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1.
以百林软木制品有限公司提供的阿尔及利亚栓皮槠(Quercus suber)软木及天然红酒塞为原料,对其细胞结构和化学成分进行研究,为红酒塞中的2, 4, 6-三氯苯甲醚(TCA)去除提供一定的指导作用。使用场发射扫描电镜观察软木的微观形态;分析栓皮槠软木的化学成分。结果表明:栓皮槠软木细胞是排列紧密的薄壁细胞,无细胞间隙。横切面和径切面成行排列,类似砖墙状;弦切面上呈现蜂窝状;软木细胞部分细胞壁上有明显褶皱,可能对TCA的去除有一定的影响。软木的各种化学成分含量为:灰分0.52%,抽提物总量13.28%,木栓脂43.41%,酸不溶木质素22.98%,纤维素3.40%,半纤维素16.41%。 相似文献
2.
Quercus variabilis Blume, the Chinese cork oak, is an oak species with a thick cork outer bark. The cork is exploited at a limited scale in China and considered of lower quality than the commercial cork from Quercus suber. We studied an industrial cork granulate feedstock of Q. variabilis in relation to cellular structure and chemical composition and compared it to Q. suber cork under a material’s perspective. The cork of Q.variabilis has 1.1 % ash, 9.6 % extractives, 34.8 % suberin and 19.1 % lignin. The monosaccharide composition with shows a predominance of hemicelluloses: glucose 42.8 % of total neutral sugars, xylose 27.5 %, arabinose 15.4 %, galactose 9.0 %, mannose 4.0 %, rhamnose 1.2 %. The FT-IR spectrum shows the indicative peaks of suberin. The composition is overall similar to that of Q. suber cork. Q. variabilis cork has the typical cellular characteristics of bark cork tissues with a regular and radially aligned structure of cells without intercellular voids. Solid volume fraction was estimated at approximately 16 %. Compared with Q. suber, the Q. variabilis cork cells are smaller, the cell wall undulation and the overall row alignment less homogeneous, the cell surface is irregular and the solid volume proportion higher. The characteristics of Q. variabilis cork support its use as a cellular material for sealing, insulation and energy absorption, but the overall quality is lower than that of Q. suber cork. The negative impact of the higher density and structural lower uniformity at tissue and cell level should be evaluated for processing and product performance. 相似文献
3.
Prof. Helena Pereira 《Wood Science and Technology》1992,26(4):259-269
Summary The thermochemical degradation of cork from Quercus suber L. was studied in the temperature range 150°C–450°C in relation to mass loss, chemical composition and the influence on the cellular structure. The degradation of cork is strongly dependent on temperature and mass losses become significant at 200°C (15% of initial dry weight) and increase rapidly for higher temperatures (27% at 250 °C, 49% at 300 °C, 62% at 350 °C) until ashing at 450 °C. The polysaccharides are the most heat sensitive components: at 200 °C, hemicelluloses disappear and cellulose is degraded to a considerable extent. Suberin is more resistant and degradation starts at approx. 250 °C; 300 °C-treated samples only contain 7% suberin.The cellular structure of cork is also significantly influenced by temperature. Upon heating, cells expand and the cell walls stretch, attaining at 250 °C a maximum cell volume increase corresponding to a factor of approximately 2. Above 300 °C, the structure of cell walls is considerably changed and show profound physical damage; in the later stages of pyrolysis, a cellular structure is no longer observed.We are grateful to Mrs. Joaquina Ferreira for her help with the chemical analysis. The research was financially supported by the Junta Nacional de Investigação Científica e Tecnológica (JNICT) and by the Instituto de Ciência e Tecnologia dos Materiais (ICTM) 相似文献
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5.
Ana Lourenço Isabel Baptista Jorge Gominho Helena Pereira 《Journal of Wood Science》2008,54(6):464-469
The pulping wood quality of Acacia melanoxylon was evaluated in relation to the presence of heartwood. The sapwood and heartwood from 20 trees from four sites in Portugal
were evaluated separately at 5% stem height level in terms of chemical composition and kraft pulping aptitude. Heartwood had
more extractives than sapwood ranging from 7.4% to 9.5% and from 4.0% to 4.2%, respectively, and with a heartwood-to-sapwood
ratio for extractives ranging from 1.9 to 2.3. The major component of heartwood extractives was made up of ethanol-soluble
compounds (70% of total extractives). Lignin content was similar in sapwood and heartwood (21.5% and 20.7%, respectively)
as well as the sugar composition. Site did not influence the chemical composition. Pulping heartwood differed from sapwood
in chemical and optical terms: lower values of pulp yield (53% vs 56% respectively), higher kappa number (11 vs. 7), and lower
brightness (28% vs 49%). Acacia melanoxylon wood showed an overall good pulping aptitude, but the presence of heartwood should be taken into account because it decreases
the raw-material quality for pulping. Heartwood content should therefore be considered as a quality variable when using A. melanoxylon wood in pulp industries 相似文献
6.
