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1.
Abstract

In this study, a new parallel and sequential extraction procedure was proposed to investigate the solubility of metals [cadmium (Cd), zinc (Zn), copper (Cu), and nickel (Ni)] and their association with soil components in naturally metal‐rich soils of Norway. Two different soils, alum shale (clay loam) and moraine (loam), developed on alum shale minerals were used. Each soil had two pH levels. For parallel and successive extractions, H2O, 0.1M NH4OAc (soil pH), 0.3M NH4OAc (soil pH), 1M NH4OAc (soil pH), and 1M NH4OAc (pH 5.0) were used. A significant amount of Cd was extracted by NH4O Ac related to concentration of NH4OAc in the extracting solution. The amounts of Zn, Cu, and Ni extracted by these reagents were almost negligible except with 1M NH4OAc (pH 5.0). Thus these metals were strongly bound to soil components. A seven step sequential extraction procedure was applied to evaluate the association of metals with soil constituents. The extractions were performed sequentially by extracting the soil with reagents having an increasing dissolution strength: 1M NH4OAc (soil pH), 1M NH4OAc (pH 5.0), 1M NH2OH.HCl (in 25% HOAc), 1M NH2OH.HCl (in 0.1M HNO3), 30% H2O2 (in 0.1M HNO3), 30% H2O2 (1M HNO3), and aqua regia. In both soils at both pH levels investigated, appreciable percentages of total Cd (20–50%) were found associated with the NH4OAc extractable fraction (mobile fraction). For Zn, Cu, and Ni, the percentage of total metal extracted with NH4OAc was low (<4%), but it increased significantly by introducing a reducing agent (NH2OH.HCl). The NH2OH.HCl‐extractable fraction was the greatest fraction (>60%) for all four metals examined. These results suggest that among the metals studied, only Cd was easily desorbed from soil and should be considered mobile and potentially bioavailable. Other metals (Zn, Cu, and Ni) were strongly associated with the soil components and should be considered less available to plants. Using the sequential fractionation technique as a measure of availability, mobility and potential bioavailability of these four metals in the alum shale soils were: Cd>Zn>Ni>Cu.  相似文献   

2.
Abstract

A study was conducted to calibrate and evaluate five buffers for the lime requirement (LR) determination of tropical peat soil. The buffers tested were the Shoemaker‐McLean‐Pratt (SMP); Mehlich; 0.1M ammonium acetate (NH4OAc); 0.1M barium acetate [(Ba(OAc)2]; and 0.1M calcium acetate [Ca(OAc)2]. Calibration was done by comparing the precision of linear regression equations adjusted to the relationships between the LR rates required to achieve pH 5.0 measured in a 1: 4 (soiltwater) ratio as determined by incubation and soil‐buffer pH values. Incubation LR using calcium carbonate (CaCO3) to achieve pH 5.0 by peat soil was utilized to calibrate each buffer. Evaluation was carried out by assessing the LR from the calibrated buffers which estimate the LR nearest to the target pH of 5.0. The calibration study showed that the SMP and Mehlich buffers were less precise than the Ba(OAc)2, NH4OAc, and Ca(OAc)2 buffers. The evaluation study indicated that the Ba(OAc)2 buffer is the most accurate, followed by NH4OAc and Ca(OAc)2 buffers. The Ba(OAc)2 buffer method is recommended for LR determination of tropical peat soil and NEUOAc or Ca(OAc)2 as an alternative method.  相似文献   

