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1.
脐橙果皮镉铅含量激光诱导无损检测试验   总被引:3,自引:1,他引:2  
为了验证激光诱导击穿光谱(LIBS)快速无损检测农产品中重金属污染物的可行性,对赣南脐橙样品进行了实验室镉铅污染处理。首先对样品LIBS试验参数进行了优化分析,根据美国NIST(National Institute of Standards and Technology)原子光谱数据库,确定试验用的最佳特征谱线位置分别为Cd226.502nm和Pb405.783nm。观测了光谱信噪比和强度随着延迟时间和激光能量的变化规律,综合考虑结果表明,最佳延迟时间和激光能量分别为1300ns和130mJ。利用优化的LIBS试验参数对镉(Cd)和铅(Pb)元素的光谱信息进行了采集。同时,采用原子吸收分光光度计对脐橙表皮中镉铅元素的真实浓度进行了检测,建立了镉铅元素特征谱线强度与真实浓度之间的关系模型,相关系数分别为0.94669和0.96059。由定标模型得到镉铅元素的检测限分别为17.375和22.782μg/g。为了验证模型的准确性,采用3个样品做了定标曲线反演分析,预测值与真实值之间的相对误差保持在10%左右。试验结果表明,LIBS技术能应用于农业安全方面的农产品重金属Cd、Pb的快速无损检测。  相似文献   

2.
为了寻求大豆油中铬(Cr)的快速检测方法,应用激光诱导击穿光谱(LIBS)技术对大豆油中Cr含量进行定量检测研究,采用松木对大豆油样品中的Cr进行富集,并利用双通道光谱仪采集其LIBS光谱信号;选择钙(Ca)422.64 nm为内标线,并以Cr的原子谱线Cr I 425.44 nm、Cr I 427.48 nm、Cr I428.94 nm及3条谱线之和为分析线,应用直接定标法和内定标法分别建立上述分析线的定标曲线。结果表明,Cr I 425.44 nm建立的定标曲线性能最佳,直接定标法和内定标法所建立的定标曲线的拟合度R2分别为0.9598和0.9894,检测限分别为14.82μg·g~(-1)和8.45μg·g~(-1);3个验证样品预测的相对误差分别为11.32%、12.78%、12.48%和7.91%、4.28%、7.64%。由此可知,LIBS技术用于大豆油中重金属Cr的检测具有一定的可行性,松木富集结合内定标法能减少定量分析误差,提高大豆油中Cr含量的预测精度。本研究结果可为食用油中重金属的快速检测提供理论依据。  相似文献   

3.
基于局部加权回归的土壤全氮含量可见-近红外光谱反演   总被引:6,自引:0,他引:6  
全氮是土壤肥力的重要指标,对作物产量具有决定性作用,采用土壤可见-近红外(Vis-NIR)光谱预测技术及时获取土壤全氮含量信息具有重要意义。采用来自5省的450个土壤样本来验证局部加权回归方法(LWR)结合Vis-NIR光谱技术预测大面积土壤全氮含量的适用性。结果表明,LWR模型的预测效果优于偏最小二乘回归(PLSR)、人工神经网络(ANN)和支持向量机(SVM),选取主成分数为5,相似样本为40时,模型验证的决定系数(RP2)为0.83,均方根误差(RMSEP)为0.25 g kg-1,测定值标准偏差与标准预测误差的比值(RPD)达到2.41。LWR从建模集中选取与验证样本相似的土样作为局部建模样本,降低了差别大的样本对模型的干扰,从而提高了模型的预测能力。因此,LWR建模方法通过大范围、大样本土壤光谱数据进行大尺度区域的全氮等土壤属性预测时能够发挥更好的作用。  相似文献   

4.
以三江源区玉树县和玛多县为研究区,利用实验室测定的As、Cu、Pb、Zn、Cr、Cd、Hg元素含量和室内采集的土壤原始光谱及其4种转换形式,建立了光谱指标与重金属含量的多元回归模型,利用决定系数(R2)、相对分析误差(RPD)及均方根误差(RMSE)评价模型的精度。研究结果表明,土壤As、Cu、Pb、Zn、Cr、Cd含量与SOM、Fe、Mn、Al、Mg等元素具有显著相关关系,Hg元素则未达到显著性水平。As、Cu、Pb、Zn、Cr和Cd元素估算模型回归方程R2达到了0.5以上,均通过了显著性检验,其中Pb、Zn和Cr元素验证样本RPD均达到了1.4以上,模型具备粗略估算能力;As、Cu和Cd元素验证样本RPD均低于1.4,模型不具备粗略估算能力。Hg元素估算模型回归方程的R2为0.28,未能通过显著性检验,无法用于对Hg含量的估算。  相似文献   

