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从国家紫色土肥力与肥料效益监测基地定位试验上 ,在第 10年水稻收获后从 0～ 30cm土层采取土壤样品 ,研究土壤K 吸附、解吸动力学过程。结果表明 ,不同施肥处理土壤K 吸附、解吸反应分别在2 4～ 32min和 4 6～ 6 4min达到平衡 ,吸附、解吸平衡量分别为 14 1～ 19 2cmolkg-1和 11 6～ 17 5cmolkg-1。相关分析说明 ,土壤阳离子交换量 (CEC)及粘粒含量是影响吸附平衡时间、吸附平衡量的重要因素 ;CEC、交换钾量是影响解吸平衡时间、解吸平衡量的重要因素。由此可见 ,长期不同施肥对土壤CEC、粘粒及交换钾量产生影响 ,从而影响了紫色土K 吸附、解吸平衡时间及吸附、解吸平衡量。平衡前钾离子的吸附、解吸速度及吸附、解吸率与反应时间lnt间存在良好的线性关系。其中反应速度直线和解吸率直线的斜率、初始反应速度及初始吸附率均与CEC、粘粒含量密切相关。Elovich方程和一级扩散方程分别为描述紫色土K 吸附、解吸反应的最优与最差模型 ,指数方程和抛物线扩散方程拟合性介于Elovich方程和一级扩散方程之间。由此可见 ,紫色土K 吸附、解吸过程不是一个单纯的过程 ,而是一个包括土体膨胀、吸附位活化、表面扩散等诸多因素的复杂过程。 相似文献
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土壤中钾素在固液相间的转化速率及数量取决于K+与土壤固相表面的作用方式,并决定着K+进入土壤后的去向和土壤供钾能力。研究K+在土壤固液相间转化的动力学性质,对于了解阳离子型养分在土壤固相表面的作用机理及评价土壤保持、供应钾素能力有重要的理论与实践意义,国内外众多学者就此展开了深入研究[1-9]。施肥是影响K+在土壤固液相间转化动力学的重要因素,而长期定位施肥试验是持续研究土壤肥力动态变化的重要手段。国内已有学者研究了长期定位施肥紫色土、非石灰性潮土K+的吸附、解吸动力学性质,明确了长期不同施肥带来的土壤基本理化性质的变化是土壤K+的吸附、解吸动力学性质差异的根本原因,比较了长期不同施肥处理带来 相似文献
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可溶性有机碳(DOC)吸附影响土壤元素化学行为。为此,本研究采用批处理法研究了DOC在长期不同施肥处理(对照CK、氮N、氮磷NP、氮磷钾NPK、化肥+秸秆还田NPKS、化肥+有机肥NPKM)潮土上的吸附动力学和等温吸附特征。结果表明,猪粪源DOC易于分解,需要添加0.025 mmol(1 mL 25 mmol/L)Na N3抑制其分解,抑制率超过90%。DOC吸附符合准二级动力学方程(R~2≥0.99)。不同施肥处理下,吸附速率常数k及初始速率常数h与平衡吸附Qe都没有显著差异,平均值分别为0.208 kg/(g·h)、1.60 g/(kg·h)和2.77g/kg。吸附等温式可用Langmuir方程很好拟合(R~2≥0.96),吸附容量(最大吸附量)Q_(max)在不同施肥处理下也没有显著差异(平均7.05 g/kg),但在N和NP等非平衡施肥下却保持高的亲合力,半饱和吸附浓度k_d分别为50.2和57.6 mg/L,吸附亲合常数K则分别为0.02和0.017 4 L/mg;相反,在NPKM处理下,显著低的亲合性发生,k_d和K分别为72.94 mg/L和0.013 8 L/mg。研究证明粘粉粒含量控制了不同施肥处理潮土对DOC的吸附;土壤有机碳水平不影响Q_(max),而且高土壤有机碳还降低其吸附亲合性。 相似文献
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磺胺嘧啶在土壤及土壤组分中的吸附/解吸动力学 总被引：2，自引：0，他引：2
抗生素在土壤中的吸附/解吸及迁移过程受其理化性质的强烈影响,其中土壤中的矿物成分,如高岭石、蒙脱石及腐殖酸等是重要控制因素。本文主要研究了磺胺嘧啶在土壤、高岭石、蒙脱石和腐殖酸中的吸附/解吸动力学过程,并对反应前后的高岭石、蒙脱石和腐殖酸进行傅里叶红外光谱(Fourier transform infrared, FTIR)表征,探讨其可能的吸附机理。结果表明:磺胺嘧啶的吸附(解吸)动力学过程,可以分为快速吸附(解吸)、吸附解吸动态平衡和吸附(解吸)平衡3个阶段;磺胺嘧啶在土壤及其3种组分中的吸附(解吸)均可在24 h内达到平衡,其浓度高低会导致土壤及其组分的吸附差异,不同土壤组分中的官能团含量、带电性质及氢键是造成吸附差异的主要原因;分别用伪一级动力学模型、伪二级动力学模型和Elovich模型对其吸附过程进行拟合,其动力学吸附过程更符合伪二级动力学模型,R20.99,主要受控于物理化学吸附;FTIR图谱表明磺胺嘧啶与高岭石以物理吸附为主,并有少量氢键作用,与蒙脱石之间主要以氢键作用完成吸附,而在腐殖酸中存在表面络合和π–π共轭作用。 相似文献
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土壤胶体的凝聚与土壤团聚体的形成密切相关。施肥改变土壤溶液环境，对土壤团聚体形成、土壤结构和土壤物质组成产生影响。探索长期不同施肥影响土壤胶体微观性质和相互作用进而影响土壤宏观现象的关联十分必要。本研究依托三十五年棕壤长期定位施肥监测试验站，选取不施肥处理（CK）、施用氮肥（N）、施用有机肥（M）、氮肥与有机肥配合施用（N+M）四种处理的土壤为研究对象，采用动态光散射技术监测不同施肥处理的土壤胶体凝聚动力学过程，通过对比分析土壤有机质含量、表面化学性质和土壤矿物组成等探究不同施肥处理对土壤胶体凝聚过程的影响。研究发现：四种长期不同施肥处理的棕壤胶体凝聚特征均表现为在低电解质浓度条件下发生慢速凝聚（RLCA）与高电解质浓度条件下的快速凝聚（DLCA）；不同施肥处理胶体在相同电解质体系中的临界聚沉浓度的大小顺序均为M > N+M > CK > N。有机肥的长期施用增加了土壤有机质含量，从而提高了胶体颗粒表面电场强度，加大了胶体颗粒间的静电斥力，加之有机质组分的空间位阻效应使得胶体的凝聚现象减弱；另一方面，长期不同施肥处理并未改变土壤黏土矿物组成类型，但对其相对含量产生影响：其中，有机肥的长期施入使2:1型伊利石的相对含量增加，1:1型高岭石的相对含量减少，长期施用氮肥使伊利石相对含量减少而高岭石相对含量增加。综上，长期不同施肥处理改变棕壤胶体的基本理化性质和矿物组成比例关系，进而影响棕壤胶体的凝聚动力学过程。 相似文献
