共查询到20条相似文献，搜索用时 31 毫秒
1.
土壤胡敏酸与铜、锌离子的络合特征及生物有效性的研究 总被引：1，自引：0，他引：1
通过田间试验研究了胡敏酸(HA)与铜、锌离子的络合特性。结果表明,施肥后土壤HA向结构复杂方向转化,HA与Cu2+、Zn2+之间的络合稳定性提高。HA-Cu2+的logk值,有机肥大于化肥;HA-Zn2+的logk值,以化肥的作用更明显。土壤HA与Cu2+或Zn2+络合,倾向于形成混合或多核络合物。施有机肥可提高HA-Cu2+或HA-Zn2+的结合强度和增加结合数量,而施化肥处理则相反。培养试验结果表明,有机肥处理的HA,玉米吸收Cu2+、Zn2+量下降,单施化肥处理下降较小;其中Cu2+吸收量受影响程度较大,而Zn2+吸收量没有那么明显。 相似文献
2.
Effect of high-oxygen and high-carbon-dioxide atmospheres on strawberry flavor and other quality traits 总被引：2，自引：0，他引：2
The effect of high-oxygen atmospheres on strawberry flavor was studied. Strawberry fruits (Fragariax ananassa Duch. cv. Camarosa) were stored at 8 degrees C in four different atmospheres: air, 5% O(2)/20% CO(2), 80% O(2)/20% CO(2), and 90% O(2)/10% CO(2). Changes in several quality parameters were evaluated. Atmospheres combining high O(2) and high CO(2) were the most effective in preventing fungal growth and enhancing strawberry firmness. Other quality parameters such as color, titrable acidity, sugars and organic acids distribution, off-flavor development, and aroma were only mildly affected by superatmospheric O(2) levels. After one week of storage, unexpected high contents of off-flavor related compounds were found in the 80% O(2)/20% CO(2) and 90% O(2)/10% CO(2) atmospheres. Evidence of an altered ester biosynthesis was also found in fruits stored under these high-O(2) atmospheres. Data obtained suggest that stress induced by high CO(2) and stress induced by high O(2) have an additive effect on strawberry flavor alteration. 相似文献
3.
Pinna MV Braschi I Blasioli S Gessa CE Pusino A 《Journal of agricultural and food chemistry》2008,56(13):5273-5277
A study was undertaken to investigate the stability of cyhalofop-butyl (2 R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]butylpropanoate (CyB), an aryloxyphenoxy-propionic herbicide, at different pH values. The hydrolysis of CyB was faster in nonsterile than in sterile water. In sterile medium, CyB degraded only to (2 R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propanoic acid (CyA), whereas in nonsterile water, also the metabolites (2 R)-2-[4-(4-carbamoyl-2-fluorophenoxy)phenoxy]propanoic acid (CyAA) and (2 R)-2-[4-(4-carboxyl-2-fluorophenoxy)phenoxy]propanoic acid (CyD) were detected. The adsorption of CyB onto clays, iron oxide, and dissolved organic matter (DOM), using a batch equilibrium method, was also studied. A lipophilic bond is responsible for CyB adsorption on DOM. CyB was adsorbed on Fe(III)- and Ca-clays through hydrogen bonding between the carbonyl oxygen and water surrounding the exchangeable cations. In the interlayer of K-clay, CyB was hydrolyzed to CyA, which remained adsorbed therein as a monomer. The acid CyA was adsorbed only by the Fe-oxide through complexation. The CyA-Fe-oxide complex was stable and did not undergo degradation. 相似文献
4.
