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1.
The 87Sr/86Sr ratios in rain at three sites in Japan were about 0.706 to 0.712, whereas those at one site in central Korea were higher (0.711 to 0.716), reflecting the difference in geology between the two countries. Because the 87Sr/86Sr ratios of exchangeable sites in soil minerals are indistinguishable from those of associated plants, aerosol Sr originating from both can be grouped together as plant-derived Sr. Spatial and temporal variations in 87Sr/86Sr and Sr/Ca ratios in the rain suggest the presence of plant-derived Sr and Ca in addition to Sr and Ca derived from sea-salt, acid-soluble aeolian carbonate from China, and cement-derived carbonate. However, systematic data on the 87Sr/86Sr ratios and elemental concentrations of soils, plants, fly-ash, and road dust are required to put reliable constraints on the provenance of atmospheric Ca.  相似文献   

2.
To elucidate the influence of airborne materials on the ecosystem of Japan??s Yakushima Island, we determined the elemental compositions and Sr and Nd isotope ratios in streamwater, soils, vegetation, and rocks. Streamwater had high Na and Cl contents, low Ca and HCO3 contents, and Na/Cl and Mg/Cl ratios close to those of seawater, but it had low pH (5.4 to 7.1), a higher Ca/Cl ratio than seawater, and distinct 87Sr/86Sr ratios that depended on the bedrock type. The proportions of rain-derived cations in streamwater, estimated by assuming that Cl was derived from sea salt aerosols, averaged 81?% for Na, 83?% for Mg, 36?% for K, 32?% for Ca, and 33?% for Sr. The Sr value was comparable to the 28?% estimated by comparing Sr isotope ratios between rain and granite bedrock. The soils are depleted in Ca, Na, P, and Sr compared with the parent materials. At Yotsuse in the northwestern side, plants and the soil pool have 87Sr/86Sr ratios similar to that of rainwater with a high sea salt component. In contrast, the Sr and Nd isotope ratios of soil minerals in the A and B horizons approach those of silicate minerals in northern China??s loess soils. The soil Ca and P depletion results largely from chemical weathering of plagioclase and of small amounts of apatite and calcite in granitic rocks. This suggests that Yakushima??s ecosystem is affected by large amounts of acidic precipitation with a high sea salt component, which leaches Ca and its proxy (Sr) from bedrock into streams, and by Asian dust-derived apatite, which is an important source of P in base cation-depleted soils.  相似文献   

3.
Aeolian particles originating from arid areas in China, termed Kosa, are considered to be a major source of non-sea-salt Ca, a dominant base cation, in acid precipitation in northeastern Asia. We extracted evaporite minerals (halite, gypsum, and carbonate) from the surface soil collected at eight desert and loess areas in northern China with water and acetic acid. Most 87Sr/86Sr ratios of the extracted fractions fell in a restricted range (0.7115 ± 0.0015) and differed from those of bulk soils and acid-insoluble minerals (0.712–0.717). The selective dissolution of the soil carbonates in the atmosphere is consistent with two facts: (1) their 87Sr/86Sr ratios are close to the maximum 87Sr/86Sr ratios of spring precipitation in Japan, when Kosa activity is marked; and (2) their mole ratios of Mg/Ca (0.15) and Sr/Ca (0.001) are almost identical to those of precipitation in China and Japan when Kosa activity is marked. The 87Sr/86Sr, Mg/Ca, and Sr/Ca ratios in the acid-soluble components can be used as indexes of Kosa aerosols in the precipitation of the northwestern Pacific.  相似文献   

4.
Négrel  P.  Pauwels  H. 《Water, air, and soil pollution》2004,151(1-4):261-285
Strontium- and sulphur-isotope data as well as major ions, from shallow and deep groundwater in three granite and Brioverian `schist' areas of the Armorican Massif (northwest France) are discussed. The investigated areas, e.g. the Pleine-Fougères, Coët Dan and Arguenon catchments, are located in Brittany with intensive agriculture covering large parts.The stable-isotope signatures of the waters plot close to the general meteoric-water line, reflecting a meteoric origin and the lack of significant evaporation or water-rock interaction. The water chemistry from the different catchments shows large variation in the major-element contents. Plotting Na vs. Cl contents and Mg, NO3, K, SO4, Sr concentrations reflect agricultural input from hog and livestock farming and fertilizer applications, with local sewage-effluent influence, although some water samples are clearly unpolluted.The δ34S(SO4) is controlled by several potential sources (atmospheric sulphate, pyrite-derived sulphates, fertilizer sulphates). Some δ18O and δ34S values are expected to increase through sulphate reduction, with higher effect on δ34S for the dissimilatory processes and on δ18O for assimilatory processes. The range in Sr contents of groundwater samples from different catchments agrees with previous work on groundwaters sampled from granitic rocks in France. The Sr content is well correlated with Mg and therefore both are related to agricultural practises. The 87Sr/86Sr ratios range from 0.71265 and 0.72009 also agreeing with Sr isotopic ratios found on granite-gneiss watersheds in France. The relationship between the 87Sr/86Sr and the Mg/Sr ratios allows defining the different end-members (e.g. rain, agricultural practises, water-rock interaction).  相似文献   

