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1.
During autumn 1982, soil samples were collected from 15 winter cereal fields in central and southern England. The soils either contained ash resulting from the burning of straw in the field or were ash free. Ash containing soils had much higher adsorption levels (measured as Kd values for chlortoluron) than ash-free soils. There were smaller differences in organic matter, pH and nutrient content between the 2 soil groups. There was a better correlation between adsorption and organic matter content for ash-free soils than for soils containing ash. The ratio of adsorption level to organic matter content for ash soils was almost twice that for ash-free soils. It was concluded that ash can make a substantial contribution to herbicide adsorption on minimally cultivated soils and that this could affect herbicide performance. In a tillage experiment where ploughing was followed by direct drilling, adsorption levels increased much more rapidly than organic matter.  相似文献   

2.
Andosol is a soil widely distributed throughout Japan and is one of the important soils for the agriculture. The name “Ando soil” was given by THORP and SMITH (19) which means dark soil with an organic matter content ranging up to 30 per cent in the darkest members of the group. In 1964, the Soil Correlation Meeting on Volcanic Ash Soils (8), organized by FAO, adopted “Andosol” for volcanic ash soil of which the active fraction is predominated by amorphous material. Andosol, moreover, has many special properties such as high sorption capacity, high accumulation of organic matter, low bulk density and low stickiness. TAYLOR (18), accordingly, named them “amorphic soils”. The latest soil classification system, 7th Approximation (15) includes andosol under the suborder andepts.  相似文献   

3.
Montane volcanic ash soils contain disproportionate amounts of soil organic carbon and thereby play an often underestimated role in the global carbon cycle.Given the central role of Al and Fe in stabilizing organic matter in volcanic ash soils,we assessed various extraction methods of Al,Fe,and C fractions from montane volcanic ash soils in northern Ecuador,aiming at elucidating the role of Al and Fe in stabilizing soil organic matter(SOM).We found extractions with cold sodium hydroxide,ammonium oxalate/oxalic acid,sodium pyrophosphate,and sodium tetraborate to be particularly useful.Combination of these methods yielded information about the role of the mineral phase in stabilizing organic matter and the differences in type and degree of complexation of organic matter with Al and Fe in the various horizons and soil profiles.Sodium tetraborate extraction proved the only soft extraction method that yielded simultaneous information about the Al,Fe,and C fractions extracted.It also appeared to differentiate between SOM fractions of different stability.The fractions of copper chloride-and potassium chloride-extractable Al were useful in assessing the total reactive and toxic Al fractions,respectively.The classical subdivision of organic matter into humic acids,fulvic acids,and humin added little useful information.The use of fulvic acids as a proxy for mobile organic matter as done in several model-based approaches seems invalid in the soils studied.  相似文献   

4.
The fertility of farmed soils in parts of the Papua New Guinea (PNG) highlands reputedly has been declining for some time owing to population pressure. To assess the extent of the problem, a survey of sweet potato gardens was conducted across four of the highlands provinces and information on soil variables was obtained for gardens on soils of volcanic and non-volcanic origins. In the absence of fertilizer application, soil fertility in the humid tropics is largely a function of soil cation exchange capacity (CEC), and soils of low CEC had previously been reported in this region. In the present study, relationships between effective CEC (ECEC) and other soil properties in moderately acidic soils (pH 5.5–6.3) were investigated to see if there was scope for improving soil cation retention characteristics through management of key soil variables. For volcanic soils of varying allophane content, ECEC was, unexpectedly, negatively correlated with soil C and soil C/N, most probably because of the formation of humus–allophane complexes which had facilitated organic matter accumulation whilst dramatically reducing the free negative charges on the material. Given the latter outcome, the indigenous practice of heaping compost in the centre of soil mounds appeared to be one of the best strategies for circumventing the problem of low CEC, as nutrients in the compost are held in an environment virtually independent of the surrounding soil mineralogy. Although the positive correlation between soil pH and soil ECEC was weak for volcanic soils, it was concluded that liming might nevertheless be an effective means of enhancing the nutrient retention characteristics of these soils provided the practicalities and costs were not prohibitive.  相似文献   

