首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 15 毫秒
1.
The effect of main chain structure of anion-containing copolyesters on the properties of copolyester sizing agents was investigated. The copolyesters were prepared by conventional two step polymerization technique from DMT, DMI, DMS, EG, and DEG. The copolyesters synthesized were characterized by atomic absorption spectroscopy,1H-NMR Spectroscopy, GC, FTIR Spectroscopy, and DSC. The solubility decreased as the DMT content increased. The copolyesters having DMT:DMI=1:1 showed the minimum viscosity. The effect of EG content on the solution stability was not clear and the samples having high DMI content showed better solution stability. The water resistance was best when only DMI and EG were used, while it was worst when DMT:DMI was 1:0.  相似文献   

2.
A series of copolyesters (Co-PETs) containing poly(ethylene glycol) (PEG), 5-sodiumsulfodimethyl isophthalate (DMS), and dimethyl isophthalate (DMI) were synthesized via the conventional two-step melt-polycondensation method. The synthesized Co-PETs were characterized by 1H-NMR spectroscopy, FT-IR spectroscopy, differential scanning calorimeter (DSC), and thermogravimetric analyzer (TGA). The DSC results showed that the melting temperature (T m) and the heats of fusion (ΔH m) of Co-PETs decreased with increasing the DMS content in Co-PET, while the inclusion of PEG did not affect their thermal properties significantly. The water absorption and the water contact angle of the Co-PET films were found to be significantly affected by the DMS content rather than PEG content. The moisture-related cooling properties of the fabric samples made of Co-PET 5 as well as PET were evaluated by using liquid moisture management tester (MMT) and Q max measurements. The MMT and Q max results indicated that Co-PET 5 fabric containing DMS 1.0 mol% and PEG 10.0 wt% in Co-PET seemed to be a good candidate for the fabric having durable cooling effects.  相似文献   

3.
We herein report the preparation and crystallization behavior of polylactide (PLA) nanocomposites reinforced with polyhedral oligomeric silsesquioxane-modified montmorillonite (POSS-MMT), which is prepared by exchanging sodium cations of pristine sodium montmorillonite (Na-MMT) with protonated aminopropylisobutyl polyhedral oligomeric silsesquioxane (POSS-NH3 +). PLA nanocomposites with 1–10 wt% POSS-MMT contents are manufactured via melt-compounding, and their structures and melt-crystallization behavior are investigated. It is characterized that POSS-MMT nanoparticles in the nanocomposites have an exfoliated structure of MMT silicates with POSS-NH3 + and partial POSS-NH2 crystals. DSC cooling thermograms suggest that the overall melt-crystallization rates of the nanocomposite with only 3 wt% POSS-MMT are remarkably enhanced in comparison with the neat PLA. From the isothermal crystallization analysis based on the Avrami model, the overall melt-crystallization of PLA/POSS-MMT nanocomposites is found to be dominated by the heterogeneous nucleation and three-dimensional spherulite growth. Isothermal melt-crystallization experiments using a polarized optical microscope show that the spherulite nucleation density of PLA/POSS-MMT nanocomposites is much higher than that of the neat PLA, whereas the spherulite growth rates of all the nanocomposites are almost identical with the rate of the neat PLA. It is concluded that the highly enhanced melt-crystallization rates of PLA/POSS-MMT nanocomposites stem from the dominant nucleation effect of POSS-MMT nanoparticles for PLA crystals.  相似文献   

4.
A novel self-colored polyethylene terephthalate (PET) was synthesized using a synthesized dye, 4-amino-N-propanoic acid-1,8-naphthalimide. For this purpose, the prepared naphthalimide dye was added upon the polycondensation step and then a self-colored PET was prepared by step-growth polymerization. The characterization of synthesized self-colored PET and naphthalimide dye were carried out using TLC, FTIR, 1HNMR, DSC, UV-visible and Fluorometery. Results indicated that, the novel fluorescent yellow-green PET with appropriate properties was obtained. The glass transition temperature of self-colored PET was 70 °C and it was measured by differential scanning calorimeter, which revealed that addition of dye to the chains of polymer did not affect the context of glass transition of polymer. UV-visible spectrum indicated that, 99 percent of dye was incorporated in polymer chains chemically. Furthermore, the intrinsic viscosity of self-colored PET was 0.556 dl/g and molecular weight of polymer was around 35000 (g/mol) and measured using the viscometer technique.  相似文献   

