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1.
Manganese (Mn) is an essential micronutrient needed for plant growth and development, but it can be toxic to plants in excess amounts. Long-term fertilizer experiment and intensive cropping alter the soil properties and also affect its plant-available Mn contents. To understand the dynamics of Mn under long-term fertilizer experiment the present study was initiated during 1972 at the experimental farm of College of Agriculture, CSK HPKV, Palampur (32° 6′ N latitude and 76° 3′ E longitude) in a randomized block design with 11 treatments replicated three times with a maize-wheat cropping sequence. The soils of the experimental area in the beginning of the experiment were acidic in reaction and taxonomically classified as Typic Hapludalfs. Surface (0.0–20 cm) and subsurface (20–40 cm) soil samples taken after the harvest of maize (kharif, 2008) were analyzed for pools of Mn and chemical indices of soil quality using standard analytical methods. Besides, the pools of Mn were also determined in the composite soil samples drawn from adjacent fallow plots. Results showed that all the pools of Mn were noticeably greater in farmyard manure (FYM)–amended plots compared to zero-fertilized plots. Although the residual fraction was found to be the most dominant fraction, organically bound and exchangeable forms were found to play major roles in the nutrient supply, crop productivity, and nutrient uptake. The greatest productivity of maize (2008) and wheat (2008–09) was recorded under the 100% nitrogen, phosphorus, and potassium (NPK) + FYM treatment. FYM and lime treatments resulted in significantly greater uptake of all the nutrients by both the crops compared to other treatments. The organically bound fraction was found to have the greatest significant and positive correlation with yield and nutrient uptake of maize and wheat crops. Further regression analysis studies revealed that the organic form was the most important pool contributing towards the variation in the parameters. Exchangeable and organically bound forms contributed significantly towards diethylene triamine pentaacetic acid (DTPA)–extractable Mn.  相似文献   

2.
This present investigation took place on a continuing long-term fertilizer experiment, initiated in 1972 at the experimental farm of the College of Agriculture CSK HPKV, Palampur, aimed at studying nutrient dynamics of micronutrients, especially Zn, after continuous use of chemical fertilizers and amendments over the previous 36 years in an acid Alfisol under a maize–wheat system. Treatments investigated were as follows: T1: Control; 100% N; 100% NP; 100% NPK (optimal application - 120:26:33(maize)/25(wheat)); 100% NPK + FYM (10 t ha−1 to the maize crop); T6: 100% NPK + lime (900 kg ha−1); T7: 100% NPK + Zn (25 kg ha−1 as ZnSO4); T8: 100% NPK + Hand weeding; T9: 100% NPK (-S); T10: 150% NPK (super-optimal application); and T11: 50% NPK (sub-optimal application). Different forms of zinc in soil were determined through a sequential extraction method. Results revealed that previous applications of high-analysis fertilizers and amendments caused a marked depletion in the pools of Zn as compared to buffer plots. All pools of Zn as well as crop productivity and Zn uptake were noticeably greater in farmyard manure (FYM)-amended plots compared with plots not receiving fertilizer. The residual fraction was the dominant form but organically bound and exchangeable forms were found to play major role in nutrient supply, crop productivity and nutrient uptake. Correlation and regression analysis studies showed that organic forms constituted the most important pool contributing towards variation in yield and uptake by maize and wheat crops. Exchangeable and organically bound forms contributed significantly towards the availability of DTPA-extractable Zn in soil.  相似文献   

