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1.

Purpose

Rice-paddy-dominated watersheds in eastern China are intensively cultivated, and lands with two crops receive as much as 550–600 kg?ha–1?year–1 of nitrogen (N), mainly through the addition of N-based fertilizers. However, stream N concentrations have been found to be relatively low. Waterways in the watersheds are assumed to be effective “sinks” for N, minimizing its downstream movement. We directly measured net sediment denitrification rates in three types of waterways (ponds, streams/rivers, and a reservoir) and determined the key factors that control net sediment denitrification. Such information is essential for evaluating the impact of the agricultural N cycle on the quality of surface water.

Materials and methods

The pond–stream–reservoir continuum was sampled every 2 months at nine sites in an agricultural watershed between November 2010 and December 2011. Net sediment N2 fluxes/net sediment denitrification rates were determined by membrane inlet mass spectrometry and the N2/Ar technique. A suite of parameters known to influence denitrification were also measured.

Results and discussion

Net denitrification rates ranged between 28.2?±?18.2 and 674.3?±?314.5 μmol N2–N?m–2?h–1 for the streams, 23.7?±?23.9 and 121.2?±?38.7 μmol N2–N?m–2?h–1 for the ponds, and 41.8?±?17.7 and 239.3?±?49.8 μmol N2–N?m–2?h–1 for the reservoir. The mean net denitrification rate of the stream sites (173.2?±?248.4 μmol N2–N?m–2?h–1) was significantly higher (p?<?0.001) than that of the pond sites (48.3?±?44.5 μmol N2–N?m–2?h–1), and the three types of waterways all had significantly higher (p?<?0.01) mean net denitrification rates in summer than in other seasons. Linear regression and linear mixed effect model analysis showed that nitrate (NO3 ?–N) concentration in surface water was the primary controlling factor for net sediment denitrification, followed by water temperature. Using monitoring data on NO3 ?–N concentrations and temperature of the surface water of waterways and an established linear mixed effect model, total N removed through net sediment denitrification in the pond–stream–reservoir continuum was estimated at 46.8?±?24.0 t?year–1 from July 2007 to June 2009, which was comparable with earlier estimates based on the mass balance method (34.3?±?12.7 t?year–1), and accounted for 83.4 % of the total aquatic N. However, the total aquatic N was only 4.4 % of the total N input to the watershed, and thus most of the surplus N in the watershed was likely to be either denitrified or stored in soil.

Conclusions

High doses of N in a rice-paddy-dominated watershed did not lead to high stream N concentrations due to limited input of N into waterways and the high efficiency of waterways in removing N through denitrification.  相似文献   

2.
2013年我国种植业化肥施用状况分析   总被引：25，自引：5，他引：25  
【目的】我国农用化肥消费量大,数据来源不同,统计口径各异,行业内大多引用国家统计局公布的数据,但该数据无法推算出氮肥、磷肥、钾肥分类消费量。我国区域间、季节间、作物间化肥消费情况的报道很少,在调节化肥供需、指导化肥行业健康发展时显得依据不足。调查种植业化肥施用状况可以为指导肥料生产、供应提供重要依据。【方法】以农业部339个国家级基层肥料信息网点为依托,根据我国农业生产习惯和我国政府部门统计习惯,将一年分为三个用肥季,1 5月份为春耕季,6 8月份为夏播季,9 12月份为秋冬种季。在三个季节,每个网点随机调查30个农户的主要种植作物施用氮肥、磷肥、钾肥、复合(混)肥(包括配合式)量,经两级土壤肥料部门审核后,采用省份、相似种植区域、全国三级逐级加权平均的方法,推算了不同区域、不同季节、不同作物单位面积施肥量;再用作物单位面积施肥量、该作物全国种植总面积、样本中施肥面积占该作物种植面积的比例推算了作物全年、不同季节化肥施用量。同时,分析了主要作物、不同季节化肥施用状况以及供需平衡情况,不同季节、不同区域供肥情况和农民的购肥习惯。【结果】2013年我国种植业化肥施用量5498万吨(折纯下同),其中,氮肥(实物量)3382万吨,磷肥1175万吨,钾肥941万吨。粮食作物化肥总用量为2782万吨,占种植业化肥总用量的50.6%;其次是果树和蔬菜,三类作物占种植业化肥施用总量的82.8%,经济、园艺作物单位面积化肥施用量大于粮食作物。春耕、夏播、秋冬种化肥施用量分别占全年化肥施用量的34.2%、35.6%、30.2%。复混肥料和尿素是农民最常购买的两种肥料,从全年来看,农民施用复混肥料和尿素的样本数分别占总样本数的72.5%和71.6%,春耕、夏播、秋冬种农民购买尿素和复合(混)肥的样本数分别占该阶段样本数的70.9%和62.9%、84.9%和78.1%、56.6%和83.9%。春耕和夏播时期农民多数选用尿素,秋冬种多数选用复混肥料,东北、西北、华中南地区农民多选用尿素,华北、西南、华东地区农民多选用复混肥料。另外,我国氮肥、磷肥供应分别过剩1080万吨、680万吨,钾肥缺口370万吨,供需矛盾突出。氮、磷、钾养分配合式为15-15-15的复混肥样本数占农民选购复混肥总样本数的33.3%,说明复混肥养分结构不尽合理。【结论】建议国家进一步遏制氮肥、磷肥过剩产能,优化产品结构,大力推广科学施肥技术。  相似文献   