Variability of the compression properties of cork 总被引：1，自引：0，他引：1
The variability of the compression properties of cork was determined after field sampling covering the main production area in Portugal (10 sites) with samples taken from 20 trees per site at the time of cork stripping. In all cases, cork showed compressive stress–strain curves typical for cellular materials, which are characterized by an approximately “elastic” region up to a 5 % strain, followed by a large plateau up to 70 % strain caused by progressive buckling of cell walls, and a steep stress increase for higher strains corresponding to cell collapse. The radial direction of compression offered higher strength. The Young’s moduli averaged 10.4 and 9.2 MPa for radial and non-radial directions, respectively, spreading from 3.5 to 22.5 MPa for the non-radial and 4.2 to 21.5 MPa for the radial directions. The geographical location of cork production was the major factor of variability. Density, annual growth ring width and chemical composition influenced compression. Cork samples with higher density showed overall larger resistance to compression. The energy absorbed per unit volume to achieve the maximal deformation with full densification of cork is higher when the average annual ring width is smaller. Cork samples with relatively higher suberin content required less stress for deformation. The results encompass the natural variability of cork and are the most extensive to characterize cork. They allow a better insight into the differences that may explain the variation in cork properties and strengthen its use either in the known applications, i.e. as a sealant, or in novel applications. 相似文献
7.
Carbon distribution in the stem of 2-year-old cork oak plants was studied by (14)CO(2) pulse labeling in late spring in order to trace the allocation of photoassimilates to tissue and biochemical stem components of cork oak. The fate of (14)C photoassimilated carbon was followed during two periods: the first 72 h (short-term study) and the first 52 weeks (long-term study) after the (14)CO(2) photosynthetic assimilation. The results showed that (14)C allocation to stem tissues was dependent on the time passed since photoassimilation and on the season of the year. In the first 3 h all (14)C was found in the polar extractives. After 3 h, it started to be allocated to other stem fractions. In 1 day, (14)C was allocated mostly to vascular cambium and, to a lesser extent, to primary phloem; no presence of (14)C was recorded for the periderm. However, translocation of (14)C to phellem was observed from 1 week after (14)CO(2) pulse labeling. The phellogen was not completely active in its entire circumference at labeling, unlike the vascular cambium; this was the tissue that accumulated most photoassimilated (14)C at the earliest sampling. The fraction of leaf-assimilated (14)C that was used by the stem peaked at 57% 1 week after (14)CO(2) plant exposure. The time lag between C photoassimilation and suberin accumulation was ～8 h, but the most active period for suberin accumulation was between 3 and 7 days. Suberin, which represented only 1.77% of the stem weight, acted as a highly effective sink for the carbon photoassimilated in late spring since suberin specific radioactivity was much higher than for any other stem component as early as only 1 week after (14)C plant labeling. This trend was maintained throughout the whole experiment. The examination of microautoradiographs taken over 1 year provided a new method for quantifying xylem growth. Using this approach it was found that there was more secondary xylem growth in late spring than in other times of the year, because the calculated average cell division time was much shorter. 相似文献
8.
Bruno D. Mattos Tainise V. Lourençon Luis Serrano Jalel Labidi 《Wood material science & engineering》2016,11(4):209-216
This study aims to evaluate the chemical composition of wood and extractives of Pinus taeda and Schizolobium parahyba (guapuruvu) as potential feedstock for new applications in the biorefinery industry. For this purpose, their content of α-cellulose, hemicellulose, insoluble lignin, hot water solubility, NaOH1% solubility, inorganic materials (ash), and monomeric sugars by high-performance liquid chromatography was quantified. Attenuated total reflectance infrared spectroscopy and thermogravimetric analysis were also used to complete the physicochemical characterization of the studied woods. The extractives were obtained by soxhlet extraction with ethanol:toluene and dichloromethane and identified with pyrolysis-gas chromatography/mass spectroscopy technique. The results showed that guapuruvu wood has the higher amount of hemicellulose (16%) when compared to pine wood (10%), which resulted in higher solubility in alkali solution. Furthermore, in relation to other biomasses, the two woods presented more percentage of lignin and minor content of hemicelluloses. The P. taeda wood presented the highest percentage of extractives mainly composed of fatty acids and aromatic hydrocarbons, while guapuruvu wood had a higher percentage of phenolic compounds and also fatty acids. Both the materials have low content of extractives with dichloromethane and were mainly composed of lipophilic compounds. 相似文献
9.