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长期施有机肥与缺素施肥对潮土微生物活性的影响 总被引：4，自引：1，他引：3
利用中国科学院封丘农业生态国家实验站潮士农田生态系统养分平衡长期定位试验地,研究长期施有机肥或缺索施肥对农田土壤呼吸强度及酶活性的影响.结果发现,与不施肥对照(CK)相比.施肥处理均不同程度地提高了土壤的呼吸强度及转化酶、脲酶与磷酸酶活性;从N、P、K平衡施肥角度比较,施有机肥[OM)与有机无机配施(1/20M+1/2NPK)的效果均显著高于施无机肥(p<0.05);从缺素施肥角度分析,缺P显著低于NPK处理(p<0.05),缺N次之,缺K影响较小.结果表明,长期配施有机肥更有利于提高潮土的微生物活性,长期缺施P肥最不利于保育潮土的微生物学质量. 相似文献
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添加牛粪对长期不同施肥潮土有机碳矿化的影响及激发效应 总被引：6，自引：2，他引：4
为了探讨长期不同施肥潮土有机碳矿化对添加牛粪的响应特征及添加牛粪对长期不同施肥潮土有机碳矿化的激发效应,以始建于1986年的长期定位试验为平台,通过室内恒温培养的方法研究添加等氮量牛粪后长期不同施肥(不施肥,CK;常量有机肥,SMA;常量化肥,SMF;常量有机无机配施,1/2(SMA+SMF))潮土有机碳矿化、土壤有机碳及活性碳库组分(微生物量碳、可溶性有机碳、颗粒有机碳和易氧化有机碳)含量的变化特征。结果表明:无论添加牛粪与否,长期不同施肥潮土有机碳矿化过程均符合一级动力学方程,而牛粪的添加显著增加了长期不施肥、长期单施化肥和长期有机无机配施土壤的有机碳矿化速率常数,增长幅度分别为21.74%、35.00%和45.00%;添加牛粪提高了长期不同施肥潮土有机碳、微生物量碳、颗粒有机碳和易氧化有机碳含量,却显著降低了可溶性有机碳含量;牛粪对长期不施肥、长期施用常量有机肥、常量化肥和常量有机无机配施潮土有机碳矿化的正激发效应分别达到了48.56%、3.60%、48.43%和3.92%,且对长期不施肥及长期施用常量化肥潮土的激发效应显著高于对长期施用常量有机肥及长期有机无机配施土壤;冗余分析显示添加牛粪对长期不同施肥土壤有机碳矿化的激发效应与土壤活性组分碳氮比呈正相关,与土壤养分含量呈负相关。该研究不仅为合理施用有机肥和实现农田生态系统的可持续发展提供理论依据,还有利于实现农业资源再利用及其效益最大化。 相似文献
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蒙山茶园土壤组分对铝吸附解吸热力学特征的影响 总被引：1，自引：0，他引：1
采用间歇法和振荡平衡法,通过实验室模拟,研究了蒙山茶园土壤(紫色土和黄壤)原土及各粒级组分对铝吸附解吸的热力学特征,并分析土壤有机质、游离氧化铁和CEC对其吸附解吸的影响。结果表明:(1)不同土壤原土及各粒级组分对铝的吸附量都随铝离子浓度的增大而增加,且各粒级土壤对铝的吸附量不同,表现为土壤颗粒比表面越大,有机质、游离氧化铁和CEC越高,其吸附量越大。紫色土原土及各粒级组分对铝的等温吸附过程用Freundlich方程描述最佳,说明紫色土对铝的吸附是多层吸附;而黄壤原土及各粒级组分对铝的等温吸附过程则用Langmuir方程描述最佳,说明黄壤对铝的吸附以单层吸附为主。(2)紫色土原土及各粒级组分对铝的解吸率表现出以下关系:粗砂粒原土细砂粒粉粒粘粒,黄壤原土及各粒级组分对铝的解吸率则表现出以下关系:细砂粒粗砂粒原土粉粒粘粒,两者解吸率的大小关系均与其有机质及游离氧化铁相反,表明两种土壤的原土及各粒级组分中有机质和游离氧化铁越高,其专性吸附率就越高,从而解吸率越小,说明土壤有机质和游离氧化铁影响土壤对铝的固持能力。(3)土壤最大吸附量与有机质、游离氧化铁含量和CEC都表现出显著或极显著的正相关关系,而其最大解吸率也均与有机质、游离氧化铁含量和CEC表现出显著或极显著的负相关关系。 相似文献
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水溶性有机碳在各种粘土底土中的吸附：土壤性质的影响 总被引：3，自引：0，他引：3
Clay-rich subsoils are added to sandy soils to improve crop yield and increase organic carbon (C) sequestration; however, little is known about the influence of clay subsoil properties on organic C sorption and desorption. Batch sorption experiments were conducted with nine clay subsoils with a range of properties. The clay subsoils were shaken for 16 h at 4 oC with water-extractable organic C (WEOC, 1 224 g C L-1) from mature wheat residue at a soil to extract ratio of 1:10. After removal of the supernatant, the residual pellet was shaken with deionised water to determine organic C desorption. The WEOC sorption was positively correlated with smectite and illite contents, cation exchange capacity (CEC) and total organic C, but negatively correlated with kaolinite content. Desorption of WEOC expressed as a percentage of WEOC sorbed was negatively correlated with smectite and illite contents, CEC, total and exchangeable calcium (Ca) concentrations and clay content, but positively correlated with kaolinite