5.
污泥与施污土壤重金属生物活性及生态风险评价   总被引:3,自引:0,他引:3  
将城市污泥以不同质量比施于土壤中构成污泥混合土壤,研究各污泥配比土壤中重金属的生物活性,并采用三种重金属评价方法(地累积指数法、潜在生态风险指数法、综合毒性指数模型)和黑麦草对重金属的吸收富集效果来对施污土壤中重金属具有的生态风险性进行评价。结果表明:污泥的添加使土壤中生物活性态Cd、Cu和Zn含量显著增加,对三种重金属具有活化作用,但对Pb却起到钝化作用。生态风险评价结果表明:污泥的添加使土壤中Pb呈现无污染和低生态风险;Cu和Zn呈现中度污染和低生态风险;Cd达到强度污染和重度生态风险,重金属潜在生态风险(RI)总体处于强度生态风险水平。当污泥添加比例大于6:10(污泥S3处理)时,施污土壤中重金属的综合毒性指数高于土壤对照。黑麦草对Cd、Pb、Cu和Zn的富集浓度与施污土壤中对应重金属的生物活性态含量存在显著正幂指数关系,同时黑麦草对施污土壤中Cd、Cu和Pb的富集能力大小与地累积指数法和潜在生态风险指数法对三种重金属具有的生态风险性的评价结果具有一致性。  相似文献   

6.
王佳  刘斌  肖柏林  李余杰  张田硕  吴璜  张玉婷 《土壤》2019,51(6):1160-1167
探索不同功能区空气降尘中重金属通量特征并对其进行污染评价,对于了解空气降尘输入对土壤中重金属累积影响具有重要意义。对重庆主城的居住区(JZ)、文教区(WJ)、商业区(SY)、郊区(JQ)、交通区(JT)和工业-居住混合区(GJ)逐月进行空气降尘通量和Cr、Ni、Cd、Pb含量的测定。结果表明,工业–居住混合区的空气降尘通量平均值最高,文教区的最低。6类功能区秋季的降尘量相对较低。Cd、Cr、Ni和Pb的平均降尘量在不同功能区分布存在差异。空气降尘中4种重金属元素的平均含量为:Cd 2.14 mg/kg、Cr 66.36 mg/kg、Ni 27.69 mg/kg、Pb 98.33 mg/kg。6类功能区降尘中Cd、Cr、Ni和Pb 4种重金属含量一般冬季较高。地积累指数法的分析表明降尘中Cd污染最严重。经推算,以空气降尘的方式向土壤中输入的重金属,使重庆主城区土壤中Cd、Cr、Ni和Pb等4种重金属元素的浓度在累积100a后仍将低于《土壤环境质量标准》中的二级标准。土壤中重金属元素增加速度最快为Cd,其次为Pb和Cr,Ni的增长为负值。  相似文献   

7.
城市化、工业化和农业集约化的发展影响着土壤环境和健康质量。本研究以位于长江三角洲地区的江苏省太仓市为典型区,采用地统计学方法对其耕层土壤中Cd、Cr、Cu、M、Hg、Pb、Zn和As等8种重金属结构特征和空间分布格局进行了分析,并用模糊数学法综合评价了土壤重金属的污染程度,结果表明:太仓市表层土壤Zn、Cu属强变异强度,呈对数正态分布;Cd、Ni、Hg、As、Cr和Pb属中等变异强度,呈正态分布。除Cd、Cr和Pb略低于背景值外,其他重金属均高于其背景值,其中以As污染指数和超标率最高。土壤重金属复合污染严重,模糊综合评价污染结果为一级。通过半方差函数模型拟合发现Hg、Cd符合球状模型,其他重金属均符合指数模型,8种重金属元素在一定范围内均存在空间相关性。采用Kriging最优内插法得到了耕层土壤重金属含量的空间分布图,发现土壤重金属含量与母质、土壤质地、有机质含量以及工业化、城市化和农业集约化程度密切相关。  相似文献   

