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1.
Abstract. Knowledge of changes in soil organic matter (SOM) fractions resulting from agricultural practice is important for decision‐making at farm level because of the contrasting effects of different SOM fractions on soils. A long‐term trial sited under Sudano‐Sahelian conditions was used to assess the effect of organic and inorganic fertilization on SOM fractions and sorghum performance. Sorghum straw and kraal manure were applied annually at 10 t ha?1, with and without urea at 60 kg N ha?1. The other treatments included fallowing, a control (no fertilization), and inorganic fertilization only (urea, 60 kg N ha?1). Fallowing gave significantly larger soil organic carbon and nitrogen (N) levels than any other treatment. Total soil SOM and N concentrations increased in the following order: urea only < straw < control < straw+urea < manure with or without urea < fallow. Farming had an adverse effect on SOM and N status; however, this mostly affected the fraction of SOM >0.053 mm (particulate organic matter, POM). The POM concentrations in the control, straw and urea‐only treatments were about one‐half of the POM concentrations in the fallow treatment. POM concentrations increased in the following order: urea only < control < straw with or without urea < manure with or without urea < fallow. The fraction of SOM <0.053 mm (fine organic matter, FOM) was greater than POM in all plots except in fallow and manure+urea plots. Total N concentration followed the same trend as SOM, but cultivation led to a decline in both POM‐N and FOM‐N. Crop yield was greatest in the manure plots and lowest in the straw, control and urea‐only plots. Results indicate that under Sudano‐Sahelian conditions, SOM, POM and FOM fractions and crop performance were better maintained using organic materials with a low C/N ratio (manure) than with organic material with a high C/N ratio (straw). Urea improved the effect of straw on crop yield and SOM concentration.  相似文献   

2.
The effect of long-term (45 years) mineral and organic fertilization on soil organic matter (SOM) quantity (organic C and N content) and quality (hot-water-soluble C content, microbial biomass C content, hydrophobic organic components of SOM, soil enzyme activities) was determined in a field experiment established in Trutnov (North Bohemia, sandy loam, Eutric Cambisol). Six treatments were chosen for investigation: unfertilized control, mineral fertilization (NPK), straw N, farmyard manure (FYM) and straw and FYM completed with mineral NPK. Soil samples were taken from the arable layer (0–20 cm) in spring over the period of 2004–2010. The positive effect of FYM on the total organic C and N content, hot-water-soluble C content and hydrophobic organic components of SOM was more than 50% higher than that of straw and mineral N fertilization. Application of straw N increased microbial biomass C content in soil and generated invertase activity above the level of FYM. Hot-water-soluble C content, hydrophobic organic components of SOM and urease activity were positively correlated with total organic C and N content (R = 0.58–0.98; p < 0.05). Addition of mineral NPK to both the straw and FYM emphasized the effect of organic fertilization in most of monitored characteristics.  相似文献   

3.
The 4‐year application of pig‐manure compost (PMC) to crop fields in Jiangsu significantly increased organic‐C and total N concentrations compared to chemical fertilization and control treatment. To identify the soil processes that led to these changes, 13C cross‐polarization magic‐angle spinning nuclear‐magnetic resonance (13C CPMAS NMR) and dipolar‐dephasing nuclear‐magnetic‐resonance spectroscopy (DD NMR) were conducted on soil organic matter (SOM) fractions separated by wet‐sieving and density fractionation procedures. This allowed characterization of the SOM quality under three contrasting fertilizer regimes. The results indicate that PMC application can alter the distribution of functional groups and improve alkyl C‐to‐O‐alkyl C ratios compared to chemical‐fertilizer treatment (CF). Alkyl C contents were increased from macroaggregate fractions (> 2 mm) to microaggregate fractions (0.05–0.25 mm) for all treatments, suggesting that recalcitrant material accumulates in the microaggregate fractions. The O‐alkyl C contents were decreased from macroaggregate fractions (> 2 mm) to microaggregate fractions (0.05–0.25 mm) under CF and PMC treatments, while no consistent trend was found for the control (NF) treatment. The alkyl C‐to‐O‐alkyl C ratios in macroaggregates were lower than those in microaggregates, indicating that the degrees of SOM decomposition were lower in macroaggregates compared to microaggregates. In all aggregate‐size classes, the amount of organic matter appeared to depend on the fertilization regime. This study provides useful information regarding the buildup of organic material in soil from long‐term manure‐compost enrichment.  相似文献   

