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1.
Terbacil (5-chloro-6-methyl-3-butyluracil) residues did not accumulate in peach orchard soil after seven consecutive annual spring applications of the herbicide at the rate of 4.5 kg/ha although carry-over of terbacil from year to year occurred. Terbacil was lost by degradation and leaching and the time required for a 50% decrease in surface soil concentration was 5–7 months in the sandy loam soil. The major part of the residues was found in the upper 15 cm of the soil profile and smaller amounts were detected to a depth of 60 cm. Terbacil leached readily in prepared columns of sandy loam soil in proportion to the amount of water added. The residual levels of terbacil in the orchard were phytotoxic to oats planted 3 years after the last application.  相似文献   

2.
Adsorption of simazine (2-chloro-4,6-bisethyl-amino-1,3,5-triazine) was 2.2–4 times greater than that of terbacil (5-chloro-6-methyl-3-t-butyl-uracil) in the same soils and adsorption of both herbicides was 2–4 times greater in the topsoils than subsoils. Adsorption was inversely correlated with herbicide movement in a thick-layer chromatography system. One year after application of 3 kg/ha to field plots, simazine residues were highest near the soil surface, whereas terbacil residues increased with soil depth in the sandy and sandy loam soils. Total residues recovered from the upper 25 cm of soils was 5% or less of the simazine originally applied, and 10% or less of the applied terbacil. In an oat seedling bio-assay, the GR50 values were generally 1.5–3 times higher for simazine than for terbacil in the same soils.  相似文献   

3.
The movement and persistence of imazaquin, oxyfluorfen, flurochloridone and terbacil residues were studied using a bioassay based on the shoot growth of Raphanus sativus L. var, radicula DC (radish) in a sandy loam soil under field conditions in 1992 and 1993. Imazaquin (0.3 kg a.i. ha-1) was more mobile in the soil than the other three compounds. In 1992, under heavy rainfall conditions, the herbicide was distributed down to 60 cm in amounts of about 0.01 mg kg-1. Conversely, in the dry year of 1993, the maximum depth of penetration was 20 cm and persistence in the surface soil layer (0-5 cm) was greater. After the first month in 1992, residues of terbacil were distributed in the 0-20 cm layer, and after 2, 3 and 5 months the herbicide had penetrated to a depth of 40 cm. In 1993, terbacil residues were distributed in the 0-10 cm layer only. In both years, residues of flurochloridone (1.0 kg a.i. ha-1) were located mainly in the 0-5 cm layer, but there was some penetration to 10 cm. Oxy-fluorfen (1.2 kg a.i, ha-1) showed least mobility in the soil profile. It was retained in the 0-5 cm layer throughout the experimental period in both. years.  相似文献   

4.
Chlorpropham, propyzamide and trifluralin were assessed in several trials, to test their potential for the control of groundkeeper potatoes (Solanum tuberosum L.). Chlorpropham was insufficiently active, but trifluralin and propyzamide at doses of 4 kg a.i./ha, or more, reduced and delayed the emergence of potato plants in the summer, after autumn/winter or spring applications. The highest dose (12 kg a.i./ha) prevented many tubers producing plants. Greatest activity was attained when the herbicides completely surrounded the tubers when active growth started in the spring. However, both residue and crop tolerance data indicated that the doses of trifluralin and propyzamide required to control the potatoes were so high that appreciable residues remained in the following summer. These damaged vegetable crops drilled in April and May, and affected cereals planted 12 months after application. Thus there is insufficient margin of selectivity between the doses required to control the potatoes and those tolerated by subsequent crops.  相似文献   