5.
Soler  A.  Canals  A.  Goldstein  S. L.  Otero  N.  Antich  N.  Spangenberg  J. 《Water, air, and soil pollution》2002,136(1-4):207-224
The use of sulfur and strontium isotopes as tracers forthe source/s of water contaminants have been applied to thewater of the Llobregat River system (NE Spain). Surfacewater samples from June 1997 were collected from theLlobregat River and its main tributaries and creeks. Thechemistry of most stream waters are controlled mainly bythe weathering of Tertiary chemical sediments within thedrainage basin. The largest variation in δ34Svalues were found in the small creeks with values rangingfrom –9.9 to 15‰, whilst in the main river channels valuesranged from 6.3 to 12.4‰. The 87Sr/86Sr ratio fordissolved strontium ranged from 0.70795 for a non-pollutedsite to 0.70882 for a polluted one. Most of the waters withhigh NO3 and low Ca/Na ratio converge to the same87Sr/86Sr value, pointing to dominant pollutantend member contribution or a mixing of pollutants with anisotopic composition around 0.7083–0.7085. Although theconcentration of the natural inputs in the river forsulfate and strontium are high, as a result of the sulfateoutcrops within the geology of the basin, their isotopiccharacteristics suggest that they can be used as adiscriminating device in water pollution problems. Howeverto establish the detailed characteristics of the isotopesas geochemical tools, specific high-resolution case studiesare necessary in small areas, where the inputs are well known.  相似文献   

6.
Base cation (BC) concentrations of rain, throughfall, percolation from leaf litter, and soil solution were periodically measured in two forests: Kannondai (red pine stand on volcanic soil) and Yasato (deciduous stands on granitic soil). Calculation of a BC budget gave the rate of BC release from soils; the BCs originated from mineral weathering and cation exchange. Weathering rates under field conditions were estimated from the Sr isotope ratios (87Sr/86Sr) of water and soil samples. Isotope ratios decreased in the order rain > throughfall > percolation > soil solution. Clay and silt had extremely high isotope ratios; this suggests that the sandy fraction, whose isotope ratio was smaller than that of the soil solution, was the main contributor to mineral weathering. Estimated BC weathering rates (kmolc·ha?1y?1) were 1.16 for Ca and 0.57 for Mg at Kannondai, and 0.82 for Ca and 0.51 for Mg at Yasato. The unexpected high weathering rate of granitic soil in Yasao was due to the wide coverage of the original parent material by volcanic ash. The contribution of cation exchange derived by subtraction was a little smaller than the weathering rates and was similar to the values estimated from a dynamic model that we developed.  相似文献   

7.
《CATENA》1998,32(2):143-151
In calculating catchment weathering rates using strontium isotope ratios, one of the parameters required is the 87Sr/86Sr ratio of the streamwater. The effect of flow rate on this ratio is not well understood with conflicting reports in the literature. To provide more detailed information on the effect of flow rate on strontium isotope ratios, the 87Sr/86Sr ratio was measured in streamwater samples taken at low and high flow rates and also in samples taken at four and eight hourly intervals during two rain events in a small catchment (area 90 ha) in andesitic lavas. The 87Sr/86Sr ratio varied over a narrow range of 0.70797 to 0.70852 for a flow rate range of 6.1 to 41.51 s−1 and showed no relationship to flow rate. Weathering of non-radiogenic plagioclase feldspar in the soils controls the isotope signature of the streamwater and the constancy of the ratio with flow rate indicates that (1) more radiogenic minerals such as K-feldspar and mica do not contribute any more significantly during high flow than during low flow, and (2) from the available information, it is not necessary to take flow rate into account when using 87Sr/86Sr ratios in weathering studies in this particular catchment, although it must be emphasized that this conclusion may not apply to other catchments. The concentration of strontium in the streamwater was inversely proportional to the flowrate.  相似文献   