3.
Long-term effects of continuous use of chemical fertilizers and manure on soil fertility and productivity of a maize–wheat system were investigated in the ongoing long-term fertilizer experiment, during rabi (2007–2008) and kharif (2008) seasons at the research farm of Chaudhary Sarwan Kumar Himachal Pradesh Agricultural University–Hill Agricultural Research and Extension Centre, Dhaulakuan. After 16 cropping cycles, bulk density decreased in plots where farmyard manure (FYM) was applied, whereas pH decreased in all the treatments. The organic carbon content of the soil increased in all the treatments except 100% nitrogen (N). Cation exchange capacity (CEC) increased in all the treatments over the initial status of the soil. Available N showed buildup over the initial status in most of the treatments. Available phosphorus (P) declined from initial status in treatments where only N was applied alone or with FYM. There was reduction in available potassium (K) status in all the treatments except 100% NPK. Continuous addition of FYM with balanced application of inorganic fertilizers improved content of exchangeable calcium (Ca) and magnesium (Mg) over initial status compared to imbalanced application of fertilizers. Continuous use of imbalanced inorganic fertilizers resulted in lesser crop yields and nutrient uptake compared to that with the application of balanced dose of inorganic fertilizers with FYM.  相似文献   

4.
Long term effects of lantana (Lantana camera L.) residue and fertilizer application were studied on copper (Cu) fractions in a Typic Hapludalf under rice-wheat cropping at Palampur, India (32°6′N, 76°3′E). A partitioning of soil Cu revealed residual Cu and organically bound Cu as the most dominant fractions followed by Cu occluded by free oxides, specifically exchangeable Cu and soil solution and exchangeable Cu. Continuous incorporation of lantana after 12 years resulted in redistribution of Cu from non-available forms to readily and potentially available forms in soil. All the Cu fractions were positively interrelated amongst themselves and with grain yield and Cu uptake in rice and wheat crops. Specifically exchangeable Cu followed by organically bound Cu were the most important Cu fraction contributing towards grain yield and Cu uptake in rice and wheat crops.  相似文献   

5.
Agricultural productivity is increasingly becoming dependent upon soil fertility, which is generally thought to be supplemented through the application of nutrients mainly through inorganic fertilizers. The present study aims to characterize the soil physical environment in relation to long-term application of farmyard manure (FYM) and inorganic fertilizers in a maize–wheat cropping system. The treatments in both the maize and wheat systems included a control (without any fertilizer or FYM), FYM (farmyard manure at 20 t ha?1), N100 (nitrogen at 100 kg ha?1), N100P50 (nitrogen and phosphorus at 100 and 50 kg ha?1), and N100P50K50 (nitrogen, phosphorus, and potash at 100, 50, and 50 kg ha?1). The treatments were replicated four times in a randomized complete block design in sandy loam soil. The root mass density in surface layers of both the crops was lower in FYM and higher in inorganic fertilizer plots. The root length density was found to be highest in FYM-treated plots and lowest in control plots. The periodic soil matric suction during wheat following maize remained highest in FYM plots followed by that in N100 plots in all the layers. The soil water storage of wheat at harvest (rice–wheat) was highest (21.1 cm) in control and lowest (17.8 cm) in FYM-treated plots. The soil water status, root growth, and crop performance improved with balanced fertilization.  相似文献   

6.
Knowledge of K-dynamics in soils can help devise practices for efficient K management in intensive rice-wheat systems. We studied the effect of long-term application of rice straw, farmyard manure (FYM) and inorganic fertilizer on total K and its distribution among different forms in 60-cm soil profile after 14 years of rice-wheat cropping. The exchangeable, the non-exchangeable and the lattice K respectively comprised 1%, 3–10% and 89–95% of total K in surface soil under different treatments. Application of rice straw and FYM positively impacted total K status of soil and its distribution among different forms. The greatest concentrations of total K, lattice K, exchangeable K and NH4OAc-extractable K were observed in plots receiving both rice straw and FYM together and the lowest in inorganic fertilizer treated plots. On the contrary, the non-exchangeable K was the highest in inorganically fertilized plots and the lowest in rice straw amended plots. The exchangeable, the water soluble and the NH4OAc-extractable K decreased with soil depth and did not indicate K movement beyond the rooting zone of the crops. The results showed that incorporation of rice residue in soil, instead of burning, besides reducing environmental pollution led to improved K-fertility of soils.  相似文献   

