANES) is a suitable method to gain information on P species in soils and organic materials. The objective of the present study was to test if P K‐edge XANES reflected differences in P fractions in fen peat due to sequential extraction and peat degradation. We investigated each one top‐ and subsoil sample of a Fibric Histosol, which differed in the degree of humification (H8 vs. H5) and concentration of total P (Pt) (1944 mg kg–1 vs. 436 mg kg–1). In the topsoil, residual P, H2SO4‐P, and NaOH‐P accounted for roughly the same proportions of Pt (≈30%). In the subsoil, residual P (64% of Pt) was more abundant than NaOH‐P (21% of Pt) and H2SO4‐P (10% of Pt). Among many different P reference standards, the P XANES spectra reflected differences in mineral P more distinctive than in organic P compounds. Phosphorus XANES spectra of the residues after each sequential extraction step all showed a prominent white‐line peak at around 2152 eV. Stepwise removal of resin‐P, NaHCO3‐P, and NaOH‐P were reflected mainly by the peak intensity but scarcely by distinct spectral features. Extraction with H2SO4 led to the disappearance of spectral features of Ca and Mg phosphates which is a first direct hint to these compounds in the peat. In conclusion, a combined sequential fractionation and spectroscopic (31P NMR, P K‐ and L‐edge XANES with linear‐combination fits) approach is proposed to overcome limitations of the present study and gain more insight into the P species in peat soils.  相似文献   

20.
The quantification of soil CO2 efflux is crucial for better understanding the interactions between driving variables and C losses from black soils in Northeast China and for assessing the function of black soil as a net source or sink of atmospheric CO2 depending upon land use.This study investigated responses of soil CO2 efflux variability to soil temperature interactions with diferent soil moisture levels under various land use types including grassland,bare land,and arable(maize,soybean,and wheat)land in the black soil zone of Northeast China.The soil CO2 effluxes with and without live roots,defined as the total CO2 efflux(FtS)and the root-free CO2 efflux(FrfS),respectively,were measured from April 2009 to May 2010 using a static closed chamber technique with gas chromatography.The seasonal soil CO2 fluxes tended to increase from the beginning of the measurements until they peaked in summer and then declined afterwards.The mean seasonal FtS ranged from 20.3±7.8 to 58.1±21.3 mg CO2-C m-2h-1 for all land use types and decreased in the order of soybean land>grassland>maize land>wheat land>bare land,while the corresponding values of FrfS were relatively lower,ranging from 20.3±7.8 to 42.3±21.3 mg CO2-C m-2h-1.The annual cumulative FtS was in the range of 107-315 g CO2-C m-2 across all land uses types.The seasonal CO2 effluxes were significantly(P<0.001)sensitive to soil temperature at 10 cm depth and were responsible for up to 62% of the CO2 efflux variability.Correspondingly,the temperature coefcient Q10 values varied from 2.1 to 4.5 for the seasonal FtS and 2.2 to 3.9 for the FrfS during the growing season.Soil temperature interacting with soil moisture accounted for a significant fraction of the CO2 flux variability for FtS (up to 61%) and FrfS (up to 67%) via a well-defined multiple regression model,indicating that temperature sensitivity of CO2 flux can be mediated by water availability,especially under water stress.  相似文献   

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