content. The relative importance of these properties varied among soil types. The soils with a high WEOC sorption capacity had medium CEC and their dominant clay minerals were smectite and illite. In contrast, kaolinite was the dominant clay mineral in the soils with a low WEOC sorption capacity and low-to-medium CEC. However, most soils had properties which could increase WEOC sorption as well as those that could decrease WEOC sorption. The relative importance of properties increasing or decreasing WEOC sorption varied with soils. The soils with high desorption had a low total Ca concentration, low-to-medium CEC and low clay content, whereas the soils with low desorption were characterised by medium-to-high CEC and smectite and illite were the dominant clay minerals. We conclude that WEOC sorption and desorption depend not on a single property but rather a combination of several properties of the subsoils in this study. 相似文献
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Zinc solubility in clay and soil suspensions was controlled by chemisorption at pH 4.5 – 7.0. The solubility in clay mineral suspensions was in the order palygorskite < montmorillonite « kaolinite and reflected the high affinity of zinc to palygorskite and the high CEC of montmorillonite. The solubility in soil suspensions was in the order Haplustoll < Torrifluvents and reflected the effect of high CEC and organic matter content of the first. The slopes of the pH-pZn curves, calculated zinc potential and sequential desorption data suggested that Zn++ ? Zn(OH)2 aqueous controlled the solubility of zinc in soil and clay mineral suspensions at pH 7.5 – 9.0. The slopes of the pH–pZn curves of two soils were, however, modified by the possible peptization of organic matter and Zn(OH)2. 相似文献
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《Communications in Soil Science and Plant Analysis》2012,43(5-6):797-809
Abstract Desorption of copper (Cu) is an important factor in determining Cu availability in calcareous soils. Kinetics of native and added Cu desorption by DTPA (diethylene‐triaminepentaacetic‐acid) from 15 highly calcareous soils of southern Iran were studied in a laboratory experiment. Our results showed that two constant‐rate, Elovich, simple Elovich, and parabolic‐diffusion equations were the best‐fitted equations among eight kinetic models used. The copper desorption pattern based on the parabolic‐diffusion equation revealed that the rate of native Cu desorption was higher in the first 2 h followed by a slower release rate, which suggests that two different mechanisms are involved. The trend may describe why the DTPA soil test has been considerably successful in predicting Cu availability in calcareous soils. Stepwise multiple regression equations indicated that CCE (calcium carbonate