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1.
《Soil Science and Plant Nutrition》2013,59(5):601-603
This is a mini-review of the research work conducted by the authors with the objective of studying ion transport in variable charge subsoils collected from different areas around the world. An attempt is made in these studies to relate the unique behavior manifested during ionic transport in these subsoils with their mineralogical, physical and chemical properties, which are markedly different from those in soils from temperate regions. The variable charge subsoils have a relatively high salt sorption capacity and anion exchange capacity (AEC) that retards anions downward movement. The AEC correlates closely with the anion retardation coefficients. Ca2+ applied with gypsum in topsoil may be transported to the subsoil and may improve the subsoil chemical properties. These results may help in developing appropriate management strategies under a range of mineralogical, physical, and chemical conditions. 相似文献
2.
《Communications in Soil Science and Plant Analysis》2012,43(7-8):1051-1070
Abstract Colloidal mineralogy is one of the main characteristics of the steady state reached in developed soils. Surface charge and other chemical and physical properties of the soil depend on colloidal mineralogy. It is, therefore, very important to further investigate the clay mineralogy of acidic variable charge subsoils in order to understand better their unusual chemical behavior. The objective of this investigation was to characterize the inorganic colloid mineralogy, chemical (subsoil solution pH and electrical conductivity), and charge properties (PZNC and PZSE) in some variable charge subsoils. Subsoil materials were collected from the southeastern United States and other tropical and subtropical areas around the world. The clay fraction mineralogy in the majority of the subsoils was dominated by the quartet kaolinite, gibbsite, goethite, and hematite. They manifested, however, a significant diversity in their charge and other chemical characteristics because the proportions and contents of mineralogical constituents, particle size distributions, and specific surface areas were very different. The pHKCl values ranged from 3.69 to 5.91. Under such conditions, pure kaolinite and aluminum/iron (Al/Fe) oxides have opposite net surface charges, and acidic subsoils are mixed charge colloidal systems. They have extremely low EC values, varying from 9.9 to 132 μS cm‐1, with corresponding ionic strengths between 0.14 and 1.86 mmol L‐1. They develop towards a “no or little charge state”; and the native pH is near the PZNC or PZSE. The overall charge characteristics and adsorption properties in these heterogenous colloidal systems are clearly a direct function of the relative contents, interactions, and surface reactivity of mineralogical soil constituents in the subsoils. 相似文献
3.
以恒电荷土壤(黄褐土和黄棕壤)和可变电荷土壤(红壤和砖红壤)为供试材料,研究了乙酸、草酸、酒石酸和柠檬酸对土壤吸附重金属铜离子(Cu2 )的影响。结果表明,在相同酒石酸浓度下,土壤对酒石酸的吸附量依次为黄棕壤(2 1 8mmolkg-1) >红壤(15 4mmolkg-1) >砖红壤(9 5mmolkg-1) ,土壤吸附有机酸后负电荷量增加,相同条件下增幅为砖红壤>红壤>黄棕壤;无有机酸配体时,供试土壤对Cu2 的吸附量为黄褐土>黄棕壤>砖红壤>红壤;加入有机酸时,随有机酸浓度增高,土壤对Cu2 的吸附一般表现为“峰”形曲线,峰所对应的有机酸浓度因有机酸类型而异,且随土壤可变电荷性质增强而增高;土壤吸附有机酸后对Cu2 的次级吸附不同于有机酸与铜共存时的竞争吸附,且因土壤性质表现迥异。这些结果意味着在存在有机酸配体的根际环境中,恒电荷土壤与可变电荷土壤对Cu2 的吸附明显不同,并将影响重金属离子在根际的转化与有效性 相似文献
4.
