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麦秸人造板胶合机理的研究 总被引：10，自引：1，他引：10
测定了麦秸表面的自由能以及异氰酸酯（ＭＤＩ）和脲醛树脂（ＵＦ）胶粘剂对麦秸表面的接触角，并用差示扫描量热法（ＤＳＣ）研究了这两种胶粘剂与麦秸之间的热反应特征。其结果表明：麦秸表面的自由能较低；ＭＤＩ与ＵＦ相比，前者对麦秸有较好的润湿性能。ＭＤＩ自身的热反应特征平稳，它可以与水发生反应。研究还表明，ＵＦ和改性ＵＦ相比，两者热反应特征明显不同，后者的吸热反应较前者提前，总吸热量减少。 相似文献
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用电子自旋共振波谱仪研究麦秸中的自由基 总被引：7，自引：0，他引：7
借助于电子自旋共振波谱仪研究了紫外光、温度、胶粘剂和机械加工对麦秸中自由基的影响。结果表明：反映麦秸自由基特征量的g因子与木材的g因子具有相同的数值。机械加工对木材及麦秸中自由基的影响相似，麦秸被加工越细小，其自由基含量越高，但麦秸的自由基含量要明显低于木材，麦秸形态变化后自由基的比例也明显低于木材，外界温度变化可以影响麦秸的自由基浓度，100℃之前，此影响不显著，100℃后，麦秸的自由基浓度明显上升，紫外光的照射对麦秸自由基浓度有影响，随着紫外光照射时间的延长，麦秸中自由基浓度逐渐增加，但增中值不大，并趋于稳定，麦秸中的自由基与胶粘剂之间可以发生利用，麦秸与秸中自由基浓度逐渐增加，但增加值不大，并趋于稳定。麦秸中的自由基与胶粘剂之间可以发生作用，麦秸与脲醛树脂胶反应后，其自由基含量略有减小。而麦秸与异氰酸酯反应后，其自由基含量有较大程度的降低。 相似文献
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Seyedeh Masoumeh Hafezi Kazem Doosthoseini 《林业研究》2014,25(3):667-670
We used silane coupling agents to improve the bonding ability between wheat straw particles and UF resin, and investigated surface properties （wettability and surface roughness） and hardness of parti-cleboard made from UF-bonded wheat straw （Triticum aestivum L.） combined with poplar wood as affected by silane coupling agent content and straw/poplar wood particle ratios. We manufactured one-layered particleboard panels at four different ratios of straw to poplar wood par-ticles （0%, 15%, 30% and 45% wheat straw） and silane coupling agent content at three levels of 0, 5% and 10%. Roughness measurements, average roughness （Ra）, mean peak-to-valley height （Rz）, and root mean square roughness （Rq） were measured on unsanded samples by using a fine stylus tracing technique. We obtained contact angle measurements by using a goniometer connected to a digital camera and computer sys-tem. Boards containing greater amounts of poplar particles had superior hardness compared to control samples and had lower wettability. Panels made with higher amounts of silane had lower Rq values. 相似文献
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ZHANG Yang JIANG Hua ZHANG Yijia Nanjing Forestry University Nanjing P.R.China 《中国林业科技(英文版)》2007,6(4):25-30
The biology treatment of cellulases or hemicellulases is used in this paper. The effects of cell ulases and hemicellulases on surface wettability and gluing property of poplar and wheat straw were investigated. It was found that the surface contact angles of poplar and wheat straw were reduced and the surface free energies were increased after treatment by these enzymes. The gluing strengths of popular and wheat straw were enhanced with the increases of the dosage of enzymes and the time of enzymatic treatment. 相似文献
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A study was conducted to test wettability changes of the wheat straw treated with different methods for the preparation of wheat straw particle board. The wheat straws were separately sprayed with two chemicals (0.6% NaOH, 0.3% H2O2) and three enzymes (lipase, xylanase, cellulase). The contact angle between water and the surface of wheat straw was measured and the spreading-penetration parameters (K-values) were also calculated with wetting model. The surfaces of treated wheat straw and control sample were scanned by means of Micro-FTIR, and their peaks arrangements were analyzed. The surface morphologies of treated wheat straw and control sample were also observed by SEM. Chemical etching was found on the exterior surfaces of the straws treated separately with 0.6% NaOH and 0.3% H2O2; furthermore, the spreading-penetration parameters (K-values) of the distilled water on the exterior surfaces of the treated wheat straw along the grain were higher than that of control. The wettability of exterior surfaces of the wheat straws treated separately with lipase, xylanase and cellulose were improved after treating for seven days, and among the three enzymes treatments, the lipase treatment showed best result. The lipase treatment and NaOH treatment were determined as better methods for improving the wettability of wheat straw surfaces. However, in the economic aspect, NaOH treatment was more practical and easier in the pretreatment for the manufacture of straw particle board. 相似文献