7.
Soil and plant samples were collected from an ongoing long-term experiment (LTE) at the Indian Agricultural Research Institute farm, New Delhi, to study the distribution of various fractions of iron (Fe) and their contribution to availability and plant uptake in a maize–wheat sequence. The optimum dose-based treatments adopted for the study were nitrogen (N), nitrogen–phosphorus (NP), nitrogen–phosphorus–potassium (NPK), NPK + farmyard manure (FYM), NPK+ zinc (Zn), and control (no fertilizer or manure). Different fractions of Fe in the soil were sequentially extracted using different extractants. Diethylenetriaminepentaacetic acid (DTPA)–extractable Fe did not differ significantly among the treatments as a result of continuous cropping for more than three decades. The overall mean total iron (Fe) content varied from 2.36 to 2.61% under different treatments. Residual Fe constitutes a major portion of total Fe in all four layers of soil. The Fe associated with easily reducible Mn and organic matter contributed directly to DTPA-extractable Fe both in pre-maize and post-wheat soil. Residual Fe contributed directly to uptake Fe by maize and wheat crops.  相似文献   

8.
Chemical speciation and bioaccumulation factor of iron (Fe), manganese (Mn), and zinc (Zn) were investigated in the fractionated rhizosphere soils and tissues of sunflower plants grown in a humic Andosol. The experiment was conducted for a period of 35 days in the greenhouse, and at harvest the soil system was differentiated into bulk, rhizosphere, and rhizoplane soils based on the collection of root-attaching soil aggregates. The chemical speciations of heavy metals in the soil samples were determined after extraction sequentially into fractions classified as exchangeable, carbonate bound, metal–organic complex bound, easily reducible metal oxide bound, hydrogen peroxide (H2O2)–extractable organically bound, amorphous mineral colloid bound, and crystalline Fe oxide bound. Iron and Zn were predominantly crystalline Fe oxide bound in the initial bulk soils whereas Mn was mainly organically bound. Heavy metals in the exchangeable form accumulated in the rhizosphere and rhizoplane soils, comprising <4% of the total content, suggesting their relatively low availability in humic Andosol. Concentrations of organically bound Fe and Mn in soils decreased with the proximity to roots, suggesting that organic fraction is the main source for plant uptake. Concentrations of Mn and Zn in the metal–organic complex also decreased, indicating a greater ability of sunflower to access Mn from more soil pools. Sunflower showed bioaccumulation factors for Zn, Fe, and Mn as large as 0.39, 0.05, and 0.04 respectively, defining the plant as a metal excluder species. This result suggests that access to multiple metal pools in soil is not necessarily a major factor that governs metal accumulation in the plant.  相似文献   

9.
To explore long-term impact of organic and inorganic fertilizers on soil health and grain quality, we monitored the enzyme activities and chemical properties of soil; and chemical composition of grain from eight treatments at an experimental field site established in 1996. There were eight treatments applied to both wheat and maize seasons: a control; four inorganic fertilizers, that is, nitrogen and phosphorus (NP), nitrogen and potassium (NK), phosphorous and potassium (PK) and nitrogen, phosphorus and potassium (NPK); farm yard manure alone (FYM) and addition of FYM at two different doses (100 and 50% of recommendation) to NPK that is, NPK + FYM and ½ NPK + FYM. After 11 years of the experiment the NPK + FYM and ½ NPK + FYM treatments had the highest yields, about 5 Mg maize ha−1 and 2 Mg wheat ha−1 with about 2 and 0.5 Mg ha−1, respectively more than the NPK treatments. The dehydrogeanse activity of soils increased significantly in FYM and ½ NPK + FYM. Except urease all other enzymatic activities were increased in those treatments, which received manure. Urease activity was higher in mineral-N applied plots. Grain protein content of both maize and wheat was highest in mineral fertilized plots. Test weight also increased significantly on application of mineral fertilizer. Plots treated with half dose of recommended mineral fertilizer along with FYM were higher in urease, phosphomono and diesterase activities than that of NPK + FYM treated plots. Long-term application of inorganic nutrients along with FYM improved grain mineral composition and yield. Inhibition of few enzymatic activities were also observed upon application of inorganic nutrients either alone or in combination.  相似文献   