研究了3种典型可变电荷土壤和4种典型恒电荷土壤在不同pH和不同浓度下单纯及共存体系中Cu2 和Zn2 的吸附及其影响因素。结果表明,两类土壤对Cu2 或Zn2 的吸附量均随平衡浓度增加而增大,符合Langmuir吸附等温式;当Cu2 、Zn2 浓度一定时,pH升高使Cu2 、Zn2 吸附量增大,但当pH >5时,Cu2 、Zn2 吸附量随pH变化甚微,出现一个接近最大吸附量的“平台”。当添加Cu2 、Zn2 浓度相同,但二种离子的总浓度不同时,平衡液的Cu2 /Zn2 浓度比均小于1,说明两类土壤对Cu2 的吸附选择性大于Zn2 ,且这种趋势不因pH和离子浓度而改变。当Cu2 、Zn2 共存时,使可变电荷土壤的Zn2 吸附量减小约70 % ,是恒电荷土壤降低量的约1.5倍;可变电荷土壤吸附一个Cu2 或Zn2 时所释放H 的平均数,明显大于恒电荷土壤者,说明可变电荷土壤对Cu2 及Zn2 的吸附中专性吸附的比例较恒电荷土壤大 相似文献
5.
《Communications in Soil Science and Plant Analysis》2012,43(11):1119-1132
Abstract The effects of mixing lime and large quantities of phosphorus and potassium fertilizers with the subsoil were studied on 16 Maryland subsoils. These subsoils were covered with 10. cm of a fertile surface soil so the subsoils’ effect would be the major variable. Soybeans were grown on these soils in the greenhouse. These subsoils received 65.2 and 83.0 ug/g of phosphorus and potassium respectively. Two treated subsoils were also studied in the field. Simulated subsoiling in the field was accomplished by digging to a depth of 50.8 cm. Lime, 148 or 440 Kg P/ha, and 186 or 558 Kg K/ha were mixed with each 15 cm depth of subsoil. Soybeans and/or barley were planted on the field plots. In general, the subsoils studied in the greenhouse indicated that the combined amendments of lime, phosphorus and potassium to the subsoils increased root production in the subsoil, nitrogen content in the soybean shoots, and yield. First year field results on the Othello (Typic Ochraquult) soil indicated that soybean yields on treated subsoil plots were not significantly different from soil receiving the same surface applications of fertilizer. However the second year after treatment, the yields of double cropped soybeans and barley were increased by 706 Kg/ha (10.5 bu/acre) and 710 Kg/ha (14.4 bu/acre) respectively when compared to similar quantities of phosphorus and potassium applied to the surface soil of nonsubsoiled plots. On the Monaouth (Typic Hapludult) soil, the first year yields of subsoil plots treated with lime, phosphorus, and potassium also failed to improve yields compared to surface application of the fertilizer. Lime, 440 Kg P/ha, and 558 Kg K/ha applied to the subsoil did significantly improve yields of full season soybeans over the untreated soil by 720 Kg/ha (10.7 bu/acre). 相似文献
6.
不同母质发育的红壤电荷特性研究 总被引：1，自引：0，他引：1
研究了3种不同母质发育的红壤中电荷的差异,比较了不同母质对电荷的影响。结果表明:3种母质发育的红壤中,紫色土发育的红壤中全部负电荷含量明显高于花岗岩发育的红壤和第四纪红色黏土发育的红壤;第四纪红色黏土发育的红壤中正电荷的含量明显高于花岗岩发育的红壤和紫色土发育的红壤;第四纪红色黏土发育的红壤、花岗岩发育的红壤和紫色土发育的红壤中正电荷与pH呈显著性负相关;第四纪红色黏土发育的红壤正电荷与有机质呈显著负相关,花岗岩发育的红壤和紫色土发育的红壤中正电荷与有机质含量呈显著正相关;第四纪红色黏土发育的红壤和紫色土发育的红壤正电荷与黏粒含量呈一元二次线性关系,花岗岩发育的红壤正电荷与黏粒含量呈极显著负相关;紫色土发育的红壤吸附的NH4+-N含量最高,第四纪红色黏土发育的红壤吸附的NO3--N含量最高。通过对3种母质发育的土壤电荷特性的研究,可为不同母质的红壤进行合理施肥与管理提供科学依据。 相似文献
7.