5.
Equilibrium and kinetic studies have been made on the adsorption of acrylonitrile(CH2=CHCN) on three soils and four minerals from aqueous solutions.It was shown that the organic matter was the major factor affecting the adsorption process in the soils.The conformity of the equilibrium data to linear type(one soil) and Langmuir type(two soils) isotherms indicated that different mechanisms were involved in the adsorption.This behavior appears bo be related to the hydrophobicity of soil organic matter due to their composition and E4/E6 ratio of humic acids.The adsorption kinetics were also different among the soils,indicating the difference in porosity of organic matter among the soils,and the kinetics strongly affected the adsorption capacity of soils for acrylonitrile.Acrylonitrile was slightly adsorbed from aqueous solutions on pyrophyllite with electrically neutral and hydrophobic nature,and practically not on montmorillonite and kaolinite saturated with Ca.However,much higher adsorption occurred on the zeolitized coal ash,probably caused by high organic carbon content(107g/kg).  相似文献   

6.
Abstract

Copper (Cu) is bound strongly to organic matter, oxides of iron (Fe) and manganese (Mn), and clay minerals in soils. To investigate the relative contribution of different soil components in the sorption of Cu, sorption was measured after the removal of various other soil components; organic matter and aluminum (Al) and Fe oxides are important in Cu adsorption. Both adsorption and desorption of Cu at various pH values were also measured by using diverse pasture soils. The differences in the sorption of Cu between the soils are attributed to the differences in the chemical characteristics of the soils. Copper sorption, as measured by the Freundlich equation sorption constants [potassium (K) and nitrogen (N)], was strongly correlated with soil properties, such as silt content, organic carbon, and soil pH. The relative importance of organic matter and oxides on Cu adsorption decreased and increased, respectively, with increasing solution Cu concentrations. In all soils, Cu sorption increased with increasing pH, but the solution Cu concentration decreased with increasing soil pH. The cumulative amounts of native and added soil Cu desorbed from two contrasting soils (Manawatu and Ngamoka) during desorption periods showed that the differences in the desorbability of Cu were a result of differences in the physico‐chemical properties of the soil matrix. This finding suggests that soil organic matter complexes of Cu added through fertilizer, resulted in decreased desorption. The proportions of added Cu desorbed during 10 desorption periods were low, ranging from 2.5% in the 24‐h to 6% in the 2‐h desorption periods. The desorption of Cu decreased with increasing soil pH. The irreversible retention of Cu might be the result of complex formation with Cu at high pH.  相似文献   

7.
The monosaccharide composition of Ando soils, which originate from volcanic ash and have high organic matter content (8–21% carbon), was quite different from that of non-volcanic ash soils (1.2–1.9% carbon), being richer in mannose, fucose and ribose, whereas there was less glucose in cellulose-like form, arabinose, xylose and rhamnose. The Ando soils were also characterized by a lower percentage of organic carbon in the form of saccharide (4.4–7.4%) in comparison with non-volcanic ash soils (10.5%), though the former soils contain a greater amount of saccharides. The monosaccharide composition of Ando soils was unrelated to the vegetation, land usage, or climatic conditions, and is presumed to be a soil characteristic resulting from the preferential accumulation of microbial polysaccharides.  相似文献   

8.
Eight soils from the Gulf of Kalloni in Lesvos Island, Greece, most of which were of low clay and low organic matter content, were used in a series of leaching experiments. The aim was to investigate the role of sewage sludge on Zn leaching and determine the soil properties that affect it. It was found that sludge addition at a low application rate (10 t ha?1) decreased Zn leaching significantly by 30%. From a regression analysis it was found that eluted Zn was reduced with increasing Fe oxides content, probably due to Zn adsorption onto them, and that Zn transport increased with clay content. This indicates that Zn leaching was facilitated by the downward movement of clay particles, which was also suggested by the erratic Zn breakthrough observed in many soils. This was further confirmed by the fact that colloid concentrations increased with clay content in the soils (R?=?0.85, P?<?0.05). The results show that the addition of sewage sludge to low organic matter and clay content soils at moderate application rates enhances soil organic carbon and increases metal retention capacity.  相似文献   