4.
An essential prerequisite for a sustainable soil use is to maintain a satisfactory soil organic‐matter (OM) level. This might be achieved by sound fertilization management, though impacts of fertilization on OM have been rarely investigated with the aid of physical fractionation techniques in semiarid regions. This study aimed at examining changes in organic C (OC) and N concentrations of physically separated soil OM pools after 26 y of fertilization at a site of the semiarid Loess Plateau in China. To separate sensitive OM pools, total macro‐OM (> 0.05 mm) was obtained from bulk soil by wet‐sieving and then separated into light macro‐OM (< 1.8 g cm–3) and heavy macro‐OM (> 1.8 g cm–3) subfractions; bulk soil was also differentiated into light OM (< 1.8 g cm–3) and mineral‐associated OM (> 1.8 g cm–3). Farmyard manure increased concentrations of total macro‐OC and N by 19% and 25%, and those of light fraction OC and N by 36% and 46%, compared to no manuring; both light OC and N concentrations but only total macro‐OC concentration responded positively to mineral fertilizations compared to no mineral fertilization. This demonstrated that the light‐fraction OM was more sensitive to organic or inorganic fertilization than the total macro‐OM. Mineral‐associated OC and N concentrations also increased by manuring or mineral fertilizations, indicating an increase of stable OM relative to no fertilization treatment, however, their shares on bulk soil OC and N decreased. Mineral fertilizations improved soil OM quality by decreasing C : N ratio in the light OM fraction whereas manuring led to a decline of the C : N ratio in the total macro‐OM fraction, with respect to nil treatment. Further fractionation of the total macro‐OM according to density clarified that across treatments about 3/4 of total macro‐OM was associated with minerals. Thus, by simultaneously applying particle‐size and density separation procedures, we clearly demonstrated that the macro‐OM differed from the light OM fraction not only in its chemical composition but also in associations with minerals. The proportion of the 0.5–0.25 mm water‐stable aggregates of soil was higher under organic or inorganic fertilizations than under no manure or no mineral fertilization, and increases in OC and N concentrations of water‐stable aggregates as affected by fertilization were greater for 1–0.5 and 0.5–0.25 mm classes than for the other classes. Results indicate that OM stocks in different soil pools can be increased and the loose aggregation of these strongly eroded loess soils can be improved by organic or inorganic fertilization.  相似文献   

5.
Soil organic nitrogen mineralization rates and possible predictors thereof were investigated for vegetable‐growing soils in Belgium. Soil organic matter (SOM) was fractionated into sand (> 53 μm) and silt+clay (< 53 μm) fractions. The latter fraction was further separated into 6%NaOCl‐oxidation labile (6%NaOCl‐ox) and resistant N and C and subsequently into 10%HF‐extractable (mineral bound) and resistant (recalcitrant) N and C. The N mineralization turnover rate (% of soil N/year) correlated with several of the investigated N or C fractions and stepwise linear regression confirmed that the 6%NaOCl‐ox N was the best predictor. However, the small R² (0.42) of the regression model suggests that soil parameters other than the soil fractions isolated here would be required to explain the significant residual variation in N mineralization rate. A next step could be to look for alternative SOM fractionations capable of isolating bioavailable N. However, it would appear that the observed relationships between N fractions and N mineralization may not be causal but indirect. The number of vegetable crops per rotation did not influence N mineralization, but it did influence 6%NaOCl‐ox N, probably as an effect of differences in crop residues returned and organic manure supply. However, the nature of this relation between management, SOM quality and N mineralization is not clear. Explanation of correlations between N mineralization and presumed bioavailable N fractions, like the 6%NaOCl‐ox N, requires further mechanistic elucidation of the N mineralization process.  相似文献   

