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1.
This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in subtropical China. 1)1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nm mineral in red soil and yellow soil is mainly 1.4-nm intergrade mineral, and in acidic yellow-brown soil (pH < 5.5) is vermiculite alone or 1.4-nm intergrade mineral together with vermiculite. The distribution and the content of 1.4-nm intergrade mineral in the mountain soils are more widespread and higher than those of the corresponding soils in horizontal zone. 2) The interlayer material of 1.4-nm intergrade mineral in these soils appears to be hydroxy-A1 polymers instead of hydroxy-Fe, proto-imogolite or kaolin-like material. There is a significant positive correlation between A1 amount extracted from the soil with sodium citrate after DCB extraction and pH value of the citrate solution after the extraction. The citrate can also extract a certain amount of silicon from the soil, but the silicon may not come from interlayer of 1.4-nm intergrade mineral. 3) It was seldom studied that either vermiculite or smectite did the natural 1.4-nm intergrade mineral come from in soil, or it was commonly thought to come from vermiculite. A recent report has revealed that it can come from smectite. There are some different behaviors between the 1.4-nm intergrade mineral derived from vermiculite and that from smectite. For example, they exert different influences on the formation of gibbsite. The 1.4-nm intergrade mineral derived from smectite may promote the formation of gibbsite in the yellow soil. 4) The type of 1.4-nm minerals in soils. i.e., vermiculite or 1.4-nm intergrade mineral, may be significant to soil properties, such as soil acidity, exchangeable Al, electric charge amount and specific surface area. Therefore, the management for the soil in which 1.4-nm mineral is mainly 1.4-nm intergrade mineral or vermiculite should be dealt with differently.  相似文献   

2.
The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evolution.Montmorillonite was found in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit,and some lateritic red soil,red soil and yellow soil with a low weathering degree.Chlorite existed mainly in coastal solonchak and paddy soil developed from marine deposit.1.4nm intergradient mineral appeared frequently in yellow soil,red soil and lateritic red soil.The content of 1.4nm intergradient mineral increased with the decrease of weathering degree from lateritic red soil to red soil to yellow soil.Hydrous micas were more in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit.and puple soil from purple shale than in other soils.Kaolinte was the most important clay mineral in the soils iun this province.The higher the soil weathering degree,the more the kaolinite existed.From yellow soil to red soil to lateritic red soil,kaolinite increased gradually,Kaolinite was the predominant clay mineral accompanied by few other minerals in typical lateritic red soil. Tubular halloysite was a widespread clay mineral in soils of Fujian Province with varying quantities.The soil derived from the paent rocks rich in feldspar contained more tubular halloysite.Spheroidal halloysite was found in a red soil and a paddy soil developed from olivine basalt gibbsite in the soils in this district was largely“primary gibbsite” which formed in the early weathering stage.Gibbsite decreased with the increase of weathering degree from yellow soil to red soil to lateritic red soil.Goethite also decreased in the same sequence while hematite increased.  相似文献   

3.
Mineral Composition and Weathering of Soils Derived from Xiashu Loess   总被引:1,自引:0,他引:1  
Mineralogical, physical and chemical analyses of the soils derived from Xiashu loess were carried out. The primary minerals of these soils were found to be mainly composed of light minerals, such as quartz, feldspar and mica, with traces of heavy minerals. Clay minerals, more complicate in composition, were dominated by hydromica, accompanied by smectite, vermiculite, chlorite, kaolinite, 2:1/1:1 randomly interstratified minerals and small amounts of quartz, goethite, lepidocrocite and hematite, Clay minerals were characterized by low crystallinity and fine particle size. In light of the quartz/feldspars ratio of the 0.01-0.05mm silt fraction, and the clay mineral composition, the freeness of iron oxide, and the silica/sesquioxide and silica/alumina ratios in < 0.002mm clay fraction, it is concluded that the weathering intensity of these soils was lower than those of red soil and yellow earth, but higher than that of brown earth, and that the soil allitization, depotassication and hydroxylation of cl  相似文献   