3.
A reliable soil test is needed for estimating mercury (Hg) availability to crop plants. In this study, four extraction procedures including 0.1 M hydrochloric acid (HCl), 1 M ammonium acetate (NH4OAc) (pH 7.0), 0.005 M diethylenetriaminepentaacetic acid (DTPA), and 0.1 M calcium chloride (CaCl2) (pH5.0) were compared for their adequacy in predicting soil Hg availability to crop plants of a rice–cabbage–radish rotation system. The amounts of Hg extracted by each of the four procedures increased with increasing equilibrium time. The optimal time required for extraction of soil Hg was approximately 30 min, though it varied slightly among the four extractants. The amounts of Hg extracted decreased with increasing soil/solution ratio, and a soil/solution ratio of 1:5 appeared to be adequate for soil Hg availability tests. The amounts of Hg extracted increased in the order of NH4OAc < CaCl2 < DTPA < HCl in silty loam soil (SLS) soil, and the order was NH4OAc < CaCl2 ≈ DTPA < HCl in yellowish red soil (YRS) soil. Significant positive correlations among the four extractants were obtained in SLS soil. In contrast, the correlations were poor in YRS soil, especially for HCl. There were significant correlations between concentrations of Hg in edible tissue of three plants and the amounts of soil Hg extractable to the four extractants for soil–rice system and soil–radish system, but not for soil–Chinese cabbage system. The 0.1M HCl extraction overall provided the best estimation of soil‐available Hg and could be used to predict phytoavailability of Hg in soil–crop systems.  相似文献   

4.
In this study, we selected three soil pedons on the shoulder, backslope, and footslope along a serpentine toposequence to measure cobalt (Co) extractability using six single‐extraction procedures. These extraction procedures are distilled water, 0.11 M acetic acid in the first step of the BCR sequential extraction (BCR1), 1 M ammonium acetate (NH4OAc; pH 7.0), 0.01 M calcium chloride (CaCl2), diethylenetriamine pentaacetic acid (DTPA), and 0.1 M hydrochloric acid (HCl). Although the Co concentrations in the water extracts of the study soils ranged from 0.15 to 0.93 mg kg?1, those with HCl extraction can be up to 22.1 mg kg?1. The extractable Co concentrations in the study soils demonstrate that the extraction capacity is in the order HCl > DTPA > CaCl2 ? NH4OAc > BCR1 > H2O. The percentages of extractable Co after applying the six single‐extraction procedures reveal that Co mobility is greatest in the soils on the backslope, moderate on the footslope, and least mobile on the shoulder.  相似文献   

5.
Surface soil (0–15 cm) and foliar samples of wheat, rice, sugarcane, and cotton crops growing in eight intensively cultivated soil series of India were collected from farmers' fields during 2004 and 2005. Analysis of soil and leaf samples indicated widespread potassium (K) deficiency in soils and crops. Potassium deficiency in wheat growing in Lukhi series (Udic Ustocrept) and Akbarpur series (Udic Haplustulf) and in cotton growing in Typic Torrifluvent were comparable to 1N ammonium acetate (NH4OAc)–K (available K) soil test values. Rice cultivated on Udic Ustocrept soils in summer monsoon season showed relatively less K deficiency in comparison to winter wheat, and K deficiency in growing rice did not match 1N NH4OAc‐K soil test values. In the Khatki series, K deficiency in sugarcane was much less than 1N NH4OAc‐K soil test values. In the Arsia series (Typic Haplustert), despite the high 1N NH4OAc‐K status of soils, K deficiency in growing wheat was observed.  相似文献   

