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1.
Frequent atmospheric measurements of the anthropogenic compound methylchloroform that were made between 1978 and 1985 indicate that this species is continuing to increase significantly around the world. Reaction with the major atmospheric oxidant, the hydroxyl radical (OH), is the principal sink for this species. The observed mean trends for methylchloroform are 4.8, 5.4, 6.4, and 6.9 percent per year at Aldrigole (Ireland) and Cape Meares (Oregon), Ragged Point (Barbados), Point Matatula (American Samoa), and Cape Grim (Tasmania), respectively, from July 1978 to June 1985. These measured trends, combined with knowledge of industrial emissions, were used in an optimal estimation inversion scheme to deduce a globally averaged methylchloroform atmospheric lifetime of 6.3 (+ 1.2, -0.9) years (1sigma uncertainty) and a globally averaged tropospheric hydroxyl radical concentration of (7.7 +/- 1.4) x 10(5) radicals per cubic centimeter (1sigma uncertainty). These 7 years of gas chromatographic measurements, which comprise about 60,000 individual calibrated real-time air analyses, provide the most accurate estimates yet of the trends and lifetime of methylchloroform and of the global average for tropospheric hydroxyl radical levels. Accurate determination of hydroxyl radical levels is crucial to understanding global atmospheric chemical cycles and trends in the levels of trace gases such as methane.  相似文献   

2.
Surface waters along a cruise track in the East Pacific Ocean were undersaturated in methyl bromide (CH(3)Br) in most areas except for coastal and upwelling regions, with saturation anomalies ranging from + 100 percent in coastal waters to -50 percent in open ocean areas, representing a regionally weighted mean of -16 (-13 to -20) percent. The partial lifetime of atmospheric CH(3)Br with respect to calculated oceanic degradation along this cruise track is 3.0 (2.9 to 3.6) years. The global, mean dry mole fraction of CH3Br in the atmosphere was 9.8 +/- 0.6 parts per trillion, with an interhemispheric ratio of 1.31 +/- 0.08. These data indicate that approximately 8 percent (0.2 parts per trillion) of the observed interhemispheric difference in atmospheric CH3Br could be attributed to an uneven global distribution of oceanic sources and sinks.  相似文献   

3.
采用田间试验研究油菜的阶段营养特性和N,P,K复肥配比的效应。结果表明,油菜在P素营养的基础上,生长前期以K素营养占主导,其次为N素,而后期(开花后)则以N素占优势,K素次之。高N配量,前期N素释放较多,有利于植株营养体生长,但后期供N不足。增大P,K配量,可调节复肥养分的释放和稳定N,P,K的供应量比,有利于平衡作物前后期的生长发育,提高产量和品质。在灰棕紫泥上,油菜以N:P:K=2:1:1的配比最佳,分别比3:1:1和1:1:1增产13.07％和6.80％,提高粗脂肪含量9.94％和6.10％。  相似文献   

4.
Ultrasonic interferometric measurements of the shear elastic properties of MgSiO3 perovskite were conducted on three polycrystalline specimens at conditions up to pressures of 8 gigapascals and temperatures of 800 kelvin. The acoustic measurements produced the pressure (P) and temperature (T) derivatives of the shear modulus (G), namely ( partial differentialG/ partial differentialP)T = 1.8 +/- 0.4 and ( partial differentialG/ partial differentialT)P = -2.9 +/- 0.3 x 10(-2) gigapascals per kelvin. Combining these derivatives with the derivatives that were measured for the bulk modulus and thermal expansion of MgSiO3 perovskite provided data that suggest lower mantle compositions between pyrolite and C1 carbonaceous chondrite and a lower mantle potential temperature of 1500 +/- 200 kelvin.  相似文献   

5.
The cross pressure (P) and temperature (T) dependence of the elastic moduli (Cij) of single-crystal samples of periclase (MgO) from acoustic wave travel times was measured with ultrasonic interferometry: partial differential2C11/ partial differentialP partial differentialT = (-1.3 +/- 0.4) x 10(-3) per kelvin; partial differential2C110/ partial differentialP partial differentialT = (1. 7 +/- 0.7) x 10(-3) per kelvin; and partial differential2C44/ partial differentialP partial differentialT = (-0.2 +/- 0.3) x 10(-3) per kelvin. The elastic anisotropy of MgO decreases with increasing pressure at ambient temperature, but then increases as temperature is increased at high pressure. An assumption of zero cross pressure and temperature derivatives for the elastic moduli underestimates the elastic anisotropy and overestimates the acoustic velocities of MgO at the extrapolated high-pressure and high-temperature conditions of Earth's mantle.  相似文献   