4.
YE Wei  WEN Qi-Xiao 《土壤圈》1996,6(2):121-128
Chemical characteristics of humic substances in soils with different mineralogical characteristics and under different utilization paterns in Zhangpu,Fujian Province,together with two pairs of cultivated soils in North China Plain were studied by chemical analysis,visible and IR spectroscopy and ^13C NMR spectrometry.For soils in Zhanpu the HA/FA ratio and both the aromaticity and the degree of humification of HA were higher in soils with montmorillonite as the predominant clay mineral than in those with kaolinite as the predominant clay mineral,provided these soils were under the same utilization pattern.While for each pair of soils with similar mineralogical characteristics the HA/FA ratio was higher and the C/H ratio and the contnet of carboxyl group of HA were lower in paddy soil than in upland soil.Among the upland soils(or paddy soils)studied the Ha/FA ratio of soil in Zhangpu with kaolinite as the predominant clay mineral was the lowest,and that of soil in Zhangpu with montmorillonite as the predominant clay mineral was the highest .the lowest.and that of soil in Zhangpu with montmorillonite as the predominant clay mineral was the highest It was concluded that the presence of montmorillonite favored the fromation and maturation of humic acid.  相似文献   

5.
The particle-size distribution and mineralogical composition of the clay (< 2 μm) and fine-sand (0.25--0.10 mm) fractions in soils of two inland valleys in Abakaliki and Bende, Southeast Nigeria, were investigated to provide basic information on soil-forming processes and agricultural potentials. These soils were silty or clayey, deriving from Cretaceous or Tertiary shale materials. The particle-size distribution and its computation on a clay-free basis revealed relatively remarkable lithologic breaks in a couple of pedons. The effect of lithologic discontinuities on soil mineralogical composition was not, however, conspicuous. Petrographic investigation revealed that quartz predominantly comprised the fine-sand fraction in the soils at both study sites. Nevertheless, the clay mineralogical composition of the soils was a mixture of kaolinite, irregularly interstratified smectite-illite intergrades (S/I), hydroxyl-Al interlayered 2:1 type clays (HICs), vermiculite, smectite, halloysite and illite along with fine-sized quartz in Abakaliki. The soils of Bende predominantly contained smectite, which was partially interlayered with hydroxyl-Al and kaolinite. It is suggested that seasonal floodwater has slowed the disintegration of weatherable clay minerals inherited from the shale, while quartz originating from the sandstone is predominant in the fine-sand fraction. Additionally, a possible soil-forming process observed at the both study sites was ferrolysis, which was indicated by a clear decreasing pattern of HICs downward in the soil profiles. The entry of S/I and vertical distribution patterns for a couple of clay minerals in the pedon suggested that the soils in Abakaliki have developed under the significant influence of aeolian dust delivered by the harmattan. The findings might describe a site-specific deposition pattern of harmattan dusts as well as hydromorphic soil-forming processes in the wetlands of the inland valleys.  相似文献   

6.
A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation (SFI), and to study the leaching loss and transformation of three kinds of nitrogen fertilizers (nitrate fertilizer, ammonium fertilizer, and urea fertilizer) in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N (NH4+-N + NO3--N) in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control (without urea addition), on the first day when soils were fertigated with urea, there were increases in NH4+-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4+-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4+-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4+-N fixation or volatilization in the soil during the fertigation process.  相似文献   