8.
利用原子吸收对新乡市居民小区表层土壤的Pb、Cd、Cu、Zn的含量进行了分析,阐明了这几种重金属元素的分布特征,并用单因子污染指数法,内梅罗综合污染指数法和潜在生态风险指数法对其进行了评价。结果表明:Pb在个别居民小区呈现富积现象,Cd、Zn在居民小区内的累积强度较大。新乡市居民小区土壤均受到重度污染,新乡市居民小区土壤潜在生态风险处于极高风险水平,各重金属元素的潜在生态风险指数大小顺序为Cd>Cu>Pb=Zn。  相似文献   

9.
农田土壤铅、镉含量影响因素地理加权回归模型分析   总被引:14,自引:2,他引:12  
为了定量分析土壤重金属含量的影响因素,以长沙城郊农田土壤Pb、Cd为例,采用传统回归模型(ordinary least squares,OLS)和地理加权回归模型(geographically weighted regression,GWR)分析比较了土壤Pb、Cd含量与影响因素间的相关关系。结果表明:长沙城郊农田土壤Pb、Cd含量存在空间自相关性,Pb、Cd的GWR模型拟合度较OLS模型高,残差不存在空间自相关,GWR模型能更好地解释土壤Pb、Cd与影响因素变量的空间异质性。土壤Pb与Cd含量呈极显著正相关;土壤pH值、有机质、氮磷含量是影响土壤Pb、Cd含量的重要因素;离河流、城镇、工矿建设用地的距离对于城郊农田土壤Pb、Cd含量也有一定影响,土壤Pb、Cd的"高-高"集聚区(土壤Pb或Cd含量高的区域被Pb或Cd含量高的其他区域所包围,区域土壤Pb或Cd含量水平较高,且空间差异程度较小)和离河流、城镇、工矿建设用地较近的农田是Pb、Cd污染风险防控的重点区域。该研究可为定量分析区域土壤重金属含量的空间结构与影响因素提供参考,为长沙城郊农田土壤重金属污染的防控提供参考。  相似文献   

10.
模拟降雨条件下污染土壤中重金属元素径流迁移特征   总被引:6,自引:0,他引:6  
探明污染土壤中重金属元素随地表径流迁移特征,对于防控重金属污染物的迁移扩散具有重要意义。通过室内模拟降雨试验,研究不同降雨强度下(55,100,120mm/h)污染土壤中Cd、Pb和Cr随地表径流迁移的特征。结果表明:径流中3种重金属元素总量在产流的前20min内逐渐降低,随后趋于稳定;产流初期(产流10min内)颗粒态重金属占径流重金属总量的比例均在80%以上;随产流时间延长,颗粒态Cd和Cr对径流重金属的贡献率快速降低,其颗粒态/溶解态的比值范围分别为47.0~0.4和12.9~0.4,而Pb则主要以颗粒态的形式存在,溶解态Pb对其随径流迁移的贡献率可忽略不计;随降雨强度增大,径流中总Cd和Pb含量显著降低,而径流中总Cr含量以及溶解态重金属含量无明显变化规律。  相似文献   