6.
In frog sartorius muscles immersed for 2 hours at 26 degrees C in normal Ringer solution, the intrafiber potassium concentration, C(K)(in millimoles per liter), was 123 +/- 2 (mean value plus or minus standard error), and the potassium activity, a(K) (in millimoles per liter), was 90 +/- 1.0. The corresponding sodium concentration and activity were 20 +/- 1 and 6.5 +/- 0.4, respectively. After overnight immersion in K+-free Ringer solution the values were: CK, 97 +/- 2; aK, 81.5 +/- 1.6; CNa, 47 +/- 2; and aNa, 11.2 +/- 0.6. The changes in aK and aNa during storage were not consistent with an exchange between predominantly "free" fiber K+ and external Na+. These results suggest that the Na+ taken up during overnight immersion largely replaced adsorbed or sequestered K+ in the fibers.  相似文献   

7.
A pulsed ruby laser (wavelength, 694.3 nanometers) was used to measure the dependence on light intensity of light-induced electron paramagnetic resonance (ERR) signal 1 for short flashes of uniform duration (400 microseconds). Approximately 10(18) photons per square centimeter per flash from the unattenuated beam were available to the sample of subchloroplast "system 1" particles from spinach. The experimental dependence of the EPR signal height plotted as a function of the total number of incident photons per flash was exponential. From measurement of the slope at a very low relative photon flux and the saturated EPR signal amplitude, the value for the cross section or "effective size" of the light-induced paramagnetic unit, sigma(EPR), was found to be 300 x 10(-17) square centimeter. This result is compared with a measured optical absorption cross section, sigma(694nm), of 2.5 x 10(-17) square centimeter, for the identical sample at the laser wavelength. The hundredfold difference in size supports the thesis that the paramagnetic state is a property of an aggregate of chlorophyll molecules of the same general size as the photosynthetic unit.  相似文献   

8.
The Voyager 2 encounter with the Neptune system included radio science investigations of the masses and densities of Neptune and Triton, the low-order gravitational harmonics of Neptune, the vertical structures of the atmospheres and ionospheres of Neptune and Triton, the composition of the atmosphere of Neptune, and characteristics of ring material. Demanding experimental requirements were met successfully, and study of the large store of collected data has begun. The initial search of the data revealed no detectable effects of ring material with optical depth tau [unknown] 0.01. Preliminary representative results include the following: 1.0243 x 10(26) and 2.141 x 10(22) kilograms for the masses of Neptune and Triton; 1640 and 2054 kilograms per cubic meter for their respective densities; 1355 +/- 7 kilometers, provisionally, for the radius of Triton; and J(2) = 3411 +/- 10(x 10(-6)) and J(4) = -26(+12)(-20)(x10(-6)) for Neptune's gravity field (J>(2) and J(4) are harmonic coefficients of the gravity field). The equatorial and polar radii of Neptune are 24,764 +/- 20 and 24,340 +/- 30 kllometers, respectively, at the 10(5)-pascal (1 bar) pressure level. Neptune's atmosphere was probed to a pressure level of about 5 x 10(5) pascals, and effects of a methane cloud region and probable ammonia absorption below the cloud are evident in the data. Results for the mixing ratios of helium and ammonia are still being investigated; the methane abundance below the clouds is at least 1 percent by volume. Derived temperature-pressure profiles to 1.2 x 10(5) pascals and 78 kelvins (K) show a lapse rate corresponding to "frozen" equilibrium of the para- and ortho-hydrogen states. Neptune's ionosphere exhibits an extended topside at a temperature of 950 +/- 160 K if H(+) is the dominant ion, and narrow ionization layers of the type previously seen at the other three giant planets. Triton has a dense ionosphere with a peak electron concentration of 46 x 10(9) per cubic meter at an altitude of 340 kilometers measured during occultation egress. Its topside plasma temperature is about 80 +/- 16 K if N(2)(+) is the principal ion. The tenuous neutral atmosphere of Triton produced distinct signatures in the occultation data; however, the accuracy of the measurements is limited by uncertainties in the frequency of the spacecraft reference oscillator. Preliminary values for the surface pressure of 1.6 +/- 0.3 pascals and an equivalent isothermal temperature of 48 +/- 5 K are suggested, on the assumption that molecular nitrogen dominates the atmosphere. The radio data may be showing the effects of a thermal inversion near the surface; this and other evidence imply that the Triton atmosphere is controlled by vapor-pressure equilibrium with surface ices, at a temperature of 38 K and a methane mixing ratio of about 10(-4).  相似文献   