5.
J. L. BROCK 《Weed Research》1972,12(2):144-149
Summary. Two trials comparing grass control by trifluralin and carbetamide in autumn-sown legumes ( Trifolium subterraneum L., T. pratense L., T. repens L., T. dubium L. and Lotus pedunculatus Cav.) were conducted. Trifluralin was used pre-sowing and carbetamide both pre-sowing and post-emergence.
Both herbicides gave good control of Lolium perenne L. and Poa annua L. at rates of 0·5 and 1·0 kg/ha a.i. for trifluralin and carbetamide respectively. Carbetamide showed no toxicity to any of the legumes up to 2·0 kg/ha except for Lotus pedunculatus at that rate, whereas trifluralin was toxic to all species at 2·0 kg/ha. Neither herbicide controlled broad-leaved weeds.
The results are discussed in terms of the effects of soil fertility, plant age and maturity on the activity of these herbicides.
La lutte contre les graminées adventices avec la trifluraline et le carbétamide dans les légumineuses récemment semées  相似文献   

6.
The persistence of dichlobenil following the application of dichlobenil granules was studied in a replicated plot experiment including both surface and incorporated treatments of 8·3 and 16·6 kg/ha ai. Soil analyses showed an initial half-life of about 4 weeks but the persistence increased with time and a year after application the half-life was about 1 year. Incorporation of the granules into the soil markedly increased the persistence of dichlobenil and its metabolite dichlorobenzamide. The most sensitive crop was carrot which was damaged by residues of only 1–2% of the recommended dose. Residues phytotoxic to carrots persisted for 2 years from the 8·3 kg/ha surface application and 5 years from the 18·6 kg/ha incorporated application. Lettuce was also highly sensitive to residues.  相似文献   

7.
Abstract

Results are given of a trial in which trifluralin, incorporated in the soil, at rates of 0.5 and 0.75 kg/ha, was combined with fluometuron at 1.6 kg/ha, and with prometryne at 1.0 kg/ha, both incorporated, pre- and post-em. and with noruron + MSMA (1.0:2.2) at 1.7 kg/ha post-em.

Best results were given by incorporated treatments of trifluralin + fluometuron (0.5 + 1.6) kg/ha, or by trifluralin incorporated at 0.5 or 0.75 kg/ha + fluometuron applied pre-em. at 1.6 kg/ha, or by trifluralin incorported at 0.75 kg/ha + prometryne applied pre-em. at 1.0 kg/ha.

It is recommended that noruron + MSMA (1.0:2.2) at 1.7 kg/ha be applied post-em. as a complementary treatment to trifluralin at 0.5 kg/ha in fields where Cyperus spp. are a problem.  相似文献   

8.
The persistence of [14C]2,4-D at a rate equivalent to 1 kg/ha was studied in the laboratory on a heavy clay and a sandy loam at 85%of field capacity and 20°C both alone and in the presence of 1 kg/ha dicamba, dichlorprop, difenzoquat, TCA, and 2,4,5-T. The persistence of 2,4,5-T was also monitored in both soils under the same conditions in the presence and absence of [14C]2,4-D. All soils were extracted at weekly intervals using aqueous acidic acetonitrile and analysed for [14C]2,4-D remainining radiochemical techniques. The extracts containing 2,4.5-T were additionally analysed gas chromatographically for that herbicide. In each soil type the half-life of the 2,4-D was similar regardless of whether applied singly or in combination with the five herbicides tested. Similarly, [14C]2,4-D did not affect the breakdown of 2,4,5-T in either soil type. The persistence of tri-allate (1·5 kg/ha) and trifluralin (0·75 kg/ha) both singly and in combination were compared using small field plots at two locations in Saskatchewan. Applications were made during May of 1977 and 1978 and the plots were sampled and analysed for herbicide(s) remaining after 10 and 20 weeks, respectively. The results indicate that within experimental error the loss of both tri-allate and trifluralin from the plots treated with the mixture was the same as from plots treated with the individual compounds.  相似文献   