7.
SUN BO  LIN XIN-XIONG 《土壤圈》1993,3(2):133-144
Decomposition experiments of ^14C-labelled sickle alfalfa in chao soils of different texture and these soils after removal of CaCO3 were carried out under field and laboratory conditions respectively.The amount of residual ^14C in,or ^14CO2 evolved from,the soils at intervals after the beginning of devomposition were measured and the distribution of native and labelled C between particle size fractions isolated from these soils was edtermined.Results showed that contents of both labelled (^14C) and non-labelled (^12C) carbon decreased with increasing particle size.The enrichment factor for ^14C was higher than that for ^12C in the clay fraction,the reverse being true for the silt enrichment factors.The effect of soil texture on the decomposition of plant material could not be observed in chao soils when the clay content was lower than 270g kg^-1,while it became obvious once CaCO3 was removed was correlated from these soils.The decomposition rate of plant material in the soil from which the native CaCO3 Was removed was correlated significantly to both the clay content of the soil and the application rate of CaCO3.A preliminary correction equation describing the effect of clay and CaCO3 on the decomposition of organic material in chao soil was derived from the results obtained.  相似文献   

8.
Little information is available on the interactive effects of inorganic and organic pollutants on carbon utilization by soil microorganisms.This study examined the effects of two common soil pollutants,lead (Pb) and bensulfuron-methyl herbicide (BSM),on decomposition of an adscititious carbon source (14C-glucose).Two contrasting paddy soils,a silty clay soil and a clay loam soil,were incubated with different concentrations and combinations of pollutants for 60 days.Orthogonal rotatable central composite design was adopted to design the combinations of the pollutant concentrations so that rate response curves could be derived.Rapid decomposition of 14C-glucose occurred in the first three days for both soils where no Pb or BSM was added (control).Overall,63%-64% of the added 14C-glucose was decomposed in the control over the 60-day incubation.The addition of Pb or BSM significantly decreased the decomposition of 14C-glucose during the first week but increased the decomposition thereafter;as a result,the percentages of 14C-glucose decomposed (57%-77%) over the 60-day period were similar to or higher than those of the control.Application of the pollutants in combination did not further inhibit decomposition compared with the control.Overall,decomposition rates were lower in the silty clay soil than in the clay loam soil,which was related to the soil texture,cation exchange capacity,and pH.The relationship between the decomposition rates and the pollutants could be well characterized by the quadratic regression orthogonal rotation model.The initial antagonistic effects of the pollutants followed by the synergistic effects on microbial activity might result from changes of the concentrations of the pollutants.  相似文献   

9.
Mineral constituents and their weathering in yellow-red soils derived from granite in middle and lower reaches of the Yangtze R iver were studied. Light minerals in fractions greater than silt contained over 80% quartz and feldspar, and heavy ones contained more than 60% various iron minerals and about 30% mica and hornblende. Kaolinite was the main clay mineral, the content of which was about 300 -400 g/kg. Quartz was weathered very weakly, Ca-feldspar was weathered over 65%, and about 25% of Na-feldspar was weathered. The vermiculitisation of mica was relativly obvious, > 50% of mica being weathered to vermiculite. Weatherable minerals were also obviously weathered, the weathering being about 60%. Soil vermiculite was evolved through the process of mica→hydromica→vermiculite-chlorite→vermiculite, which was closely related to leaching situation and oxidic condition.  相似文献   

10.
土壤矿物吸附和土壤团聚体对土壤有机碳含量的影响研究   总被引:3,自引:1,他引:2  
Soil organic carbon (SOC) can act as a sink or source of atmospheric carbon dioxide; therefore, it is important to understand the amount and composition of SOC in terrestrial ecosystems, the spatial variation in SOC, and the underlying mechanisms that stabilize SOC. In this study, density fractionation and acid hydrolysis were used to assess the spatial variation in SOC, the heavy fraction of organic carbon (HFOC), and the resistant organic carbon (ROC) in soils of the southern Hulunbeier region, northeastern China, and to identify the major factors that contribute to this variation. The results showed that as the contents of clay and silt particles (0--50 μm) increased, both methylene blue (MB) adsorption by soil minerals and microaggregate contents increased in the 0--20 and 20--40 cm soil layers (P < 0.05). Although varying with vegetation types, SOC, HFOC, and ROC contents increased significantly with the content of clay and silt particles, MB adsorption by soil minerals, and microaggregate content (P < 0.05), suggesting that soil texture, the MB adsorption by soil minerals and microaggregate abundance might be important factors influencing the spatial heterogeneity of carbon contents in soils of the southern Hulunbeier region.  相似文献   