11.
【目的】以富士(Fuji)、 秦冠(Qinguan)嫁接在平邑甜茶(Malus hupehensis Rehd.)上的当年生盆栽苗为试验材料,采用砂培方法,研究了缺氮胁迫和干旱对富士和秦冠生长情况、 光合参数、 植株各部位氮磷钾含量及氮素利用效率的影响,分析比较了低氮干旱条件下富士和秦冠生长及氮素利用的差异,以期为果树生产高效肥水利用提供理论指导。【方法】试验共设四个处理: 正常氮正常水(ZZ)、 低氮正常水(DZ)、 正常氮干旱(ZG)、 低氮干旱(DG)。氮素和水分均设置两个水平,分别为正常氮(6 mmol/L NO-3-N)、 低氮(0.3 mmol/LNO-3-N)、 正常供水(保持盆中砂子相对含水量为饱和含水量的80%~85%)、 干旱处理(保持盆中砂子相对含水量为饱和含水量的60%~65%)。【结果】富士和秦冠的生物量(茎和叶)、 株高茎粗等生长指标以及光合速率、 气孔导度、 蒸腾速率均为正常氮正常水(ZZ)>低氮正常水(DZ)>正常氮干旱(ZG)>低氮干旱(DG),并且相对应处理下秦冠的以上指标均高于富士;正常供水下,缺氮处理使富士、 秦冠的根冠比比正常氮处理均有所增加,富士提高了2.05%,秦冠提高了22.40%。富士和秦冠的氮、 磷、 钾含量均表现出正常氮正常水(ZZ)>低氮正常水(DZ)>正常氮干旱(ZG)>低氮干旱(DG); 氮、 钾元素含量在植株各部位的分布顺序依次是叶>根>茎,磷元素则是根>叶>茎;光合氮素利用效率(PNUE)和氮素利用效率表现为秦冠处理之间差异极显著,富士处理之间差异不显著;秦冠的PNUE和NUE明显高于富士,在低氮正常水(DZ)处理下,秦冠氮肥利用率比富士高42.07%,在低氮干旱(DG)处理下高64.14%;低氮胁迫下富士和秦冠的NUE显著提高,并且秦冠提高的幅度高于富士。【结论】施用氮肥能够显著提高富士与秦冠的干物质量,同等水肥条件下,秦冠生长优于富士;水分亏缺会减少叶片对氮的吸收,干旱条件下适度增施氮肥,可提高果树的抗旱能力;低氮干旱胁迫下秦冠的生长指标、 光合指标及氮素利用效率指标均优于富士,表现出较强的抗低氮干旱胁迫的能力。  相似文献   

12.
Laser-induced breakdown spectroscopy (LIBS) is a new technique for the analysis of plant material. This study investigates the application of LIBS to pasture-based plant samples. The LIBS measurements were obtained from pelletized pasture samples (100 samples) that had been also analyzed by inductively coupled plasma–optical emission spectroscopy (ICP-OES) following microwave digestion for calibration and comparison purposes. Comparisons for elements sodium (Na), potassium (K), magnesium (Mg), calcium (Ca), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), boron (B), phosphorus (P), and sulfur (S) showed that LIBS could be used for almost all the standard profile total elements with concentrations down to low mg/kg levels (observed error of Na: 0.024 percent, K: 0.18 percent, Mg: 0.016 percent, Ca: 0.073 percent, P: 0.017 percent, Mn: 31 mg/kg, Fe: 150 mg/kg, Zn: 6.6 mg/kg, and B: 1.1 mg/kg). Elemental analysis at less than mg/kg levels was not possible using LIBS. The elements S and Cu were particularly difficult to analyze with reliability using LIBS at the concentration levels found in the plant samples. Replacing microwave digestion and subsequent ICP analysis with a direct analysis of dried plant samples using LIBS has the potential to improve the productivity and reduce the cost of testing.  相似文献   

13.
正The Center for Agricultural Resources Research(CARR),the Institute of Genetics and Developmental Biology(IGDB),Chinese Academy of Sciences,invites applicants for several research group leader positions.CARR is one of the research organizations in Chinese Academy of Sciences(CAS).We seek nominations and applications from individuals who have expertise and a record of accomplishment in research areas related to ecology,agro-hydrology,  相似文献   

14.
The responses of tallgrass prairie plant communities and ecosystem processes to fire and grazing are well characterized. However, responses of invertebrate consumer groups, and particularly soil-dwelling organisms, to these disturbances are not well known. At Konza Prairie Biological Station, we sampled soil macroinvertebrates in 1994 and 1999 as part of a long-term experiment designed to examine the effects and interactions of annual fire, mowing, and fertilization (N and P) on prairie soil communities and processes. For nearly all taxa, in both years, responses were characterized by significant treatment interactions, but some general patterns were evident. Introduced European earthworms (Aporrectodea spp. and Octolasion spp.) were most abundant in plots where fire was excluded, and the proportion of the total earthworm community consisting of introduced earthworms was greater in unburned, unmowed, and fertilized plots. Nymphs of two Cicada genera were collected (Cicadetta spp. and Tibicen spp.). Cicadetta nymphs were more abundant in burned plots, but mowing reduced their abundance. Tibicen nymphs were collected almost exclusively from unburned plots. Treatment effects on herbivorous beetle larvae (Scarabaeidae, Elateridae, and Curculionidae) were variable, but nutrient additions (N or P) usually resulted in greater densities, whereas mowing usually resulted in lower densities. Our results suggest that departures from historical disturbance regimes (i.e. frequent fire and grazing) may render soils more susceptible to increased numbers of European earthworms, and that interactions between fire, aboveground biomass removal, and vegetation responses affect the structure and composition of invertebrate communities in tallgrass prairie soils.  相似文献   

