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1.
The environmental impact of arsenic and heavy metals on a 105 km2 area of the historical and recent mining site of Villa de la Paz-Matehuala, San Luis Potosí (Mexico) was evaluated. Results of soil samples reported concentrations between 19–17 384 mg kg-1 As, 15–7200 mg kg-1 Cu, 31–3450 mg kg-1 Pb and 26–6270 mg kg-1 Zn, meanwhile, the concentrations in dry stream sediment samples were found to vary between 29–28 600 mg kg-1 As, 50–2160 mg kg-1 Pb, 71–2190 mg kg-1 Cu, and 98–5940 mg kg-1 Zn. The maximum arsenic concentration in pluvial water storage ponds (265 μg L-1), near the main potential sources of pollution, exceed by 5 times the Mexican drinking water quality guideline (50 μg L-1). The arsenic concentrations in water storage ponds and stream sediments decrease as distance from the potential sources increase. A special case is the `Cerrito Blanco' area located 5 km east of Matehuala, where the highest arsenic concentration in water was found (>5900 μg L-1), exceeding by 100 times the established guideline, thus representing a severe health risk. The results suggest that arsenic and heavy metal dispersion from their pollution sources (historical and active tailings impoundments, waste rock dumps and historical slag piles), is mainly associated in this site with: (1) fluvial transportation of mine waste through streams that cross the area in W–E direction; and (2) aeolian transportation of mineral particles in SW–NE direction. Finally, control measures for pollution routes and remediation measures of the site are proposed.  相似文献   

2.
Monthly dustfall samples collected in 16 sites in the Tel-Aviv urban areas, as well as those collected in 10 rural sites in Israel during several years of measurements, were analyzed for their physical properties and chemical content. Although dustfall measurements represent a very simple and crude technique the analysis of the data provides some very interesting conclusions: (a) The southwest part of Israel, which is scarcely populated, suffers from high dustfall values due to dust storm blowing from the Sahara and other arid lands to the east Mediterranean during the spring. (b) On an annual basis the natural dustfall of dust storms origin amounts to 25 to 30% of the Tel-Aviv residential area deposition or 3 to 4 tonne km?2 mo?1. (c) Mapping of dustfall data within an urban region reflects fairly well the main industrial and commercial activities within the city. (d) In residential areas the inorganic water insoluble fraction of the dust is contributed by natural sources, while the organic fraction is mostly of anthropogenic origin. The inorganic water soluble fraction is spread in a uniform pattern within the city.  相似文献   

3.
Arsenic speciation in farmed Hungarian freshwater fish   总被引：2，自引：0，他引：2  
Arsenic speciation analysis was carried out on freshwater farmed fish collected from an area with elevated groundwater arsenic concentrations in Hungary as well as from outside of the area (control samples). The arsenic species were determined by high-performance liquid chromatography-inductively coupled plasma mass spectrometry on methanol extracts of the muscle tissue from the fish. Catfish (Claries gariepinus) were raised in geothermal water where the average total arsenic concentrations were 167 (contaminated sites) and 15.1 ng As mL(-1) (control); they were all fed an artificial diet containing 2880 microg As kg(-1) total arsenic, mostly present as arsenobetaine. In the catfish, the accumulated total arsenic (2510-4720 microg As kg(-1)) was found mostly in the form of arsenobetaine suggesting that uptake of arsenic was dominated by their diet. Carp (Cyprinus carpio) were cultured in surface lakes with no significant arsenic pollution and had total arsenic concentrations ranging from 62 to 363 microg As kg(-1). The arsenic species found in the carp extracts differed markedly from those in the catfish in that no arsenobetaine was detected. Most samples of carp from the investigated sites contained low concentrations of As(III) (arsenite), As(V) (arsenate), MA (methylarsonate), and DMA (dimethylarsinate), and no other compounds were detected. The four individuals from the control site, however, all contained appreciable levels of oxo-arsenosugar-glycerol and oxo-arsenosugar-phosphate. Indeed, the oxo-arsenosugar-phosphate dominated the speciation pattern for these carp contributing about 75% of the sum of species. The contrast between these two freshwater aquaculture species regarding total arsenic and arsenic species has relevant toxicological aspects in terms of food safety.  相似文献   