8.
We determined the chemical compositions of acidic stream waters on the rural, mountainous island of Yakushima (YK), and compared them with those of near-neutral stream waters in other mountainous watersheds in Japan. The pH and concentrations of the predominant sea-salt components (i.e., Cl?, Na+, Mg2+) in YK water, particularly in streams with small watersheds, decrease with elevation, while the concentration of Al increases. In contrast, water in northwestern YK contains higher concentrations of non-sea-salt SO42? and NO3? and of rock-derived cations such as Si and Ca2+ than water in eastern to southern YK. This clearly shows that the anthropogenic pollutants on YK are dominantly derived from the northwestern to western Asian continent rather than from Japan's main islands, which lie to the northeast. These pollutants are responsible for stream acidification on YK and for accelerating chemical weathering, mainly of plagioclase, in northwestern YK. Large amounts of acid rain on YK may enhance the formation of secondary minerals that strongly adsorb heavy metals, which can partly account for the low concentrations of heavy metals in YK waters.  相似文献   

9.
The natural Sr isotope composition of acid leached soils developed on loess, under beech forest, in central Belgium was used as a tracer of soil forming processes, in conjunction with physico‐chemical and quantitative mineralogical investigations. Attention was focused on weathering and exchange processes, with special emphasis on the origin of the current soil exchangeable fraction and the influence of the atmospheric deposition and biological cycling on the calcium exchangeable pool (Sr acts as a proxy for Ca). The determination of 87Sr/86Sr ratios was made on the bulk soil, on the clay‐ and silt‐size soil separates, on 0.1 m HCl extracts, on the labile pool, on the soil solution and on the bulk precipitation. The acid leached soil profiles are characterized by a sequence of weathering processes that is highlighted by both mineralogical and isotopic changes. From the calcareous unweathered loess (pH 7.5) to the uppermost soil horizons (pH < 4.0) the evolution of the 87Sr/86Sr isotope ratio clearly reflects: (i) the selective weathering of Ca‐plagioclase (small 87Sr/86Sr ratio) and the increasing proportion of resistant K‐ and Rb‐rich minerals (large 87Sr/86Sr ratio) in the uppermost soil horizons; and (ii) a downward translocation of clay minerals with a large isotopic ratio, a physical breakdown of muscovite and a non‐congruent chemical weathering of K‐feldspar. The influence of organic restitutions or atmospheric deposition is not significant. The comparison between the Sr isotopic signature of the soil solution, and the exchangeable and HCl‐extractible soil fractions provides information about cation exchange efficiency, soil–water interaction and the origin of the exchangeable pool.  相似文献   

10.
Mine tailings can provide a long-term source of environmental contamination. Lead-zinc mine tailings can represent a source of toxic elements-Pb and Zn through mobilization into surface water, and then into downstream rivers. Previous studies have shown that migration of heavy metals can be mitigated by carbonate rock. This research investigates the characterization of heavy metals and sulphur isotope in a downstream river of the Shanshulin Pb-Zn mine, which is located in Guizhou province in China, a typical carbonate area in the world. A slight alkalinity (pH > 8) of the river water is maintained owing to the carbonate rich country rocks. The results of this study show that heavy metals in water can be strongly adsorbed by suspended solids and therefore decrease more quickly than in sediments. Pb and Zn contents in water close to the waste pile are 6780 μg L-1 and 324 μg L-1 (Pb and Zn in water not affected by mine waste piles are only 3.71 μg L-1 and 11.6 μg L-1), respectively, meaning that the water is severely contaminated by the pile. Thirty kilometers downstream Pb and Zn contents in water drop quickly to 3.15 μg L-1 and 16.4 μg L-1. In contrast, Pb and Zn contents in sediment close to the waste pile are 4553 mg kg-1 and 7971 mg kg-1, respectively, and are still high 30 km downstream with measurements of 3334 mg kg-1 and 7268 mg kg-1 , respectively (Pb and Zn contents in sediment not affected by mine waste piles are only 20 mg kg-1 and 120 mg kg-1). This indicates that the impact of tailings on the sediment can be much further than on water. In sediment, Pb exists mostly as carbonate and oxide fractions, Zn mostly as sulfide+organic fraction, and Cu mostly as sulfide+organic, residual and carbonate fractions. Sulphur characteristics indicate that sulphur in sediment originates from mine tailing, soil and suspended solids in other tributaries, whereas sulphur in water originates from mine tailing dissolution, spring water, rain water and dissolution of gypsum. In conclusion, the environmental impact of mine tailing can be indicated by heavy metals content, sulphur content and sulphur isotope of sediment. On the other hand, heavy metal content, sulphur content or sulphur isotope of water are possibly not good indicators for mine impact due to mitigation of carbonate rocks, sorption of heavy metals, as well as interference of gypsum layers.  相似文献   

