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1.
Bulk precipitation was sampled every 2 weeks for more than 2 yr in a lowland catchment in the eastern part of the Netherlands and dissolved constituents were determined. This paper discusses only concentrations of the main constituents: S04, NH4, Cl, NO3, Na, Ca, H, Mg, and K (in decreasing order) and tries to delineate specific source regions for these ion species. Despite the complex character of precipitation chemistry and the rather long sampling interval, statistical evaluation (cluster- and discriminant analyses) of the data provided discriminating results. Four sources could be distinguished: seaspray supplying major part of Na, Mg, and CI; industrial activities (Ruhr area) contributing excess amounts of Cl and SO4 in association with NH4; rural activities supplying N03, while K, Ca and excess amounts of Na and Mg mainly derive from local dust. No clear source area could be detected for H, but it was shown that SO2-emission is the main source of acidification of precipitation at the study catchment.  相似文献   

2.
Water samples from 18 springs and 13 drainage canals and subcanals were collected from Al-Ahsa Oasis. Concentrations of total dissolved salts, Cl, SO4 HCO3, B, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, V, Ti, and Zn were determined. The soil salinity development (SSD), the adjusted Na ratio (adj. SAR), the adjusted Na adsorption ratio (adj. RNa), and exchangeable Na percentage (ESP) were calculated. Sodium was the most abundant cation in all water samples followed by Ca, Mg, Sr, and K in descending order. Concentrations of all other metals were below 0.1 mg L–1. Chloride was the most abundant anion, followed by SO4 and HCO3 in these waters. A significant correlation (P < 0.05)=" between=" na=" and=" cl=" in=" water=" samples=" was=" found.=" thermodynamic=" calculations=" revealed=" that=" an=" appreciable=" fraction=" of=" ca=" and=" mg=" in=" spring=" and=" drainage=" waters=" were=" associated=" with=">4 and HCO3 ions. Calcium increased from less than 10 meq L–1 in spring waters to > 16 meq L–1, Mg was doubled, and Na and Cl increased several times in the drainage waters. The salinity and sodicity hazards of the spring and drainage waters were classified as C4S2 i.e. high salinity with medium sodicity problems.  相似文献   

3.
The ionic composition of 55 aerosol samples and 31 precipitation events collected in a coastal site in southern Sardinia (Capo Carbonara, 39°06 N; 09°31 E) were compared. The samples were collected during one year period (Oct'90/Oct'91) and showed high variability in composition according to meteorological conditions. Rain and soluble part of aerosol showed a strikingly similar ionic composition: most significant anions were chlorine and sulphate, and sodium is the principal cations, followed by magnesium and calcium. The acid events are associated with N-NW trajectories (anthropogenic influxes from N. Europe) with avg. pH=4.65, non sea salt (nss) Ca=60 eq/l and NO3/nssSO4=0.6. Southern precipitations are influenced by Saharan dust alkaline effects, with avg. pH=6.75,nssCa=271 eq/l and NO3/nssSO4=0.4. Na/Cl ratio in rain is similar to sea water (0.87), whilst in aerosols there is a Cl loss (Na/Cl=1.10), probably due to reaction with nitric acid. Total fluxes of Ca, Mg, NO3 and SO4 were 104, 9, 64 and 113 g/cm2, and wet deposition exceeded (65–90%) dry deposition. Scavenging ratios (SR) as defined by the equation:SR=[(Ci)rain/(Ci)air] *d, (d=1200g/m3) were calculated, using geometric means (Ci) of precipitation and aerosols collected concurrently during the period (a total of 23 samples). The SR values are Ca=3400, Cl=2400, Na, K, SO4=1700, Mg=1000 and NO3=750. These numbers could be useful to infer total fluxes by using simply rainwater ionic composition in Mediterranean semi-arid sites like Sardinia.  相似文献   

4.
Following 13‐year treatments of soil pH and nitrogen (N) source in a peach orchard of North Carolina, the concentration of calcium (Ca), magnesium (Mg), N, phosphorus (P), and potassium (K) in leaves, shoots, trunks and roots, as well as soil pH, soil exchangeable Ca, Mg, and K content, were determined. Through liming, higher soil pH treatment enhanced soil Ca and tissue Ca level. Among six N sources examined, the highest values of soil pH and soil Ca, Mg, and K were detected following poultry manure application. Compared to ammonium sulfate [(NH4)2SO4], calcium nitrate [Ca(NO3)2] increased soil pH and soil Ca and K content, but reduced soil Mg. For most of macronutrients examined in peach tissues, the highest levels were found in manure treatment. Mineral N sources containing Ca(NO3)2 resulted in high tissue Ca and low tissue N. In the above‐ground tissues, Mg concentration was relatively low following application of mineral N materials containing Ca, K, or sodium (Na). Acid‐ forming N, especially (NH4)2SO4, reduced tissue Ca and P. The magnitude of impact of liming and N source on macronutrients was tissue‐type dependent, with leaves and other new growth the most sensitive ones while trunks seldom responded to the treatments.  相似文献   