WANG Jing-Hua 《土壤圈》1995,5(3):193-202
The sensitivity of a large number of variable charge soils to acid rain was evaluated through examining pH-H2SO4 input curves. Two derivative parameters, the consumption of hydrogen ions by the soil and the acidtolerant limit as defined as the quantity of sulfuric acid required to bring the soil to pH 3.5 in a 0.001mol L-1 Ca(NO3)2 solution, were used. The sensitivity of variable charge soils was higher than that of constant charge soils, due to the predominance of kaolinite in clay mineralogical composition. Among these soils the sensitivity was generally of the order lateritic red soil > red soil > latosol. For a given type of soil within the same region the sensitivity was affected by parent material, due to differences in clay minerals and texture. The sensitivity of surface soil may be lower or higher than that of subsoil, depending on whether organic matter or texture plays the dominant role in determining the buffering capacity. Paddy soils consumed more acid within lower range of acid input when compared with upland soils, due to the presence of more exchangeable bases, but consumed less acid within higher acid input range, caused by the decrease in clay content. 相似文献
8.
9.
THE EFFECT OF SOIL COMPOSITION AND ENVIRONMENTAL FACTORS ON THE SHRINKAGE OF SOME CLAYEY BRITISH SOILS 总被引：4，自引：0，他引：4
The shrinkage potential of natural clods from a variety of clayey soils was measured and related to their physical, chemical and mineralogical properties. It is shown that the most important factors affecting shrinkage are initial bulk density, clay content, organic carbon content and cation exchange capacity of the peroxidised clay, and mica-smectite content on a whole soil basis. Multiple regression equations involving the initial bulk density, clay content, organic carbon and cation exchange capacity accounted for 87 and 82 per cent of the variation in total shrinkage of topsoils and subsoils respectively. Because of restrictions on shrinkage imposed by factors such as climate, crops, ground-water and moisture release characteristics of soils, soils with a high shrinkage potential may not behave very differently to soils with a much lower potential. On these grounds it is concluded that the shrinkage criteria used in US Taxonomy are not applicable in Britain. 相似文献
10.
《Communications in Soil Science and Plant Analysis》2012,43(12):1431-1451
Abstract Many soil properties are determined by the surface charge on the soil particles. A range of methods for determining the surface charge properties is available from the literature. However, the interpretation of the results obtained and the theoretical basis of some of the methods is confusing with different terms having different meanings for different authors. Thus, the study of surface charge properties and the theoretical basis is particularly difficult for a newcomer to the field. This paper presents a review of the major concepts as used in the current literature and highlights the problems encountered when applying these concepts to the determination of the surface charge properties. 相似文献
11.
12.
Termite mounds in relation to the surrounding soils in the forest and derived savanna zones of southeastern Nigeria 总被引：1，自引：0，他引：1
Some physical and chemical properties of the two common termite mounds in southeastern Nigeria, Macrotermes (MM) and Cubitermes (CM) mounds, were compared and their relationships with the surrounding top and subsoils investigated. Percentage sand, silt, pH, calcium, magnesium, potassium, sodium, iron, and organic carbon were higher and clay and penetrometer resistance lower in the CM than the MM. Sand, silt, organic carbon, and calcium decreased and clay increased from the forest to the derived savanna in the CM, but no clear trend was shown with the other properties in both the CM and the MM. Most of the nutrients were higher in the CM than in the adjacent top or subsoil but the reverse was the case with the MM. More nutrients are associated with the inorganic fractions of the soil than with the organic carbon in the mounds and the soils surrounding them. The Ca:Mg ratio in the mounds and the top and subsoils adjacent to them was low for most crops but the K:Mg ratio was mostly adequate. Because of these differences in properties and sizes of the mounds, different management strategies are recommended for them and the soils around them. 相似文献
13.
我国长江以南地区的土壤富含铁铝氧化物,其土壤胶体表面电荷具有可变性,显著不同于温带地区的恒电荷土壤,因而称之为可变电荷土壤。开展可变电荷土壤的表面特性研究对农业可持续发展、土壤资源保护等均具有重要的现实意义。电位滴定法是开展可变电荷土壤表面特性研究最直接有效的方法。本文首先总结了电位滴定法的实验条件设置对可变电荷土壤表观电荷零点的影响,在此基础上,归纳了应用电位滴定法结合表面络合模型开展可变电荷土壤酸碱特性的研究进展,分类讨论了黏土矿物组成、氧化物、有机质等相关影响因子对可变电荷土壤酸碱缓冲能力的影响,并展望可变电荷土壤表面酸碱缓冲能力的未来研究。本文将有助于初学者理解可变电荷土壤,呼吁更多学者关注可变电荷土壤的酸碱缓冲特性研究及其在土壤资源可持续利用中所起的重要作用。 相似文献
14.