3.
参考作物蒸散量(ET_0)是确定植被生态系统需水量的关键因子,其时空分布特征及主要影响因素分析对于制定植被恢复策略与区域水资源配置方案具有重要意义。本文基于FAO-56 Penman-Monteith公式和广西地区25个气象站点1960—2010年的逐日资料,计算了各站点的ET_0,在此基础上采用GIS的克里金插值、Spearman秩次相关法和通径分析方法分析了广西喀斯特与非喀斯特地区ET_0的时空变化特征及其影响因子。结果表明,51年来广西各站点多年平均ET_0为1 138 mm×a~(-1);空间分布呈由南向北、由低纬度向高纬度递减的特征,高值区主要分布在非喀斯特地区,低值区主要分布在喀斯特地区。喀斯特与非喀斯特地区年ET_0累积距平曲线均呈"N"型分布;20世纪70年代最高,90年代最低,21世纪以来年ET_0有所回升,但仍低于51年平均值。此外,喀斯特地区ET_0年际变化小于非喀斯特地区。日照时数、风速和平均温度是影响非喀斯特地区年ET_0变化的主要气象因子,而相对湿度则通过与其他气象因子的相互作用间接对喀斯特地区年ET_0的变化产生较大影响。在季节尺度上,日照时数和平均气温在各季节都是ET_0最主要的影响因子,与ET_0呈正相关关系;风速在喀斯特地区冬、春两季对ET_0的间接作用系数为负,在非喀斯特地区并未发现这一现象。了解不同地区ET_0的变化趋势是植被生态需水定额计算的必要措施。  相似文献   

4.
A protozoological survey was performed on a waste-stabilization pond to isolate, identify, and determine the incidence of ciliates present in these waters. The correlation between the species found and the physicochemical parameters was investigated. One hundred and eighty samples were analyzed from February 1983 to February 1984. Free-living ciliates isolated include:Carchesium polypinum Linnaeus,Vorticella microstoma Ehrenberg,Vorticella convallaria Linnaeus,Didinium balbiani Fabré-Domergue,Amphileptus claparedei Stein,Spathidium spathula Müller,Litonotus fasciola Ehrenberg,Paramecium caudatum Müller,Paramecium aurelia Ehrenberg,Tetrahymena vorax Kidder,Tetrahymena pyriformis Ehrenberg,Cyclidium glaucoma Müller,Aspidisca costata Ehrenberg, andStylonychia putrina Stokes. The performance of the pond was predominantly anaerobic. The temperature, total alkalinity, and nitrate concentration were the most variable parameters in the system studied.  相似文献   

5.
Proteolytic bacterial communities, which mineralize organic nitrogen, play a key role in agricultural systems. In this study, alkaline metalloprotease (apr) gene fragments from proteolytic bacteria were investigated in bulk and rhizosphere paddy soil from four fields under organic management (for 2, 3, 5, and 9 years), and from one field under conventional management (for 2 years). We analyzed the abundance and structure of the proteolytic bacterial communities using real-time quantitative PCR and denaturing gradient gel electrophoresis. Our results showed that the abundance of proteolytic bacteria ranged from 1.57?×?108 to 8.02?×?108?copies/g of soil. In addition, the abundance of the proteolytic bacteria in the paddy soils under organic management was significantly higher than those in the paddy soil under conventional management. Moreover, the gene copy numbers in the rhizosphere soils were significantly higher than those in the bulk soils. The abundance of proteolytic bacteria tended to increase with the duration of organic management, with the highest abundance being found in the soil that had been under organic management for 5 years. However, the proteolytic bacteria communities in the paddy soils were not significantly affected by management practices. Phylogeny analysis showed that all gel bands obtained represented genes from Pseudomonas. Additionally, correlation analysis and canonical correspondence analysis showed that C/N, C, and N were important factors that influenced the abundance and community structure of the proteolytic bacteria. These results suggest that proteolytic bacteria are indicators in organic management systems, depolymerize organic N and hence maintain soil sustainability.