11.
The strontium isotope ratio (87Sr / 86Sr) of brown rice (Oryza sativa L.) was determined by multiple collector inductively coupled plasma mass spectrometry (MC-ICP-MS) in order to evaluate the values of 87Sr / 86Sr for use in the estimation of the area of rice production. Sample solutions were prepared from 5 g of rice samples using the acid (HNO3-HClO4-HF) digestion method. Removal of rubidium from the sample solutions was performed using ion-exchange resin (Dowex 50W X8). The Sr isotope ratios were determined with a precision of < 0.01% (RSD, repetitions = 60) by MC-ICP-MS. Typical analysis time for a single sample was about 15 min, reflecting the high sample throughput. The Sr isotope ratios of the Japanese rice samples ranged from 0.706 to 0.709. The Sr isotope ratios of the Chinese and Vietnamese rice samples (0.710 to 0.711) were slightly higher than those of almost all the Japanese samples. Australian rice showed the highest Sr isotope ratio (0.715 to 0.717) among all the rice samples examined. In contrast, the Sr isotope ratio of Californian rice (0.706) was lower than that of almost all the Japanese samples. The variation in the 87Sr / 86Sr ratios for the rice samples analyzed in this study clearly demonstrated that the Sr isotope ratios could provide a key information for the estimation of rice provenance.  相似文献   

12.
Wet and dry deposition inputs and streamflow output of Cd, Mn, Pb, Zn, and Al were measured intermittently at four deciduous forested watersheds in the southeastern United States between 1976 and 1982. Atmospheric inputs to each site were similar, varying by factors of 1.1 to 2.2 for the different metals. Metal levels in precipitation indicate that these sites are representative of rural, continental areas. Metals in rain exhibit significant temporal and spatial trends, with concentrations generally higher during summer than winter at all sites and generally lowest at the more remote site. The concentrations of Cd and Pb in both wet and dry deposition decreased between the period 1976 to 1977 and 1981 to 1982. Ion ratios and enrichment factors suggest that Mn is largely soil derived in atmospheric samples while Cd, Pb, and Zn are enriched over typical soil levels. Factor analysis indicates that soil components influence both Al and Mn while fine aerosol components influence Cd in wet and dry deposition. Both components influence the behavior of Pb. Dry deposition dominated the input of Mn and Al to each site, while wet deposition was the major input process for the other metals (54 to 85% of total). On an annual basis, deposited Cd, Pb, and Zn are strongly retained in each watershed: 2% of the Pb, 8 to 29% of the Cd, and 8 to 34% of the Zn inputs were transported in stream flow. Deposited Mn and Al are retained to a lesser degree and show a net loss from two sites. Metal export is controlled by stream pH, organic carbon, bedrock geology, and hydrologic characteristics of each site.  相似文献   

13.
We investigated the vertical profile of element distributions in the soil column on a granite substrate at three sites on the island of Yakushima, a world natural heritage site in southwestern Japan, where stream acidification due to acid rain is of increasing concern. Statistical analysis shows that the elements in the granitic soil can be classified into three groups according to their mineralogical derivations: Group 1 (K, Mg, Mn, Rb, and Nb), group 2 (Fe, Ti, Zr, Cr, and Pb), and group 3 (Ca, Na, Sr, and P), which are related to the presence of K-feldspar and K-mica, Fe-Ti oxides, and plagioclase and apatite, respectively. The pattern of distribution of group-1 elements in the soil column differs slightly among the sites because of differences in the proportions of K-feldspar and K-mica, The organic surface soil is enriched in group-2 elements and shows a strong magnetic susceptibility, indicating the presence of biogenetic magnetite. At all sites, Ca and Sr are intensely depleted due to the selective dissolution of plagioclase. Ca depletion compared to the original granite reaches more than 90 % in the C horizon, resulting in a decreasing capacity for the neutralization of acid rain and an increasing contribution of atmospheric Ca to the surface soil and vegetation.  相似文献   