equivalent), CEC (cation exchange capacity), and clay content are the most important soil characteristics that predict the rate constants of the kinetic models. Mean extractant recovery percentage (ERP) of the soils was only 20%, which indicated that after 20 days, DTPA extracted only one‐fifth of added Cu. Regression equations indicated that as soil OM (organic matter) content increased, the value of ERP decreased. From results reported herein it seems that CCE, CEC, and clay are the most important factors controlling Cu release from highly calcareous soils of southern Iran. However, the initial soil Cu desorption rate is probably controlled by CEC. 相似文献
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《Communications in Soil Science and Plant Analysis》2012,43(21):2532-2544
The adsorption isotherms indicated that the adsorption of boron (B) increased with its increasing concentration in the equilibrium solution. The Langmuir adsorption isotherm was curvilinear and it was significant when the curves were resolved into two linear parts. The maximum value of adsorption maxima (b1) was observed to be 7.968 mg B kg?1 in Garhi baghi soil and the bonding energy (k) constant was maximum at 0.509 L mg?1 in Jodhpur ramana soil. The Langmuir isotherm best explains the adsorption phenomenon at low concentrations of the adsorbent, which of course was different for different soils. There was significant correlation between b1 and clay (r = 0.905**), organic matter contents (r = 0.734*), and cation exchange capacity (CEC; r = 0.995**) of soils. A linear relationship was observed in all the soils at all concentration ranges between 0 and 100 mg B L?1, indicating that boron adsorption data conform to the Freundlich equation. Soils that have a higher affinity for boron adsorption, like Garhi baghi, tended to desorb less amount of boron, that is, 43.54%, whereas Ballowal saunkhari desorbed 48.00%, Jodhpur ramana 48.42%, and Naura soil 58.88% of the adsorbed boron. Boron desorption by these soils is positively and significantly correlated with the sand content (r = 0.714**) and negatively with clay content (r = ?0.502*) and CEC (r = ?0.623**). The maximum value of 37.59 mg kg?1 for desorption maxima (Dm) was observed in Garhi baghi soil and also a constant related to B mobility (Kd) was found to be maximum in Garhi baghi (0.222 L kg?1) soil Note: *P<0.05; **P<0.01. 相似文献
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《Communications in Soil Science and Plant Analysis》2012,43(15-16):2547-2563