6.
Investigations carried out at Field F3 of the Halle long‐term fertilization trials using data from 1974 to 1983 showed that with adequate supply of mineral N‐fertilizer soil organic matter (SOM) had no significant effects of yield. Similarly enhanced SOM did not justify a reduction of mineral N (Stumpe et al., 2000). The studies presented here examine the effects of the SOM differences existing after the termination of those trials in 1986 up until 1997 (then mainly differences of hardly decomposable SOM) in comparison to farmyard manuring with enhanced mineral N application (3‐factor‐experiment). As with total SOM, hardly decomposable SOM did not directly affect yields. The effects of FYM treatment observed at lower mineral‐N levels were compensated for by enhanced mineral‐N supply. The direct effect of FYM (40 t ha—1) corresponded to a mineral‐N supply of about 60 kg ha—1 and the residual effect to about 20 kg ha—1. The differences of the C‐content in the soil at the beginning of the present studies continued throughout the experimental period of 12 years. In addition, significant differentiation has been caused by FYM and N fertilization in comparison to unfertilized treatments. The major finding is that differences in SOM content do not lead to yield differences on physically good soils (chernozem‐like soils) if appropriate compensation by mineral‐N fertilization takes place.  相似文献   

7.
Soil test indicators are needed to predict the contribution of soil organic N to crop N requirements. Labile organic matter (OM) fractions containing C and N are readily metabolized by soil microorganisms, which leads to N mineralization and contributes to the soil N supply to crops. The objective of this study was to identify labile OM fractions that could be indicators of the soil N supply by evaluating the relationship between the soil N supply, the C and N concentrations, and C/N ratios of water extractable OM, hot‐water extractable OM, particulate OM, microbial biomass, and salt extractable OM. Labile OM fractions were measured before planting spring wheat (Triticum aestivum L.) in fertilized soils and the soil N supply was determined from the wheat N uptake and soil mineral N concentration after 6 weeks. Prior to the study, fertilized sandy loam and silty clay soils received three annual applications of 90 kg available N (ha · y)?1 from mineral fertilizer, liquid dairy cattle manure, liquid swine manure or solid poultry litter, and there was a zero‐N control. Water extractable organic N was the only labile OM fraction to be affected by fertilization in both soil types (P < 0.01). Across both test soils, the soil N supply was significantly correlated with the particulate OM N (r = 0.87, P < 0.001), the particulate OM C (r = 0.83, P < 0.001), and hot‐water extractable organic N (r = 0.81, P < 0.001). We conclude that pre‐planting concentrations of particulate OM and hot‐water extractable organic N could be early season indicators of the soil N supply in fertilized soils of the Saint Lawrence River Lowlands in Quebec, Canada. The suitability of these pre‐planting indicators to predict the soil N supply under field conditions and in fertilized soils from other regions remains to be determined.  相似文献   

8.
A long‐term fertilization experiment with monoculture corn (Zea mays L.) was established in 1980 on a clay‐loam soil (Black Soil in Chinese Soil Classification and Typic Halpudoll in USDA Soil Taxonomy) at Gongzhuling, Jilin Province, China. The experiment aimed to study the sustainability of grain‐corn production on this soil type with eight different nitrogen (N)‐, phosphorus (P)‐, and potassium (K)–mineral fertilizer combinations and three levels (0, 30, and 60 Mg ha–1 y–1) of farmyard manure (FYM). On average, FYM additions produced higher grain yields (7.78 and 8.03 Mg ha–1) compared to the FYM0 (no farmyard application) treatments (5.67 Mg ha–1). The application of N fertilizer (solely or in various combinations with P and K) in the FYM0 treatment resulted in substantial grain‐yield increases compared to the FYM0 control treatment (3.56 Mg ha–1). However, the use of NP or NK did not yield in any significant additional effect on the corn yield compared to the use of N alone. The treatments involving P, K, and PK fertilizers resulted in an average 24% increase in yield over the FYM0 control. Over all FYM treatments, the effect of fertilization on corn yield was NPK > NP = NK = N > PK = P > K = control. Farmyard‐manure additions for 25 y increased soil organic‐matter (SOM) content by 3.8 g kg–1 (13.6%) in the FYM1 treatments and by 7.8 g kg–1 (27.8%) in the FYM2 treatments, compared to a 3.2 g kg–1 decrease (11.4%) in the FYM0 treatments. Overall, the results suggest that mineral fertilizers can maintain high yields, but a combination of mineral fertilizers plus farmyard manure are needed to enhance soil organic‐matter levels in this soil type.  相似文献   