9.
Direct catalytic hydration of terminal alkenes to primary alcohols would be an inexpensive route to industrially useful alcohols and a convenient synthetic route for the synthesis of terminal alcohols in general. The reaction between trans- PtHCl(PMe(3))(2) (where Me = CH(3)) and sodium hydroxide in a one-to-one mixture of water and 1-hexene yields a species that, at 60 degrees C and in the presence of the phasetransfer catalyst benzyltriethylammonium chloride, catalyzes selective hydration of 1-hexene to n-hexanol at a rate of 6.9 +/- 0.2 turnovers per hour. Hydration of 1-dodecene to n-dodecanol occurs at a rate of 8.3 +/- 0.4 turnovers per hour at 100 degrees C. Deuterium labeling experiments with trans-PtDCl(PMe(3))(2) show that hydration involves reductive elimination of a C-H bond. At low hydroxide concentrations (<8 equivalents), hydration of the water-soluble olefin 3-butene-1-ol to 1,4-butanediol exhibited a first-order dependence on hydroxide concentration for loss of catalytic activity. This suggests that hydroxide attacks the coordinated alkene slowly. At high hydroxide concentrations, the rate of catalysis was hydroxide-independent and first order in alkene. Substitution of coordinated water (k(1) = 9.3 +/- 0.5 x 10(-3) liters per mol per second) appears to be limitng under these conditions.  相似文献   

10.
Photometry and spectroscopy of the object Cha Halpha 1, located in the Chamaeleon I star-forming cloud, show that it is a approximately 10(6)-year-old brown dwarf with spectral type M7.5 to M8 and 0.04 +/- 0.01 solar masses. Quiescent x-ray emission was detected in a 36-kilosecond observation with 31.4 +/- 7.7 x-ray photons, obtained with the Rontgen Satellite (ROSAT), with 9final sigma detection significance. This corresponds to an x-ray luminosity of 2.57 x 10(28) ergs per second and an x-ray to bolometric luminosity ratio of 10(-3.44). These are typical values for late M-type stars. Because the interior of brown dwarfs may be similar to that of convective late-type stars, which are well-known x-ray sources, x-ray emission from brown dwarfs may indicate magnetic activity.  相似文献   

11.
Modern distance determinations to galaxies were reviewed and placed on a uniform and self-consistent scale. Based on eight separate but not entirely independent techniques, the distance to the Virgo cluster was found to be 15.8 +/- 1.1 megaparsec. Twelve different determinations yield a Coma/Virgo distance ratio of 5.52 +/- 0.13 and hence a Coma distance of 87 +/- 6 megaparsec. With a cosmological redshift of 7210 kilometers per second, this gives a Hubble parameter H(0) (local) of 83 +/- 6 kilometers per second per megaparsec. From the velocity-distance relation of rich clusters of galaxies, the ratio of the value of H(0) (global) to the value of H(0) (local) was determined to be 0.92 +/- 0.08. In other words, the cluster data do not show a statistically significant difference between the local and global values of the Hubble parameter. If one nevertheless adopts this relation between H(0) (global) and H(0) (local), then the value of H(0) (global) is 76 +/- 9 kilometers per second per megaparsec. This observed value differs at the approximately 3sigma level (where sigma is the standard deviation of the distribution) from values in the range 36 less, similar H(0) less, similar50 kilometers per second per megaparsec, which are derived from stellar evolutionary theory in conjunction with standard cosmological models with a density parameter (Omega) that is equal to 1 and a cosmological constant (lambda) that is equal to 0.  相似文献   