Abbreviations: CM: conventional management; OM: organic management; DGGE: denaturing gradient gel electrophoresis; qPCR: real-time quantitative PCR detecting system; COFCC: China organic food certification center; CCA: canonical correspondence analysis  相似文献   

6.
A simple method (the inversed auger hole method) for measuring field-saturated hydraulic conductivity (Kfs) was investigated. Measurements were carried out in the spring, summer and autumn at three depths in two Swedish clay soils (Ultuna and Limsta, with clay contents of 45–60%0 and 65–80%, under barley and grass/clover ley respectively). Seasonal fluctuations in Kfs at Limsta were more pronounced, and were observed deeper in the profile. This was attributed primarily to larger structural changes due to a higher capacity for swell/shrink (normal shrinkage over the available water range) and an earlier drying up of the soil under grass/clover ley. It was shown that the measured Kfs values were strongly correlated with the total inter aggregate (macro-) porosity (et), estimated from a simple model of soil shrinkage. Combining the data from both soils, a single power-law relation was adequate (r= 0.73) to describe the variations in Kfs with et  相似文献   

7.
Two diploid cytotypes of Chenopodiumalbum have earlier been proposed as the probable ancestors ofhexaploid C. album in Gangetic Plainof West Bengal on the basis of cytomorphological data. The present study withthe diploid cytotypes of C. album (onebroad leaved, another narrow leaved), one wild species, C.murale and the hexaploid C.album utilizing parameters like seed protein, isozyme,RAPD, tissue culture along with conventional cytomorphological data supports ourearlier hypothesis of allopolyploid origin of hexaploid C.album. The results indicate that all the three diploidprogenitors have contributed for the evolution of present day semi-cultivatedhexaploid C. album. This study furthersuggests that the diploid cytotypes had been evolved sympatrically.  相似文献   

8.
Chinese cabbage plants [Brassica pekinensis (Lour) Rupr. cv. Nagaoka 50] were cultivated experimentally for two years (1993 and 1994) using a semi‐forcing technique of floating rowcovers, polyethylene (T1), polypropylene (T2), versus no floating row‐covers, control (T0). Five samplings were made, taking four plants per each replication and total phosphorus (P) (Ptotal), inorganic P (Pi), and calculated organic P (Porg) were determined as well as foliar acid phosphatase activity (FAPA). The aerial and root temperatures of the treatments T1 and T2 exceeded those of T0. The Ptotal concentration showed no significant variations with treatment, whereas the Pi concentrations increased in Ti and T2 and Porg decreased in both treatments with respect to T0. The FAPA was influenced a similar way as Pi, raising with temperature. The contents (mg plant‐1) of Ptolal, Pi, and Porg were greater in T1 and T2 than in T0, and this could be due to the fact that the highest temperatures (root and aerial zone) generated by the plastic rowcovers favored the absorption of P, thereby boosting FAPA and the fresh and dry weights, and yield.  相似文献   

9.
This study evaluates soil properties in organically managed olive groves and natural zones in a mountainous area of Andalusia, Spain. Two soil types (Eutric Regosol and Eutric Cambisol) and the most common soil management methods (tillage and two intensities of grazing) were studied. Both soil types in the groves had values not much lower than those in the natural areas. Average (±SE) values in the groves were 1.58 ± 0.71% for organic carbon, 323 ± 98 g kg?1 for macroaggregate stability, 1.11 ± 0.16 g cm?3 for bulk density, 3.5 ± 1.6 mm h?1 for saturated hydraulic conductivity and 1209 ± 716 mg CO2 kg?1 for soil respiration. Overall, these values tended to be lower in the tilled compared with that in the grazed groves. The average phosphorus soil content (5.83 ± 5.22 mg kg?1) was low for olive production and within adequate ranges for N (0.12 ± 0.05%) and K (142 ± 81 mg kg?1). Soil erosion was high in the tilled groves (35.5 ± 18.2 t ha?1 year?1) with soil loss correlating with indicators of soil degradation such as organic carbon content and water stable macroaggregates. In the grazed groves, soil loss was moderate with no clear indications of soil degradation. Overall, there was significant farm‐to‐farm variability within the same soil and land management systems. Olive production had a moderate effect on soil degradation compared with natural areas and olive cultivation could be sustained in future if cover crop soil management replaced tillage, especially in the most sloping areas.  相似文献   