11.
绰墩遗址古今水稻土黏土矿物特征比较研究   总被引:4,自引:2,他引:2  
程月琴  杨林章  曹志洪 《土壤》2011,43(4):617-622
在江苏绰墩山遗址考古发掘中,发现了在剖面不同深度埋藏的距今约6000年的史前水稻土层、距今约3 000年的商周史前的古水稻土层和现代水稻土层.本研究为了比较古今水稻土黏土矿物特征的差异,以土壤剖面P01(包含史前古水稻土、商周史古水稻土和现代水稻土)与P03(仅含商周时期古水稻土和现代水稻土)为对象,测定其各种形态铁锰...  相似文献   

12.
As a consequence of global warming, additional areas will become ice-free and subject to weathering and soil formation. The most evident soil changes in the Alps will occur in proglacial areas where young soils will continuously develop due to glacier retreat. Little is known about the initial stages of weathering and soil formation, i.e. during the first decades of soil genesis. In this study, we investigated clay minerals formation during a time span 0-150 years in the proglacial area of Morteratsch (Swiss Alps). The soils developed on granitic till and were Lithic Leptosols.Mineralogical measurements of the clay (< 2 μm) and fine silt fraction (2-32 μm) were carried out using XRD (X-ray Diffraction) and DRIFT (Diffuse Reflectance Infrared Fourier Transform). Fast formation and transformation mechanisms were measured in the clay fraction. The decreasing proportion of trioctahedral phases with time confirmed active chemical weathering. Since the start of soil formation, smectite was actively formed. Some smectite (low charge) and vermiculite (high charge) was however already present in the parent material. Main source of smectite formation was biotite, hornblende and probably plagioclase. Furthermore, irregularly and regularly interstratified clay minerals (mica-HIV or mica-vermiculite) were formed immediately after the start of moraine exposure to weathering. In addition, hydroxy-interlayered smectite (HIS) as a transitory weathering product from mica to smectite was detected. Furthermore, since the start of soil evolution, kaolinite was progressively formed. In the silt fraction, only little changes could be detected; i.e. some formation of an interstratified mica-HIV or mica-vermiculite phase.The detected clay mineral formation and transformation mechanisms within this short time span confirmed the high reactivity of freshly exposed sediments, even in a cryic environment.  相似文献   

13.
对太湖平原地区高产的黄泥土型水稻土的全土(<1毫米)及7个粒级(1—0.25,0.25—0.05,0.05—0.01,0.01—0.005,0.005—0.002,0.002—0.001和<0.001毫米)共8个土样,进行测定。结果表明:黄泥土粘粒部分(<0.002毫米)的粘土矿物,主要由水云母、高岭和蒙脱组成。粗粘粒级(0.002—0.001毫米)和细粘粒级(<0.001毫米)中粘土矿物的分配有明显差异;砂粒级(1—0.05毫米)中除了主要的石英外,还含有少量“铁锰砂”,所以该粒级中的SiO2含量较粉粒级(0.05—0.002毫米)的低,而Fe2O3的含量则相反,容积磁化率也较高;可塑性和膨胀性都是在<0.002毫米时才始现。上述特点与作者过去所研究的白土型水稻土类似。但是,与国内外报道的几种旱地土壤的资料有所不同。  相似文献   