Abstract Time dependent zinc (Zn) desorption in eight benchmark soils of India was studied in relation to various pH values and ionic strengths. Soil samples were equilibrated in solutions containing 10 μg Zn g‐1 soil at pH 5.5,6.5, and 7.5 for 48 h at 25±2°C, and adsorbed Zn extracted with calcium chloride (CaCl2) for various periods of time. Desorption of Zn decreased with increasing pH, and the desorption rate decreased abruptly at pH 7.5. In contrast, an increase in the equilibration period and ionic strength of the background electrolyte increased Zn desorption. Four rival kinetic models were fitted and evaluated for their suitability for describing the Zn desorption process. Reaction rate constant (ß) calculated from the Elovich model for the different soils ranged from 9.99 to 25 (mg Zn kg‐1)‐1. The different kinetic models tested indicated that Zn desorption in soils was a diffusion controlled process. The desorption was rapid in the first 4 h, followed by slower phase in the rest of the time at all the pH values indicating a biphasic desorption, characteristic of a diffusion controlled process. The ß value for the Elovich equation showed a strong association with soil clay content and cation exchange capacity (CEC). Further, the best prediction of Zn desorption reaction rate constant could be made using multiple‐regression equation with soil clay content and CEC as variables. 相似文献
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钾肥在砖红壤中的淋失特征初步模拟研究 总被引：3，自引：1，他引：3
通过室内大型土柱模拟研究钾肥在砖红壤中的淋失特征,结果表明:K 在砖红壤中运移速度较快,灌水30mm即3d后既可从20cm处淋出;60cm处渗漏液中K 浓度在39d后随着时间的推移逐渐下降,淋失浓度与施肥量表现出正相关;45d后120cm处渗漏液中K 浓度才随着施肥量的增加而上升,推测其运移速度为2 7cm/d。K 在120cm处的累计淋失量与施肥量成正相关,其淋失率为3 28%。应用方程lnYt=a blnt可拟合不同钾肥施用量下砖红壤中120cm处K 的累计淋失量随时间的变化关系。 相似文献
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Phosphate desorption from the surface of soil mineral particles by a phosphate-solubilizing fungus 总被引：1，自引：0，他引：1
High phosphate (Pi) sorption in soils is a serious limiting factor for plant productivity and Pi fertilization efficiency, particularly in highly weathered and volcanic ash soils. In these soils, the sorbed Pi is so strongly held on the surfaces of reactive minerals that it is not available for plant root uptake. The use of phosphate-solubilizing microorganisms (PSM) capable of Pi desorption seems to be a complementary alternative in the management of these soils. The aim of this study was to evaluate the effectiveness of the soil fungus Mortierella sp., a known PSM, to desorb Pi from four soil minerals differing in their Pi sorption capacity. The fungus was effective in desorbing Pi from all tested minerals except from allophane, and its desorption depended on the production of oxalic acid. The effectiveness of the fungus to desorb Pi was ranked as montmorillonite > kaolinite > goethite > allophane. The quantity of desorbed Pi increased by increasing the amount of sorbed Pi. The Pi sorption capacity expressed as P0.2 value (amount of P required to increase a solution P concentration up to 0.2 mg L?1) was a good indicator of the effectiveness of Mortierella sp. to desorb Pi from soil minerals. 相似文献