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1.
Abstract

A variety of higher plants and microorganisms, especially soil fungi, form anthra-quinone pigments (Thomson 1987) and, although many of these compounds are biologically active as antibiotics, chelating agents and possible contributors of humic substance formation (Kumada 1987), little information is available about their distribution and role in soil systems.  相似文献   

2.
Roy W. Simonson 《Geoderma》1979,22(4):333-335
The name “Ando soils” was introduced in 1947 during reconnaissance soil surveys in Japan by American soil scientists. The name identified a great soil group of the intrazonal order in the then current U.S. system. The group consists of soils that had rather thick, dark A1 horizons, were derived from volcanic ash and were acid in reaction. The great soil group was later recognized in places as far apart as Alaska, France and New Guinea. Although the original name is being phased out at the present time, it has been the source of two other names that are in current use, viz., Andepts and Andosols.  相似文献   

3.
Linear regression equations between the logarithm of the total soil moisture potential and soil moisture content in the hygroscopic moisture range (Landau–Deryagin law) were derived for typical soils from different natural zones of European Russia. From these equations, a compact algorithm was developed for calculating the hydration energy of soils, which increases from 1280 to 10600 J/kg in the following soil series: heavy loamy soddy podzolic soil–heavy loamy gray forest soil–medium loamy light chestnut soil–heavy loamy brown semidesert soil–light clayey solonchak–light clayey chernozem–medium clayey krasnozem. Relationships were revealed between the hydration energy of soils, the specific surface of soils, the content of physical clay in soils, and the concentration of hydrated exchangeably adsorbed ions.  相似文献   

4.

Purpose

Adsorption and desorption are important processes that influence the transport, transformation, and bioavailability of atrazine in soils. Equilibrium batch experiments were carried out to investigate the adsorption–desorption characteristics of atrazine. The objectives of this study were to (1) determine and quantify the main soil parameters governing atrazine adsorption and desorption phenomena; (2) find the correlativity between the identified soil parameters; and (3) investigate the universal desorption hysteresis traits.

Materials and methods

Fifteen soils with contrasting physico-chemical characteristics were collected from 11 provinces in eastern China. The equilibrium time was 24 h both for adsorption and desorption experiments. Atrazine was detected by Waters 2695/UV HPLC.

Results and discussion

Adsorption isotherms of atrazine could be well described by the Freundlich equation (r?≥?0.994, p?<?0.01). The total organic carbon (TOC) was the first independent variable that described 53.0 % of the total variability of K f, followed by the pH (9.9 %), and the clay (4.0 %) and silt (1.2 %) contents, separately; while the primary soil properties that affect desorption parameters included the TOC, pH, free Fe2O3 (Fed) and the sand content, with the biggest contribution achieved by the TOC (ranged from 48.5–78.1 %). The results showed that when the content ratio of clay to TOC (RCO) was less than 40, the atrazine adsorption was largely influenced by the organic matrix, while when the RCO was greater than 40, they were vital affected by the clay content.

Conclusions

Adsorption–desorption isotherms of atrazine in soils were nonlinear. The content of TOC, clay, and iron oxides, as well as the pH value were the key soil parameters affecting the adsorption–desorption of atrazine in soil, among which the RCO especially exhibited relevance. Additionally, the desorption hysteresis existed for atrazine retention in all 15 tested soils, and the hysteretic effect enhanced with the increasing time for desorption. This would be ascribed to the heterogeneity physical–chemical properties of these soils.  相似文献   

5.
Abstract

As soil phosphorus (P) availability changes with soil type and time after fertilizer application, use of a P availability index, “F”; (fraction of added P remaining available after a given time), was evaluated for 28 Portuguese soils as a function of soil P extractant (Egner, Fe‐oxide strip, Mehlich 3, and Olsen). The F index values, based on a short‐term P recovery after 2‐h and 24‐h soil‐P equilibration periods, were related to longer‐term F values determined after a 90 day soil‐P equilibration of soil and P (r=0.87 to 0.98; P<0.001). Soil sorption was related to F values (r=0.73 to 0.88; P<0.001). The results suggest that the 2‐h and 24‐h equilibration procedures could be used as a rapid prediction of P fertilizer availability in Portuguese soils widely ranging in P sorptivity.  相似文献   