pH对砖红壤和黄棕壤Cu~(2+)吸附与解吸的影响 总被引：3，自引：0，他引：3
对砖红壤和黄棕壤在不同浓度、不同pH下吸附和解吸Cu2+进行了测定。结果表明, 2种土壤Cu2+吸附量均随平衡液中Cu2+浓度增加而增大,两者关系较好地符合Langmuir吸附方程。Cu2+吸附量随pH升高而增加,Cu2+分配系数的对数与pH呈极显著的线性正相关,吸附一个Cu2+所释放H+的平均数砖红壤(1. 19)大于黄棕壤(1. 01)。可解吸Cu2+的数量随pH升高和吸附Cu2+的数量增加而增加,在pH4~6下,黄棕壤吸附Cu2+及可解吸Cu2+的比例(平均为10. 5% )大于砖红壤(平均为3. 1% )。由此认为, 2种土壤吸附Cu2+虽以专性吸附为主,但砖红壤的表面吸附点位较少,专性吸附点位的比例较高,对Cu2+的亲和性或专性吸附性大于黄棕壤。 相似文献
5.
Macías FA Marín D Oliveros-Bastidas A Chinchilla D Simonet AM Molinillo JM 《Journal of agricultural and food chemistry》2006,54(4):991-1000
Compounds with a (2H)-1,4-benzoxazin-3(4H)-one skeleton have attracted the attention of phytochemistry researchers since 2,4-dihydroxy-(2H)-1,4-benzoxazin-3(4H)-one (DIBOA) and 2,4-dihydroxy-7-methoxy-(2H)-1,4-benzoxazin-3(4H)-one (DIMBOA) were isolated from plants belonging to the Poaceae family. These compounds exhibit interesting biological properties, such as phytotoxic, antimicrobial, antifeedant, antifungal, and insecticidal properties. These chemicals, in addition to a wide variety of related compounds involved in their metabolism, detoxification mechanisms, and degradation on crop soils and other systems, have high interest and in some cases potential agronomic utility. This paper presents a complete review of the methods employed for their synthetic obtention in addition to some of the authors' own contributions to their chemistry. The degradation and phytotoxicity experiments carried out in ongoing research into the potential agronomic utility of these compounds required large amounts of them, which were obtained from natural sources. This paper presents a modified methodology to access DIMBOA from Zea mays cv. Apache and to obtain 2-O-beta-D-glucopyranosyl-2,4-dihydroxy-(2H)-1,4-benzoxazin-3(4H)-one (DIBOA-Glc) and DIBOA from Secale cereale L. New synthetic methodologies were employed for the obtention of the lactams 2-hydroxy-(2H)-1,4-benzoxazin-3(4H)-one and 2-hydroxy-7-methoxy-(2H)-1,4-benzoxazin-3(4H)-one and the malonamic acids N-(2-hydroxyphenyl)malonamic acid and N-(2-hydroxy-7-methoxyphenyl)malonamic acid. The aminophenoxazines 2-amino-7-methoxyphenoxazin-3-one and 2-acetamido-7-methoxyphenoxazin-3-one have been synthesized in the authors' laboratory by novel procedures. All of the methodologies employed allowed the desired compounds to be obtained in high yield and in an easy-to-scale manner. 相似文献
6.
不同浓度钙营养液对烟草矿质营养吸收与积累的影响 总被引：9，自引：1，他引：9
本文采用温室水培的方法,研究了不同的钙素供应水平对烟草各种矿质养分的吸收与积累的影响。结果表明,在其它养分形态与浓度一致条件下,随着钙浓度从75mgL-1提高到900mgL-1,烟草生长量呈抛物线型变化。钙浓度为150mgL-1时烟株干物质量最大。超过150mgL-1,随钙的增加而下降,当钙素达900mgL-1(K/Ca为1/6)时,烟株生长严重受抑。随着供钙水平由低到高,烟株氮、磷、钾、锌、锰含量均呈抛物线型变化,含钙量呈直线上升关系,而镁和铜含量则随钙浓度提高而显著下降。烟株各养分积累量均随营养液钙浓度提高呈抛物线型变化,但不同养分出现最大积累量时的营养液钙浓度却不相同。不同供钙水平上烟叶中各元素含量的变化特征与全株的结果基本一致。在低钙浓度范围(75~300mgL-1),钙对钾有协合关系,增钙促进提钾,大于300mgL-1后有拮抗作用,提钙导致降钾。钙与镁、锌、铜、锰间也存在明显的交互作用。烟叶中各元素含量与积累量的变化趋势与整株基本一致。 相似文献
7.