5.
Long term performance of conductivity of p-toluene sulfonic acid (pTSA) doped electrochemically synthesized polypyrrole (PPy) films was estimated from accelerated aging studies between 80 °C and 120 °C. Conductivity decay experiments indicated that overall aging behavior of PPy films deviated from first order kinetics at prolonged aging times at elevated temperatures. However, an approximate value for the activation energy of the conductivity decay of PPy was calculated as E=47.4 kJ/mol, enabling an estimate of a rate constant of k=8.35×10−6/min at 20 °C. The rate of decrease of conductivity was not only temperature dependent but also influenced by the dopant concentration. A concentration of 0.005 M pTSA in the electrolyte resulted in a conductive film and when this film was exposed to 120 °C for a period of 40 h, the conductivity decayed to about 1/20 of its original value. The concentration of pTSA was increased to 0.05 mol/l and when the resulting film was aged in the same way, it showed a decrease in the conductivity to about 1/3 of its original value. Both microwave transmission and dc conductivity data revealed that highly doped films were considerably more electrically stable than lightly doped films. The dopant had a preserving effect on the electrical properties of PPy.  相似文献   

6.
The thermal behavior, morphology, ester-interchange reaction of Poly(trimethylene terephthalate) (PTT)/Poly(ethylene terephthalate) (PET) melt blends were investigated over the whole composition range(xPTT/(1-x)PET) using a twinscrew Brabender. The melt blends were analyzed by differential scanning calorimetry (DSC), nuclear magnetic resonance spectroscopy (13C-NMR), and scanning electron microscopy (SEM). Single glass transition temperature (T g ) and cold crystallization temperature (T cc ) were observed in all melt blends. Melt blends were found to be due to the ester-interchange reaction in PTT/PET blend. Also the randomness of copolymer increases because transesterification between PTT and PET increases with increasing blending time. This reaction increases homogeneity of the blends and decreases the degree of crystallinity of the melt blends. In PTT-rich blends, mechanical properties decrease with increase of PET content compared with that of pure PTT. And, in PET-rich blends, tensile modulus decreases with increase of PTT content, but tensile strength and elongation is similar to that of pure PET.  相似文献   

7.
A meta‐analysis of feeding trials using grass silages was conducted to predict production responses for dairy cows fed grass silage. They were divided into two subsets: 69 diets from 11 studies were used for comparison of silages made from primary growth and regrowth grass (harvesting subset), and another 157 diets from 24 studies were used for comparison of digestibility influenced by the maturity of grass ensiled (D‐value, digestible organic matter in dry matter) (maturity subset). The minimum prerequisite for an experiment to be included in the data set was that milk production, feed intake, silage characteristics and concentrate ingredients were reported. Both subsets were analysed using the mixed model procedures of SAS. The mean response in dry‐matter intake (DMI) and silage DMI to improved silage D‐value was 0.0175 and 0.0161 kg per unit D‐value (g/kg DM) respectively. The average increase in milk and energy‐corrected milk yield was 0.30 and 0.37 kg per 10‐unit increase in silage D‐value respectively. Milk protein concentration increased, and fat concentration tended to increase with enhanced silage D‐value. Each 10‐unit increase in D‐value reduced milk yield by 0.092 kg at a given dietary metabolizable energy intake (MEI), suggesting that the ME concentration of high D‐value silages was overestimated. Cows fed regrowth silage produced 0.55 kg/day more energy‐corrected milk than those fed primary growth silage at a given dietary MEI. The prediction models can be used to improve ration formulation systems or incorporated into economic models for optimizing milk production in various farming systems.  相似文献   

8.
Nylon 4, which can be synthesized by anionic ring-opening polymerization, has good mechanical properties and a very high affinity for water owing to its high polarity. On the other hand, despite its high melting temperature, the polymer has not been commercialized because of its low thermal stability. In this study, copolymerization of 2-pyrrolidone (C4) with 2-piperidone (C5) was performed to reduce the melting temperature of Nylon 4 homopolymer. The copolymerization reaction was controlled by changing the comonomer content, catalyst content, temperature, initiator content, and reaction time. The Nylon copolymers were characterized by 1H-nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. The hydrophilic properties of Nylon 4 and its copolymers were evaluated by surface free energy analysis and moisture regain measurement. The intrinsic viscosity and polymerization yield of Nylon 4 increased with increasing catalyst concentration until 5 mole% and decreased with further increases in catalyst loading. The proton NMR spectrum revealed the composition of the Nylon 4/5 copolymer to be 62.5 % C4 moiety at a 5:5 comonomer feed ratio. The melting temperature of the Nylon 4/5 copolymers decreased considerably according to the composition. The moisture regain of the Nylon 4/5 copolymer was higher than 6.4 % even at 77.3 % C4 in composition.  相似文献   