14.
Naturally occurring isotopes of elements like strontium have proved to be good tools for tracing the past and for monitoring of processes in the present. The spread and variation in87Sr/86Sr ratios make Sr isotopes a powerful tool when it comes to detecting trends in the soil-vegetation system. There is also a great potential in combining different parameters like soil, water, biological material and isotopes for detecting environmental changes over short as well as long time periods. Sampling of the past is a difficult task but biological material, in combination with inorganic material, proves advantageous as environmental archives. There is also the possibility of using museum collections as environmental historic archives. This paper discusses the potential of using the natural87Sr/86Sr ratio as a tracer for environmental studies. The results presented point to an ongoing impoverishment of the environment and show that the temporal trend in Sr isotope composition for different media is similar despite material and location of test area.  相似文献   

15.
The concentration of some trace metals, like Fe, Mn, Cu, Pb, Zn, Co, Cr and Ni, was measured in the potable water of Cuttack City,India during winter, summer and rain events in the course of a two year period. Apart from Fe, all other trace metals fell well within the maximum permissible limit set by WHO for drinking water. On the basis of spatial/temporal variations, weathering of rocks and anthropogenic input were found to be main sources of trace elements in the ground water. The considerable temporal changes indicate that a majority of trace metals is entering the aquifer during rain fall.Factor analysis of the trace element data suggest that Fe, Mn and Cr are interrelated with each other and derived significantly from the aquifer, whereas input of Pb and Co may be due to atmospheric deposition in the study area.  相似文献   

16.
Yu  Ruilian  Lin  Chengqi  Yan  Yu  Hu  Gongren  Huang  Huabin  Wang  Xiaoming 《Journal of Soils and Sediments》2019,19(3):1499-1510
Purpose

The purposes of this paper are to investigate the geochemical characteristics of rare earth elements (REEs) in the surface sediments of Jiulong River, southeast China, to probe the provenance compositions of the sediments, and to analyze the potential anthropogenic influence on REEs in the sediments. REEs and Sr-Nd isotopes were selected as the tools because REEs can be used to identify the anthropogenic effects on sediments and Sr-Nd isotopes have been widely known as powerful tracers for provenance analysis.

Materials and methods

Fifty-three samples of surface sediments (0~5 cm) were collected from Jiulong River. The concentrations of REEs and Sr-Nd isotopic compositions in the surface sediments were determined by inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry (TIMS), respectively. The chondrite-normalized and WRAS-normalized REEs patterns, enrichment factor, plots of La-Th-Sc and La/Yb-∑REE, and plots of εNd(0) vs 87Sr/86Sr and εNd(0) vs δEu are presented.

Results and discussion

The mean concentration of ΣREEs in the surface sediments of Jiulong River was 254.25 mg kg?1. The mean values of ΣLREEs (227.6 mg kg?1), ΣHREEs (26.64 mg kg?1), and (La/Yb)N ratios (9.24) suggested an enrichment of LREEs compared to HREEs. Negative Eu anomalies were observed in the surface sediments. The distribution patterns of REEs in the surface sediments from different areas of Jiulong River were remarkably similar. The values of 87Sr/86Sr, 143Nd/144Nd, and εNd(0) were 0.714091~0.733476, 0.511875~0.512271, and ??14.88~??7.16, respectively. The plots of εNd(0) vs 87Sr/86Sr, εNd(0) vs 1/[Nd], and εNd(0) vs δEu indicated that the sediments in Jiulong River were mainly derived from natural geological processes and the REEs might be also influenced by anthropogenic activities such as Fujian Pb-Zn deposit, coal ash, and industrial sludge.

Conclusions

The REEs in the surface sediments at different sites are similar in geochemical characteristics, with a right-inclined distribution pattern and higher enrichment of light REEs (LREEs) compared to heavy REEs (HREEs), and a negative Eu anomaly but no evidence of Ce anomaly. The sediments in Jiulong River were mainly derived from natural geological processes (granite and magmatic rocks), and the REEs in the sediments were also influenced by anthropogenic activities (Fujian Pb-Zn deposit, coal ash, and industrial sludge).