9.
Glasshouse studies showed that low doses of paraquat inhibited the germination of Lolium perenne L. broadcast directly onto the paraquat-sprayed surfaces of a sphagnum and a peat soil, but that higher doses were necessary to produce phytotoxic symptoms on mineral soils, a compost and a loam. On all soils residual activity increased rapidly with increasing dose once the minimum phytotoxic dose was reached. On a sandy soil, residual activity increased almost linearly from the lowest to the highest dose applied. At 9·0, 4·5 and 2·24 kg/ha phytotoxicity on a compost was not affected by changes in the volume of application, but at 1·68 kg/ha and lower, reducing the volume from 562 1/ha to 281 and 112 1/ha resulted in increased phytotoxicity. Phytotoxic residues were eluted from paraquat-treated compost surfaces by percolating de-ionized water up soil columns but residual activity was not removed from the eluted surfaces. Surface irrigation of paraquat-treated surfaces with water previously percolated through columns of untreated soil reduced residual activity by 45%.  相似文献   

10.
The persistence of [14C] 2,4-D at a rate equivalent to 1 kg/ha was compared under laboratory conditions in samples of heavy clay, sandy loam, and clay loam at 85% of field capacity moisture and 20 ± 1°C which had either received no pre-treatment, or had been pre-treated for 7 days at the 2 μg/g level with the herbicides benzoylprop-ethyl, diclofop-methyl, dinitramine, flamprop-methyl, nitrofen, picloram, tri-allate, trifluralin, and a combination of tri-allate and trifluralin. The breakdown of [14C] 2,4-D was also studied in the same soils that had similarly received pre-treatments of 2 μg/g of the cereal seed dressing Vitaflo-DB, the insecticide, malathion, and a combination of Vitaflo-DB and malathion. In each soil type, the half-life of the 2,4-D was similar regardless of whether the soil had, or had not, received any pre-treatment, indicating that none of the chemicals investigated adversely affected the soil degradation of 2,4-D.  相似文献   

11.
An investigation of the persistence of trifluralin was conducted as field experiments over a two year period at latitudes 60°N and 70°N respectively, paying special attention to the soil and climatic conditions. These experiments included glasshouse bioassays with Lolium multiflorum. gas-chromatographic residue analyses and qualitative and quantitative studies on soil bacteria. Special attention was devoted to clay minerals as well as to the soil organic matter. 100 g or 500 g of trifluralin a.i. ha?1 were applied in the spring 1978 with a reapplication on half of the area the following spring (1979). The phytotoxicity of trifluralin appeared more severe on re-treated plots compared with single applications even at approximately equal residue levels. Trifluralin did not seem to have any real influence on the total number of soil bacteria. A qualitative change of the bacterial flora was however observed as a relative increase of non-sporeformers, Gram negatives and Actinomy-cetes and a relative depression of the Coryneform bacteria/Arthrobacter group. Even at a recommended dosage, a carry-over phytotoxicity the following year may occur, especially when the content of organic matter in the soil is low. Care should therefore be taken when using this herbicide on the same field in two successive years. The properties of the soil seemed to exert a greater influence than the climatic factors on the persistence of trifluralin.  相似文献   

12.
BACKGROUND: Pesticides used on cauliflower and cabbage, which are important vegetable crops for India, must be investigated for the persistence and magnitude of their residues in the crops and soil to ensure human and environmental safety. The behaviour of spinosad, an effective insecticide with a favourable environmental profile, was investigated in field trials under subhumid and subtropical conditions. RESULTS: The persistence of spinosad in soil, cabbage and cauliflower was evaluated at two application rates (17.5 and 35.0 g ha(-1)) by high-performance liquid chromatography (HPLC). At 17.5 g ha(-1), spinosad persisted up to 7 days in soil, cabbage and cauliflower. However, at 35.0 g ha(-1), spinosad residues persisted up to 7 days in soil and 10 days in cabbage and cauliflower. CONCLUSION: The dissipation of the insecticide from soil, cabbage and cauliflower appeared to occur in a single phase and conformed to first-order kinetics. The half-lives of spinosad residues in cabbage, cauliflower and soil were calculated as 1.5, 2.8 and 2.8 days respectively for the 17.5 g ha(-1) treatment, and as 2.6, 2.0 and 2.0 days for the 35 g ha(-1) treatment.  相似文献   