5.
Loading of chemical elements in precipitation at the Solling For the period 1969–1976 (NH4, NO3: 1971–1976) monthly values of concentrations and flows of the ions NH4, H, Na, K, Ca, Mg, Fe, Mn, Al, Cl, NO3, SO4, P and organic bound N in precipitation are passed on. From the correlations between elements the following main ion sources are concluded: sea water (Na, Cl), combustion processes (SO4, NO3, NH4), lime dust after dissolution by H2SO4 and HNO3 (Ca, Mg), soil dust after dissolution by H2SO4 and HNO3 (Al, Fe), leaching from plants (K, NO3, SO4, Mg, Ca), biogenic contaminations (P, organic N, K, NH4, NO3). Seasonal variations in the concentrations are most evident for Na and Cl, less for NH4, SO4 and NO3. During the measuring period the flux of NH4 is significantly increased; for H and SO4, less for NH4, Mg, Ca and Fe, the increasing trend was interrupted in winter 1973/74 (oil crisis). Consequences for sampling are discussed.  相似文献   

6.
Rainwater samples (N = 51) were collected at Rampur, an areafree from anthropogenic activity during the monsoon of 1997 and1998. The concentration of ions follows a general pattern as Ca> NH4 > Mg > SO4 > Cl > F >Na > NO3 > K > HCOO >CH3 COO. The pH of precipitation ranges between 5.9 and 7.4. The levels of Ca and Mg at this site are higher than otherremote sites, probably dominated by particles of soil origin.Good correlation between Ca, NO3, SO4, HCOO and CH3COO indicate that a fraction of NO3, SO4, HCOOand CH3COO may be derived from soil or associated with Ca and Mg after neutralization. The order of neutralization factorCa (2.19) > NH4 (1.26) = Mg (1.26) indicates that majorneutralization occurred by Ca. Factor analysis suggested thatCa, Mg, Na, K, NO3, SO4, HCOO and CH3COO arecontributed by soil. NH3 is known to exist as(NH4)2SO4, NH4NO3 and NH4Cl. Theymay be formed in the atmospheric water droplets by scavenging ofaerosols and reaction of gaseous species.  相似文献   

7.
Abstract

The mineral ion contents of seven halophytic species in the family Chenopodiaceae, and associated soils were examined. Each species was found growing in soils with wide ranges of salinity, sodicity and salt ion composition. Absolute concentrations of Na, Ca, Mg, K, Cl and SO4 in shoot tissue differed significantly among species. Species were classified into two groups: (1) chloride halophytes, with ion composition dominated by Na and Cl (Atriplex patula, Chenopodium rubrum, Salicornia rubra and Suaeda depressa), and (2) alkali halophytes, with relatively high K, Mg, Ca and low Cl contents (Chenopodium salinum, Kochia scoparia and Salsola pestifer). All species accumulated ? and excluded SO4, relative to concentrations of these ions in soil. Salsola pestifer was unique in strongly excluding Na.  相似文献   

8.
The aims of this trial were to determine the spatial and temporal variability of the nutrients in petiole sap in a tomato crop under greenhouse and to determine the number of sub-samples for a representative sample. The experiment consisted of the selection of 20 sampling points. Petiole of fully expanded leaf was collected weekly in order to determine Cl, NO3-N, H2PO4-P, SO4-S, Na, K, Ca and Mg concentrations. Our results showed that variations of NO3-N, Na, Ca and K concentrations in sap were affected by the spatial distribution, whereas SO4-S and Mg concentrations in sap were affected by their temporal distribution. The spatial variability of our experiment could be related to radiation, yield and antagonism between nutrients, whereas the time variability could be related to the phenological stage of the plant and the antagonism between nutrients. The suggested number of petiole sub-sample ranging from 25 to 113 depending on nutrient.  相似文献   

9.
Abstract

Some irrigation waters have a high Mg/Ca ratio. The objective of the experiment reported herein was to compare the effect of high Mg in combination with different anions and different EC levels on the growth of corn (Zea mays L.). Corn was grown in the greenhouse in a calcareous soil equilibrated and irrigated with the following waters: 1) tap water (check, EC = 0.078 dS/m, SAR = 0.1); 2) Mg(HCO3)2, EC=1 dS/m; 3) Mg(HCO3)2, EC = 3; 4) MgSO4) EC=1; 5) MgSO4, EC=3; 6) MgSO4, EC = 6; and 7) and 8) mixed salts (Ec = 3 & 6 dS/m, SAR = 5, Ca: Mg = 3: 1, Cl: SO4 = 2: 1). Yield depressions of top growth caused by mixed‐salt waters (EC = 3 & 6) were 17 and 26%, respectively, compared to yields obtained with tap water. Single‐salt MgSO4 waters (EC = 1, 3 & 6) reduced corn tops 19, 38, and 59%, respectively, more than the mixed‐salt solutions at equivalent soil salinity levels probably due to Mg‐induced Ca deficiency. The Mg(HCO3)2 waters (EC = 1 & 3) reduced top growth 45 and 87% more than the mixed salt solutions. Thus Mg (HCO3)2 was more than twice as depressive on corn top growth as MgSO4. Corn root growth depression was similar to top growth depression. Leaf Ca: Mg ratio was related to their ratio in the soil solution. The leaf Ca and Mg concentrations were almost the same for plants irrigated with Mg(HCO3)2 or MgSO4 at EC = 1. Therefore, Mg: Ca ratio of leaves did not explain the yield differences between the two Mg salts. Nutrient imbalances and a high pH of 9 were possibly responsible for the lower yields in the presence of Mg(HCO3)2.  相似文献   