15.
Abstract

A 3-year study was carried out to investigate quality parameters in 14 tree fruit and berry species grown in southern Norway. The species were blueberry, apple, aronia, sour cherry, sweet cherry, red raspberry, strawberry, blackcurrant, gooseberry, red currant and elderberry, harvested along with wild bilberry, cloudberry and lingonberry. Significant differences between species were identified for all quality parameters. The coefficient of variation between species was lowest for pH (12.5%), dry matter (18.9%) and soluble solids (25.3%), followed by titratable acids (59.3%), total phenolics (83.8%), antioxidant capacity FRAP (85.7%) and antiradical power by the DPPH-assay (97.8%), total monomeric anthocyanins (132%) and ascorbic acid (137%). Average coefficient of variation within species were lower and ranged from 4 (pH) to 62% (ascorbic acid). Only the FRAP values were significantly affected by harvesting year with lower levels in 2004 than in 2005 and 2006. There were significant interactions between species and harvesting year for dry matter, soluble solids, pH, ascorbic acid and FRAP. The results indicate generic ranges in composition within species independent upon growing location and climate, and the composition of the tree fruits and berries is not likely to deviate from these ranges. It is concluded that desirable composition of tree fruits and berries and their products should primarily be achieved by selection among species rather than searching fors broadened variation within individual species.  相似文献   

16.
Potassium (K) fixation and release in soil are important factors in the long-term sustainability of a cropping system. Changes in K concentration and characteristics of K fixation and release in rhizosphere and nonrhizosphere soils in the rapeseed (Brassica napus L.)–rice (Oryza sativa L.) rotation were investigated using a rhizobox system. The concentrations of different forms of K in both rhizosphere and nonrhizosphere soils decreased with plants compared to without plants, regardless of K fertilizer application. Potassium uptake by crops mainly came from the rhizosphere soil. In the treatment without K fertilizer (–K), the main form of K supplied by the soil to the crops was 1.0 mol L?1 nitric acid (HNO3) nonextractable K, followed by nonexchangeable K, and then exchangeable K. In the treatment with K fertilizer (+K), the main K forms supplied by the soil to the crops were exchangeable K and nonexchangeable K. The amount and rate of K fixation after one cycle of the rapeseed–rice rotation was greater in rhizosphere soil than in nonrhizosphere soil. The amount and rate of K fixation of soil in the +K treatment were significantly less than in the –K treatment. The cumulative amounts of K released with 1.0 mol L?1 ammonium acetate (NH4OAc) and 1.0 mol L?1 HNO3 extraction increased with the increasing numbers of extractions, but the K-releasing power of soil by successive extraction decreased gradually and finally became almost constant. The release of K was less in rhizosphere soil than in nonrhizosphere soil. The release of K in the +K treatment was similar to that in the –K treatment in rhizosphere soil, but the K release in nonrhizosphere soil was greater with the +K than the –K treatment. Overall, the information obtained in this study will be helpful in formulating more precise K fertilizer recommendations for certain soils.  相似文献   