Galletti S Bernardi R Leoni O Rollin P Palmieri S 《Journal of agricultural and food chemistry》2001,49(1):471-476
(5R)-5-Vinyl-1,3-oxazolidine-2-thione, (2S)-1-cyano-2-hydroxy-3-butene, and two diastereoisomeric erythro-(2S)- and threo-(2S)-1-cyano-2-hydroxy-3,4-epithiobutanes were prepared in pure form starting from (2S)-2-hydroxybut-3-enyl glucosinolate (epiprogoitrin). This glucosinolate was isolated in almost pure form using ripe seeds of Crambe abyssinica and then hydrolyzed under different conditions. The hydrolysis was carried out using either myrosinase immobilized on nylon, to produce (5R)-5-vinyl-1,3-oxazolidine-2-thione, or the endogenous myrosinase contained in defatted crambe meals, to produce the other epiprogoitrin-derived products. After purification and physicochemical characterization, all four myrosinase degradation products were tested for their biological activity. A bioassay on Lactuca sativa was chosen as a simple test to determine their apparent action on living tissues. (5R)-5-Vinyl-1,3-oxazolidine-2-thione negatively affected mainly root growth, whereas (2S)-1-cyano-2-hydroxy-3-butene affected the early phase of germination, and both (2S)-1-cyano-2-hydroxy-3,4-epithiobutane diastereoisomers appeared to negatively affect both germination and root growth at doses 5-10 times lower than those of (2S)-1-cyano-2-hydroxy-3-butene or (5R)-5-vinyl-1,3-oxazolidine-2-thione. 相似文献
8.
采用L9(34)正交设计,探讨氮、磷、钾肥配施对幼龄腰果植株生长和结果的影响.试验结果表明,对于2龄腰果植株,最佳施肥组合为N1P1K1,年施氮(N)150 g/株、磷(P2O5) 50 g/株和钾(K2O) 50 g/株处理,可以促进植株生长;对于3龄腰果植株,年施氮250～450 g/株处理,植株的冠幅、株高增量随着氮施用量增加而增大,磷、钾影响不显著;现蕾期和初花期,P2O5 90 g/株和K2O 200 g/株处理的植株现蕾、开花枝梢比例最高,施氮影响不显著;盛花坐果期,施N 350 g/株、P2O5 150 g/株和K2O 150 g/株处理的植株现蕾开花枝梢比例最高.氮和钾对3龄植株结果影响较大,年施N 250～450 g/株处理,平均株产量随着氮施用量的增加而增加,最佳施肥组合为N3P1K2,施N 450 g/株、P2O5 90 g/株和K2O 150 g/株处理,可以促进3龄腰果植株结果.3龄植株腰果产量与初花期叶片钾(K)含量(0.43%～0.47%)和盛花坐果期叶片N含量(1.89%～2.20%)呈直线显著正相关. 相似文献
9.
The biosynthesis of the monoterpene (S)-linalool and the sesquiterpene trans-(S)-nerolidol in fruits of Fragaria x ananassa Duch. cv. Eros and Florence and of the monoterpene (-)-alpha-pinene in Fragaria vesca was investigated by in vivo feeding experiments with [5,5-2H2]mevalonic acid lactone (d2-MVL) and [5,5-2H2]-1-deoxy-d-xylulose (d2-DOX). The feeding experiments indicate that (S)-linalool and trans-(S)-nerolidol in Fragaria x ananassa Duch. and (-)-alpha-pinene in F. vesca are exclusively synthesized via the cytosolic mevalonic acid pathway without any contribution from the plastidial 1-deoxy-D-xylulose/2-C-methyl-D-erythritol 4-phosphate (DOXP/MEP) route. Inhibition experiments revealed that even the presence of mevastatin, an export of plastid-derived isopentyl diphosphate/dimethylallyl diphosphate, cannot be induced. However, the enantioselective analysis shows that in Fragaria x ananassa Duch. cv. Eros and Florence both linalool enantiomers are present and that only (S)-linalool is labeled after administration of d2-MVL. Therefore, the origin of (R)-linalool in these fruits remains unknown. Contrarily, in Fragaria x ananassa Duch. foliage (R)-linalool is the dominant enantiomer. Feeding experiments revealed an incorporation of d2-MVL and d2-DOX at equal rates exclusively into (S)-linalool. Only in F. vesca foliage, where (R)-linalool is present at high enantiomeric purity (ee > 90%), is a de novo biosynthesis of the (R)-enantiomer via the DOXP/MEP pathway detectable. These results demonstrate a complex intraplant variation of (R)- and (S)-linalool biosynthesis via the cytosolic and plastidial route. 相似文献
10.