6.
Abstract

The recovery of applied zinc (Zn) by plants is relatively small. Coupled with lack of leaching, this leads to accumulation of Zn in topsoil which may result in unfavorable growth conditions for the subsequent plants. Different extractants may be used for assessing the Zn status of soils previously treated with Zn sources. The extractability of retained Zn is influenced by soil properties. This experiment was conducted to study the influence of selected properties of calcareous soils on extractability of Zn by three popular Zn soil tests. Twenty samples from surface horizons (0–20 cm) of highly calcareous soils of southern Iran (pH 7.9 to 8.5; calcium carbonate equivalent 16 to 58%) previously treated with three levels of Zn (0, 10, and 20 mg Zn kg‐1 soil as ZnSO4#lb7H2O) in triplicate and under one crop of corn (Zea mays L.) were extracted with DTPA, EDTA‐(NH4)2CO3 and Na2‐EDTA. Extractability (EXT) in a particular extractant was defined as the slope of the regression line, relating extractable Zn of each soil to the rate of applied Zn, multiplied by 100. The EXT values of soils ranged from 24.9 to 73.0% for DTPA, 47.2 to 84.4% for EDTA‐(NH4)2CO3, and 28.2 to 56.7% for Na2‐EDTA. Stepwise regression equations showed that cation exchange capacity (CEC) and calcium carbonate equivalent (CCE) followed by clay content were the most influential soil properties in EXT of retained Zn of highly calcareous soils. The EXT values decreased with increase in CEC, and CCE but increased with increase in clay.  相似文献   

7.
Abstract

Adsorption of a small amount of P by soil from a solution, which delivers concentrations approximating the composition of soil solution systems, was measured for a heterogeneous group of 343 soils using 32P‐labelled KH2PO4 solution. The method allowed accurate determination of small quantities of P and identified the P under consideration as that added from solution. Simple correlations and stepvise linear regression analyses indicated that soil pH, Ca, P, Al, Fe, organic matter and particle size significantly influenced the amount of P adsorbed by the soils.  相似文献   

8.
The effect of sodium dodecylbenzenesulfonate （SDBS）, an anionic surfactant used widely in household products and industrial processes, on saturated hydraulic conductivities （Ksat） of an Anthrosol saturated with sodium （Na-soil） or calcium （Ca-soil） was analyzed in a laboratory experiment using the constant head method, and adsorption and dispersion experiments were also conducted to infer the possible mechanisms of Ksat fluctuations. The results showed that SDBS was more intensely adsorbed in the Ca-soil than in the Na-soil. With an increase in the SDBS concentration, the stability of the Na-soil suspensions decreased when the SDBS concentration was less than 1.2 mmol L^-1 and then above this concentration, increased markedly, while the stability of the Ca-soil suspensions increased gradually at all SDBS concentrations studied. With an increase in the SDBS concentration, the Ksat of the Na-soil increased, which resulted mainly from the increase of water channels in the soil because of the coagulation of the soil particles, while the Ksat of Ca-soil decreased mainly on account of the clogging of partial water channels by precipitated Ca（DBS）2 and the fine soil particles generated.  相似文献   

9.
Abstract

Several rainwater samples and 14 profiles of Hawaii's volcanic ash‐derived soils were analyzed for sulfur (S). Atmospheric deposition was an important S source at the coast (24 kg S/ha), but its contribution decreased with increasing distance from the sea (1 kg S/ha at 24‐km inland). The S concentration of rainwaters also decreased linearly with increasing rainfall.

Several thousand mg SO4‐S/kg can be extracted from many volcanic ash‐derived soils of Hawaii, and it was often required at least four extractions [0.04 M Ca(H2PO4)2, 1:10 soil to solution ratio] to completely desorb this SO4. There was a close association of high SO4 retention with high rainfall. This might have resulted from (1) the development of a solid phase with high SO4 retention under intense weathering conditions, (2) more total SO4 received by the soils from atmospheric deposition, and (3) past fertilization of sugarcane grown in high rainfall areas.