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Improvement mechanism of bondability in UF-bonded reed and wheat straw boards by silane coupling agent and extraction treatments 总被引：4，自引：0，他引：4
The effects of silane coupling agents and extractives on the wettability of reed and wheat straws were investigated. The inherent wettability of these materials was low but could be significantly improved by treating with silane coupling agents. The degree of improvement achieved by each silane coupling agent was different: Vinyl silane had almost no effect on wettability, epoxide silane was found to be more effective for reed straw, and amino silane was better for wheat straw. The wettability of these materials could also be improved by ethanol-benzene extraction, which resulted in more improvement in wheat straw than reed straw. The analyses of untreated reed and wheat straws by electron spectroscopy for chemical analysis (ESCA) revealed that there was much silicon on both the outer and inner surfaces of the former but only on the outer surface of the latter. The influence of hot-water extractives and silane coupling agents on the gelation time and pH of urea formaldehyde (UF) resin was also examined. The addition of extractives was found to increase the gelation time. Amino silane greatly retarded the gelation of OF resin, whereas epoxide and vinyl silanes had no influence on resin gelation. This retardation was found to be due to an increase in the pH of the resin. 相似文献
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麦秸刨花板的耐水性能研究 总被引：3，自引：0，他引：3
本文研究了用MDI与UF两种胶粘剂以不同比率混合后制造的麦秸刨花板的耐水性能。结果表明：随着胶粘剂中MDI比率的增加，麦秸刨花板的耐水性能提高，但改善的程度逐渐趋缓；在一定范围内，提高麦秸刨花板的密度，可以降低其吸水厚度膨胀率。 相似文献
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Wheat straw particleboard bonded with a urea–formaldehyde (UF) resin, usually employed in the manufacture of wood-based particleboards, or with a resin based on epoxidised oil was manufactured using a compression molding machine. The effects of resin type on internal bond strength, flexural modulus, and thickness swelling were examined. The properties of boards using UF resins were poor. Internal bond strength and thickness swelling, linked to adhesion quality, were especially low. The high compatibility between straw particles and oil-based resin was explained in terms of straw surface free energy. In straw, this parameter exhibits a much lower polar component than wood species and leads to higher compatibility with resins based on oil than with water-soluble systems like UF. 相似文献
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硅烷偶联剂对稻草板力学性能的影响 总被引：2，自引：0，他引：2
以稻草为原料生产人造板,成为高效利用稻草资源、缓解木材供需矛盾的一条有效途径。本文通过硅炕偶联剂（SCA）改善稻草表面润湿性,用脲醛树脂胶黏剂（UF）胶结制戍稻草板,分析SCA用量和UF用量对稻草板力学性能的影响。结果表明：施胶量为16％、SCA添加量为1％时,板子的静曲强度和内结合强度达到GB／T4897．4—2003中A类刨花板优等品的要求。 相似文献
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稻草原料酸碱性及稻草中密度纤维板的性能 总被引：8，自引：2，他引：8
测试分析了稻草原料的ｐＨ值和缓冲容量，分别使用脲醛树脂胶和异氰酸酯胶在特定工艺条件下压制了稻草中密度纤维板，并测试了板材性能。结果表明：１）稻草秸秆原料呈弱碱性，缓冲容量远高于普通木材；经热磨处理获得的稻草纤维呈弱酸性，其缓冲容量虽较稻草秸秆有一定幅度的下降，但仍高于普通木材；２）脲醛树脂或异氰酸酯稻草中密度纤维板的性能都明显优于相应的碎料板；在密度０．８０ｇ／ｃｍ３和施胶量１７％的条件下，脲醛树脂稻草中密度纤维板性能达到国标ＧＢ／Ｔ１７６５７－１９９９一等品的要求，在密度０．８０ｇ／ｃｍ３和施胶量６％的条件下，异氰酸酯稻草中密度纤维板性能达到国标ＧＭ／Ｔ１７６５７－１９９９优等品要求。 相似文献
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YU Wenji REN Dinghua MA Hongxia ZHOU Yue Research Institute of Wood Industry Chinese Academy of Forestry Beijing P.R.China 《中国林业科技(英文版)》2005,4(2):66-74
China is one of the major production countries forwood-based panel products, and its production wasranked in the second place in the world in 2003. Onthe other hand, however, China is also a country withshortage of forest resources. As the main raw material,wood supply is becoming a serious problem with thefast growing of panel production. Fortunately, thereare plenty of agricultural residues in China, and thisgives the possibility to use agri-based fibers instead ofwood. Many wood-based pane… 相似文献