4.
The soils were sampled from the center of airborne contamination caused by long time activity of a copper/nickel smelter complex in the Kola Peninsula, Russia. The soil specimens were taken from an area about 250 km2, which included the town of Monchegorsk, with frequency of 1 sample (plot) per 3 km2 and heavy metals nickel, copper, cobalt, chromium, lead, cadmium, strontium, iron, manganese and arsenic were measured. The soil surrounding the Smelter, including the inhabited territory of the town, was found to be contaminated by nickel and copper to levels 450- and 250 times higher in comparison to the background, respectively. These soils were found to be extremely toxic and represented a severe threat to human health. Elevated concentrations of iron and arsenic caused by smelter emissions were found too.  相似文献   

5.
Terrestrial moss and humus (the O-horizon) are often used separately for determining and monitoring airborne heavy metal pollution. Here, we directly compare the results of analyses of moss and humus samples taken at a density of one site per 300 km2 in a 12 000 km2 area (45 samples) around the nickel smelter in Nikel, the nickel ore roasting plant in Zapoljarnij, both in Russia, and the iron ore mine and mill near Kirkenes in Norway. The samples were air dried, digested in conc. HNO3 and analysed for more than 30 elements by ICP-MS and ICP-AES at the laboratory of the Geological Survey of Finland (GTK). For most elements, observed levels and variations are considerably greater in soil than in moss. The main contaminants, Ni and Cu, reach equally high median levels in the moss and soil, but maximum values are far higher in soil. Both media show comparable regional distribution patterns for the heavy metals, but not for sulphur. Cu and Ni can be used to delineate the limits of contamination in the survey area. Both media show the same picture, with a generally very steep gradient from east to west and background levels being reached 30–50 km from the nickel smelter. When moss is used, Cu/Ni, Cu/S and Ni/S ratios can be used to separate input from the smelting and roasting proccesses in Russia. Both media are well suited to use separately to detect airborne pollution in this heavily contaminated area. The moss data are generally easier to interpret, but moss is not available at the most polluted sites. Levels for many elements other than Cu and Ni are close to the detection levels in moss samples, but not in humus samples. Information gathered from both media thus complement each other in a regional multi-element survey.  相似文献   

6.
钢铁工业区降尘对周边土壤的影响   总被引：5，自引：1，他引：5  
分别在南京的两个钢铁厂收集降尘并采集周边表土,并用ICP-AES和磁化率仪分析得到16种元素含量和表土、地面尘的磁化率。结果表明,两个钢铁工业区的大气降尘的年沉降通量分别为190t km-2a-1和407 t km-2a-1,这可能会影响着周边地区土壤的形成;Al、K、Na、Ti、V在降尘中的含量显著低于表土,而Ca,Fe,Zn,Mn,Pb,Cu在降尘中含量要显著高于表土;表土的磁化率除水田外均大于100×10-8m3kg-1,并且地面尘的磁化率要远远高于表土的磁化率。研究表明,钢铁工业区降尘对其周边土壤中污染元素的积累有明显影响,突出地表现在土壤表层重金属含量升高,而磁化率可以很好地表征这种表聚的特点。  相似文献   