Summary A culm sample of Phyllostachys makinoi was investigated by analysis of its chemical composition, and by electron microscopic observations of the cell wall structure before and after extraction and degradation procedures. Quantitative determination of the components resulted in 2.6% extractives, 25.5% lignin, 45.3% alpha-cellulose, and 24.3% polyoses. The main polyose is an arabinoxylan with a Xyl: Ara ratio of about 17:1. The electron micrographs show a lamellar deposition of lignin and polyoses within the secondary walls. Lignin is obviously soluble by parts in alkaline as well as in acidic reagents. Sodium hydroxide solution removes cell wall substance mainly from the secondary walls, whereas trifluoroacetic acid removes substance from compound middle lamellae. 相似文献
10.
The aim of this study is to characterise the properties of juvenile and mature heartwood of black locust (Robinia pseudoacacia L.). Content, composition and the subcellular distribution of heartwood extractives were studied in 14 old-growth trees from
forest sites in Germany and Hungary as well as in 16 younger trees of four clone types. Heartwood extractives (methanol and
acetone extraction) were analysed by HPLC-chromatography. UV microspectrophotometry was used to topochemically localise the
extractives in the cell walls. The natural durability of the juvenile and mature heartwood was analysed according to the European
standard EN 350-1. Growth as well as chemical analyses showed that, based on extractives content, the formation of juvenile
wood in black locust is restricted to the first 10–20 years of cambial growth. In mature heartwood, high contents of phenolic
compounds and flavonoids were present, localised in high concentrations in the cell walls and cell lumen of axial parenchyma
and vessels. In juvenile wood, the content of these extractives is significantly lower. Juvenile wood had a correspondingly
lower resistance to decay by Coniophora puteana (brown rot fungus) and Coriolus versicolor (white rot fungus) than mature heartwood. 相似文献
11.
《Southern Forests》2013,75(3):215-220
The infection and association between the wood wasp Sirex noctilio and the fungus Amylostereum areolatum is responsible for large-scale tree mortality in the Midlands of the KwaZulu-Natal province in South Africa. An exploratory investigation on the effect of the infestation of trees by the wood wasp and its associated fungus on the chemical composition of Pinus patula pulpwood was undertaken. Various tree classes representing different levels of physiological growth stress from this infestation were compared. Together with the above stress agents, fire damage to P. patula trees was also considered as a possible cause of changes in pulpwood chemical composition. Chemical analyses to determine the Seifert cellulose and Klason lignin contents as well as the levels of water- and solvent-soluble extractives were conducted using published Tappi standard methods. The results indicated only negligible differences between infestation levels (tree classes) with respect to Seifert cellulose and Klason lignin contents. In contrast, highly significant differences were observed for solvent- and water-borne extractives. It is evident from the results that P. patula trees engage a defence strategy to counter the effects of the infestation and the resulting physiological stress. The results of the chemical analyses suggest that trees should not be harvested any younger than the intended rotation age of 12 years and at the time of harvesting all the biomass, including the infected wood, should be sent to the pulp mill. Fire-damaged trees can be utilised in the same way as healthy trees when applying the TMP process provided the charcoal on the outer bark is removed. The usefulness of a biplot to simultaneously display the various tree classes and their chemical composition is illustrated. 相似文献
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14.
工业林木荷木材化学成分及其变异的研究 总被引：2，自引：0，他引：2
按照国家木材化学成分分析标准,对工业林木荷木材化学成分进行了测定,结果表明12年生和14年生木荷木材化学成分含量为：热水抽提物6．93％和5．06％;1％NaOH抽提物18．42％、17．42％;苯醇抽提物1．64％、2．48％;纤维素48．06％、50．72％;多戊糖20．99％、20．68％;木质素24．20％、23．10％;pH值为5．46和4．99。以上7个指标在树干不同高度的差异均未达到显著性水平。而热水、苯醇抽提物含量和pH值在两树龄间的差异达到1％显著水平,1％NaOH抽提物和主要化学成份含量的差异不显著。 相似文献
15.
火炬松纸浆材化学成分及其在树干高度上的变异规律 总被引：1，自引：1，他引：1
对18年生人工林火炬松纸浆材的化学成分含量进行了系统地测试,分析和讨论了火炬松化学成分含量在树干高度方向上的变异规律.结果表明:1、火炬松纸浆材的灰分、冷水、热水、苯醇和1%N aOH抽提物含量,纤维素、戊聚糖和木质素含量平均值分别为0.33%、1.59%、3.21%、2.32%和13.66%、47.98%、15.10%、29.66%;2、沿树干高度方向,火炬松木材灰分含量和纤维素含量变化不明显;热水和苯醇抽提物含量逐渐减小;冷水抽提物和木质素含量表现出先增加后减小或者逐渐减小的趋势;1%N aOH抽提物含量则表现出先减小后增加的趋势;戊聚糖含量表现出逐渐增加或减小的趋势.方差分析表明,火炬松木材各化学成分含量在沿树干高度方向的变化不显著. 相似文献
16.