Low concentrations of soil solution SO4‐S in relation to large amounts of P‐extractable SO4 suggest that a S bearing mineral, such as basaluminite, may be controlling soil‐solution SO4. Furthermore, SO4 adsorption isotherms of these volcanic soils generally show a bi‐phasic property, and suggest that 40 to 80 mg SO4‐S/kg is required to maintain 3 ‐ 6 mg SO4‐S/L in the soil solution, a concentration range considered adequate for the growth of most crops.  相似文献   

10.
An analytical solution for advance of solute front in soils   总被引：3，自引：0，他引：3  
Based on the assumption that solute transport in a semi-infinite soil column or in a field soil profile can be described by the boundary-layer method, an analytical solution is presented for the advance of a solute front with time. The traditional convection-dispersion equation (CDE) subjected to two boundary conditions: 1) at the soil surface (or inlet boundary) and 2) at the solute front, was solved using a Laplace transformation. A comparison of resident concentrations using a boundary-layer method and an exact solution (in a semi-infinite-domain) showed that both were in good agreement within the range between the two boundaries. This led to a new method for estimating solute transport parameters in soils, requiring only observation of advance of the solute front with time. This may be corroborated visually using a tracer solution with marking-dye or measured utilizing time domain reflectometry (TDR). This method is applicable to both laboratory soil columns and field soils. Thus, it could be a step forward for modeling solute transport in field soils and for better understanding of the transport processes in soils.  相似文献   

11.
Abstract

This work is included in a wide field of research on the dynamics of synthetic chelates in calcareous soils of South‐East of Spain. Through the application of Freundlich isotherm to the process of formation‐decomposition of chelate FeEDDHA, equations of type: Cs = A . tn . Cm o are obtained, where A, n and m, are ctes., Cs, the concentration of iron chelated added to the soil, and t, interaction time of chelate with the soil. In this way we can predict the rhythm of the solution process of Fe in calcareous soils.  相似文献   

12.
Some physical (density, coefficient of filtration, particle-size composition, etc.) and chemical (contents of carbonates, organic carbon, nitrogen, etc.) properties of an alluvial calcareous soil were studied in Central Anatolia (Konya province, Çumra region). These heavy-textured (medium clay) soils with a low content of organic carbon (less than 1%) have favorable agrophysical properties due to the stable structure of the pore space. The studies of the water regime of soils under drop irrigation confirm the favorable hydrological properties of these soils. The use of the known agrophysical estimates (after Medvedev, the index of the optimal water regime, etc.) has revealed the high dispersal of the data related to the low humus content in these heavy-textured soils. The favorable structure of the pore space is suggested to be stipulated by the active activity of the numerous and diverse representatives of soil biota. Four phyla predominate in the microbio-logical composition of the soils studied; among them, Actinobacteria is the dominant. The composition of this phylum is dominated by the elevated number of both higher (Streptomyces) and lower (three species of Rhodococcus) actinobacteria. The high biodiversity of bacteria against the background of their great total number and the developed trophic interactions in the microbial community promote the well-balanced production of specific metabolites, including gaseous ones (CO2, H2). This circumstance allows this clayey soil to function rather actively while protecting the pore space against compaction and maintaining the optimal density, porosity, and hydrological properties.  相似文献   

13.
Abstract

Phosphorus sorption studies were conducted on volcanic ash influenced surface horizons of 29 northern Idaho soils. Results show that the amount of P sorbed was significantly correlated with citrate‐dithionite extractable aluminum (r = .64**), but not with Fe. Other significantly correlated soil properties were: percent base saturation (r = ‐.73**), percent clay (r = .42**), and exchangeable acidity (r = .39*).  相似文献   

14.
Abstract

The environmental impact of copper sulfate (CuSO4#lb5H2O) must be evaluated before the chemical can be registered as a pesticide to control the apple snail (Pomacea canaliculata) in Hawaii's wetlands. To help achieve this goal, we investigated the sorption‐desorption reactions of CuSO4#lb5H2O with six wetland‐taro soils (Tropaquepts) of Hawaii. Our results indicated that: (i) copper (Cu) was sorbed rapidly: 98.0–99.9% of the added Cu was removed from solution within one hour when the loading rate was less than or equal to 300 mg Cu kg‐1 [initial Cu concentration = 30.0 mg Cu L‐1 or 12 kg (ha‐cm)‐1 as CuSO4#lb5H2O which is 10 times the maximum recommended rate of pesticide applications, (ii) Cu sorption increased as soil pH increased from 5.0 to 8.0, and (iii) sorption capacity varied from 210 mg Cu kg‐1 in a Tropaquept from Kauai Island to 500 mg Cu kg‐1 in another Tropaquept from Maui Island, after seven days of incubation at soil‐solution pH 6.0 and total solution Cu concentration of 0.10 mg Cu L‐1, a Cu level deemed toxic to some living organisms. It appears that more Cu was sorbed (less Cu remained in solution) if the soil contained high organic carbon (C) and low indigenous Cu. Also, there was an inverse relationship between Cu sorption and desorption by the soils tested: the more Cu a soil can sorb, the tighter it holds Cu, and the less Cu it releases. Since soil pH increases by 1 to 1.5 units upon flooding and Cu sorption increases with increasing pH, the recommended practice of flooding the soil for at least 48 hours between CuSO4#lb5H2O application and crop planting should be followed.  相似文献   