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17.
Sequential leaching experiments using H2O, H2O2, NH4Cl, and HCl were performed on surface soils on an andesite substrate at four sites in the Kawakami mountainous area, central Japan. The solutions extracted from the dehydrated soil by H2O, H2O2, and NH4Cl have relatively constant ratios with respect to Ca, Mg, and Sr, while they have variable 87Sr/86Sr ratios depending on the site. The elemental ratios and Sr isotopes in the extracted solution are different from those of the soil minerals but identical to those of the soil solution and the plants. Sr isotopic data indicate that the residues after extraction from fine-grained minerals by NH4Cl and HCl are a mixture of acid-resistant minerals derived from bedrock and from arid areas in China. We suggest that there is a vital exchange of Sr and other cations between plants and the soil pool of exchangeable cations through the soil solution, while soil minerals, except chlorite, do not participate in the exchange reaction.  相似文献   

18.
The Influence of acid deposition on stream and lake water chemistry was studied in a forested watershed of Hyogo prefecture, Japan. Monthly sampling of four streams, one artificial lake, and precipitation was carried out from 1995 to 2000. The pH of the monthly bulk precipitation and rainwater were ranged from 4.06 to 7.10. No trends were evident during the monitoring periods. The pH and alkalinity in the four streams, which flow into the artificial lake, ranged from 6.37 to 8.72 and 0.077 meqL?1 to 0.485 meqL?1, respectively. The differences in the water quality of the four streams were related to the geology of each watershed. Lower pH and alkalinity were observed during high- discharge periods. On the other hand, the pH and alkalinity of the outflow from the lake ranged from 6.47 to 7.36 and 0.195 meqL?1 to 0.339 meqL?1, respectively. No acidification of the aquatic environment was observed during the investigated periods. The results suggest that this forested ecosystem has the capacity to neutralize incoming acid deposition.  相似文献   

19.
Ninety-one ground water samples (predominantly from springs) in two mineralized areas of the Ouachita Mountains in west-central Arkansas, were analyzed for Fe, Mn, Zn, Cu, Co, Ni, Pb, Hg, Sb, Sr, Ba, Ca, and Li. These areas contain Mn, barite, strontianite, cinnabar, stibnite and scattered Pb-Zn mineralization, Cumulative frequency curves were used to determine the threshold and anomalous concentrations for each element in the two areas. These values were, in general, higher in the ground water from the more mineralized area for several of the base metals, but most notably for Mn and Fe, the principal metals in the Mn oxide minerals. The United States Environmental Protection Agency (EPA, 1976) criteria for Fe (300 μg L ?1) and Mn (50 μg L?1) in drinking water were exceeded, respectively, in 34% and 30% of the springs in Area I, and 13% and 23% in Area II. One spring exceeded the EPA Hg criterion (2 μg L?1) and 3 springs exceeded the 50 μg L?1 criterion for Pb. In spite of the large number of anomalous Ba concentrations, the highest concentration of Ba was 930 μg L?1 (EPA criterion 1000 μg L ?1).  相似文献   

20.
Zabowski  D.  Henry  C. L.  Zheng  Z.  Zhang  X. 《Water, air, and soil pollution》2001,131(1-4):261-273
The impacts of mining to watersheds are highly variabledepending on the type of mining, processing of ores, andenvironmental factors. This study examined the Hei River incentral China, for impacts of gold and iron mining onconcentrations of metals in river water, river sediments andstream-channel soils. No production processing of ores occurson-site at either mine. Total metal content and extractablemetals using DTPA were determined. Total concentrations of Cd,Cu, Pb and Zn were high in some stream sediments and soils nearthe mine sites; metal concentrations ranged from 4–24, 11–100,11–380, and 33–1600 μg g-1 for Cd, Cu, Pb, and Zn,respectively, in soil. Total cadmium was high in all soilsand sediments. Extractable metals were low, with the exceptionof Pb and Cu. At the gold mine, extractable Pb ranged from 8 to33%; extractable Cu ranged from 3 to 21% of total metalconcentration. Chromium and Ni were not above typicalconcentrations in either soils or river sediments. An abundance of carbonates, high river water pH, and high water flow rates all appear to contribute to limiting quantities of metals in the river water. If mining activities are not changed, impacts of mining on downstream metal concentrations in river water should be nominal.  相似文献   

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