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The main objective of this research is to evaluate the wettability of the processed bamboo surfaces. The important surface energy and acid-base properties for processed bamboo have been estimated by using contact angle techniques. According to the results, the change of ages has a positive relation with the contact angles of water on processed bamboo. The contact angles were increased after the bamboo surface treated in high temperature condition and preservation. The different treat methods have a strong influence on acid-base energy component insurface of bamboo. Compared with pinewood, the surface of bamboo seems to be stronger in the acid-base energycontribution. 相似文献
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Development of high-performance UF-bonded reed and wheat straw medium-density fiberboard 总被引：10，自引：1，他引：10
Guangping Han Shuichi Kawai Kenji Umemura Min Zhang Takahisa Honda 《Journal of Wood Science》2001,47(5):350-355
Urea formaldehyde resin-bonded reed and wheat straw fiberboards were produced from the fibers made under different steam cooking conditions in refining processes at densities of 500 and 700kg/m3. The effect of steam cooking conditions on the board properties was examined. The steam pressure and cooking time for reed and wheat straws were 0.4MPa/10min and 0.4MPa/5min, respectively, and 0.6MPa/3min and 0.6MPa/10min for both straws. The effect of steam cooking treatment before the fiber refining process on the wettability and weight losses of the straws was also investigated. The results indicated that the mechanical properties and linear expansion of the straw medium-density fiberboard (MDF) were improved with increasing steam cooking pressure and time during the refining process, whereas the thickness swelling (TS) did not vary much. The wettability of the straws was improved by cooking treatment. The steam cooking conditions had little effect on the wettability of the straw surfaces. For reed and wheat straws, the weight losses increased with increasing steam pressure and cooking time. In addition, it was found that the properties of MDF were significantly higher than those of particleboard, especially the internal bond (IB), where the IB values of MDF were more than 10 times higher than those of particleboard. All the properties of the straw MDF, except the TS of wheat board, can meet the requirement of JIS fiberboard standard. The high performances of MDF could be due to the improved wettability and the removal of extractives during the refining process. 相似文献
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选取丙烯酸酯、聚氨酯、丙烯酸-聚氨酯共聚物3种水性漆为滴液,用接触角测试仪对3种水性漆在杨木表面的接触角进行测试,对比分析其对杨木表面润湿性的影响。结果表明:未进行超纯水稀释的水性漆中,丙烯酸酯、共聚物水性漆在杨木径切面的润湿性优于弦切面,聚氨酯水性漆则反之;共聚物水性漆相比于其他两种漆润湿性更好,聚氨酯次之,丙烯酸酯水性漆的润湿性则相对较差。相比未进行超纯水稀释的水性漆,经稀释处理的3种水性漆在杨木表面的接触角均有不同程度的下降。接触角下降率分析表明:丙烯酸酯水性漆相比其他两种漆在杨木表面的润湿性更好,此外共聚物水性漆在杨木弦切面润湿性优于径切面,而其他两种水性漆则相反。 相似文献
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Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were used to study ambient-aged wood
fibers and their effects on the mechanical properties of medium-density fiberboard (MDF). It was found that MDF made with
ambient-aged fibers had poorer mechanical properties than MDF made with fresh fibers; this difference resulted from the alterations
of surface characteristics of wood fibers after ambient aging, which led to poor wettability of the urea–formaldehyde (UF)
resin applied to the aged wood fibers. After 6 months of ambient aging, the concentration of carbonyl groups in the fibers
increased by 144%, while the pH value of wood fiber decreased from 5.2 to 4.7. SEM showed that much more UF resin agglomerated
on the surface of ambient-aged fibers and the breakage of MDF made with aged fiber frequently occurred at the resin-fiber
interfaces, indicated the poorer wettability of UF resin to fibers due to the decrease in surface energy after aging. 相似文献