10.
The physical quality of the soil, which creates suitable environment for the availability and uptake of the plant nutrients, is generally ignored. Though the effect of organic manures on soil physical quality has been widely appreciated but that of inorganic fertilizers is studied to a lesser extent. The present study carried out during 2004–2005 aims to characterize the soil physical quality in relation to the long-term (32 years) application of farmyard manure (FYM) and inorganic fertilizers in maize (Zea mays L.) wheat (Triticum aestivum L.) cropping system. The treatments during both maize and wheat crops were (i) farm yard manure at 20 Mg ha−1 (FYM), (ii) nitrogen at 100 kg ha−1 (N100), (iii) nitrogen and phosphorus at 100 and 50 kg ha−1 (N100P50) and (iv) nitrogen, phosphorus and potassium at 100, 50 and 50 kg ha−1 (N100P50K50) in addition to (v) control treatment, i.e. without any fertilizer and/or FYM addition. The treatments were replicated four times in randomized block design in a sandy loam (Typic Ustipsament, non-saline, slightly alkaline). Bulk density, organic carbon content, structural stability of soil aggregates and water holding capacity of 0–60 cm soil layer were measured.The application of FYM to maize increased the organic carbon by 16% whereas N100P50K50 increased it by 21%. The increased organic matter with both FYM and N100P50K50 increased the total soil porosity and decreased soil bulk density from that in control plots. The mean weight diameter (MWD) was highest in FYM plots of both maize (0.160 mm) and wheat (0.172 mm) closely followed by that in N100P50K50 plots. The effect of FYM in increasing the MWD decreased with soil depth. The average water holding capacity (WHC) was higher with FYM and N100P50K50 application than that in control plots. The MWD, total porosity, OC content and WHC improved with the application of balanced application of fertilizers. The grain yield and uptake of N, P and K by both maize and wheat were higher with the application of FYM and inorganic fertilizers than in control plots. The uptake of N, P and K increased with the application of FYM and N100P50K50.  相似文献   

11.
In a long-term fertilizer experiment at the Indian Agricultural Research Institute, New Delhi, with maize, wheat, and cowpea, various forms of potassium (K) and their contribution toward K uptake were found to be affected by fertilizer use and intensive cropping. The treatments included for the study were a control, 100% nitrogen (N), 100% N–phosphorus (P), 50% NPK, 100% NPK, 100% NPK + farmyard manure (FYM at 15 t ha?1 to maize only), and 150% NPK. The concentration of nonexchangeable K was greatest, followed by exchangeable K and water-soluble K. The study revealed no significant change in water-soluble K concentration in surface soil compared to N, NP, and control, indicating existence of an equilibrium between different K forms. Application of 100% NPK significantly increased water-soluble K concentration in surface soil compared to N, NP, and control treatments after maize, wheat, and cowpea. Application of NPK + FYM and 150% NPK resulted in greater quantities of all the K forms as compared to other treatments. Among the three forms, water-soluble K contributed predominantly to K uptake by maize and wheat; however, nonexchangeable K contributed significantly to K uptake by cowpea.  相似文献   

12.
于2017—2019年在吉林省农安县设置大田试验,采用双因素裂区设计,主区为秸秆还田J(12000 kg/hm^2)、秸秆不还田W,副区为施镁M3(施纯镁10 kg/hm^2)、不施镁M0,包含JM3(秸秆+镁肥)、JM0(秸秆+无镁肥)、WM3(无秸秆+镁肥)、WM0(常规)4个处理。结果表明:玉米生育期,土壤交换镁含量逐渐降低,至成熟期,JM3处理土壤交换镁含量比WM3、JM0、WM0分别提高6.59%,8.47%,14.09%。施用镁肥促进玉米植株对镁素养分的吸收,秸秆还田配施镁肥进一步增加了玉米植株对镁素养分的吸收,WM3处理玉米镁素积累量比WM0平均提高12.30%;JM3处理的镁素积累量比WM3、JM0、WM0处理分别提高9.79%,15.99%,23.28%。春玉米干物质积累量随着生育期的进行逐渐增加,施镁肥能提高干物质积累量与春玉米产量,在成熟期WM3(无秸秆+镁肥)的干物质积累量与产量分别比WM0(常规)提高5.30%与4.38%,JM3(秸秆+镁肥)的干物质积累量与产量比WM0(常规)分别提高11.50%与5.52%。综上可以得出,施用镁肥可以显著提高土壤交换镁含量,促进春玉米植株对镁素养分的吸收,增加干物质积累量及提高春玉米产量。秸秆还田配施镁肥不但可以提高土壤交换镁含量,保持土壤镁素在整个玉米生育期的持续有效供应,还进一步促进春玉米植株对镁素的吸收,提高了干物质积累量及春玉米产量。  相似文献   