10.
Selenium (Se) is an essential element for humans but is not considered as essential for plants. However, its beneficial role in improving plant growth and stress tolerances is well established. In order to study the role of Se in cadmium (Cd) toxicity in pepper (Capsicum frutescens cv. Suryankhi Cluster), this experiment was carried out in greenhouse conditions. Treatments comprised Cd [0, 0.25, and 0.5 mM cadmium chloride (CdCl2)] and Se [0, 3, and 7 µM sodium selenite (Na2SeO3)] with three replications. The result showed that Cd decreased chlorophyll a, chlorophyll b, and carotenoids, whereas Se supplementation diminished Cd toxicity on photosynthetic pigment. Selenium at 7 µM significantly increased the leaf area in the plants grown at 0.25 mM Cd. The application of Se at 3 µM with 0.25 mM Cd and Se at 3 µM and Se at 7 µM with 0.5 mM Cd increased the activity of catalase (CAT). Selenium at 7 µM decreased the proline content of pepper leaves exposed to Cd at 0.5 mM (30%). Selenium significantly enhanced the antioxidant activity of leaves, which was diminished by Cd toxicity. In general, Se has a beneficial effect on plant growth and is an antioxidant enzyme of pepper cv. Suryankhi Cluster under Cd stress and non-stress conditions.  相似文献   

11.
I. D&#;AZ  J. TORRENT 《土壤圈》2016,26(5):636-642
Maintaining soil phosphorus(P) at adequate levels for plant growth requires assessing how the long-term P balance(viz., the difference between P inputs and outputs) results in changes in soil test P. The hypothesis that routinely measured soil properties can help predict the conversion factor of P balance into Olsen P was tested at 39 sites in agricultural areas of the Mediterranean region in Spain. A set of soil samples from each site was analyzed for Olsen P, inorganic P(P extracted using 0.5 mol L~(-1) H_2SO_4), pseudototal P(P extracted using 0.5 mol L~(-1) H_2SO_4 following ignition at 550℃), and organic P(the difference between pseudototal P and inorganic P). Organic and Olsen P were uncorrelated in most of the 39 soil sets, which suggests that organic P content changed little with P inputs and outputs. The slopes of the regression lines of Olsen P against pseudototal and inorganic P, which were used as two different measures of the conversion factor, ranged widely(from 0.03 to 0.25 approximately), with their average values(about 0.10) being similar to those found in long-term experiments conducted in temperate areas. Neither conversion factor was significantly correlated with any routinely measured soil property; however, the conversion factor for inorganic P was significantly lower for calcareous soils than for noncalcareous soils. Our negative results suggest the need to isolate the influence of soil properties from that of management systems and environmental factors relating to P dynamics in future studies.  相似文献   

12.
Abstract

The zinc (Zn) content of ten selected soils in Louisiana was partitioned into the following fractions: water‐soluble, exchangeable, chelated, organic and residual. In seven of the soils, water‐soluble > exchangeable < chelated < organic < residual Zn. In three of the soils, water‐soluble < exchangeable < chelated < organic < residual Zn.

The ten soils contained an average of 1.7, 0.9, 2.6, 4.4 and 86.4 per cent of the total in the water‐soluble, exchangeable, chelated, organic and residual mineral Zn fractions respectively.  相似文献   

13.
A study was made of the formation of anaerobiosis in a waterlogged soil. A dilute soil suspension containing NO?3, Fe3+, sodium citrate, a limited amount of O2, and trace elements was used as a model of waterlogged soil. Polarography was used to detect dissolved O2, Fe3+ and Fe2+. The fates of the NO?3 and Fe3+ during and after O2 consumption by the microorganisms were studied in a specially designed vessel. A close correspondence was obtained between the reduction of NO?3, NO?2 and Fe3+ and the growth of denitrifying bacteria in the closed system employed. From the experimental results we presume that microorganisms which respire NO?3 are also capable of utilising Fe3+ in their respiration. The mechanisms of reduction of these chemical species by the microorganisms are also discussed, emphasising the possibility of the participation of chemical reduction of NO?2 by Fe2+ in the over-all reduction process.  相似文献   