14.
The mineralogical composition of agrogray, dark gray, and agro-dark gray soils (Luvic Greyzemic Retic Phaeozems); agro-dark gray residual-calcareous soils (Calcaric Cambic Phaeozems); clay-illuvial agrochernozems (Luvic Chernic Phaeozems); and agrochernozems with migrational–mycelial carbonates (Haplic Chernozems) developed in the forest-steppe of Central Siberia within the Irkutsk Depression has been studied. The clay (<1 μm) fraction separated from these soils consists of mixed-layer minerals with alternating layers of hydromica, smectite, vermiculite, and chlorite; the proportions between them change within the soil profiles. The clay fraction also contains hydromicas, kaolinite, chlorite, and some admixture of the fine-dispersed quartz. Each type of the soils is characterized by its own distribution pattern of clay material with specific alternation of layers in the mixed-layer formations. Mixed-layer minerals of the chlorite–vermiculite type predominate in the upper horizons of texture-differentiated soils. Down the soil profile, the content of mixed-layer mica–smectitic minerals increases. In the clay fraction of arable dark gray-humus soils with residual carbonates, the distribution of the clay fraction and major mineral phases in the soil profile is relatively even. An increased content of well-crystallized kaolinite is typical of these soils. The parent material of agrochernozems has a layered character: the upper horizons are generally depleted of clay, and the middle-profile and lower horizons are characterized by the considerable kaolinite content. In general, the clay material of soils of the Tulun–Irkutsk forest-steppe differs considerably from the clay material of foreststeppe soils developed from loesslike and mantle loams in the European part of Russia. In particular, this difference is seen in the proportions between major mineral phases and between biotitic and muscovitic components, as well as in the degree of crystallinity and behavior of kaolinite and chlorite.  相似文献   

15.
辽宁省西部是低山丘陵区,年平均温度7.1℃,年平均降雨量400—500毫米,降雨集中在夏季,具有明显的大陆性气候特征,干燥度小于1,属半干旱类型.植被为油松柞木和草原灌木丛林.土壤属棕色森林土向栗钙土过渡的褐土地带.母质主要为花岗片麻岩风化物.山麓缓坡和河谷两岸为黄土丘陵.在黄土沉积物覆盖层下,常见红色风化壳露头,即红色粘土层.此外,并有松软易风化岩层,如砂岩、页岩和变质岩等.本区近百年来,由于自然植被受到严重破坏,大量水土流失,土壤侵蚀严重,土壤有机质含量低,成为辽宁省的低产区.因此,鉴定本区不同母质的土壤矿物胶体组成及其特征,不仅可以研究这一特定自然条件下土壤矿物的转化和形成,并且有助于了解土壤特性和肥力特征.  相似文献   

16.
Chemical and mineralogical properties of a soil chronosequence in the high mountain zone between 3857 m and 4120 m a.s.l. in Central Nepal (Langtang valley) are presented. The soils have been developed in moraine deposits which consist of acid gneisses. They were classified as Entisols, and Spodosols. XRD analyses of the clay and fine silt fraction show increasing changes with distance from the recent Lirung glacier, depending on the time of deposition, resp. soil age. Alteration of illite to interstratified minerals and to hydroxy-Al interlayered minerals or pedogenic chlorite with increasing soil development could be observed. The interstratified minerals could be identified as random and regular illite-interlayered vermiculite mixed-layer minerals. Intensification of the X-ray signals of the fine silt fraction is given compared to the clay. With increasing soil development differences between the clay and fine silt fraction seem to increase. Indications are given of interstratification of the mica-pedogenic chlorite and chloriteinterlayered vermiculite type in the more intensively weathered soils.  相似文献   