7.
Dust deposition and particle size in Mali, West Africa   总被引：5，自引：0，他引：5  
Dust deposition samples were collected during April and May (1990) at four sites on the inland delta region of Mali in West Africa. High dust deposition rates were measured and characterised by considerable variations between sites. A major dust plume passed over the area, following a dust storm near Gao, 500 km to the east, however the contribution of this plume to overall deposition was surprisingly small.Dust particle-size characteristics indicate mixing of dusts from three sources. Long-distance dust deposition producing fine deposits (mainly < 5 μm); dust from regional sources producing deposits mainly in the size range 20–40 μm; and local dust arising from human activities, particularly vehicle and livestock movements, producing relatively coarse material in the size range 50–70 μm, plus some fines. Local dusts appear to have made the greatest contribution to deposition, with a moderate (though less than expected) contribution from the plume and a minor contribution from long-distance dusts.These results have implications for dust deposition studies aimed at quantifying dust contributions to soils. Although these Mali dust deposition rates are high (2.5–28.6 t−1 km−2 day−1), the significant proportion of locally derived dust means that new dust inputs to the soils of the Inland Delta region of Mali are small.  相似文献   

8.
The total concentrations of nickel, copper, chromium, strontium, arsenic, lead, cadmium and cobalt were measured in berries and mushrooms, as well as manganese and iron in mushrooms. The study area (about 3500 km2) is situated on the border of the northern taiga and tundra forests (68–69°N) and is affected by emissions from the extensive Ni-Cu smelter complex at Monchegorsk, Kola Peninsula, NW Russia. Part of the study area, extending along the railway line used for transporting apatite concentrate, contains elevated quantity of strontium. Berries of Vaccinium vitis-idaea (82 samples), Vaccinium myrtillus (28), Rubus chamaemorus (42) and Empetrum hermaphroditum (40) and mushrooms of Leccinum auantiacum (47 samples), Leccinum scabrum (32), Russula vesca (25), Lactarius torminosus (8), Lactarius trivialis (9), Suillus luteus (10) and Xerocomus subtomentosus (20 specimens) were collected from 98 locations during 1987–1992. The nickel and copper concentrations in the berries, and nickel in mushrooms, correlated satisfactorily with the corresponding metal concentrations in the soil. The berries and mushroons growing over an area of at least 3000 km2 around the smelter complex are unsuitable for human consumption due to the elevated nickel concentrations caused by the smelter dust emissions. The berries and mushrooms gathered in the studied polluted forests were found to be contaminated by nickel by a factor of 15–30 times (berries) and 15–40 times (mushrooms) more than the background level. Increased levels of strontium were found close to the railway line. The concentrations of all the other metals in the studied area did not exceed sanitary standards.  相似文献   

9.
The aim of the present study was to elucidate thedistribution of particulate polycyclic aromatichydrocarbons (PAH) in the air of a remote Norwayspruce (Picea abies (L.) karst.) stand.The study encompassed a total of twenty differentcongeners. Particles in ambient air were alternativelycollected by two different Berner cascade impactors atthe field site in Northern Bavaria over a 14-weeksperiod from the end of April through to the end ofJuly 1994 and subsequently analyzed for their PAHcontent. The concentrations of total suspendedparticulate matter (TSP) ranged from 9–31 μg m-3,suggesting that the field site is an area with a lowlevel of airborne particles. There was a negativerelationship of total particle concentrations with theamount of canopy precipitation due to particle washout at precipitation events. The distribution of theparticle masses on the different size fractions witha maximum in the 1-μm range is typical for remoteareas and indicates a medium-range transport. Theaerosol-bound PAH load decreased from spring sampleswith 2–4 ng m-3 to values <1 ng m-3 in the summersamples. Concurrently, the proportion of low molecularweight congeners in the total PAH load declined.Frequently, the highest PAH concentrations (referringto the air) were found in the 0.1–3 μm sizeseparates (accumulation mode). The results suggestthat apart from PAH input to the soil with litter, dryand wet deposition of aerosol particles is animportant pathway of PAH contamination of acid forestsoils in the Fichtelgebirge mountain range.  相似文献   