17.
Biologically enhanced dissolution offers a method to speed removal of chlorinated solvent dense non-aqueous-phase liquid (DNAPL) sources such as tetrachloroethene (PCE) and trichoroethene (TCE) from aquifers. Bioremediation is accomplished by adding an electron donor to the source zone where fermentation to intermediates leading to acetic acid and hydrogen results. The hydrogen and possibly acetic acid are used by dehalogenating bacteria to convert PCE and TCE to ethene and hydrochloric acid. Reductive dehalogenation is thus an acid forming process, and sufficient alkalinity must be present to maintain a near neutral pH. The bicarbonate alkalinity required to maintain pH above 6.5 is a function of the electron donor: 800 mg/L of bicarbonate alkalinity is sufficient to achieve about 1.2 mM TCE dechlorination with glucose, 1.7 mM with lactate, and a much higher 3.3 mM with formate. Laboratory studies indicate that in mixed culture, formate can be used as an electron donor for complete conversion to ethene, contrary to pure cultures studies indicating it cannot. Various strategies can be used to add electron donor to an aquifer for DNAPL dehalogenation while minimizing pH problems and excessive electron donor usage, including use of injection-extraction wells, dual recirculation wells, and nested injection-extraction wells.  相似文献   

18.
Staff members of the Department of Botany of Palacký University in Olomouc and Gene Bank Department – Workplace Olomouc, Research Institute of Crop Production in Prague, Czech Republic, conducted an expedition in seven European countries (Austria, Czech Republic, France, Germany, Italy, the Netherlands, Switzerland) in August/September 1999 to collect wild Lactuca spp. germplasm and study its geographic distribution, ecology and biodiversity. During the mission, more than 600 locations were visited resulting in the collection of 602 seed samples (accessions) of wild Lactuca species and 13 seed samples of related genera (Chondrilla and Mycelis). Lactuca serriola f. serriola, L. serriola f. integrifolia, L. saligna and L. viminea subsp. chondrilliflora were prevalent in southern Europe (Italy, France), however, only L. serriola was common in central and western Europe (Austria, Czech Republic, Germany, Netherlands, Switzerland). The greatest diversity of Lactuca species was found in France, where also the most seed samples (165) were collected. The most characteristic habitats with a high density of Lactuca spp. populations were observed along roads and highways, grassy ditches, ruderal communities, and dust-heaps. Natural infections by powdery mildew (Erysiphe cichoracearum) and downy mildew (Bremia lactucae) on some wild Lactuca spp. were observed. Recent observations concerning the geographic distribution, population structure, habitats, and natural occurrence of diseases of Lactuca spp. are discussed. This assemblage of genetic resources of Lactuca spp. can serve as the basis of future studies of species diversification, spatial population structure, plant microevolution, domestication processes, and genetic variability of host-parasite interactions.  相似文献   

19.
Inoculation of wheat seedlings with the plant growth-promoting bacterium Azospirillum brasilense Cd was immobilized in alginate microbeads and, without applying any stress, significantly increased the quantity of several photosynthetic pigments, such as chlorophyll a, chlorophyll b, and the auxiliary photoprotective pigments violaxanthin, zeaxanthin, antheroxanthin, lutein, neoxanthin, and β-carotene. This resulted in greener plants with no apparent visible stress. After monitoring the quantity of photosynthetic pigments for 4 weeks, we observed that inoculated plants had higher quantities of pigments in shoot and stem. The greatest difference in the quantity of all pigments between inoculated and noninoculated plants occurred in the first week of growth. Regardless of treatment, the quantity of pigments in stems was three to four times less than the quantity of these pigments in shoots. Application of Azospirillum, either as liquid inoculant or as alginate microbeads, did not alter the positive effect of the bacteria on pigment production or the positive response of the plants towards A. brasilense Cd inoculation.  相似文献   

20.
Three slow-growing legume trees used for desert reforestation and urban gardening in the Sonoran Desert of Northwestern Mexico and the Southwestern USA were evaluated whether their growth can be promoted by inoculation with plant growth-promoting bacteria (Azospirillum brasilense and Bacillus pumilus), unidentified arbuscular mycorrhizal (AM) fungi (mainly Glomus sp.), and supplementation with common compost under regular screenhouse cultivation common to these trees in nurseries. Mesquite amargo (Prosopis articulata) and yellow palo verde (Parkinsonia microphylla) had different positive responses to several of the parameters tested while blue palo verde (Parkinsonia florida) did not respond. Survival of all tree species was over 80% and survival of mesquite was almost 100% after 10 months of cultivation. Inoculation with growth-promoting microorganisms induced significant effects on the leaf gas exchange of these trees, measured as transpiration and diffusive resistance, when these trees were cultivated without water restrictions.  相似文献   

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