9.
Texture is one of the major criterions in soil classification, probably because it has a decisive influence on soil properties. This is particularly true for volcanic ash soils. Most ashes are largely composed of sand and silt particles with little clay (11, 15). The ash weathers very rapidly (1), and clay site particles less than 2 microns in diameter occur even within a few months, as shown by Ishii at the authors' laboratory. Those clay size particles produced in the early stage of weathering are slightly weathered ones (2), and are still subject to rapid weathering, losing bases and silica under humid and well drained conditions. In consequence the clay fraction of volcanic ash soils is composed of particles which vary in degree of weathering from slightly altered glass and feldspar to true clay mineraloids and minerals. The clay fraction of younger soils as a whole is less and that of older ones is more weathered. Weathering brings a remarkable change in the properties of volcanic ash soils; for example, an inerease in soil acidity, lowering of base saturation and bulk density, or accumlation of organic matter. These changes must exert a great influence on soil fertility directly or indirectly.  相似文献   

10.
The retention of phosphate and the content of available phosphate were estimated by a new method with monobasic sodium phosphate (pH 4.5) and the Olsen's method, respectively, on the Principal soils in the central valley in Chile. Trumaos (Andosols) are, in general, distinctly in the value of P-retention than other soils with the exception of trumaos of alluvial origins. This characteristic of trumaos can be employed for the identification of trumaos among r soils and alluvial trumaos among ordinary ones. The P-retention value of volcanic ash soils of decreases with the crystallization of the amorphous inorganic materials. According to the data of P-retention, certain rojos arcillosos (red clays) are presumed to have surface horizons of volcanic ash origins. Granitic rojos arcillosos are notably low in P-retention compared with other arcillosos. The organic matter content and P-retention value of soils are closely related to each other, suggesting that both organic matter and phosphate are retained by soils on the same a erials though by different mechanisms.

The content of available phosphate in surface horizons varied from soil to soil and no difference was noticeable among the soil groups of trumaos, rojos arcillosos, and paddy soils. Also no relation was found between the P-retention value and available phosphate content. However, in lower horizons where plant roots are scarce or absent, no available phosphate was found in trumaos in contrast to the presence of an appreciable amount of phosphate in rojos arcillosos. Phosphate of native trumaos appear to be practically insoluble. The surface soil rich in available phosphate was limited to cultivated fields, suggesting that the available phosphate was largely due to the remnant of applied fertilizers and partly to the remains of organic phosphorus from plants and soil organisms. The content of available phosphate tends to decrease with time after application of phosphates, and a significant negative correlation coefficient was obtained between the amount of available phosphate and the P-retention value of soils at least by three months after application of phosphate. The higher the P-retention value of soils, the less the content of available phosphate, and the faster the fixation of phosphate.  相似文献   

11.
It is essential to analyze chemical properties including the amount of various materials and the soil colloid characteristics in forest soils to forecast wood production and the distribution of and variations in the environmental functions of forest soils, such as conservation of stream water and carbon sequestration. Approximately 70% of the forest soils in Japan consists of Brown Forest Soils (BFS), which are considered to be typical zonal soils under the humid-temperate and warm-temperate regime of Japan. BFS were subclassifled into several groups according to the soil moisture environment along the slope and morphological properties. However, even the same type of soil may display different properties depending on the climatic conditions, parent materials and vegetation types. In the present study, the variations in the carbon content, nitrogen content, cation exchange capacity and some properties depending on the parent materials, were clarified by using 34 sola of BFS, and 3 sola of black soils (BLS) for comparison, which were distributed in the submontane zone of the Kanto and Chubu districts in central Japan under the same climatic conditions. We observed differences in the pH, cation exchange capacity, base saturation and clay content among BFS samples derived from various parent materials. The BFS derived from volcanic ash contained obviously larger amounts of carbon and nitrogen than the BFS derived from other parent materials. However, the BFS derived from volcanic ash differed from the BLS derived from volcanic ash in the vertical distribution pattern of carbon and nitrogen. Thus, even in the submontane zone of the Kanto and Chubu districts, the chemical properties of BFS varied considerably with the parent materials. It was concluded that the classification of BFS by the parent materials was useful for evaluating the ability of the BFS, that cover 70% of the forests in Japan, to store various materials.  相似文献   

12.
Abstract

We investigated boron (B) adsorption characteristics for 16 acid alluvial soils as a function of equilibrium B concentration (0–80 μg/mL) and the effect of soil properties on such adsorption. The adsorption data for the soils could be described by Freundlich, Temkin, and BET isotherm equations over the entire concentration ranges studied, and by Langmuir and Eadie‐Hofstee equations only over a limited range. In general, the B adsorption capacity and the energy of retention of the soils calculated from different equations are low, the average Langmuir adsorption maxima and bonding energy constant being 21.47 μg/g and 0.113 mL/μg, respectively, making B susceptible to leaching losses. Simple and multiple regression analysis show that the adsorption capacities are significantly influenced by organic carbon (C), cation exchange capacity (CEC), and different forms of aluminium (Al) content in soils. The energy related constants are also influenced by the forms of Al in soils. Existence of significant correlations between constants obtained from different equations confirmed the adsorption characteristics of the soils.  相似文献   