10.
Arsenic pollution in ground water in India and Bangladesh is considered to be the largest contamination problem in the world. About 15?–?18% of the area of West Bengal, India comes under the threat of arsenic (As) contamination and around 5.36 million people are exposed to this hazard. A detailed isoline map corresponding to variations in arsenic concentration and their spatial distribution was prepared for the study area, which comprised two villages Ghentugachi and Gotera in Nadia district, West Bengal and the total area covered was 808 hectares. The pattern of arsenic contamination was highly irregular and diverse. About 11.2% of the study area was affected most (?>?0.50?mg As l?1) with sample As values reaching 0.71 and 0.80?mg?l?1. About 22.5% of the area had As content between 0.20 and 0.50?mg?l?1 and 33.9% of study area had As content below the WHO guideline of 0.01?mg As/l. Thus the local population living around these areas is vulnerable and exposed to arsenic contamination. None of the water samples exceeded the allowable limit (1.0?mg As l?1) of As for water used in irrigation purposes. The spatial distribution map helped to determine zones with different As concentrations, making it possible to identify high-risk zones.  相似文献   

11.
Electrocoagulation (EC) has been evaluated as a treatment technology for arsenic (As) removal. Experiments were developed in an electrochemical reactor with three parallel iron plates. Current densities of 15, 30, and 45 A m?2 were used to treat model water and 45 A m?2 to treat underground water (GW). For both types of water, the EC process was able to decrease the residual arsenic concentration to less than 10?μg L?1. However, the treatment time for As removal from GW was higher. This phenomenon was attributed to the competition of dissolved species present in GW such as silica and calcium with arsenic for the adsorption sites on the ferric oxyhydroxides flocs generated during the EC process. A procedure is proposed to reduce such interference by the addition of a silica adsorption inhibitor compound into the GW achieving a reduction in the process time. The adsorption of arsenic species over adsorbent was found to follow Lagergren adsorption model.  相似文献   

12.
Abstract

To evaluate the effect of increasing forest disturbances on greenhouse gas budgets in a taiga forest in eastern Siberia, CO2, CH4 and N2O fluxes from the soils were measured during the growing season in intact, burnt and clear-felled larch forests (4–5 years after the disturbance). Soil temperature and moisture were higher at the two disturbed sites than at the forest site. A 64–72% decrease in the Q 10 value of soil CO2 flux from the disturbed sites compared with the forest site (5.92) suggested a reduction in root respiration and a dominance of organic matter decomposition at the disturbed sites. However, the cumulative CO2 emissions (May–August) were not significantly different among the sites (2.81–2.90 Mg C ha?1 per 3 months). This might be because decreased larch root respiration was compensated for by increased organic matter decomposition resulting from an increase in the temperature and root respiration of invading vegetation at the disturbed sites. The CH4 uptake (kg C ha?1 per 4 months [May–September]) at the burnt site was significantly higher (–0.15) than the uptake at the forest (–0.045) and clear-felled sites (0.0027). Although there were no significant differences among the sites, N2O emission (kg N ha?1 per 4 months) was slightly lower at the burnt site (0.013) and higher at the clear-felled site (0.068) than at the forest site (0.038). This different influence of burning and tree felling on CH4 and N2O fluxes might result from changes in the physical and chemical properties of the soil with respect to forest fire.  相似文献   

13.
Purpose

The study was conducted to quantify the polycyclic aromatic hydrocarbons (PAHs) accumulation in urban soils from different functional areas via atmospheric inputs with particulate matter.

Materials and methods

PAH concentration and pattern were measured in the particulate matter of snow depositions, in the upper layers of artificial soils from densely built-up areas and in the undisturbed natural soils (Umbric Retisols) from green park area. Samples were collected in 2011–2013 at 58 sites with different traffic activities located at the territory of the Eastern Administrative Okrug of Moscow. The soil samples and filters with particulate matter were extracted by pressurized liquid extraction using Dionex ASE200. Clean-up analyses were performed on SPE cartridges filled with silica gel. Concentrations of PAHs were determined by high-performance liquid chromatography using an Agilent 1100 System equipped with fluorescent detector.