9.
Particulate organic matter (POM) plays important role in soil organic carbon (SOC) retention and soil aggregation. This paper assesses how quality (chemical composition) of four different‐quality organic residues applied annually to a tropical sandy loam soil for 10 years has affected POM pools and the development of soil aggregates. Water‐stable aggregate size distribution (>2, 0·25–2, 0·106–0·25 mm) was determined through wet sieving. Density fractionation was employed to determine POM (light—LF, and heavy—HF fractions, 0·05–1 mm). Tamarind leaf litter showed the highest SOC (<1 mm) accumulation, while rice straw showed the lowest. LF‐C contents had positive correlations with high contents of C and recalcitrant constituents, (i.e. lignin and polyphenols) of the residues. Dipterocarp, a resistant residue, showed the highest LF‐C, followed by the intermediate residues, tamarind, and groundnut, whereas HF was higher in groundnut and tamarind than dipterocarp residues. Rice straw had the lowest LF‐ and HF‐C contents. Tamarind had the highest quantity (51 per cent) of small macroaggregates (0·25–2 mm), while dipterocarp had the most (2·1 per cent) large macroaggregates (>2 mm). Rice straw had the lowest quantities of both macroaggregates. Similar to small‐sized HF (0·05–0·25 mm), small macroaggregates had positive correlation with N and negative correlation with C/N ratios, while large macroaggregates had positive correlations with C and recalcitrant constituents of the residues. Tamarind, with intermediate contents of N and recalcitrant compounds, appears to best promote small macroaggregate formation. Carbon stabilized in small macroaggregates accounted for the tamarind treatment showing the largest SOC accumulation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

10.
Nitrate leaching, overall N balance, and organic‐C build‐up in a semi‐arid agro‐ecosystem in NW India was estimated from the results of a long‐term manurial trial with farmyard manure (FYM) and mineral‐N fertilizer in operation since 1967 at the Research Farm of CCS Haryana Agricultural University, Hisar, India. The model LEACHN was calibrated for the wheat‐growing period November 2000 to April 2001 and the leaching of nitrate during this period was predicted to 48 kg N ha–1 without mineral‐N fertilization and 59 kg N ha–1 with addition of 120 kg mineral‐N fertilizer, both with the addition of 15 t ha–1 FYM. The N balance for the simulation period showed that the 120 kg N ha–1–mineral N fertilization compared to zero mineral N, both plus FYM, resulted in only slightly higher crop uptake, leaching losses, and NH3 volatilization, and a negligible increase of N in organic matter. The largest amount remains as an additional build‐up of mineral N in the profile (84.3 kg N ha–1) which is prone to losses as ammonia or nitrate. The model was used to simulate organic‐C build‐up with FYM and a decrease of organic C without FYM for a period of 33 y (1967–2000). The simulated C build‐up to about 0.1 g kg–1 agreed very well with the measured values and showed that additional mineral‐N fertilization will not have any significant effect on organic‐C content. Simulations with the assumption of no FYM application showed a gradual decrease of organic C from its starting value of 0.046 g kg–1 in 1967 down to almost half of this. This agreed well with the observed organic‐C values of 0.028 g kg–1 as measured for unmanured plots.  相似文献   

11.
The influence of fertilization on organic‐carbon fractions separated by density and particle size in Heilu soil (Calcic Kastanozems, FAO) was investigated in a 20‐year (1979–1999) long‐term experiment on the Loess Plateau of China. Compared to an unfertilized treatment, N application alone did not increase total organic carbon (TOC) and its fractions of density and particle size. However, the treatment of N + P fertilization significantly increased salty‐solution–soluble organic carbon (SSOC), microbial biomass C (MB‐C), and organic C associated with fine silt. When manure was applied alone and in combination with N and P fertilizer, the light fraction of organic C (LFOC), SSOC, and MB‐C were increased significantly, and the TOC was as high as that of a native Heilu soil. Organic C associated with different particle‐size fractions was also increased significantly, and the allocation of C among the fractions was altered: the proportions of C in sand (>50 μm), coarse‐silt (20–50 μm), and fine‐clay (<0.2 μm) fractions were increased whereas fine‐silt (2–20 μm) and coarse‐clay (0.2–2 μm) fractions were decreased. It is concluded that N fertilizer alone is not capable of restoring organic‐matter content in the Heilu soils of the Loess Plateau and that C‐containing material like manure and straw is necessary to produce significant increase in soil organic carbon in these soils.  相似文献   