6.
Compost of separately collected green yard and organic household wastes may contain high amounts of Zn. Hence, substrates basing on compost can result in Zn phytotoxicity. The aim of the investigations was to identify a suitable reagent to characterize phytoavailable Zn in compost-peat substrates. Petunia hybrids were cultivated in compost-peat substrates with increasing Zn amounts (basic load, 400, 800, 1600 mg kg?1 d.m. aqua regia soluble). Extractable Zn was determined by extraction of fresh and dried substrates with H2O, 1 M NH4NO3, 0.1 M CaCl2, 1 M NH4OAc, and CaCl2-DTPA (0.01 M + 0.002 M). The Zn content of plants increased significantly with increasing Zn application and decreasing pH. The result of CaCl2 and NH4OAc extraction reflected the influence of pH on Zn phytoavailability quite well and the correlation with the plant Zn content was very good. Extraction with H2O and NH4NO3 did not give acceptable results. Extraction with CaCl2-DTPA was inconsistent for all trials and thus not suitable. The percentage of CaCl2-extractable Zn in relation to the aqua regia soluble content at the same pH varied over the trials. Thus, the phytoavailable content of the substrates is influenced by additional factors, besides Zn supply and pH. The result of CaCl2 extraction of dried substrates resulted in the best reflection of Zn phytoavailability and was used for all further investigations, including determination of critical values of phytotoxic Zn. Plant yield was not influenced by the Zn treatments. However, Zn induced chlorosis of petunias occurred at a plant Zn content > 160 mg kg?1 d.m. and a phytoavailable Zn content in the substrate > 6 mg l?1 in CaCl2 extract and > 2.6 mg l?1 in NH4OAc extract, respectively.  相似文献   

7.
采集浙江杭州郊区富春江沿岸镉(Cd)污染水稻土，选择前期试验筛选的对土壤Cd钝化效果良好、可显著降低稻米Cd的4种调理剂，开展室内培养试验和温室盆栽试验，探讨不同调理剂种类(袁梦YM、祝天峰ZTF、天象一号TX1、永清YQ)、用量(推荐用量、3倍推荐用量)和调理剂与生石灰配施对污染水稻土Cd的稳定效果及对水稻生长和糙米Cd含量的影响。室内培养试验结果发现，添加调理剂能使土壤pH显著升高，落干条件下土壤pH增幅较淹水条件下更为明显；施用推荐用量调理剂，土壤硝酸铵提取态Cd显著下降，调理剂推荐用量+生石灰处理较调理剂推荐用量处理下降更为显著；总体上，同一调理剂3倍推荐用量处理下硝酸铵提取态Cd降幅更大，表明硝酸铵提取态Cd受土壤pH影响显著，且YM、TX1调理剂对硝酸铵提取态Cd的降低效果较好。盆栽试验结果显示，施用石灰和商品调理剂均可实现水稻稳产或增产，并显著降低水稻糙米Cd含量，与调理剂施用后土壤Cd有效性降低相一致。含钙、能调节土壤pH并辅以有机质和养分的复合调理剂因兼具养分作用，对水稻稳产增产、糙米Cd含量降低更为有效。  相似文献   

8.
Abstract

Zinc of index corn leaves samples from 91 Minnesota sites on numerous soil types was correlated with soil Zn extracted by four routine procedures. The EDTA?(NH4)2CO3 ‐ extractable soil Zn was more closely correlated with leaf Zn than soil zinc extracted by 0.1N HCl, EDTA‐NH4OAc, or by NH4OAc ‐ dithizone. Soil pH, CaCO3 equivalent, extractable P, and organic matter of both acid and calcareous soils were negatively correlated with leaf Zn. When EDTA ? (NH4)2CO3 ‐ extractable Zn was included with routine soil tests, a prediction equation for corn leaf Zn was formulated and compared with analytical values. However, the use of 1.4 ppm EDTA ? (NH3)2CO3, ‐ extractable soil Zn alone as a critical value was equally effective in predicting leaf Zn.  相似文献   

9.
Abstract

Soil pot culture experiment was conducted on 22 soils of Balewal‐Phaguwala‐Narike (BPN) and 24 soils of Isri‐Langrian‐Narike (ILN) associations using rice (PR 106) as test crop at 0 and 7.5 ppm Zn levels. Chelating extractants 0.005M DTPA, 0.01M EDTA‐(NH4)2CO3 and 0.05M EDTA, extracted more soil Zn than double‐acid and were significantly correlated with each other as well as with soil pH and clay in BPN and only with clay in ILN soil association. Soil CaCO3 governed the double‐acid extractable Zn in these soils. Dry matter yield and Zn uptake by rice significantly increased with 7.5 ppm Zn application. The response was higher in ILN than BPN soil association, The DTPA method gave the highest correlation with Bray's yield and Zn uptake (r =0.72 and 0.55) followed by 0.05M EDTA (r ‐ 0.75 and 0.61) or EDTA‐(NH4)2CO3 (r =0.70 and 0.61). The predictability of rice yield improved from 18–27 to 27–35, 32–43, 34–44 and 51–55 percent as a result of stepwise inclusion of pH, CaCO3, organic carbon (OC) and clay respectively in the regression equation alongwith Zn extracted by chelating agents.