环境温度和CO2浓度升高对湖北早稻氮素含量及产量的影响 总被引：1，自引：0，他引：1
采用改进后的开顶式气室（OTC）,大田原位模拟温度升高2℃和CO2浓度增加60μL·L-1的未来气候情景,观测其对湖北地区早稻植株全氮、土壤氮素及产量的影响。试验设置对照(CK)、增温（增2℃,IT）、增CO2 (增60μL·L-1,IC)以及增温+CO2（增2℃+增60μL·L-1,IT+IC）4个处理,3次重复,随机区组排列,对早稻各生育期植株全氮含量、土壤NH4+-N和NO3--N含量以及产量构成进行监测。结果表明：（1）温度和CO2浓度升高以及二者同增会增加早稻生育早期（特别是分蘖期）植株体内全氮含量,分蘖期以后各处理间差异不显著,籽粒全氮含量差异亦不显著;土壤NH4+-N含量与植株全氮变化规律类似,在早稻生育早期,温度和CO2浓度升高以及二者同增会增加土壤NH4+-N含量,分蘖期以后各处理间差异不显著;（2）温度升高使拔节期、成熟期土壤NO3--N含量降低,抽穗期土壤NO3--N含量增加;CO2浓度增加会提高拔节期、成熟期,降低抽穗期土壤NO3-N含量;（3）CO2浓度升高,早稻增产13.4%,与CK差异极显著（P<0.01）,而单独增温或增温+增CO2处理早稻产量与CK差异不显著。 相似文献
11.
Mandal S Joardar S Das S Bhattacharyya A 《Journal of agricultural and food chemistry》2011,59(21):11727-11734
The photodegradation of the carboxamide acaricide hexythiazox in three different solvent systems (aqueous methanolic, aqueous isopropanolic, and aqueous acetonitrilic solutions) in the presence of H(2)O(2), KNO(3), and TiO(2) under ultraviolet (UV) light (λ(max) ≥ 250 nm) and sunlight (λ(max) ≥290 nm) has been assessed in this work. The kinetics of photodecomposition of hexythiazox and the identification of photoproducts were carried out using liquid chromatography-mass spectrometry. The rate of photodecomposition of hexythiazox in different solvents followed first-order kinetics in both UV radiation and natural sunlight, and the degradation rates were faster under UV light than under sunlight. Hexythiazox was found to be more efficiently photodegraded in the presence of TiO(2) than in the presence of H(2)O(2) and KNO(3). Two major photoproducts were separated in pure form using column chromatography and identified according to IR, (1)H NMR, and mass spectral information as cyclohexylamine and 5-(4-chlorophenyl)-4-methylthiazolidin-2-one. Another nine photoproducts were identified according to LC-MS/MS spectral information. The plausible photodegradation pathways of hexythiazox were proposed according to the structures of the photoproducts. 相似文献
12.