软木是以栓皮栎的栓皮为原料,具有弹性、保温隔热、防滑耐磨、消音减震、安全无毒等特性的一种可再生绿色材料,产品广泛用于国计民生等重要行业和领域。文中介绍了世界软木资源分布情况、软木用途和产业趋势,综述了国内外软木细胞结构、化学成分、工艺与产品研发等概况,在比较欧美各国与我国软木产品标准制定/修订现状的基础上,概述了我国对现行软木纸标准LY/T 1320-2010和软木纸试验方法LY/T 1321-2013的修订研究过程。提出了加强我国软木研发的建议,即紧跟软木脂研究国际前沿,加大软木脂基础与应用技术研究;加强软木行业标准建设,实现软木产品标准国际化、单项化、功能化;加强软木产品开发利用以及软木资源的培育以提升我国软木产品竞争力,促进我国软木行业健康快速高效发展。 相似文献
17.
采用我国木材化学成分分析国家标准,对人工林米老排木材化学成分进行了测定和研究分析.结果表明:人工林米老排木材冷水抽提物含量和热水抽提物含量分别为2.67%和3.12%,1%NaOH抽提物含量为17.08%,纤维素含量为47.49%,综纤维素含量为80.42%,木素含量为28.80%,pH值为5.44;木材冷水抽提物和综纤维素含量在树干的不同高度上略有差异,但方差分析检验,差异不显著,热水抽提物、1%NaOH抽提物、纤维素和木素含量在树干的不同高度上差异显著,达到1%显著性水平;由树基往上,热水抽提物含量略呈两端高、中间低的趋势,冷水抽提物、1%NaOH抽提物和木素的含量逐渐降低,综纤维素含量和木材pH值逐渐升高;纤维素含量在树干上的分布规律为中间高、两端低,而且从树干中部往上的降低幅度较大. 相似文献
18.
G. Nguila Inari M. Pétrissans S. Dumarcay J. Lambert J. J. Ehrhardt M. Šernek P. Gérardin 《Wood Science and Technology》2011,45(2):369-382
Chemical composition of Norway spruce and pine, two softwood species, has been investigated by X-ray Photoelectron Spectroscopy
(XPS). Contrary to results previously obtained with beech wood, which allow to obtain information on bulk chemical composition
from surface composition analysis, XPS analysis appears to be unsuitable for the characterisation of Norway spruce and pine
wood chemical composition. Indeed, chemical compositions calculated from XPS data differ strongly from those obtained from
microanalyses which are in good agreement with theoretical composition described in the literature. XPS analysis of both the
softwood surfaces indicated high carbon contents explained by migration of lipophilic extractives to the surface under the
influence of the vacuum necessary for XPS analysis. Nonvolatile extractives contained in wood were extracted and deposited
on glass plates and analysed. Survey and detailed C1s spectra indicated similar signals to those recorded on wood surfaces.
This phenomenon was not observed when samples had been previously extracted before analysis. These results strongly evidenced
that extractives present in both species are able to migrate through resin canals from the bulk of the sample to the surface
when put into ultra high vacuum. XPS presents, therefore, some limits in the case of the analysis of softwood species containing
extractives able to migrate to the surface during analysis. This behaviour, difficult to control, could lead to erroneous
interpretations due to extractives enrichment of the surface under the effect of vacuum. 相似文献
19.
Botryosphaeria canker of cork oak (Quercus suber L.), caused by Botryosphaeria corticola, is a well-known factor contributing to the decline of this forest species and is a serious disease in the main cork-producing countries of the Western Mediterranean basin. In this work, fungicides with the potential for controlling the disease were selected using a combination of in vitro tests and field trials. Fourteen fungicides in different chemical families were tested in vitro to evaluate their effect on inhibition of mycelial growth. The most effective fungicides were benomyl, carbendazim, cyprodinil + fludioxonil, thiabendazol and thiophanate-methyl; these compounds were then further tested under field conditions. In the field trials, carbendazim and thiophanate-methyl were the most effective fungicides, as shown by efficacy indices, in reducing debarked trunk surface affected by cankers (76% and 50–65%, respectively). These results suggest that the occurrence of Botryosphaeria canker on cork oak can be reduced effectively with the application of selected fungicides after cork removal from the trees. 相似文献
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