The critical levels of DTPA, EDTA‐(NH4)2CO3 and EDTA extractable Zn significantly differed in the two associations and were 0.69, 0.82 and 1.24 ppm in BPN and O.BC, 1.09 and 1.42 ppm in ILN soil association. Soil properties further affected the critical levels. This for DTPA available Zn was 0.80 and 1.03 ppm in soil containing less and greater than 2% CaCO3, 1.03 and 0.80 ppm in soils containing less and greater than 0.25% OC. These values for EDTA‐(NH4)2CO3 available Zn were 1.09 and 0.91 ppm Zn in soils containing less and greater than 15% clay suggesting that critical levels of Zn for each category of soil properties should be considered while making recommendations of Zn fertilization of crops.,  相似文献   

10.
Most Brazilian soil-testing laboratories use Mehlich 1 and 1.0 M potassium chloride (KCl) solutions as extractants for the determination of phosphorus (P), potassium (K), and sodium (Na) and for exchangeable calcium (Ca), magnesium (Mg), manganese (Mn), and aluminum (Al) in agricultural soil samples. Other laboratories use a combination of exchangeable ionic resin and KCl procedures. With recent adoption of the inductively coupled plasma (ICP-OES) in routine soil-testing laboratories, soil extraction with 1.0 M ammonium chloride (NH4Cl) became an alternative due to the possibility of determining all exchangeable elements in one run (Ca, Mg, K, Mn, Na, and Al), leaving determination of phosphorus (P) with Mehlich 1 or exchangeable ionic resin. To evaluate the performance of the NH4Cl solution, an experiment was carried out with thirty-seven samples of soils representative of the southernmost state of Brazil, Rio Grande do Sul. Four extraction solutions [Mehlich 1 at soil/solution ratio of 1:10 and 1.0 M ammonium acetate (NH4OAc), 1.0 M KCl, and 1.0 M NH4Cl at soil/solution ratio 1:20] were used with three different shaking times (5, 30, and 60 min). Correlation coefficients among all methods were high. Mehlich 1 did not perform well against NH4OAc and NH4Cl, despite the high correlation coefficients, with values consistently lower for K, even when the time of extraction was increased from 5 to 30 or 60 min. However, for concentrations less than 0.30 cmol kg?1 (i.e., in the range of K deficiency), both solutions performed similarly. Calcium and Mg increased with time of shaking. Comparable values of exchangeable Ca, Mg, and K, as well as of Al and Mn, were obtained with 1.0 M NH4Cl with 60 min shaking and the standard procedures of 1.0 M NH4OAc and 1.0 M KCl. The determination of Al by traditional titration/back-titration of the 1.0 M KCl solution gave slightly greater results compared to ICP-OES obtained using extraction with 1.0 M NH4Cl. The results indicate that for Ca, Mg, Mn, and Al, it is possible to replace the traditional 1.0 M KCl extraction with 1.0 M NH4Cl solution, with 60 min shaking time and a soil/solution ratio of 1:20.  相似文献   