Hampel D Swatski A Mosandl A Wüst M 《Journal of agricultural and food chemistry》2007,55(22):9296-9304
The biosynthesis of the monoterpenes (-)-alpha-pinene, linalool, and the norisoprenoids alpha- and beta-ionone in raspberry fruits (rubus idaeus L.) was investigated by in vivo feeding experiments with [5,5-(2)H2]-mevalonic acid lactone and [5,5-(2)H2]-1-deoxy-D-xylulose. The volatile compounds were extracted by stirbar sorptive extraction and analyzed using thermal desorption-multidimensional gas chromatography-mass spectrometry (TD-enantio-MDGC-MS). The feeding experiments demonstrate that (-)-alpha-pinene and (S)-linalool are exclusively synthesized via the cytosolic mevalonic acid pathway. In contrast, (2)H-labeled (R)-(E)-alpha-ionone and (2)H-labeled (E)-beta-ionone are detectable after application of d2-1-deoxy-D-xylulose and d2-mevalonic acid lactone, respectively. However, (R)-linalool reveals no incorporation of either one of the fed precursors, even though this enantiomer is detectable in the fruit tissue. 相似文献
13.
Kubec R Krejcová P Simek P Václavík L Hajslová J Schraml J 《Journal of agricultural and food chemistry》2011,59(10):5763-5770
Two novel, structurally unusual cysteine derivatives were isolated from the bulbs of Allium stipitatum (Allium subg. Melanocrommyum) and shown to be S-(2-pyridyl)cysteine N-oxide and S-(2-pyridyl)glutathione N-oxide. The former compound is the first example of a naturally occurring alliinase substrate that contains an N-oxide functionality instead of the S-oxide group. In addition, S-methylcysteine S-oxide (methiin) and S-(methylthiomethyl)cysteine 4-oxide (marasmin) were found in the bulbs. Presented data suggest that the previously reported identification of S-(2-pyridyl)cysteine S-oxide was most likely erroneous. The alliinase-mediated formation of pyridyl-containing compounds following disruption of A. stipitatum bulbs was studied by a combination of HPLC-MS, HPLC-PDA, DART-MS, and NMR techniques. It was found that no pyridyl-containing thiosulfinates are present in homogenized bulbs in detectable quantities. Instead, various pyridine N-oxide derivatives are formed, including N-hydroxypyridine-2(1H)-thione (pyrithione), 2-(methyldithio)pyridine N-oxide, 2-[(methylthio)methyldithio]pyridine N-oxide, di(2-pyridyl) disulfide N-oxide, and di(2-pyridyl) disulfide N,N'-dioxide. This represents the first report of pyrithione formation as a natural product. 相似文献
14.
不同NPK配置对强筋小麦群体生物量与产量的效应研究 总被引：7，自引：0，他引：7
在关中川道灌区以强筋小麦陕253为材料,研究了不同NPK配置对其不同生育期生物产量、群体数量和产量的效应,结果表明提高施肥量可显著增加生物产量、群体数量及产量,处理平均值分别比常规处理增加11.9%~43.6%、4.1%~17.4%和8.3%,其最佳N、P、K配置依次为N135kg hm-2,P2O5和K2O各120kg hm-2、N135kg hm-2,P2O5225kghm-2,K2O120kg hm-2和N225kg hm-2,P2O5和K2O各120kg hm-2。在目前常规投肥水平下适度增加钾肥有利于生物产量的显著提高,增加磷肥和钾肥有利于群体数量的提高,增施氮钾肥有显著的增产效果。产量的最佳NPK配比较常规处理增产19.1%,其增加养分的平均产量4.44 kg kg-1,比各处理平均养分产量高1.6倍。 相似文献
15.