14.
The 87Sr/86Sr ratios in rain at three sites in Japan were about 0.706 to 0.712, whereas those at one site in central Korea were higher (0.711 to 0.716), reflecting the difference in geology between the two countries. Because the 87Sr/86Sr ratios of exchangeable sites in soil minerals are indistinguishable from those of associated plants, aerosol Sr originating from both can be grouped together as plant-derived Sr. Spatial and temporal variations in 87Sr/86Sr and Sr/Ca ratios in the rain suggest the presence of plant-derived Sr and Ca in addition to Sr and Ca derived from sea-salt, acid-soluble aeolian carbonate from China, and cement-derived carbonate. However, systematic data on the 87Sr/86Sr ratios and elemental concentrations of soils, plants, fly-ash, and road dust are required to put reliable constraints on the provenance of atmospheric Ca.  相似文献   

15.
Abstract

Earlirose rice (Oryza sativa L. ) and Hawkeye soybeans (Glycine max L.) were grown in solution culture with A12(SO4)3 in concentrations of 0, 10‐6, 10‐5, 10‐4, 10‐3 M. Only at 10‐4 (slightly) and at 10‐3 M were there yield depressions due to Al. The threshold concentration of Al for toxicity was about 20 μg/g in rice shoots and about 30 μg/g in soybean leaves. The solution level necessary for these concentrations was 8 μg Al/ml. Plant concentrations which caused severe toxicity were 70 μg Al/g plant with 81 μg Al/ml solution. Most Al remained in roots, but leaves contained more than did stems of soybeans. The high Al decreased Fe, Cu, and Mn concentrations in shoots of rice and decreased Fe, Cu, and Zn in roots of rice. The high Al resulted in decreased Fe and Zn in leaves of soybeans. No Fe deficiency symptoms were present due to the high Al.  相似文献   

16.
Understanding the sensitivity of soil respiration to temperature change and its impacting factors is an important base for accurately evaluating the response of terrestrial carbon balance to future climatic change, and thus has received much recent attention. In this study, we synthesized 161 field measurement data from 52 published papers to quantify temperature sensitivity of soil respiration in different Chinese ecosystems and its relationship with climate factors, such as temperature and precipitation. The results show that the observed Q10 value (the factor by which respiration rates increase for a 10 °C increase in temperature) is strongly dependent on the soil temperature measurement depth. Generally, Q10 significantly increased with the depth (0 cm, 5 cm, and 10 cm) of soil temperature measuring point. Different ecosystem types also exhibit different Q10 values. In response to soil temperature at the depth of 5 cm, alpine meadow and tundra has the largest Q10 value with magnitude of 3.05 ± 1.06, while the Q10 value of evergreen broadleaf forests is approximately half that amount (Q10 = 1.81 ± 0.43). Spatial correlation analysis also shows that the Q10 value of forest ecosystems is significantly and negatively correlated with mean annual temperature (R = −0.51, P < 0.001) and mean annual precipitation (R = −0.5, P < 0.001). This result not only implies that the temperature sensitivity of soil respiration will decline under continued global warming, but also suggests that such acclimation of soil respiration to warming should be taken into account in forecasting future terrestrial carbon cycle and its feedback to climate system.  相似文献   

17.
The microbial community structure and function under forest in tropical peatlands are poorly understood. In this study, we investigated the microbial community structure and diversity in natural peat swamp forest soil, disturbed peat soil and mineral soil in Central Kalimantan, Indonesia, using 454 pyrosequencing. The results showed that the natural peat soil had the greatest fungal species richness (Chao1), which was significantly (p < .05) larger than that in the other two soils. Community structure of both fungi and bacteria in natural peat soil differed significantly from that in the disturbed peat soil (p = .039 and p = .045, respectively). Ascomycota (40.5%) was the most abundant phylum across the three soils followed by Basidiomycota (18.8%), Zygomycota (<0.1%) and Glomeromycota (<0.1%). The linear discriminant analysis with effect size (LEfSe) showed that Ascomycota (p < .05) and genus Gliocephalotrichum (p < .05) dominated in natural peat soil. Functionally, pathotrophs were more abundant in disturbed peat soil (p < .05). Proteobacteria (43.8%) were the most abundant phylum followed by Acidobacteria (32.6%), Actinobacteria (9.8%), Planctomycetes (1.7%). Methylocystis, Telmatospirillum, Syntrophobacter, Sorangium and Opitutus were the more abundant genera in disturbed peat soil, whereas Nevskia and Schlesneria were more abundant in mineral soil and natural peat soil, respectively. The natural peat forest soil supported a more diverse microbiology; however, the land use of such a soil can change its microbial community structure. The results provide evidence that the disturbance of tropical peat land could lead to the introduction and spread of a large number of fungal diseases  相似文献   