11.
Abstract

In soil samples from two study sites in southern Norway, exchangeable cations were determined using two different ammonium (NH4)‐salts as extractant. As expected, the cation exchange capacity (CEC) determined in 1M ammonium acetate (NH4OAc), buffered at pH 7.0 was higher than the CEC measured in ammonium nitrate (NH4NO3). By contrast, the amount of exchangeable calcium (Ca), magnesium (Mg), and barium (Ba) was lowest in the NH4OAc extract, in particular in the upper soil horizons high in organic matter (O‐ and E‐horizon). This suggests that NH4 in 1M NH4OAc does not compete effectively with multivalent base cations. The relatively high levels of exchangeable base cations in NH4NO3 could not be explained by increased weathering. An increase in selectivity of especially divalent cations may explain the relatively low amount of exchangeable base cations extracted by NH4OAc, as this involves increased deprotonation and thus a higher negative charge.  相似文献   

12.
The suitability of seven chemical extractants was evaluated on 24 Indian coastal soils for prediction of plant-available potassium (K) to rice (Oryza sativa L. var. NC 492) grown in modified Neubauer technique. Average amounts of soil K extracted were in descending order: 0.5 M NaHCO3 > neutral 1 N NH4OAc > 0.02 M CaCl2 > Bray and Kurtz No.1 > 1 N HNO3 > 0.1 N HNO3 > distilled water. The highest simple correlation with plant K uptake was obtained with 0.1 N HNO3-K (r = 0.848) and lowest with CaCl2-K (r = 0.805). Predictive models were developed using plant K uptake as the dependent variable and extractable soil K, sand, silt, soil pH, and electrical conductivity as the independent variables. Based on the final R2 and ease of measurement, distilled water, 1 N NH4OAc, and 0.1 N HNO3 models were the best predictors of plant-available K in coastal soils when used along with sand or soil pH.  相似文献   

13.
本工作是研究在CaCO3体系和石灰性土壤体系中NH3的挥发与磷的吸附之间相互作用的化学变化,结果表明:在NH4Cl—CaCO3体系中,通气的pH值比不通气的低,但溶液中Ca2+浓度正好相反。在K2HPO4-CaCO3体系中,在24小时内,通气与不通气的,CaCO3吸附磷没有差异。在24小时反应期间,在DAP-CaCO3体系中,因溶液pH值不断增高,NH3的挥发对CaCO3吸附磷的影响也就逐渐降低。在石灰性土壤体系中,施用尿素加过磷酸钙或单施尿素时,几乎没有发现NH3的挥发,而施DAP时,在6天后,NH3的挥发损失占加入的56%,且DAP处理的土壤,其水溶性磷未通气比通气的高。尿素加过磷酸钙处理的,其水溶性磷通气与未通气的没有差异。另外,尿素加过磷酸钙或过磷酸钙单独处理的土壤,水溶性磷含量均相同。所有这些均表明,在石灰质体系中,NH3的挥发(如果发生的话)能够加强CaCO3对磷的吸附,而磷的吸附又能加强NH3的挥发,两者是相互影响和相互促进的过程。  相似文献   

14.
Abstract

To assess soil-to-plant transfer of various elements more precisely, the concentrations of the elements extracted from soil samples using eight chemical solutions were compared with the results of a pot cultivation experiment of komatsuna (Brassica rapa L. var. perviridis) or buckwheat (Fagopyrum esculentum M.) using the soils. From agricultural fields in Aomori, Japan, 16 soil samples were collected. Elements in the samples were extracted using acids (1 mol L?1 HNO3, 0.1 mol L?1 HNO3, 0.01 mol L?1 HNO3), chelating agents (0.05 mol L?1 EDTA), neutral salt solutions (1 mol L?1 NH4OAc, 1 mol L?1 NH4NO3, 0.01 mol L?1 CaCl2) and pure water. The 28 elements in the extracted solutions and plant samples were determined. The extractability of many metals was higher in 1 mol L?1 HNO3, 0.1 mol L?1 HNO3 and the 0.05 mol L?1 EDTA solutions than in the other extractants. Higher extractability using the NH4OAc solution than the NH4NO3 solution was observed for some elements, in particular U. Extractability by pure water was not always lowest among these methods, probably because of dispersion of colloidal substances in the extracted solution. The pot cultivation experiment showed that the concentrations in soil and in the extracted fraction using 1 mol L?1 HNO3, 0.1 mol L?1 HNO3 or the EDTA solution did not correlate with the concentration in plant samples for most elements. Plant uptake of Zn, Y and La by komatsuna correlated well with their concentrations in extracts with neutral salt solutions or 0.01 mol L?1 HNO3. Concentrations of Al, Cu and Cd in buckwheat were also correlated with the concentrations in the extracts.  相似文献   