The effects of controlled-atmosphere (CA) storage on the firmness, respiration rate, quality, weight loss, total phenolics and flavonoids contents, and total antioxidant activities of the Pilgrim and Stevens cultivars of cranberries (Vaccinium macrocarpon Aiton) have been studied during storage in atmospheres of 2, 21, and 70% O(2) with 0, 15, and 30% CO(2) (balance N(2)); and 100% N(2) at 3 degrees C. Elevated CO(2) concentrations decreased bruising, physiological breakdown, and decay of berries, thereby reducing fruit losses. Respiration and weight loss of fruits decreased, but fruit softening increased, at higher CO(2) concentrations. Accumulations of acetaldehyde, ethanol, and ethyl acetate varied by cultivar and storage atmosphere but were generally highest in the 2 and 70% O(2) and 100% N(2) atmospheres and increased in response to elevated CO(2) concentrations. Overall, the 30% CO(2) plus 21% O(2) atmosphere appeared optimal for the storage of cranberries. Sensory analysis is required, however, to confirm that accumulations of fermentation products at this atmosphere are acceptable for consumers. Stevens fruits had a higher phenolics content and total antioxidant activity than Pilgrim fruits. The storage atmosphere did not affect the content of total phenolics or flavonoids. However, the total antioxidant activity of the fruits increased overall by about 45% in fruits stored in air. This increase was prevented by storage in 30% CO(2) plus 21% O(2). 相似文献
16.
17.
Evening primrose meal (EPM: 1% and 2%, w/w) reduced (p 相似文献
18.
为探究暗管排水条件下盐渍化农田最适宜的水氮制度，在河套灌区暗管布设区开展2年田间试验，设置低水(120 mm, I1)、中水(210 mm, I2)和高水(330 mm, I3)3个灌溉水平及低氮(0 kg/hm2,N1)、中氮(105 kg/hm2,N2)和高氮(210 kg/hm2,N3)3个追氮水平，分析不同水氮组合对土壤脱盐率及向日葵水氮利用效率和产量品质的影响。结果表明：暗管排水条件下，高水中氮(I3N2)的脱盐效果最佳，较其他水氮处理的脱盐率平均提高5.82%。高水(高氮)条件下，产量随着施氮量(灌水量)的增加而升高，其中高水高氮(I3N3)的产量最高，平均为5 129.72 kg/hm2。相同灌水量下，高氮(N3)水平的灌溉水利用效率最高，追氮量越大，肥料偏生产力越低。低水(I1)和中水(I2)条件下高氮(N3)水平最有利于籽仁蛋白质和必需氨基酸的合成。高水(I3)条件下，中氮(N2)水平有利于籽仁蛋白质和必需氨基酸的合成，低氮(N1)水平最有利于籽仁粗脂肪的合成。各灌水水平中，中水(... 相似文献
19.
Liu H Cheng S Liu J Du Y Bai Z Du Y 《Journal of agricultural and food chemistry》2008,56(14):5634-5638
Two oligosaccharide derivatives, beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-4)-alpha-D-ManpOMe (1) and beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-6)-beta-D-Glcp-(1-4)-alpha-D-ManpOMe (2), have been synthesized efficiently using a convergent glycosylation strategy of 2 + 3 and 2 + 5. 1,6-Anhydro-beta-D-glucopyranose, which was prepared from cotton pyrolysis, was applied as a key synthon in the synthesis, significantly simplifying the preparation. The bioassay suggested that these two oligosaccharides can both stimulate the growth of maize cultured in liquid medium at a concentration of 3 ppm. 相似文献
20.
Cirillo T Ritieni A Visone M Cocchieri RA 《Journal of agricultural and food chemistry》2003,51(27):8128-8131
Two lots of human foodstuffs from conventional and organic brand foods were purchased from supermarkets and analyzed for three Fusarium toxins, deoxynivalenol, by GC-ECD, and fumonisins B(1) and B(2) (FB(1)-FB(2)), by LC-MS. The occurrence of deoxynivalenol contamination was higher than 80% in both organic and conventional foods; fumonisin B(1) was found in 20% of organic foods and in 31% of conventional ones and fumonisin B(2) in more than the 32% of the food samples from both the agricultural practices. The highest median concentration of deoxynivalenol occurred in conventional rice-based foodstuffs (207 microg/kg): that of fumonisin B(1) in conventional maize-based foods (345 microg/kg) and that of fumonisin B(2) in organic wheat-based foods (210 microg/kg). 相似文献