12.
Sustainable agricultural land use requires an assessment of degradable soil organic matter (SOM) because of its key function for soil fertility and plant nutrition. Such an assessment for practical land use should consider transformation processes of SOM and its sources of different origin. In this study, we combined a 120‐day incubation experiment with thermal decay dynamics of agricultural soils altered by added organic amendments. The aim was to determine the abilities and limits of thermal analysis as a rapid approach revealing differences in the degradability of SOM. The carried out experiments based on two independent sampling sets. The first sample set consisted of soil samples taken from non‐fertilized plots of three German long‐term agricultural field experiments (LTAEs), then artificially mixed with straw, farmyard manure, sheep faeces, and charcoal equal to 60 Mg ha?1 under laboratory conditions. The second sample set based on soil samples of different treatments (e.g., crop type, fertilization, cultivation) in LTAEs at Bad Lauchstädt and Müncheberg, Germany. Before and after the incubation experiment, thermal mass losses (TML) at selected temperatures were determined by thermogravimetry indicating the degradability of organic amendments mixed in soils. The results confirmed different microbial degradability of organic amendments and SOM under laboratory conditions. Thermal decay dynamics revealed incubation‐induced changes in the artificial soil mixtures primarily at TML around 300°C in the case of applied straw and sheep faeces, whereas farmyard manure showed mainly changes in TML around 450°C. Charcoal did not show significant degradation during incubation, which was confirmed by TML. Detailed analyses of the artificial soil mixtures revealed close correlations between CO2‐C evolution during incubation and changes in TML at 300°C with R2 > 0.96. Results of the soils from LTAEs showed similar incubation‐induced changes in thermal decay dynamics for fresh plant residues and farmyard manure. We conclude that the practical assessment of SOM could be facilitated by thermal decay dynamics if modified sample preparation and evaluation algorithms are used beyond traditional peak analysis.  相似文献   

13.
The aggregate formation and stability are controlled by the dynamics of soil organic matters (SOM), but how it is related to SOM chemical composition within different‐sized aggregates is largely unknown during manure fertilization. In this study, the variations of intra‐aggregate organic carbon (OC), including intra‐particulate organic matter (iPOM) and mineral‐associated organic matter, were quantitatively and qualitatively analysed, and then, their effects on aggregate formation and stability were assessed under four treatments: control (CK), mineral fertilizer (NPK), reduced manure (30%M) and manure fertilizers (M). Manure application (M) significantly increased macroaggregate proportion, mean weight diameter (MWD), and OC contents within different‐sized aggregates compared to CK, NPK, and 30%M. The OC accumulation of macroaggregate in M was attributed to OC content increase in silt plus clay subfraction rather than iPOM with more labile organic groups; oppositely, in microaggregate it was located in the relatively stable fine iPOM. The macroaggregate formation and stability were controlled by the fine iPOM within macroaggregates, whose abundant polysaccharide‐C and aliphatic‐C after manure fertilization advanced the microbial growth except for Gram‐positive bacteria, which further promoted macroaggregate formation and stability. The free silt plus clay fraction also affected macroaggregate formation and stability, and its polysaccharide‐C derived from microorganisms or decomposing SOM was positively associated with MWD and macroaggregate proportion. Because polysaccharide‐C can be easily associated with mineral particles, further improving micro‐ or macroaggregation. We conclude that continuous manure fertilization could increase labile SOM accumulation within aggregates and then facilitate microbial growth, which collectively are responsible for aggregate formation and stabilization.  相似文献   

14.
The impact of organic fertilization and the level of mineral nitrogen fertilization on organic nitrogen and humus balance was studied in a long-term field experiment IOSDV Jable in central Slovenia (sub-Alpine climate, average annual precipitations 1345 mm, average annual temperature 9.5°C, heavy hydromorphic silty loam, umbric Planosols). During the period 1993–2010, precipitation increased significantly at an average rate of 19 mm a?1; over the same period, average annual temperature increased by 0.025°C (l.f.). The increase in annual precipitation had a negative impact on the yield of all crops (maize, wheat and oats). Increases in mineral N rate led to increased yields. At the highest mineral nitrogen rate, farmyard manure (FYM) did not have a positive impact on yield in the investigated crops, although there was a positive effect of straw incorporation on the yield of maize and oats, and a negative impact on the yield of winter wheat. The organic carbon (Corg) level in the soil increased for all treatments, including FYM or straw and mineral N fertilization. The N content in the soil decreased in the treatment with no organic fertilization and no mineral N, and in the treatment with straw and no mineral N. Corg was increased in treatments with organic fertilization and the highest N rates and remained the same in treatments with moderate N fertilization. All C balances were negative.  相似文献   