15.
Human exposure to toxic heavy metals via dietary intake is of increasing concern. Heavy-metal pollution of a rice production system can pose a threat to human health. Thus, it was necessary to develop a suitable extraction procedure that would represent the content of metal available to rice plants (Oryza sativa L.). The aim of this study was to predict, on the basis of single extraction procedures of soil heavy metals, the accumulation of heavy metals (cadium, lead, copper, and zinc) in rice plants. Six extracting agents [Mehlich 1, Mehlich 3, EDTA (ethylenediaminetetraacetic acid), DTPA–TEA (diethylenetriaminepentaacetic acid–triethanolamine), ammonium acetate (NH4OAc), and calcium chloride (CaCl2)] were tested to evaluate the bioavailability of heavy metals from paddy soils contaminated with lead–zinc mine tailings to rice. The extraction capacity of the metals was found to be of the order EDTA > Mehlich 3 > Mehlich 1 > DTPA–TEA > NH4OAc > CaCl2. The correlation analysis between metals extracted with different extractants and concentrations of the metals in the grain and stalk of the plant showed positive correlations with all metals. The greatest values of correlation coefficients were determined between the NH4OAc- and CaCl2-soluble fractions of soil and contents in plants in all four metals studied. Therefore, NH4OAc and CaCl2 were the most suitable extractants for predicting bioavailability of heavy metals in the polluted soils to rice. The results suggested that uptake of heavy metals by rice was mostly from exchangeable and water-soluble fractions of the metals in the soils. Soil-extractable metals were more significantly correlated with metal accumulation in the stalk than in the grain. The pH had more significant influence on availability of heavy metals in the soils than total content of metals and other soil properties. The bioavailability of metals for rice plants would be high in acidic soils.  相似文献   

16.
Solution concentrations of total Al and of mononuclear Al ions were determined as a function of pH for two acid soils. Polynuclear hydroxy-Al was taken as the difference between total and mononuclear Al. Salt concentration at 1 : 5 soil: solution ratio was varied from 0·008 to 1·o equiv/l, for CaCl2, KCl, and NH4OAc at pH 4·8. Polynuclear hydroxy-Al concentrations increased with electrolyte concentration and the valency of the desorbing cation, and rose to 0·2 mM (equivalent to 3 meq/kg soil) in unbuffered salt suspensions, and to 1·0 mM in NH4OAc at pH 4·8. Polynuclear hydroxy-Al thus behaves like a normal exchangeable cation. I.0M NH4OAc released much more total A1 from some of the more acid samples than might have been expected from its pH of 4·8.  相似文献   

17.
有机肥无机肥配施对稻田氨挥发和水稻产量的影响   总被引：64，自引：17，他引：64  
在南方红壤区双季稻田进行田间试验,研究等氮、磷、钾量条件下,有机无机肥配施对稻田氨挥发及水稻产量的影响。结果表明,有机无机肥配合施用能显著地降低稻田氨挥发,减少氮素损失,提高氮肥利用率。单施化肥(尿素),其氨挥发损失达37.8%,而单施有机肥和有机无机肥各半配合施用,氨挥发损失分别为0.7％-1.0％和7.2％-18.2％。田间氨挥发持续的时间,早稻约在施肥后20d,晚稻为9-10d。虽然有机无机肥各半配合施用的水稻产量与单施化肥的相近,均比对照提高约70％,但前者的氮损失少,其氮肥利用率为34.9％,高于化肥处理(33.2％)和有机肥处理(28.0%)。有机无机肥配合施用对提高水稻产量和降低氮肥环境负效应的综合效应最佳。  相似文献   