13.
The Static Fertilization Experiment Bad Lauchstädt (1902) consists of a crop rotation of sugar beets, spring barley, potatoes and winter wheat. Three farmyard manure (FYM) treatments and six mineral fertilizer treatments are combined orthogonally. Comparing the first and last decades, crop yields nearly doubled. In unfertilized plots, yields and N uptake by crops also increased when comparing first and last decades. On average for the decade 2001–2010, N uptake in unfertilized plots amounted 51.6 kg ha?1. Although soil organic carbon (SOC) levels for unfertilized plots remain almost unchanged, SOC increases slowly in the most highly fertilized treatment, resulting in a gradual widening of differences in SOC between the most extreme treatments to 0.952%. Climate change and increased harvesting and root residues due to rising yields are suggested as an explanation. Except for the plot with the highest application of mineral and organic fertilizer, in all treatments more N was taken up by crops than was applied by fertilizers. Higher FYM input leads to more unfavourable N balances because N release from FYM cannot be controlled. Considering atmospheric N input, only in the exclusively mineral fertilized treatment is N balanced out. Similar results are found for C balances: the exclusively mineral fertilized treatment shows the most favourable C balance.  相似文献   

14.
A long‐term fertilizer experiment, over 27 years, studied the effect of mineral fertilizers and organic manures on potassium (K) balances and K release properties in maize‐wheat‐cowpea (fodder) cropping system on a Typic Ustochrept. The treatments consisted of control, 100% nitrogen (100% N), 100% nitrogen and phosphorus (100% NP), 50% nitrogen, phosphorus, and potassium (50% NPK), 100% nitrogen, phosphorus, and potassium (100% NPK), 150% nitrogen, phosphorus, and potassium (150% NPK), and 100% NPK+farmyard manure (100% NPK+FYM). Nutrients N, P, and K in 100% NPK treatment were applied at N: 120 kg ha—1, P: 26 kg ha—1, and K: 33 kg ha—1 each to maize and wheat crops and N: 20 kg ha—1, P: 17 kg ha—1, and K: 17 kg ha—1 to cowpea (fodder). In all the fertilizer and manure treatments removal of K in the crop exceeded K additions and the total soil K balance was negative. The neutral 1 N ammonium acetate‐extractable K in the surface soil (0—15 cm) ranged from 0.19 to 0.39 cmol kg—1 in various treatments after 27 crop cycles. The highest and lowest values were obtained in 100% NPK+FYM and 100% NP treatments, respectively. Non‐exchangeable K was also depleted more in the treatments without K fertilization (control, 100% N, and 100% NP). Parabolic diffusion equation could describe the reaction rates in CaCl2 solutions. Release rate constants (b) of non‐exchangeable K for different depth of soil profile showed the variations among the treatments indicating that long‐term cropping with different rates of fertilizers and manures influenced the rate of K release from non‐exchangeable fraction of soil. The b values were lowest in 100% NP and highest in 100% NPK+FYM treatment in the surface soil. In the sub‐surface soil layers (15—30 and 30—45 cm) also the higher release rates were obtained in the treatments supplied with K than without K fertilization indicating that the sub‐soils were also stressed for K in these treatments.  相似文献   