15.
Abstract

Contamination of soils by heavy metals is one of the environmental problems that the scientific community faces today. Such soils are difficult to treat because the heavy metals cannot be destroyed. Moreover, they are usually bonded with other contaminants, in particular organic ones. The presence of these organic pollutants can make the removal of metals from soils substantially more complicated. One way of coping with the problem which has been studied in recent years is the use of fixing agents which make the heavy metals unavailable to the plants, or prevent their leaching towards the groundwater. Inorganic fixing agents in particular have been tested and found to be suitable, but some organic ones can also be used, at least as temporary fixing materials. This paper gives preliminary results on remediation techniques using compost and Trichoderma viride Pers.: Fr. as heavy metal fixing agents.  相似文献   

16.
Two Fe chlorosis‐inducing calcareous soils were incubated for up to 5 months, at room temperature and field capacity, with Fe‐EDDHA, Fe‐DTPA, FeSO4, an amino acid chelate “Fe‐Metalosate”;, an oxide “Micronized‐Iron”;, and a precipitated Fe‐S compound “Iron‐Sul”;. Other treatments included DTPA chelate alone, elemental S and H2SO4 at comparable rates. Both water‐soluble, and DTPA‐extractable Fe fractions were measured periodically from each sample. All water‐soluble sources decreased with time. Soluble Fe was highest after Fe‐EDDHA addition but was not detectable after “Fe‐Metalosate”; and FeSO4. Acidification to neutralize CaCO3 significantly increased DTPA‐extractable Fe, which remained high with increasing incubation time. “Micronized‐Iron”; and S had only a slight effect on DTPA‐ extractable Fe. Though Fe‐EDDHA is the most efficient Fe material, pelleted acidified Fe sources, i.e., “Iron‐Sul”;, may be more economical for some crops in the long term.  相似文献   

17.
Acid soils are widespread and limit global plant production. Aluminum(Al)/manganese(Mn) toxicity and phosphorus(P) deficiency are the major limiting factors affecting plant growth and productivity on acid soils. Plants, however, have evolved various strategies to adapt to these stresses. These strategies include using both external and internal mechanisms to adapt to Al toxicity, regulating Mn uptake, translocation, and distribution to avoid Mn toxicity, and orchestrating a set of P transport me...  相似文献   

18.
There are specific aspects in the problem of optimization of the physical conditions of soil fertility that are determined by the genetic features of soils and by the degree of their transformation under anthropogenic impacts. An assessment of the major agrophysical parameters of the loamy soddy-podzolic soils on the Chepetsk-Kil’mez interfluve (Kirov oblast) is presented. A comparison between the actual and optimal parameters of the agrophysical properties of these soils shows that the most significant differences are observed in the soil structural status, the bulk density, and the water permeability.  相似文献   

19.
Morphological studies of soils using microscope, set up by Kubiëna, have been followed and modified especially in recent years in several countries2,3,4,6,7,13,16,18,19. We find that microscopic observation of thin sections of soils is one of the most useful tool for classification of soil characteristics. Although there have been many methods to make thin sections of soils, unfortunately we can find no satisfactory procedures for us.  相似文献   

20.
A simple trapping procedure for concentration of volatile organic compounds present in a head space and the subsequent analysis of the retained compounds by combined gas chromatographymass spectrometry is described. The procedure was used to study the organic metabolites evolved from various soils when they were amended with glucose and incubated under argon. A number of organic acids, alcohols, aldehydes and esters were evolved during a 4 week period. Less than 10 per cent of the added carbon was recovered as organic compounds, which was largely due to poor recovery of volatile organic acids from soil. Some implications of the observations to microbial ecology are discussed.  相似文献   

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