12.
The abunldanzces of uranium and thorium were measured mass spectrometrically as 0.59 +/- 0.02 and 2.24 +/- 0.06 parts per million, respectively, in the fines of Apollo 11 builk sample. The ratio (235)U/(238)U was 0.007258 +/- 0.000016, in agreement with terrestrial uranium. The following upper limits were set: (236)U/(238)U相似文献   

13.
Miller AA 《Science (New York, N.Y.)》1969,163(3873):1325-1326
The glass-transition temperature of water (T(g)) has been calculated by use of the Tammann-Hesse viscosity equation with the viscosity equal to 10(13) poise at T(g). The derived value of T(g),162 +/- 1 degrees K, is significantly higher than previous estimates.  相似文献   

14.
[目的]通过研究黄栌叶片光合特性对氮磷钾配施处理的响应,探讨光合特性与氮磷钾肥的关系,为黄栌的养分管理提供科学依据.[方法]以黄栌盆栽苗为试验材料,根据L9(34)正交设计进行氮肥(N为0、6、12 g/株)、磷肥(P为0、10、20 g/株)和钾肥(K为4、8、12 g/株)试验,设置10个处理,分别为T1(N1P1...  相似文献   

15.
A measurement and interpretation on a molecular level of a phase transition in an ordered Langmuir monolayer is reported. The diagram of surface pressure (pi) versus molecular area of a monolayer of chiral (S)-[CF(3)-(CF(2))(9)-(CH(2))(2)-OCO-CH(2)-CH (NH(3)(+))CO(2)(-)] over water shows a change in slope at about pi(s)= 25 millinewtons per meter. Grazing-incidence x-ray diffraction and specular reflectivity measurements indicate a solid-solid phase transition at pi(s). The diffraction pattren at low pressures reveals two diffraction peaks of equal intensities, with lattice spacings d of 5.11 and 5.00 angstroms; these coalesce for pi >/=pi(s). Structural models that fit the diffraction data show that at pi> pi(s) the molecules pack in a two-dimensional crystal with the molecules aligned vertically. At pi < pi(s) there is a molecular tilt of 16 degrees +/- 7 degrees . Independent x-ray reflectivity data yield a tilt of 26 degrees +/- 7 degrees . Concomitant with the tilt, the diffraction data indicate a transition from a hexagonal to a distorted-hexagonal lattice. The hexagonal arrangement is favored because the -(CF(2))(9)CF(3) moiety adopts a helical conformation. Compression to 70 millinewtons per meter yields a unit cell with increased crystallinity and a coherence length exceeding 1000 angstroms.  相似文献   

16.
本文采用密闭箱-气相色谱法研究不同沼液灌溉模式,小麦-玉米轮作条件下温室气体的排放特征,并运用全球增温潜势(GWP)和气体排放强度(GHGI)对小麦-玉米排放的温室效应进行估算。研究表明,在冬小麦-夏玉米轮作周期中,以清/沼比2∶1配比的沼液灌溉,小麦灌3次,玉米灌溉1次的处理(T3)和小麦灌溉4次,玉米灌溉1次的处理(T4)与常规施肥(CF)相比,GWP连续两年没有显著性差异,T3、T4和CF在2016年的GWP为2 990.82±285.00、3 235.48±307.05、3 047.35±315.11;T3、T4和CF在2017年的GWP为2 865.61±296.44、3 069.10±318.44和2 741.70±284.37。但小麦季灌溉1次,玉米灌溉1次处理(T1)和与小麦灌溉2次,玉米灌溉1次的处理(T2)的GWP比CF处理相比显著降低。T1和T2处理在2016年和2017年的GWP分别为2 578.57±279.39、2 586.13±263.01;2 702.59±300.75、2 733.19±260.81,T1和T2处理2016年比CF处理降低了15.38%和11.31%;2017年比CF处理降低了5.67%和0.31%。针对产量进行分析,T2、T3、T4和CF处理连续两年差异性不显著,其中T4处理在2016年产量比CF处理提高了4.12%。T3、T4的温室气体排放强度与常规施肥处理(CF)连续两年差异性不显著,2016年T1和T2处理与CF处理相比显著降低了0.56%,2017年T2处理和CF处理相比差异性不显著。综合考虑GWP与作物产量的因素,T2处理(小麦季2∶1沼液灌溉2次,玉米季2∶1沼液灌溉1次,施氮量为315 kg·hm~(-2))为最优选择,所以T2处理是可以替代化肥且较合理的灌溉模式。  相似文献   