15.
Zinc (Zn) deficiency is widespread in alkaline and calcareous soils. Limited information is available on the effect of preceding crops on the distribution of Zn in soil solid phase. This field study was conducted to investigate the changes in Zn chemical forms in soil solid phase as affected by four preceding crops [Sunflower (Heilianthus annuus L. cv. Allstar), Sorghum (Sorghum bicolor L. cv. Speed Feed), Clover (Trifolium pratense L.) and Safflower (Carthamus tinctorius L. cv. Koseh-e-Isfahan)] in a calcareous soil. A control treatment with no preceding crop (fallow) was also used. Our results showed that the preceding crops increased Zn concentration in exchangeable fraction (EXCH-Zn), the organically bound zinc form (ORG-Zn) and zinc bound to iron and manganese oxides (FeMnOX-Zn) while decreased carbonates bound-zinc (CAR-Zn) and residual zinc forms (RES-Zn). However, the changes in Zn fractions were dependent on the preceding crop type. The EXCH-Zn and ORG-Zn pools can be considered labile pools that play significant roles in supplying Zn for plants. Among the preceding crops used in this experiment, clover (Clo) had the highest effect on transforming CAR-Zn form to EXCH-Zn and ORG-Zn labile forms and thus resulted in the highest Zn accumulation in tissues of the target wheat (Triticumaestivum L. cv. Back Cross). Although the changes in chemical forms of Zn in the soil solid phase are complex and dependent on various factors, our findings showed that the preceding crops significantly increased the concentration of Zn in exchangeable and organic matter pools and in turn resulted in higher uptake of Zn by the target wheat.  相似文献   

16.
Farmyard manure (FYM) improves various soil parameters and to a large extent, the availability of water and nutrient to crops when it is applied to the soil. This study aims to further investigate the short-term effects of different levels of FYM on maize plants and soil parameters. Maize plants grown in pot culture were treated with no FYM (control), recommended NPK (inorganic fertilizers), and FYM at 2, 4, 6, 8, and 10 t ha?1 along with recommended NPK, and the cultures were analyzed 8 weeks after germination. Soil bulk density and soil pH decreased with the increasing levels of FYM, whereas soil porosity, soil organic matter (SOM), soil water content, plant height, root and shoot yield, and NPK uptake of maize were increased compared with the control or recommended NPK, respectively. The present results indicate that short-term application of higher FYM levels improves soil properties. Furthermore, the application of FYM at only higher rates significantly increases the nutrient uptake of maize plants due to improved soil properties. The supply of different amounts of nutrients increases biomass and nutrient uptake in plants.  相似文献   

17.
Experiments under laboratory and greenhouse conditions were conducted to study the response of maize (Zea mays L.) to Zn fertilizer applications (Zn-phenolate, Zn-EDDHA, Zn-EDTA, Zn-lignosulfonate, Zn-polyflavonoid, and Zn-heptagluconate) in an Aquic Haploxeralf soil. The application of Zn complexes significantly increased Zn uptake by the plant compared with that in the control soil. The highest enhancements were obtained in soil treated with Zn-EDTA, Zn-lignosulfonate, and Zn-EDDHA. The highest percentages of Zn taken up by the plants occurred when 20 mg x kg(-1) Zn was applied as Zn-EDTA fertilizer and 10 mg x kg(-1) as Zn-lignosulfonate fertilizer. In the greenhouse experiment, Zn speciation in soil after harvesting showed that almost all Zn was found in the residual fraction followed by metal in the water-soluble plus exchangeable fraction and metal bound to organic matter. The most effective fertilizers maintaining Zn in the most labile fractions were Zn-phenolate, Zn-EDTA, and Zn-lignosulfonate. Conversely, in the incubation experiment, only a small percentage of Zn was found in the water-soluble plus exchangeable fraction and no differences in the Zn distribution were observed between the different fertilizer treatments. The micronutrient content in maize was positively correlated with the water-soluble plus exchangeable Zn as well as with the available Zn determined by the diethylenetriaminepentaacetic acid and Mehlich-3 methods, in the greenhouse experiment. Results of this study showed that the incubation experiment in acidic soil is not a suitable tool to establish the different effectiveness of Zn chelates in plants.  相似文献   