9.
The PLA/PAE blends with four different weight ratios were prepared by melt mixing. PLA and PAE in PLA/PAE blends were almost immiscible while the weak interaction between PLA and PAE existed. The sub-micrometer PAE domains were dispersed in PLA matrix uniformly. The physical aging of PLA could be inhibited by introducing PAE. For PLA/PAE, the structure formed by physical aging at room temperature induced the accelerated crystallization of PLA during heating. However, for neat PLA, the structure formed by physical aging had a negligible effect on the crystallization of PLA during heating. The isothermal crystallization kinetics of neat PLA and PLA/PAE were analyzed by Avrami theory. The values of Avrami exponent were within the range 2.1–3.0. The crystallization rate of PLA was enhanced significantly by addition of PAE.  相似文献   

10.
A new monomer (2-N,N-dimethylamino-4,6-bis(2-furan)-pyrimidine) was synthesized and its homopolymer was successfully prepared by using ferric trichloride as an oxidant. The structure of monomer and polymer were fully characterized by 1H-NMR, FT-IR, UV, fluorescent spectroscopy, and X-ray diffraction. The N,N-dimethylformamide solution of the polymer showed a UV-Vis peak at 387 nm and the PL spectrum gave a peak at 517 nm. We have observed that the polymer was sensitive to inorganic acids and the protonation behavior was investigated applying inorganic acids such as HCI and H2SO4. The corresponding UV-Vis peaks were observed at 464 and 357 nm, respectively. X-ray diffraction data shows that polymer had a certain crystalline region. The polymer exhibited an [η] value of 0.21 dl/g at 25 °C in H2SO4 (w=98 %).  相似文献   

11.
We have synthesized a series of copolymers with different compositions of acrylonitrile (AN, 80–100 wt%), methyl acrylate (MA, 4–20 wt%) and itaconic acid (IA, 0–3 wt%) by using an efficient aqueous suspension polymerization, and have investigated the molecular structure and thermal stabilization behavior of PAN homopolymer, AN/MA-based bipolymers, and AN/MA/IA-based terpolymers by adopting 1H/13C-NMR and thermal FT-IR analyses. The viscosity-average molecular weight of the synthesized polymers were measured to be ~263,000 g/mol. The reactivity ratios of AN and MA for all the copolymers were evaluated to be 0.99 and 1.05, respectively. Accordingly, the output compositions of the synthesized copolymers were quite consistent with the input monomer compositions. The 13C NMR analysis revealed that all the synthesized polymers have an atactic chain configuration, regardless of the feed composition. The structural evolutions during the thermal stabilization process of the copolymers in air environment were characterized by monitoring the temperature-dependent changes of characteristic absorbance bands at 2240 cm-1 (C≡N), 1595 cm-1 (C=N) and 1660 cm-1 (C=O) with aid of thermal FT-IR spectroscopy. It was found that the IA unit in the terpolymers accelerated the oxidation and cyclization reactions, unlike the retarding effect of MA unit, and that the onset temperatures of the oxidation reaction of the copolymers with IA unit was lower than that of the cyclization reaction.  相似文献   

12.
In the UK, two demethylation inhibitor (DMI) fungicides, myclobutanil and fenbuconazole, are recommended for controlling apple scab. Experiments were conducted to determine whether the sensitivity of V. inaequalis to myclobutanil was correlated with that to fenbuconazole. There was a marked reduction in the sensitivity of V. inaequalis to myclobutanil; averaged ED50 values increased from 0.338 mg L−1 in the baseline population to 2.945 mg L−1 for isolates from a commercial orchard. Overall, the average ED50 value for fenbuconazole was only about 20% of that for myclobutanil for the baseline population. There was an overall significant positive correlation in the fungal sensitivities to myclobutanil and fenbuconazole, but such correlation only accounted for 40% of the total observed variability. In addition, the magnitude of this cross-resistance varied among orchards. The finding is discussed in the context of fungicide deposition in relation to disease control.  相似文献   