13.
Soil incorporated. pre-sowing application of trifiuralin in cotton or of benfluralin in gruundnut, each at 1–68 kg a.i., ha, cut labour requirement for handweeding to levels where the tenant could he largely independent of hired labour, Economic returns from a combination of these herbicides plus supportive hand- weeding for herbicide-resistant species compared favourably with those from hand- weeding only as presently recommended. Application and incorporation of trifluralin and benfluralin fited well into existing practices for seedbed preparation and any likely modifications of these. There was no evidence of crop phytoxicity and crop maturity was not affected. Residue analysis indicated no soil residue problems for crops in rotations and no residues were detected in crop seed. Trifluralin applied many months in advance of cotton planting in the dry season, did not start to disappear until the soils were wetted just before couon planting.  相似文献   

14.
Ten herbicides, bromacil, chlorthal-dimethyl, diphenamid, diuron, fluometuron, neburon, prometryne, pyrazon, simazine and trifluralin at two doses were repeatedly sprayed, in autumn and in spring, for 4 consecutive years on non-cultivated, sprinkler-irrigated field plots. Herbicidal effect was assessed at 1–2 month intervals on the natural weed population and after each observation a paraquat + diquat spray destroyed emerged weeds. The response of various weed species to herbicides varied markedly but a herbicide-induced shift in the composition of weed population did not occur, presumably because of the paraquat treatment. The overall phytotoxicity to weeds present was, in decreasing order: diuron, bromacil, simazine, trifluralin, prometryne, neburon, fluometuron, pyrazon, diphenamid, chlorthal-dimethyl. Persistence of herbicides was in decreasing order: diuron = bromacil, simazine, neburon (at higher rate), fluometuron, trifluralin, prometryne. Control produced by pyrazon improved with the number of applications, but that of diphenamid and chlorthal-dimethyl remained weak and short. After repeated applications, the activity of these herbicides increased or remained at similar level, but in no case decreased. Soil samples were taken 5 months after each application and bioassayed. Phytotoxic residues were detected beneath the disturbed top-soil from bromacil, diuron, fluometuron and simazine after the first application, and from neburon after the second application; residues from trifluralin were found in the top soil only after the fifth application. After the seventh spraying, residues of bromacil were found in the 45–60-cm soil layer. Ammonia content in soil samples taken from treated plots after the fourth, sixth and seventh application was generally similar to the untreated control. In these samples, nitrate content appeared to be correlated negatively with remaining weed number; the control thus contained less nitrate than efficient herbicidal treatments. Soil samples taken after the seventh application of bromacil, diuron, fluometuron, neburon and simazine, which contained appreciable residual concentrations, did not show significant differences from control, in an in vitro nitrification test.  相似文献   

15.
Field experiments at Lacombe on a Ponoka loam soil (9·6% organic matter) during 1982 and 1983 investigated the tolerance of spring wheat (Triticum aestivum L.) cv. Neepawa in a weed free situation to trifluralin applied at 0·0–3·0 kg ai ha?1 in the autumn or spring and incorporated to a depth of 10 cm. Rates of trifluralin above 1·0 kg ai ha?1 applied in the autumn or spring reduced the percent stand of wheat compared to an untreated control. Two weeks after emergence the crop showed 37 or 47% injury indicated by delayed growth, following application at 1·0 kg ai ha?1 in the autumn or spring, respectively. The wheat recovered throughout the course of the growing season. At harvest, trifluralin applied in the autumn or spring at rates below 1·0 kg ai ha?1 caused a yield increase while higher rates caused a yield decrease compared to the untreated control. Spring application caused a greater yield loss than autumn application. The tolerance of spring wheat to trifluralin at rates required for weed control (1·1 kg ai ha?1 or higher) on this soil type is marginal.  相似文献   

16.
Effects of glyphosate, paraquat, trifluralin and atrazine on activities of dehydrogenase, phosphatase and urease in one soil were measured. Only glyphosate at 21.6 kg/ha was found to inhibit the enzyme activities and generally the results were not statistically significant. Enzyme activity associated with micro-organisms proliferating in soil supplemented with lucerne meal was similarly not affected by the herbicides. Interpretation of results from enzyme activity measurements in soils treated with herbicides is discussed. It is proposed that effects of natural stress can be used to judge the relative importance of herbicide induced change.  相似文献   