15.
The effects of organic and mineral fertilization on four soil organic matter (SOM) fractions (non-protected, physically protected, chemically protected, and biochemically protected) and microbial community composition were investigated by sampling soil of a 35-year-long fertilization experiment. The SOM fractions were investigated by combined physical and chemical approaches, while microbial community composition was determined by phospholipid fatty acid analysis (PLFA). Organic C (SOC) was primarily distributed within the microaggregate-protected particulate organic matter (iPOM) and the hydrolysable and non-hydrolysable silt-sized (H-Silt, NH-Silt) fractions, which accounted for 11.6–16.9, 23.4–28.9, and 25.4–30.6% of the total SOC content, respectively. The contributions of these “slow” fractions (iPOM, H-Silt, NH-Silt) to the increased SOC were 178–293, 118–209, and 85–109% higher after long-term sole manure or manure in combination with inorganic N fertilization compared with unfertilized soil (control). The combination of manure and mineral fertilizers increased the coarse and fine non-protected C (cPOM and fPOM) contents much more (34.1–60.7%) than did manure alone. PLFAs, bacteria, G (+) bacteria, and actinomycete abundances were the highest in soil with manure, followed by soil treated with manure combined with mineral N. The addition of inorganic and organic fertilization both altered the microbial community composition compared with the control. All SOM fractions contributed to 81.1% of the variance of the PLFAs-related microbial community composition by direct and indirect effects. The change in coarse unprotected particulate organic matter (cPOM) was the major factor affecting soil microbial community composition (p < 0.001). Our study indicates that physical, chemical, and biochemical protection mechanisms are important in maintaining high SOC level after the addition of manure. A close linkage between soil microbial community composition and cPOM suggests that C availability is an important factor for influencing microbial composition after long-term inorganic and organic fertilization.  相似文献   

16.
The effects and residual effects of farmyard manure (FYM), straw fertilization and mineral N fertilization were investigated in Field F of the long‐term fertilization trial in Halle (Saale), Germany. With sufficient mineral N fertilization, FYM and straw did not directly affect yield. The application of FYM alone increased the yield of potato less than those of silage maize and sugar beet. With low mineral N fertilization, however, residual effects of FYM, applied to root crops, were observed in the following cereal crops. Application of more mineral N to root crops had the same residual effects. In case of omitted mineral N fertilization, the humus content of the soil decreased rapidly. This implies that almost no stable humic material had been accumulated by application of FYM and straw. The calculated N loss increased with enhanced organic fertilization. In case of mineral N fertilization the content of organic C (Corg) was slightly higher (1.4 to 1.5%) than without any N fertilization (1.3%). FYM and straw (with same amounts of dry matter) likewise enhanced the Corg‐content and, consequently, the content of decomposable C (Cdec). In general, organic fertilizers should not be applied in too large amounts to avoid N losses.  相似文献   

17.
We investigated whether the long‐term application of compost from agricultural waste improved soil physical structure, fertility and soil organic matter (SOM) storage. In 2006, we began a long‐term field experiment based on a rice–wheat rotation cropping system, having a control without fertilizer (NF) and three treatments: chemical fertilizers (CF), pig manure compost (PMC) and a prilled mixture of PMC and inorganic fertilizers (OICF). Following the harvest of wheat in 2010, the mean‐weight diameter (MWD) of water‐stable aggregates and the concentration of C and N in bulk soil (0–20 cm; <2 mm fraction) were significantly greater (P < 0.05) in PMC and NF plots than in CF or OICF plots. Pig manure compost significantly increased the proportion of >5‐mm aggregates, whereas CF significantly increased the proportion of 0.45‐ to 1‐mm aggregates. The C and N contents of all density fractions were greater in PMC than in other treatments with levels decreasing in the following order: free particulate organic matter (fPOM) >occluded particulate organic matter (oPOM) > mineral‐combined SOM (mineral–SOM). Solid‐state 13C CPMAS NMR spectra showed that alkyl C/O‐alkyl C ratios and aromatic component levels of SOM were smaller in PMC and OICF plots than in CF plots, suggesting that SOM in PMC and OICF plots was less degraded than that in CF plots. Nevertheless, yields of wheat in PMC and NF plots were smaller than those in CF and OICF plots, indicating that conditions for producing large grain yields did not maintain soil fertility.  相似文献   