17.
Voyager 2 radio occultation measurements of Saturn's atmosphere probed to the 1.2-bar pressure level, where the temperature was 143 +/- 6 K and the lapse rate apparently equaled the dry adiabatic value of 0.85 K per kilometer. The tropopause at both mid-latitude occultation locations (36.5 degrees N and 31 degrees S) was at a pressure level of about 70 millibars and a temperature of approximately 82 K. The stratospheric structures were very similar with the temperature rising to about 140 K at the 1-millibar pressure level. The peak electron concentrations sensed were 1.7 x 10(4) and 0.64 x 10(4) per cubic centimeter in the predawn (31 degrees S) and late afternoon (36.5 degrees N) locations. The topside plasma scale heights were about 1000 kilometers for the late afternoon profile, and 260 kilometers for the lower portions and 1100 kilometers for the upper portions of the topside predawn ionosphere. Radio measurements of the masses of Tethys and Iapetus yield (7.55 +/- 0.90) x 10(20) and (18.8 +/- 1.2) x 10(20) kilograms respectively; the Tethys-Mimas resonance theory then provides a derived mass for Afimas of (0.455 +/- 0.054) x 10(20) kilograms. These values for Tethys and Mimas represent major increases from previously accepted ground-based values, and appear to reverse a suggested trend of increasing satellite density with orbital radius in the Saturnian system. Current results suggest the opposite trend, in which the intermediate-sized satellites of Saturn may represent several classes of objects that differ with respect to the relative amounts of water, ammonia, and methane ices incorporated at different temperatures during formation. The anomalously low density of lapetus might then be explained as resulting from a large hydrocarbon content, and its unusually dark surface markings as another manifestation of this same material.  相似文献   

18.
采用一种类Fenton试剂法,即Fe3+和H2O2的组合代替Fe2+和H2O2的组合法,对氧化降解苯酚的影响因素及反应动力学进行研究。结果表明:当Fe3+、H2O2的加入量分别为1.3×10-3和1.3×10-2mol·L-1,且初始pH值约为4时,苯酚的降解率最大,几乎达到100%。同时分别用一级动力学、二级动力学及复合一级动力学方程对该条件下的反应进行拟合,复合一级动力学方程能最佳拟合相应的动力学过程,但2个平行反应的速率系数k1≈9.24k2,因此可近似认为是一级动力学过程。  相似文献   

19.
By trapping molecules between two gold electrodes with a temperature difference across them, the junction Seebeck coefficients of 1,4-benzenedithiol (BDT), 4,4'-dibenzenedithiol, and 4,4'-tribenzenedithiol in contact with gold were measured at room temperature to be +8.7 +/- 2.1 microvolts per kelvin (muV/K), +12.9 +/- 2.2 muV/K, and +14.2 +/- 3.2 muV/K, respectively (where the error is the full width half maximum of the statistical distributions). The positive sign unambiguously indicates p-type (hole) conduction in these heterojunctions, whereas the Au Fermi level position for Au-BDT-Au junctions was identified to be 1.2 eV above the highest occupied molecular orbital level of BDT. The ability to study thermoelectricity in molecular junctions provides the opportunity to address these fundamental unanswered questions about their electronic structure and to begin exploring molecular thermoelectric energy conversion.  相似文献   

20.
Gaseous, neutral H(2)O was detected in the coma of comet Halley on 22.1 and 24.1 December 1985 Universal Time. Nine spectral lines of thev(3) band (2.65 micrometers) were found by means of a Fourier transform spectrometer (lambda/triangle uplambda approximately 10(5)) on the NASA-Kuiper Airborne Observatory. The water production rate was approximately 6 x 10(28) molecules per second on 22.1 December and 1.7 x 10(29) molecules per second on 24.1 December UT. The numbers of spectral lines and their intensities are in accord with nonthermal-equilibrium cometary models. Rotational populations are derived from the observed spectral line intensities and excitation conditions are discussed. The ortho-para ratio was found to be 2.66+/-0.13, corresponding to a nuclear-spin temperature of 32 K (+5 K, -2 K), possibly indicating that the observed water vapor originated from a low-temperature ice.  相似文献   

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