18.
The anionic nature and high cation exchange capacity (CEC) of clinoptilolite zeolite can be exploited to reduce ammonia (NH3) loss from urea and to improve soil chemical properties to increase nutrient utilization efficiency in lowland rice cultivation. A closed-dynamic airflow system was used to determine NH3 loss from treatments (20, 40, and 60 g clinoptilolite zeolite pot?1). Seed germination study was conducted to evaluate the effects of clinoptilolite zeolite on rice seed germination. A pot study was conducted to determine the effects of clinoptilolite zeolite on rice plant growth variables, nutrient uptake, nutrient recovery, and soil chemical properties. Standard procedures were used to determine NH3 loss, rice plant height, number of leaves, number of tillers, dry matter production, nutrient uptake, nutrient recovery, and soil chemical properties. Application of clinoptilolite zeolite (15%) increased shoot elongation of seedlings and significantly reduced NH3 loss (up to 26% with 60 g zeolite pot?1), and increased number of leaves, total dry matter, nutrient uptake, nutrient recovery, soil pH, CEC, and exchangeable Na+. Amending acid soils with clinoptilolite zeolite can significantly minimize NH3 loss and improve rice plant growth variables, nutrient uptake, nutrient recovery, and soil chemical properties. These findings are being validated in our ongoing field trials.  相似文献   

19.
Abstract

Twenty surface soil samples were collected from Nainital Tarai (foothills of Himalya) where “Khaira”; disease (Zn deficiency of rice) is prevalent. Rice (Oryza sativa L. variety IR‐8) was grown in pots for 8 weeks after transplanting. Experiments were conducted to determine the suitability of five soil Zn extractants: dilute acid (HCl + H2SO4) mixture; DTPA‐(NH4) 2CO3, pH 7.3; dithizone; NH4OAc, pH 4.6; and 2N MgCl2 to predict Zn deficiency. Critical values for soil available Zn were established for rice by the old and new Cate and Nelson procedures1.

Zinc extracted from the soils with dithizone; NH4OAc, pH 4.6; 0.2N MgCl2. and DTPA‐(NH4) 2CO3 pH 7.3 was significantly correlated with the uptake of Zn by the rice plants. The correlation between Zn extracted with the dilute acid (HCl + H2SO4) mixture and plant Zn was not statistically significant. The ex‐tractants which extracted greater quantities of Zn gave higher critical values and vice versa. It is concluded that all extracting solutions except the dilute acid (HCl + H2SO4) mixture were found to he suitable for predicting available Zn in rice soils of Tarai.  相似文献   

20.
Abstract

A new soil test procedure using 1M NH4Cl was developed for the extraction of plant‐available cadmium (Cd) from soils. Five grams of soil is weighed into a 50‐mL polyethylene vial to which 30 mL of 1M NH4Cl solution is added. The soil suspension is then shaken on a horizontal shaker for 16 h at 25°C at 180 cycles per min. The suspension is then centrifuged at 2,500g for 5 min and the supernatant filtered through a 0.45 μm nitrocellulose filter under vacuum. Cadmium in the extract is then determined at 228.8 nm on a graphite furnace equipped atomic absorption spectrophotometer. A highly significant correlation was observed between the natural logarithm (In) of 1M NH4Cl‐extractable Cd in soils and the Cd content in the grain of durum wheat (Triticum turgidum var. durutn L.) grown on the same soils (r = 0.974, p = 3.8 x 10‐7). In comparison with several commonly used extradants, such as ABDTPA, CaCl2, NH4OAc, and NH4NO3, the 1M NH4Cl‐extracted Cd from soils was found to be a better index of Cd availability.  相似文献   

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