Results and discussion

Mean values of PAH input with snow particles were 45–57 μg/m2 for recreational and residential zones, and 140–264 μg/m2 for traffic zones. The samples of depositions from different functional areas showed a similar PAH pattern and consisted primarily of 3–4-ring PAHs. Total PAH concentrations in upper layers of artificial soils showed similar mean values of 1.43–2.21 μg/g for all functional zones. The PAH content in soils from the park area was twofold lower than that from the built-up area (0.34–0.63 μg/g), despite equal levels of atmosphere contamination on these territories. The upper layers of natural soils from recreational and traffic zones showed slight differences in PAH content, though PAH input with snow was fivefold higher in the traffic zone. Compared with airborne depositions, soils contained significant amounts of 5–6-ring PAHs.

Conclusions

A high level of soil PAH contamination in urban areas of Moscow, several orders of magnitude higher than the current PAH input to them from the atmosphere, indicates a lack of direct connection of the PAH pool in soils with this source. The high PAH content in the upper layer of constructed soils can be the result of repeated use of materials subjected to a constant technogenic impact for the production of artificial soils.

  相似文献   

14.
A multi-stage particle sampling instrument and a particle counter were operated at the ground monitoring site in Fukuoka where was directly exposed to the outflow of air masses from the Asian continent during the springtime of 2005. The bulk and individual dust particles were analyzed simultaneously by ICP-MS and micro-PIXE, respectively. The ground-based observation of dust storm by the Japan Meteorological Agency and by the NOAA HYSPLIT dispersion-trajectory model indicated that dust storm was driven from the Chinese continent including dust source area. The number concentration of gigantic particles (e.g., larger than 5 μm) was measured to be 10 times higher in an Asian dust storm (hereafter called “ADS”) period than in a non-ADS period. There is an outstanding increase of mass concentration in the range of 3.5–7.7 μm in ADS event. In ADS event, soil fraction accounts 57.9–70.1% of particle mass concentration in coarse particles larger than 3.5 μm. Micro-PIXE analysis enables us to classify individual dust particles into several types. The particles with 3.5–5.1, 5.1–7.7, and 7.7–10.9 μm experienced aging processes by 60.6, 69.2, and 77.2%, respectively. On the basis of the reconstructed elemental maps by micro-PIXE analysis, the chemical transformation of dust particles was also presumed.  相似文献   

15.
The concentration and size distribution of bacterial and fungal aerosol was studied in 15 houses. The houses were categorized into three types, based on occupant density and number of rooms: single room in shared accommodation (type I), single bedroom flat in three storey buildings (type II) and two or three bedroomed houses (type III). Sampling was undertaken with an Anderson six-stage impactor during the summer of 2007 in the living rooms of all the residential settings. The maximum mean geometric concentration of bacterial (5,036 CFU/m3, ± 2.5, n?=?5) and fungal (2,124 CFU/m3, ± 1.38, n?=?5) aerosol were in housing type III. The minimum levels of indoor culturable bacteria (1,557 CFU/m3, ±1.5, n?=?5) and fungal (925 CFU/m3, ±2.9, n?=?5) spores were observed in housing type I. The differences in terms of total bacterial and fungal concentration were less obvious between housing types I and II as compared to type III. With reference to size distribution, the dominant stages for culturable bacteria in housing types I, II and III were stage 3 (3.3–4.7 μm), stage 1 (7 μm and above) and stage 5 (1.1–2.1 μm), respectively. Whereas the maximum numbers of culturable fungal spores were recovered from stage 2 (4.7–7 µm), in housing type I, and from stage 4 (2.1–3.3 μm) in both type II and III houses. The average geometric mean diameter of bacterial aerosol was largest in type I (4.7 μm), followed by type II (3.89 μm) and III (1.96 μm). Similarly, for fungal spores, type I houses had the highest average mean geometric diameter (4.5 μm), while in types II and III the mean geometric diameter was 3.57 and 3.92 μm, respectively. The results indicate a wide variation in total concentration and size of bioaerosols among different residential settings. The observed differences in the size distributions and concentrations reflect their variable airborne behaviour and, as a result, different risks of respiratory exposure of the occupants to bioaerosols in various residential settings.  相似文献   