18.
The effect of cereal straw with added mineral N fertilization on crop yields, N uptake, total organic C content and hot water soluble C content in topsoil and on the relationships between organic C content in topsoil and organic matter balance was evaluated in a long-term field experiment established in 1966. The effect of straw plus mineral N fertilization was similar to the effect of farmyard manure (FYM) in the dry matter yields and also in the N uptake by plants. The effect of straw and mineral N fertilization on the organic C accumulation in soil was inferior to the effect of farmyard manure. Relationships between organic matter balance and total organic C content in the topsoil was positive and statistically significant. A favourable effect of mineral NPK fertilization on the C sequestration to soil was related to the effect of FYM fertilization.  相似文献   

19.
The maintenance and accumulation of soil organic carbon (SOC) in agricultural systems is critical to food security and climate change, but information about the dynamic trend and efficiency of SOC sequestration is still limited, particularly under long‐term fertilizations. In a typical Purpli‐Udic Cambosols soil under subtropical monsoon climate in southwestern China this study thus estimated the dynamic, trend and efficiency of SOC sequestration after 22‐year (1991–2013) long‐term inorganic and/or organic fertilizations. Nine fertilizations under a rice–wheat system were examined: control (no fertilization), N, NP, NK, PK, NPK, NPKM (NPK plus manure), NPKS (NPK plus straw), and 1.5NPKS (150% NPK plus straw). Averagely, after 22‐years SOC contents were significantly increased by 4.2–25.3% and 10.2–32.5% under these fertilizations than under control conditions with the greatest increase under NPKS. The simulation of SOC dynamic change with an exponential growth equation to maximum over the whole fertilization period predicted the SOC level in a steady state as 18.1 g kg?1 for NPKS, 17.4 g kg?1 for 1.5NPKS, and 14.5–14.9 g kg?1 for NK, NP, NPK, and NPKM, respectively. Either inorganic, organic or their combined fertilization significantly increased crop productivity and C inputs that were incorporated into soil ranging from 0.91 to 4.63 t (ha · y)?1. The C sequestration efficiency was lower under NPKM, NPKS, and 1.5NPKS (13.2%, 9.0%, and 10.1%) than under NP and NPK (17.0% and 14.4%). The increase of SOC was asymptotical to a maximum with increasing C inputs that were variedly enhanced by different fertilizations, indicating an existence of SOC saturation and a declined marginal efficiency of SOC sequestration. Taken all these results together, the combined NPK plus straw return is a suitable fertilizer management strategy to simultaneously achieve high crop productivity and soil C sequestration potential particularly in crop rotation systems.  相似文献   

20.
Findings of previous studies suggest that there are relations between thermal stability of soil organic matter (SOM), organo‐mineral associations, and stability of SOM against microbial decay. We aimed to test whether thermal oxidation at various temperatures (200°C, 225°C, 275°C, 300°C, 400°C, or 500°C) is capable of isolating SOM fractions with increasing stability against microbial degradation. The investigation was carried out on soils (Phaeozem and Luvisol) under different land‐use regimes (field, grassland, forest). The stability of the obtained soil organic carbon (SOC) fractions was determined using the natural‐13C approach for continuously maize‐cropped soils and radiocarbon dating. In the Luvisol, thermal oxidation with increasing temperatures did not yield residual SOC fractions of increasing microbial stability. Even the SOC fraction resistant to thermal oxidation at 300°C contained considerable amounts of young, maize‐derived C. In the Phaeozem, the mean 14C age increased considerably (from 3473 y BP in the mineral‐associated SOC fraction to 9116 y BP in the residual SOC fraction after thermal oxidation at 300°C). An increasing proportion of fossil C (calculated based on 14C data) in residual SOC fractions after thermal oxidation with increasing temperatures indicated that this was mainly due to the relative accumulation of thermally stable fossil C. We conclude that thermal oxidation with increasing temperature was not generally suitable to isolate mineral‐associated SOC fractions of increasing microbial stability.  相似文献   

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