17.
Abstract

V.I.v. captafol spray treatments applied using a 1.8m swath (3.3 kg a.i./ha/application) were more effective than treatments using a 3.6 m swath (1.67 kg a.i./ha/application). At sites with more than 700 mm rainfall during the crop's field life weekly applications were more effective than spraying at 10- and 14-day intervals, but at the drier sites (< 650 mm rainfall) spraying at 10 days was adequate.  相似文献   

18.
Granular formulations of chlorfenvinphos, chlormephos, disulfoton, phorate and pirimiphos-ethyl were broadcast at 2 kg a.i./ha and incorporated to 100 mm into a sandy-loam soil either in May or in September 1971. The relative persistence of their residues, including insecticidally active oxidation products, after both application dates was disulfoton > chlorfenvinphos > phorate > pirimiphos-ethyl > chlormephos. When applied in September all the insecticides persisted for longer than when applied in May. Degradation was slower during the winter while the mean soil temperature at 100 mm depth remained below 6 to 7°C. Rising soil temperature in the following spring rapidly increased the rates of degradation of chlorfenvinphos, chlormephos and pirimiphos-ethyl residues but not of disulfoton- and phorate-derived residues, predominantly the parent sulphones, which had been leached deeper. Ten months after the September application, half the total residues derived from disulfoton and phorate were found below the initial incorporation depth, whereas the other insecticides showed relatively little downward movement. It was concluded that late summer/early autumn applications for carrot fly control would leave appreciable residues of some insecticides in the soil at the beginning of the next growing season which may contribute to the terminal residues in crops. These would be minimised if moderately persistent compounds were used or if doses of persistent ones were substantially reduced.  相似文献   

19.
Blackgrass (Alopecurus myosuroides Huds.) was controlled by 2 kg/ha of metoxuron in glasshouse trials while winter wheat, cultivar Cappelle Desprez, tolerated 4 kg/ha. Blackgrass was controlled by 1.2 kg/ha of chlortoluron. Winter wheat previously damaged by freezing was injured by 2.5 kg/ha of chlortoluron applied at an early stage. Seedlings not exposed to freezing were not damaged by 2.5 kg/ha applied at the 4- and 5-leaf stage. Breakdown of chlortoluron and metoxuron in the soil was attributed, in part, to microbial action. More than one-third of the chlortoluron applied at 2 kg/ha disappeared in 6 weeks when applied in early spring while one half disappeared in 3 weeks when applied 2 months later. The bioassay, used to determine the amount of chlortoluron or metoxuron in the soil, was found to be adequate for metoxuron in only one of three soils. The bioassay results, for both herbicides, were affected by the addition of calcium carbonate to the soil, by sterilization of the soil, and by leaching. In comparisons of results in two sandy loams and a clay loam, the observed differences could not be altogether accounted for by differences in pH nor by changes in adsorption of metoxuron. When perennial ryegrass was grown in sandy loam, and treated with metoxuron before or after emergence, different watering regimes did not give any difference in weight of top growth.  相似文献   

20.
J. L. BROCK 《Weed Research》1972,12(2):150-154
Summary. The effects of pre-sowing incorporated applications of trifluralin and carbetamide on the growth and nodulation of Trifolium pratense L., T. repens L., T. dubium L. and Lotus pedunculatus Cav. were examined. At rates of 1·0 and 2·0 kg/ha a.i. of trifluralin and carbetamide respectively, nodulation and growth of all legumes was reduced. Root dry weight/plant and nodules/plant were positively correlated, suggesting that the herbicides affected plant growth but not the soil rhizobial population. There were several herbicide rate × legume species interactions.
Effets des herbicides trifluraline et carbétamide sur la formation de nodosités et la croissance des plantules de légumineuses  相似文献   

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