Abstract. In most soils of temperate regions nitrate is not held on soil surfaces and moves freely in solution. But when soils carry positive charges, nitrate is held as an exchangeable anion. As a result, leaching of nitrate is delayed relative to the movement of water. The delay can be predicted provided the anion exchange capacity (AEC) can be measured and the concentration of counter-anions is known. For soils with variable charge, the AEC varies with both pH and ionic strength, and the effective AEC should be determined under conditions similar to those in soil solution. A simple leaching method is described which satisfies this requirement. Delays in the leaching of nitrate measured in columns of repacked soil were strongly related to the AEC. 相似文献
15.
A. Romero Díaz P. Marín Sanleandro A. Snchez Soriano F. Belmonte Serrato H. Faulkner 《CATENA》2007,69(3):282-293
This study aims to identify some of the factors contributing to the piping process in abandoned terraces in seven sites located in the Murcia Region (southeast Spain). The local landscape has the appearance of badland geomorphology, possessing deep valleys which until the 1970s were terraced and cultivated. The terraces have now been abandoned to the piping process. The research focuses on the relationship between the size and position of pipes and the physical and geochemistry properties of the local highly dispersive marl lithology; and the extent to which the reworking of the materials for terrace cultivation has exacerbated piping erosion.Morphologically, the terracing in the stream beds has resulted in a series of gentle benches separated by steeper risers with variable ‘drop’, (riser height). A series of flat infiltration surfaces result, and because the resculpting produces a reduced bulk density infill with enhanced throughflow, infiltrating water is forced along steep hydraulic gradients to a low outfall at the base of the riser.Paralleling studies of land levelling and terrace abandonment in similar materials elsewhere, piping in the study area is shown to be closely related to the physical and chemical characteristics of the materials its sodicity and dispersive character. Considerable differences in structure, texture, mineralogical composition and material's surface crust and subsoil geochemical properties emerged from ‘site signature’ plots, and these results suggest that agricultural processes affect the dispersive character of the crust materials, presumably because agricultural activity increases the buffering effect of organic acids on the dispersed clay. This is supported by the observation that on the one site that was levelled but not used for agriculture, a stable organically-distinct crust like the abandoned agricultural sites has not formed. The changes to the material's aggregate stability and bulk density properties when terracing occurs is examined, but insufficient evidence is available from the data collected to unpick the causes of aggregate stability changes in the study plots. The way in which differences between crust and subsoil enhance infiltration is discussed, and the role of the terrace ‘drop’ in influencing hydraulic gradients and pipe development is illustrated. A possible index to describe the relationship between evacuated material volumes and the controlling parameters discussed above is tested.It is concluded that terracing which is intended as a conservation practice has, in dispersive materials, actually enhanced piping, leading to the abandonment of farming. 相似文献
16.
The saturated hydraulic conductivity, Ksat, was measured on soil samples collected from the plough layer and the subsoil. A range of naturally occurring soil bulk densities was obtained by sampling in different years, with different crops and within and without wheel-tracks, etc. It was found that, for the plough layer, quite good linear relationships exist between the logarithm of Ksat and the bulk density. However, for the subsoils, the value of Ksat usually lies above the regression line for found for the corresponding plough layer. This “excess” hydraulic conductivity of subsoils is attributed to the presence of biopores, especially root channels. The lower hydraulic conductivity of the plough layer, relative to the subsoil, is attributed to the destruction of these biopores by tillage. A simple model for the separate contributions of soil texture and root channels to the overall value of Ksat is presented. It is concluded that subsoil tillage could cause significant reductions in Ksat with potentially serious environmental consequences unless it is repeated periodically. 相似文献
17.