16.
The metal content was determined in soil and vegetation around the eastern zone of the disused sulphur and copper mines at Avoca (southeast Ireland). A 250 m × 250 m grid survey was conducted covering a total area of 4 km2. The mining belt was in the centre of the investigated site and was sampled separately. Iron, Zn, Cu and Cd concentrations in soil and plant material were determined, in addition to soil organic matter content and soil pH. Soil samples taken from the spoil showed elevated Cu and Cd concentrations, and low soil pH and organic matter content. At least 50 per cent of the agricultural sites examined around the East Avoca Mine showed elevated soil Cu and Cd concentrations, whereas Zn and Fe soil concentrations were within the range for unpolluted soils. None of the vegetation analysed had elevated Zn, Cd, Fe or Cu concentrations. Overall there was no indication of serious metal contamination in either soils or vegetation surrounding the mine in spite of extensive dust deposition during open-pit mining activity 15–30 years ago. However, a plume of elevated Cu in the soil was identified, which originated from a large spoil heap and had been spread for some 2·0 km by the prevailing wind.  相似文献   

17.
The concentrations of seven metals (Fe, Pb, Mn, Ni, Cd, Cu, and Cr) associated with the total suspended particles (TSPs) were analyzed regularly from the four sampling sites of different land-use types within the boundary of Won Ju city, Korea during1991 through 1995. The mean concentration data for the four sitesselected to represent grassland, residential, commercial, and industrial areas fell in a relatively broad range of: 1440–2240 (Fe), 88–326 (Pb), 2–4 (Cd), 8–21 (Cr),194–469 (Cu), 32–95 (Mn), and 15–26 (Ni) ng m-3. The data, when compared across the different study sites, generally exhibited systematic trends in accordance withthe site-selection scheme; most metals exhibited increase in their concentration levels across grassland through industrial site. Examinations of data also indicated the possibility that spatial factors play complicated roles on both long- and short-term distribution of metals. From all four sites studied, severalmetals (e.g., Fe, Pb, Mn, Ni, and Cd) consistently showed theirseasonal trends characteristic of high winter/spring values. In addition, the analysis of long-term distribution trendsindicated that the concentrations of many metals droppedsteadily at four sites (e.g., Fe, Pb, and Mn). When these metaldata were compared among different sites (land-use types), significant correlations were seen frequently for such metals asFe, Pb, Cd, and Cr. Investigations of inter-metal relationshipsindicated that strong correlations were more abundant from such metal pairs as Fe-Pb, Pb-Mn, and Mn-Fe. In addition, the cases for such strong correlations were seen more abundantly from grassland (and residential) than industrial (and commercial) site. Factor analysis was also conducted to distinguish sourceprocesses affecting metal distributions in the study area. Results of this analysis suggest that the metal distributions ofthe individual sites may be affected most significantly by distinctive source processes of their own.  相似文献   