13.
An experiment involving forty-five British Friesian cows in mid-late lactation was carried out to evaluate the effects of ensiling on herbage digestibility, dry-matter intake and milk production. The herbage from the primary growth of a predominantly perennial ryegrass sward that had received 123 kg N ha?1 was zero grazed (ZG) from 27 April to 24 May 1992. Before going onto the experimental diets all animals were offered a common silage as the sole diet and dry-matter intakes and milk yields were recorded. The herbage was mown, picked-up with a precision-chop harvester and offered as the sole diet, twice daily, 10 fifteen cows that were on average 176 days into lactation. On May 20 herbage from the same sward was harvested identically to the ZG herbage and ensiled, alternative loads being untreated (UT) or treated with formic acid (2.4 l?1) (FA). For silages UT and FA respectively, pH values were 3.94 and 3.92 and ammonia nitrogen concentrations were 95 and 75 [g(kg total N?1)]. Forty-two days after ensiling, the silages were fed twice daily as the sole diet to thirty cows which were on average 166 days into lactation. The feeding interval was 28 days and the last 7 days was the main recording period for each treatment. For diets ZG, UT and FA, dry-matter intakes (DMI) (kg d?1), milk yields (kg d?1), fat plus protein yields (kg d?1). milk fat concentration (g kg?1), milk protein concentration (g kg?1)and fat plus protein yields [kg (kg DMI)?1] were 12.70, 11.51 and 12.07 (Av s.e.d. = 0.458); 12.79, 10.01 and 10.18 (Av s.e.d. = 0.346); 0.900, 0.649 and 0.682 (Av s.e.d. = 0.026); 39.8, 33.7 and 36.7 (Av s.e.d. = 0.174); 32.9, 29.9 and 30.0 (Av s.e.d. = 0.83); 0.073, 0.055 and 0.055 (Av s.e.d. = 0.003). UT treatment significantly increased dry matter (DM), organic matter (OM). energy and crude fibre digestibilities and the digestible OM concentration. UT and FA compared with ZG altered rumen fermentation patterns, significantly decreasing butyrate and increasing valerate concentrations. FA treatment significantly decreased the non-glucogenic ratio. It is concluded that ensiling using formic acid had no effect on forage DMI relative to the parent fresh herbage. Ensiling either untreated or with formic acid significantly decreased milk yield and milk fat plus protein yield, resulting in a lower efficiency of conversion of DMI to milk fat plus protein.  相似文献   

14.
Functionalized poly(ethylene terephthalate) (PET) fibers were synthesized by grafting of maleic acidmethacrylamide (MAA-MAAm) monomer mixtures by using benzoylperoxide as initiator onto PET fibers in an aqueous medium. The functionalized fibers were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimeter, and scanning electron microscopy. The effects of reaction conditions, such as monomer mixture ratio, monomer mixture and initiator concentration, polymerization time, and temperature on grafting were investigated. In alone grafting of MAA, grafting was not observed. However, the use of MAAm as a comonomer increased the amount of MAA inserted to the PET fiber up to 40.7 %. An increase in the temperature between 75 and 95 °C and also, increase in monomer mixture concentration between 0.50 and 1.00 M increased the grafting rate and saturation graft yield. The graft yield has shown an increase up to an initiator concentration of 1.0×10−2 M and decreased afterwards. The grafting increased the dyeability with disperse, acidic and basic dyes, and water absorption capacity but decreased the thermal stability of the fibers.  相似文献   

15.
A cellulose-graft-poly(methyl acrylate) was synthesized by free radical initiating process and the ester functional groups were converted into the hydroxamic acid ligand. The intermediate and final products are characterized by FT-IR, FE-SEM, HR-TEM and XPS technique. The pH of the solution acts as a key factor in achieving optical color signals of metalcomplexation. The reflectance spectra of the [Cu-ligand]n+ complex was found to be a highest absorbance at 99.8 % at pH 6 and it was increased upon increasing of Cu2+ ion concentrations and a broad peak at 700 nm was observed which indicated the charge transfer (π-π transition) metals-Cu complex. The adsorption capacity of copper was found to be superior (336 mg g?1) rather than other transition metals such as Fe3+, Co3+, Cr3+, Ni2+, Mn2+ and Zn2+ were 310, 295, 288, 250, 248 and 225 mg g-1, respectively at pH 6. The experimental data of all metal ions fitted significantly with the pseudo-second-order rate equation. The transition metal ions sorption onto ligand were well fitted with the Langmuir isotherm model (R2>0.99), which suggested that the cellulose-based adsorbent known as poly(hydroxamic acid) ligand surface is homogenous and monolayer. The reusability of the poly(hydroxamic acid) ligand was checked by the sorption/desorption process up to ten cycles without any significant loss in its original sensing and removal performances.  相似文献   