13.
Soil properties varied in water retention; due to soil texture and organic matter content. Variations of texture in many soils are effected mostly to soil forming factors of parent materials of the soil, biological activities, climactic variation, and duration of soil reaction. While the organic matter contents are affected totally by the environmental conditions of the soils. Water holding capacity of different soils influences plants growth and development in diverse soil characteristics of the world and determines soil productivity. Water resources for agricultural activities are limited, particularly in arid environment and soil water holding capacity of arid soil is very low. Kuwait can be good example of arid environment with limited water resources for agriculture activities and possess soil of coarse texture with very low organic matter content (Anonymous, 1997). Agricultural development in Kuwait meets many problems for crop production and urban landscaping. Water resources are limited and the quality is deteriorating at the same time soil water holding capacity is very low. Enormous amount of water, particularly desalinated expensive water is wasted for agricultural activities. This paper will study various parts of Kuwaiti soils water holding capacity and develop water retention data for efficient water irrigation and improvement of plant growth.  相似文献   

14.
Soil erosion is a widespread phenomenon in Andean South America, where many regions are covered with soils derived from volcanic parent materials. Climate-induced differences in the genesis of these soils have been demonstrated along toposequences on volcanic slopes. This research was conducted to study the impact of such differential pedogenesis on erodibility and runoff-infiltration characteristics along an altitudinal Entisols–Inceptisols–Andisols sequence in the Andes of northern Ecuador. Surface soils were packed into small pans and placed on a 9% slope, and a simulated rainstorm with varying intensities was applied for a duration of 30 min. The runoff-erosion behaviour of the studied volcanic ash soils is strongly affected by their pedological development. Accumulation of organic matter and precipitation of active amorphous materials at high elevations have led to the formation of well-developed Andisols with very stable aggregate structure. These soils remain wettable when air-dried, show very high infiltration capacity and, consequently, low potential for runoff generation and soil erosion. Low organic matter contents and absence of active amorphous materials at low elevations have led to the formation of weakly aggregated Entisols and Inceptisols. These soils are susceptible to surface crusting, which lowers their infiltration capacity and increases their erodibility. However, in comparison with other soils of different origin and composition, the interrill erodibilities determined for these more erodible low-elevation soils are classified as low. The findings of this study suggest that upland soil erosion is not a major threat to sustainability in the studied volcanic landscape, which is generally confirmed by field observations.  相似文献   

15.
Soil properties varied in water retention; due to soil texture and organic matter content. Variations of texture in many soils are effected mostly to soil forming factors of parent materials of the soil; biological activities; climactic variation; and duration of soil reaction. While the organic matter contents are affected totally by the environmental conditions of the soils. Water holding capacity of different soils influences' plant growth and development in diverse soil characteristics of the world and determines soil productivity. Water resources for agricultural activities are limited, particularly in arid environment and soil water-holding capacity of arid soil is very low. Kuwait can be good example of arid environment with limited water resources for agriculture activities and possess soil of coarse texture with very low organic matter content (Anonymous, 1997). Agricultural development in Kuwait meets many problems for crop production and urban landscaping. Water resources are limited and the quality is deteriorating at the same time soil water holding capacity is very low. Enormous amount of water, particularly desalinated expensive water is wasted for agricultural activities. This paper will study various parts of Kuwaiti soils water holding capacity and develop water retention data for efficient water irrigation and improvement of plant growth.  相似文献   

16.
Abstract

The adsorption of Zn by soil and subsoil samples from the slopes of the Irazu and Poas volcanoes in Costa Rica was correlated with soil properties and represented by Langmuir isotherms.