17.
Properties and mineralogy of fine fractions separated from agrochernozems forming a three-component noncontrasting soil combination in the Kamennaya Steppe have been characterized. The soil cover consists of zooturbated (Haplic Chernozems (Clayic, Aric, Pachic, Calcaric)), migrational-mycelial (Haplic Chernozems (Clayic, Aric, Pachic)), and clay-illuvial (Luvic Chernozems (Clayic, Aric, Pachic)) agrochernozems. All the soils are deeply quasi-gleyed because of periodical groundwater rise. The mineralogy of the fraction <1μm includes irregular mica–smectite interstratifications, di- and trioctahedral hydromicas, imperfect kaolinite, and magnesium–iron chlorite. The profile distribution of these minerals slightly varies depending on the subtype of spot-forming soils. A uniform distribution of clay minerals is observed in zooturbated agrochernozem; a poorly manifested eluvial–illuvial distribution of the smectite phase is observed in the clay-illuvial agrochernozem. The fractions of fine (1–5 μm) and medium (5–10 μm) silt consist of quartz, micas, potassium feldspars, plagioclases, kaolinite, and chlorite. There is no dominant mineral, because the share of each mineral is lower than 35–45%. The silt fractions differ in the quartz-to-mica ratio. The medium silt fraction contains more quartz, and the fine silt fraction contains more micas.  相似文献   

18.
The mineralogies of ‘Tirs’ (Typic Pelloxererts), and ‘Debs’ (Typic Haploxerolls and Typic Xerochrepts) soils of the Gharb plain in north-western Morocco are investigated, with special attention given to the determination of the nature of the smectitic phase using the lithium test (Li test) and the alkylammonium method. The sand and silt mineralogy of Tirs soils is dominated by quartz with small amounts of feldspars and kaolinite. The sand and silt fractions of Dehs soils also contain significant amounts of mica, chlorite, and interstratified phyllosilicates. The clay minerals of Tirs soils are predominantly a high-charge smectite. The estimated interlayer charge for this phase is 0.61 mol(c)/O10(OH)2 and the fraction of tetrahedral charge varies from 38 to 44%. Although the percentage tetrahedral charge is less than 50%, the smectitic phase behaves as beidellite with the Li test. Dehs clays are more heterogeneous, consisting of smectite, vermiculite, illite, kaolinite, chlorite, and interstratified illite/smectite and illite/vermiculite. The Li test and the alkylammonium method demonstrate that a high-charge smectite or vermiculite is interstratified with illite. A low-charge montmorillonite is also present both in Tirs and in Dehs soils. The high-charge beidellitic phase is believed to be a transformation product of mica, whilst the low charge montmorillonite is thought to be inherited from the parent material.  相似文献   

19.
红壤水稻土肥力性状的演变特征   总被引:23,自引:0,他引:23  
大田条件下 ,通过选点采样分析 ,研究了不同利用年限红壤水稻土的物理、化学和生物学性质的动态变化特征。荒地红壤水耕利用后 ,土壤颗粒组成呈现规律性变化 ,粘粒 (<0 0 0 2mm)含量从荒地红壤的 3 9%下降到 80a稻田土壤的 1 7% ,而粉砂 (0 0 2~ 0 0 0 2mm)含量升高。土壤pH一般增加 0 5~ 1个单位 ;0~ 1 0cm土壤有机碳和全氮含量从荒地红壤的 4 5 8gkg- 1和 0 3 9gkg- 1增加到 3 0a红壤稻田的1 9 6gkg- 1和 1 62gkg- 1,其后 ,即使利用时间长达 80a ,土壤有机碳和全氮含量并没有显著差异 ;土壤全磷含量 ,经 3a水耕利用后可从荒地红壤的 0 5gkg- 1提高到 1 3gkg- 1,表明通过施肥可使红壤磷素快速积累 ;而在水耕利用过程中 ,红壤稻田土壤的钾素含量呈下降趋势 ,经 80a利用的红壤稻田 ,0~ 1 0cm土壤钾素含量仅为荒地红壤的 80 % ;全铁和游离铁的含量也呈下降趋势。随着水耕熟化过程 ,细菌数量和脲酶活性也明显升高。不同利用年限红壤稻田土壤的各项性状指标的变化结果还表明 ,荒地红壤水耕利用后要达到高度熟化的稻田土壤肥力水平 ,需要经过 3 0a的时间  相似文献   

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