16.
Natural sawdust of Calabrian pine was explored as low-cost industrial by-product for a hetero-bireactive dye removal from aqueous solution in this study. Batch experiments were carried out to investigate the effects of contact time and dye concentration on biosorption efficiency. Maximum biosorption amounts were achieved almost in the 20-30 min of contact for the studied dye range (50-200 mg l -1). An increase in the dye concentration resulted in decrease in the percent dye removal and increase in the biosorption capacity of biosorbent. Different kinetic and isotherm models were used to examine the biosorption experimental data for elucidating the dye removal mechanism. The equilibrium data were best represented by Freundlich isotherm model confirming multilayer coverage. The kinetics of dye biosorption best obeyed the pseudo-secondorder equation. The negative value of standard Gibbs free energy change (-3.61 kJ mol-1) indicated that physical forces were involved in the spontaneous dye biosorption. Thus, the sawdust as a possible non-conventional biosorbent presented an interesting option for bioremediation of contaminated environments by such unsafe dyes.  相似文献   

17.
Adsorption of Pb(II) ions from aqueous solution onto tobacco stems has been investigated to evaluate the effects of initial lead ion concentration, adsorbent dosage, contact time, pH and temperature on the removal of Pb(II) systematically. The optimal pH value for Pb(II) adsorption onto the tobacco stems was found to be 5.0. The removal of lead ions for concentrations 10, 30 and 50 mg L−1 using 0.8 g adsorbent at contact time of 120 min and at temperature of 299 K were 94.37%, 92.10% and 90.43%, respectively. Thermodynamic parameters such as standard Gibbs free energy (ΔG°), standard enthalpy (ΔH°), and standard entropy (ΔS°) were evaluated by applying the Van’t Hoff equation, which describes the dependence of equilibrium constant on temperature. The thermodynamics of Pb(II) adsorption onto the tobacco stems indicated that the adsorption was spontaneous and endothermic. Langmuir and Freundlich isotherms were used to analyze the equilibrium data at different temperatures and the equilibrium data were found to fit Freundlich isotherm equation better than Langmuir isotherm. The adsorption was analyzed using pseudo-second-order kinetic equation.  相似文献   

18.
In the polycondensation reaction of polyethyleneterephthalate(PET), Sb2O3 can react effectively as a catalyst, if physically transformed. Sb2O3 powder is transformed into liquid solution by dissolving in ethylene glycol(EG). Homogeneous catalyst is made by mixing this liquid solution with glycols having different solubility. The efficient reaction of PET polymerization is expected by using homogeneous catalyst. PET was synthesized using homogeneous catalysts of 4 wt.% Sb2O3 solution dissolved in glycol[EG, 2,2-bis(4-(2-hydroxyethoxy)phenol)propane(BHPP), neopentyl glycol(NPG), and 1,3-propandiol(PD)]. PET using EG-BHPP(Sb2O3) catalysts shows the highest I.V. within a reaction time of 120 min. In the p-d analysis, PET using EG-BHPP(Sb2O3) catalysts has the fastest propagation rate and slowest degradation rate. EG-BHPP(Sb2O3) catalysts are more efficient than EG(Sb2O3) catalysts and Sb2O3 powder catalysts.  相似文献   

19.
In order to get stronger interaction between dyes and PET fabrics, the ester groups were introduced into biomass alizarin. 1,2-diacetoxyanthraquinone was synthesized in high yield by treating biomass alizarin with different esterification conditions. The di-esterified alizarin was characterized and confirmed by FT-IR, HPLC-MS, and 1H-NMR. The build-up property and the dyeing performance of alizarin and esterified alizarin on PET were investigated, respectively. The results show that the optimum esterification condition is treating biomass alizarin with acetic anhydride and anhydrous sodium acetate at 60 °C for 1.5 h. The build-up property of esterified alizarin is better than that of the biomass alizarin. Moreover, samples dyed with esterified alizarin without auxiliary and mordant can exhibit good levelness and fastness property. It means that the esterified alizarin is supposed to perform environment friendly dyeing for PET fabric.  相似文献   

20.
Development of a novel fixed site carrier membrane (FCM), supported by PET fabric for metal ion separation is reported. The membranes were prepared by dipping PET fabric into the methylene chloride solution of Poly(5-vinyl-m-phenylene-m′-phenylene-32-crown-10)_ (P(VCE)), a polymeric metal ion carrier. It was found that the flux of mono-valent metal ion transported across the membrane is significantly differed from each other and the flux decreases in the order Cs+>Rb+>K+>Na+>Li+ irrespective to the anion except perchlorate anion. It was explained in terms of the stability of the complex, formed by crown ether unit of the P(VCE) and the various metal ions, meanwhile, the lower rate of transport in the presence of perchlorate anion was ascribed to its low hydrophilicity.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号