18.
The effects of copper (Cu) application on the Cu distribution in various pools were investigated in laboratory and pot culture experiments with two Alfisols. The total soil Cu was fractionated into water‐soluble plus exchangeable (CA‐Cu), inorganically‐bound (AAC‐Cu), organically‐bound (PYR‐Cu), oxide‐bound (OX‐Cu), and residual (RES‐Cu) forms. The relative contribution of these fractions to Cu uptake by wheat was calculated through path coefficient analysis, a statistical technique that differentiates between correlation and causation. Copper fertilizer was applied at rates of 0, 5, and 10 mg (kg soil)—1 and FYM at rates of 0 and 10 t ha—1. Results indicated that the amounts of Cu present in CA‐Cu were very small. The CA‐Cu, AAC‐Cu, PYR‐Cu, and OX‐Cu fractions were increased and RES‐Cu was not significantly affected by the Cu application. No significant variation (P ≤ 0.01) was observed between Cu application with and without FYM on the distribution of different fractions of soil Cu except PYR‐Cu in Patancheru soil. Among the levels, application of 10 mg Cu (kg soil)—1 showed the maximum increase in different fractions of soil Cu. The per cent increase in Cu concentration in different fractions followed the order CA‐Cu > AAC‐Cu > PYR‐Cu > OX‐Cu > RES‐Cu. The path analysis showed that the PYR‐Cu and AAC‐Cu are the most important fractions for maintaining the available Cu pool in soils.  相似文献   

19.
An experiment was conducted to evaluate the effect of zinc (Zn) rates and vermicompost levels on distribution of Zn forms of a calcareous soil. After incubation periods, soil samples were air dried, and a sequential extraction scheme was used to fractionate Zn into soluble and exchangeable, bound to carbonate, organically bound, bound to manganese (Mn) oxide, bound to amorphous iron (Fe) oxide, bound to crystalline Fe oxide, and residual forms. In untreated soil, Zn was mainly in the residual fraction. Increasing rates of applied Zn significantly increased all forms of Zn. Carbonate and residual forms showed the greatest increase. Application of vermicompost significantly increased all fractions except Mn-oxide form. This increase was more pronounced for organically bound, soluble, and exchangeable forms, indicating an increase in bioavailability of soil Zn. Incubation time significantly decreased soluble, exchangeable, and organically bound forms but increased other forms of Zn, meaning a significant reduction in Zn phytoavailability in soil with time.  相似文献   

20.
ABSTRACT

Soil and plant samples were collected from on-going long-term experiment at Indian Agricultural Research Institute, New Delhi farm to study the distribution of various forms of copper (Cu) and their contribution to availability and plant uptake in maize (Zea mays L.)—wheat (Triticum aestivum L.) sequence. The optimum dose-based treatments selected for the study were nitrogen-phosphorus-potassium (NPK), NPK + Farmyard manure (FYM), NPK+ zinc (Zn) and control (no fertilizer or manure). Uptake of Cu by maize and wheat varied from 17.0 to 37.5 and 60.8 to 149.3 g ha?1, respectively, under different treatments. Copper uptake by wheat was significantly higher under 100% NPK + FYM than that with 100% NPK. There was no significant difference among the treatments with respect to diethylenetriaminepentaacetic acid (DTPA)-extractable Cu in 0–15, 15–30, 30–45, and 45–60 cm soil layers. However, with increasing depth of soil, it showed declining trend under all the treatments. Mean value of total Cu was 28, 32, 25, and 21 mg kg?1 in 0–15, 15–30, 30–45, and 45–60 cm depths, respectively. Major part of the total Cu was present as residual form. Sorbed copper (SORB–Cu) contributed directly towards its availability both in pre-sowing maize and post-harvest wheat soil samples. SORB–Cu and organic matter bound Cu (OM–Cu) contributed directly towards the uptake by the component crops. Copper associated with easily reducible manganese, carbonate, and iron and aluminum oxides were most recalcitrant forms present in soil and their effects on availability and crop uptake were adverse.  相似文献   

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