18.
We examined the influence of a forested landscape on the quality of water in a stream originating on an urban landscape and flowing through National Forest lands. Sample sites included an urban stream (URB), a site on the same stream but within a National Forest (FOR) and 2 km downstream from the URB site, and a small, undisturbed, forested reference tributary of the main stream (REF). We monitored stream water quality from March 2002 through June 2003. Average base flows for the three stream sites were URB = 184 L s?1, FOR = 420 L s?1, and REF = 17 L s?1. We analyzed weekly stream water samples for NO3 ?, NH4 +, PO4 +, Cl?, K, Ca, Mg, SO4, SiO2, pH, conductivity, total suspended solids (TSS), and bacteria on a monthly basis. Most solutes were higher in concentration at the URB site, as were conductivity, TSS, and bacteria counts. Reductions in NO3 ?, NH4 +, and PO4 + concentrations between the URB and FOR sites were inferred from changes in nutrient:chloride ratios. Bacteria populations were greater and more responsive to stream temperature at the URB site. Water quality responses to changes in stream discharge varied among sites but were greater at the URB site. By all measures, water quality was consistently higher at the FOR site than at the URB site.  相似文献   

19.
In order to test whether major reductions in acid inputs had improved water quality sufficiently for fish populations to recover, we stocked wild European perch (Perca fluviatilis) in three highly acidified lakes that had previously supported this species, and in one limed lake. The fish, which were introduced from a local lake (donor lake), generally ranged from 12 to 16 cm in total length, and were stocked at densities of 117–177 fish ha?1. The untreated lakes were highly acid, with minimum pH values and maximum inorganic aluminium concentrations (Ali) during the spring of 4.6–4.7 and 118–151 µg L?1 respectively. In the limed lake, the corresponding values for pH and Ali ranged between 5.8 and 6.6 and 5 and 19 µg L?1 respectively. Gill-netting in two subsequent years after the introduction yielded only a few recruits (0+) and one adult in one of the three acidified lakes in one year only. However, stocked perch reproduced successfully in both years in the limed lake. There was a significant linear relationship between the catches (CPUE) of juvenile perch (age 0+) in the different lakes in the autumn and the water quality in May (time of hatching), both in terms of Ali (r 2=0.934, P<0.05) and pH (r 2=0.939, P<0.05). Our data suggest unsuccessful recruitment in waters of pH <5.1 and Ali>60 µg L?1.  相似文献   

20.
Unusually low net N mineralization in soils relatively rich in total organic C and N was repeatedly reported for sandy arable soils in NW Europe. In order to adequately account for it in simulation models, it is necessary to know the involved substances and processes. Therefore, 9 arable top soils (< 6% clay) with a wide range of total organic C (1.1%–5.2%) and C : N ratios (12–35) were studied. The soils varied strongly in the mineralizability of soil organic N which was determined via long‐term laboratory incubations (> 200 d). It was hypothesized that mineralization was controlled by antioxidants, and the Trolox equivalent antioxidant capacity (TEAC) of the soils was measured. In addition, pyrolysis–field ionization mass spectrometry (Py‐FIMS) was applied to investigate the influence of the molecular‐chemical composition of soil organic matter. In these soils, the compound class of sterols from Py‐FIMS analysis was most closely, negatively correlated with the mineralizability of soil organic N (r2 = 0.75, p = 0.003). This was probably not an antioxidative effect, because the TEAC values did not correlate sufficiently with the mineralizability and the sterol intensities. However, the negative relation with sterols could be causal, since the correlation was about as close with other components of the compound class of sterols and even closer with the main plant sterol beta‐sitosterol (r2 = 0.84, p = 0.001). In addition, the variability among samples was strongly governed by the proportions of sterols, and sterols also had a high discriminating power in discriminant analysis. Furthermore, the proportions of sterols were extraordinary in those arable podzol soils that developed under previous heath‐ or woodland (up to 10.2% of total ion intensity from Py‐FIMS). In conclusion, the inhibitory effect of these compounds needs to be investigated in more detail in order to optimize parameterization of N as well as C simulation models especially for podzolized, sandy arable soils with former heath‐ or woodland vegetation.  相似文献   

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