18.
We describe an approach for evaluating the representativeness of eddy covariance flux measurements and assessing sensor location bias (SLB) based on footprint modelling and remote sensing. This approach was applied to the 12 main sites of the Fluxnet-Canada Research Network (FCRN)/Canadian Carbon Program (CCP) located along an east-west continental-scale transect, covering grassland, forest, and wetland biomes. For each site, monthly and annual footprint climatologies (i.e. monthly or annual cumulative footprints) were calculated using the Simple Analytical Footprint model on Eulerian coordinates (SAFE). The resulting footprint climatologies were then overlaid on to images of the Normalized Difference Vegetation Index (NDVI) and Enhanced Vegetation Index (EVI) derived from LANDSAT Thematic Mapper (TM) imagery, which were used as surrogates of land surface fluxes to estimate SLB. Results indicate that (i) the sizes of annual footprint climatology increased exponentially with increasing cumulative footprint percentages and, for a given percentage of footprint climatology, the footprint areas were significantly different among the sites. Typically, the 90% annual footprint climatology areas varied from 1.1 km2 to 5.0 km2; (ii) using either NDVI or EVI as the flux surrogate, the SLB was less than 5% for most sites with respect to the reference area of interest (Ar) at 90% annual footprint climatology (scenario A) and a circular area with radius of 1 km centred at the individual tower (scenario B), with several exceptions; (iii) the SLB decreased with increasing size of footprint climatology for all sites for both scenarios A and B; (iv) out of 12, eight flux towers represented most of the ecosystem surrounding the towers for an area of 0.3 km2 up to 10 km2 with a satisfactorily low bias of <5%, whereas four towers represented areas ranging from only 0.75 to 4 km2; and (v) the seasonal differences in monthly SLB using NDVI as a flux surrogate were about 1-4% for most sites for both scenarios A and B.  相似文献   

19.
Distributions of Mn, Zn, Cu, Ni, Cr, Pb, As, and Cd in Finnish surface waters were studied by comparing two data sets: samples from 154 headwater lakes collected by the Water and Environment Administration in 1992 and samples from 1165 headwater streams collected during the environmental geochemical mapping program of the Geological Survey of Finland in 1990. It was expected that headwater lakes with catchments smaller than 1 km2 and high lake percentage (ratio of lake area to catchment size) would be more influenced by atmospheric trace metal deposition than the streams, with average catchment size of 30 km2. The lakes with highest arsenic concentrations lie in an area with greenstones and arsenic-rich black schists. The same lakes have high copper concentrations, which evidently are derived from the Cu-rich greenstones of the catchment. The high copper concentrations of streams and lakes in the industrialized region of the southwest coast are due to several anthropogenic sources. The highest concentrations of chromium occur in brown stream and lake waters rich in humic matter, while manganese and zinc concentrations, which are controlled by acidity, tend to be elevated in low-pH waters. The high nickel concentrations in lakes in southwestern Finland probably are due to anthropogenic input, while Ni anomalies in stream and lake water in eastern Finland are correlated with high Ni contents of glacial till. The lead concentrations in lakes are mainly of airborne anthropogenic origin. The pattern of atmospheric deposition is reflected in the concentrations of Cd, As, Cu, Zn, and Ni in headwater lakes, but land-use, the natural distribution of metals in the overburden, water acidity, and the amount of humic substances influence the distribution of trace metals in both lakes and streams. Thus the trace metal distribution in headwater lakes cannot be used alone to estimate the contribution of anthropogenic atmospheric deposition to metal anomalies in Finnish surface waters.  相似文献   

20.
Mining operations are potential sources of airborne metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern USA by climate models may make contaminated atmospheric dust and aerosols increasingly important, with potential deleterious effects on human health and ecology. Fine particulates such as those resulting from smelting operations may disperse more readily into the environment than coarser tailings dust. Fine particles also penetrate more deeply into the human respiratory system and may become more bioavailable due to their high specific surface area. In this work, we report the size-fractionated chemical characterization of atmospheric aerosols sampled over a period of a year near an active mining and smelting site in Arizona. Aerosols were characterized with a ten-stage (0.054 to 18???m aerodynamic diameter) multiple orifice uniform deposit impactor (MOUDI), a scanning mobility particle sizer (SMPS), and a total suspended particulate collector. The MOUDI results show that arsenic and lead concentrations follow a bimodal distribution, with maxima centered at approximately 0.3 and 7.0???m diameter. We hypothesize that the sub-micron arsenic and lead are the product of condensation and coagulation of smelting vapors. In the coarse size, contaminants are thought to originate as Aeolian dust from mine tailings and other sources. Observation of ultrafine particle number concentration (SMPS) show the highest readings when the wind comes from the general direction of the smelting operations site.  相似文献   

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