Soil pH, texture and free aluminum and sesquioxide content correlated significantly with Zn adsorption. No correlation with organic matter content was found probably due to the variable nature and properties of its compounds. The adsorption maxima ("b”; values) calculated by the Langmuir equation are higher for the soils developed on the more weathered Poas than for the more recent Irazu ash. The bonding energy constants ("K") followed a similar trend.  相似文献   

17.
Abstract

The influence of some soil properties on hot 0.02 M calcium chloride (CaCl2) extractable boron in the Argentine Pampas was studied. The selected soils represent an extensive area in the middle west of the country where most of the grain crops are produced. Soils have all developed on loess and cover a wide range of organic matter, pH, and exchangeable calcium. The most representative soils are Typic Argiudolls and Typic Haplustolls. Two hundred soil samples were taken in order to characterize their 0.02 M CaCl2 extractable boron content and study the boron behavior with regard to other soils properties and environmental conditions. The amounts of extracted boron on all samples had a significant correlation with soil organic carbon (positive), and soil pH (negative). The regression equation between extractable boron and organic carbon content was y=0.1021+0.3722 OC R2: 0.51. Since solubility in hot CaCl2, 0,02 M is considered an availability index, these results support the hypothesis that organic carbon content is the main boron reserve for plants. When a multiple regression was calculated, both variables organic carbon and pH explained 57% of variation in extractable boron. The studied area can be subdivided into regions with different boron content, within each region the relationship between boron content and organic carbon and pH were also different. The exchangeable calcium content had a light influence especially in the subsuperficial layer. The influence of environmental conditions on boron content and its relationship with soil properties were discussed.  相似文献   

18.
Influence of Soil Properties on the Release of Dissolved Organic Matter (DOM) from the Topsoil A percolation experiment over a period of three month with small monoliths from forest and grassland soils varying in their anthropogenic changes was carried out to identify, to weigh and to quantify important soil properties for DOM release from the topsoil. Quality of soil organic matter determines the amount of DOM released from the topsoil if the soils have a low ability to adsorb and to precipitate DOM. Favorable conditions for high DOC concentrations in the soil solution are wide C/N ratios in the soil and in the hot water soluble fraction, a high soil content of hot water soluble organic carbon and a high portion of hot water soluble organic carbon in the total organic carbon content. Anthropogenic changes of the soils are effective to DOM release via changing quality of soil organic matter. Long dry periods and large water fluxes can further increase DOM release. The effects of soil organic matter can be disguised in soils with a high DOM retention capacity (high CEC, high content of exchangeable bases, Feox and Fed). Then adsorption and precipitation determine DOM release from the topsoil and contribute to a decrease of DOM release.  相似文献   

19.
上海地区土壤持水特性研究   总被引：11，自引：0，他引：11  
土壤水的研究,从Henri Darcy(1856)提出达西定律算起,已有一百多年历史.经历了由经验到理论、由静态到动态、由定性到定量、由宏观到微观逐步深入发展的过程[1].1877年Briggs L.J.提出毛管假说,将土壤孔隙组成的孔道看成是一些大小不同的毛细管,认为表面张力是土壤保持水分的主要原因.  相似文献   

20.
The present study investigated the impact of long‐term soil management on the metal retention capacity of soil. We examined the sorption behaviour of Cu, Cd and Zn in soils and in the various particle‐size fractions of these soils, which had been amended with farmyard manure, mineral fertilizers or were fallow for 38 years in a long‐term field experiment. The soils investigated contained different amounts and origins of organic matter and differed in soil pH, but the mineral phase showed less response to the different soil managements. Batch adsorption and desorption experiments as well as a sequential fractionation schema, which defines seven geochemical fractions, were used to investigate the retention properties of soil. Sequential extraction was conducted with original as well as with metal‐spiked soils. Results showed that amounts of Cu, Cd and Zn retained differed by a factor of more than 3 among the treatments in the long‐term field experiment, when a massive concentration of metal was added to soil. An increased sorption on smaller particle size fractions occurred (clay ≫ silt > fine sand ≥ coarse sand) due to the larger surface area as well as the greater carbon content in the smaller fractions. Soil sorption behaviour in another long‐term field experiment was estimated based on the present particle‐sorption data. Differences in the sorption behaviour were related to differences in soil mineralogy and amounts of Fe‐ and Mn‐oxides. Fractionation of the original and the metal‐spiked soil underlined the contribution of organic matter to sorption capacity (sequence: Cu ≫ Cd > Zn). Different organic matter contents and a different soil pH considerably changed the amounts of metals in the defined geochemical fractions. Freshly added Cu, Cd and Zn ions were found mainly in more mobile fractions. In contrast, metals in non‐spiked soils appeared in less‐mobile fractions reflecting their long‐term sorption behaviour.  相似文献   

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