The papers in this special issue present results of the European Union (EU) concerted action “Experiences with the impact of subsoil compaction on soil crop growth and environment and ways to prevent subsoil compaction”. The results and conclusions of earlier research on subsoil compaction are memorized and it is emphasized that the conclusions are still sound: high axle load traffic on soils of high moisture content causes deep and persistent subsoil compaction. The concerted action on subsoil compaction in the EU and an almost identical concerted action on subsoil compaction in central and eastern Europe are briefly introduced. This special issue presents a selection of papers of the concluding workshop of the concerted action on subsoil compaction in the EU. It includes three papers on modeling the impact of subsoil compaction on crop growth, water availability to plants and environmental aspects; three papers on modeling of subsoil compaction by heavy machinery; four papers on measurement of soil mechanical and physical properties in relation to subsoil compaction and four papers on methods to determine the risk of subsoil compaction and to identify prevention strategies. The trends in agriculture in relation to subsoil compaction are discussed. A positive trend is that policy makers in the EU and worldwide recognize soil as a vital and largely non-renewable resource increasingly under pressure. A negative trend is that wheel loads in agriculture are still increasing causing severe damage to subsoils. The conclusion is that European subsoils are more threatened than ever in history. Manufactures, agricultural engineers and soil scientists should collaborate and research should be initiated to solve this problem and find solutions. Subsoil compaction should be made recognized by all people involved from farmer to policy maker. Therefore an assessment of the existence and seriousness of subsoil compaction throughout Europe should be initiated. 相似文献
18.
Abstract In this paper we describe the susceptibility of Swedish subsoils to compaction and discuss strategies for prevention of traffic-induced subsoil compaction against the background of experiences from wheeling experiments conducted in Sweden during recent years. The susceptibility of Swedish subsoils to compaction must be considered high because subsoils are often wet during field operations and machinery with high wheel loads is used. The risk of subsoil compaction could be reduced by technical solutions, such as the use of dual and tandem wheels instead of single wheels, low tyre inflation pressure or tracks. However, each of these solutions has its limitations. Results from several wheeling experiments on different soils indicate that residual deformations occur even when the applied stress is lower than the precompression stress. Hence, soil compaction could not be avoided completely by limiting the applied stress to the precompression stress. 相似文献
19.
《Communications in Soil Science and Plant Analysis》2012,43(15-16):2441-2457
Abstract The charge properties of three soils developed on granulite and serpentinite were investigated. These soils contain large amounts of organic matter, free iron oxide, and clay, and are therefore a good medium for measuring the interactions between those components. Cation‐ and anion‐exchange capacities (CEC and AEC) were measured in percolation experiments with and without ammonium acetate buffer pretreatment, using various electrolyte concentrations. The measurements were repeated after removal of sesquioxides and/or organic matter. In addition, potentiometric titrations were carried out to determine the ‘point of zero salt effect’ of each sample. Untreated samples showed a mutual blocking of positive charge on sesquioxides and negative charge on organic matter, leading to decreased CEC and negligible AEC values. Because the AEC is fully blocked, the natural soils do not have a ‘point of zero net charge’ (PZNC), and the apparent ‘points of zero salt effect’ (PZSE) obtained in potentiometric batch titrations are artifacts. Positive charge appeared only after the removal of organic matter. Percolation with acetate buffer strongly increased the measured CEC in samples containing organic complexes. After removal of organic matter, a slight buffer effect remained. This is attributed to the release of sesquioxides from organic complexes and clay surfaces by preferent binding to the acetate anion. 相似文献
20.
E. TESSENS 《European Journal of Soil Science》1984,35(4):615-624
Clay movement was studied in a large number of well-drained soils from Peninsular Malaysia, with a kaolinite mineralogy and an udic or perudic moisture regime. Dispersion in subsoils was found to be related to the net charge on the clay, while in topsoils it was virtually independent of charge or weathering status, and all but one topsoil dispersed well. Accumulation of the dispersed clay is thought to be mainly through flocculation, and as such accounts for the absence of clay coatings in many subsoil horizons. A number of criteria are proposed to distinguish between highly weathered Ultisols and Oxisols, in an effort to improve on the currently used inconclusive properties, such as fine clay to total clay ratio. 相似文献