10.
The influence of 15 annual applications of composted (CM) or stockpiled (SM) beef feedlot manure with straw (ST) or wood-chip (WD) bedding on electrical conductivity (EC), soluble cations and anions (Na, K, Ca, Mg, SO4-S, Cl), sodium adsorption ratio (SAR), potassium adsorption ratio (PAR), and pH of a clay loam soil (0–15 cm) in southern Alberta was examined in an irrigated barley silage cropping system. Manure type (CM versus SM) had a significant effect on certain soil salinity parameters. Calcium, Mg, Na, K, and SO4-S were significantly (p ≤ 0.05) greater for SM- than CM-amended soils for certain bedding materials and rates. Electrical conductivity, concentration of soluble cations and anions (Na, K, SO4-S, Cl), SAR, PAR, and pH in the surface soil were greater for ST than WD bedding. Two exceptions were Ca and Mg, where soil concentrations were generally greater for WD than ST. Salinity parameters were greater with increased application rate, and greater for amended than unamended soils. Overall, bedding had considerably more significant effects on soil salinity parameters compared to manure type. Wood-chip bedding may be a management tool for feedlots to lower EC, soluble cations and anions, and pH of surface soils.  相似文献   

11.
A powerful 7.3 magnitude earthquake struck Taiwan on September 21, 1999. The stream water chemistry (pH, total alkalinity, conductivity, sodium, potassium, calcium, magnesium, ammonium, fluoride, chloride, sulfate, and nitrate) has been monitored since 1995 at the Guandaushi forestry riparian zone in central Taiwan. Collected data was used as a basis for comparing pre- and post-earthquake impacts. The pH, conductivity, and concentrations of Na, Ca, Mg, SO4, and HCO3 in stream water were lowest during the summer season, when stream water discharge was highest. On the other hand, the lowest concentrations of Cl, NH4, and NO3 in stream water occurred during the winter season, when stream water discharge was lowest. Also, K and F showed very little seasonal fluctuation in concentration. Downward trends in K and Ca were found 14 months prior to the earthquake; although, an upward trend occurred in NH4 at the same time.  相似文献   

12.
Liming-induced changes in cation exchangeability were studied in six samples from acid sulphate soils (pH 3.9-4.7) incubated with water or with equivalent quantities of Ca(OH)2 or KOH. The extractability of acid cation species susceptible to hydrolysis was shown to be affected not only by increased pH but also by the kind of the cation and related electrochemical properties of the base used. Both liming treatments practically eliminated the exchangeable Al. In the virgin soils, however, the polynuclear Al-complexes formed by Ca(OH)2 treatment seemed to have been hydrolyzed further. The superiority of Ca(OH)2 was assumed to be due to the higher valency of its cation and its act of provoking a higher increase in ionic strength. The liming agents affected to varying extents also the extractability of base cations. Exchangeable soil K seemed to decrease by the KOH treatment and the soil Ca by the Ca(OH)2 treatment, whereas K and Ca were only slightly, if any, affected by the Ca(OH)2 and KOH treatments, respectively. Thus, the reductions were assumed to be attributable to other factors than increased pH. A fixation of K and a possible precipitation of Ca as CaSO4 were discussed. Ca(OH)2 decreased in all soil samples the exchangeability of Mg more than did KOH. The depression was not related to the Al polymerization and, thus, cannot entirely be ascribed to specific sorption on Al gel. The results imply that liming may affect base cation exchange reactions by neutralizing exchangeable Al of high bonding strength and by replacing it by cations of the liming agent.  相似文献   

13.
A computer simulation was done to illustrate how the equilibrium solubility and speciation of Al in well-aerated soil solutions may be affected by pH (from 2.0 to 10.0), organic acids (citric, oxalic, phthalic, and salicylic acid), metal ions (K, Mg, Ca, Al, Fe), inorganic ligands (F, OH, SO4, PO4, CO3, and SiO3), and type of Al-containing solid [kaolinite, gibbsite, or amorphous Al(OH)3] thought to be present. The simulation indicated that the type of Al-oxide/hydroxide considered has a substantial influence on the inorganic and organic equilibrium composition of the soil solution, and on the occurrence (or non-occurrence) of other Al-minerals such as KA13(SO4)2(OH)6 (alunite) and Al(SO4)(OH)-5H2O (jurbanite).  相似文献   

14.
Results from a factorial acid treatment and liming experiment in a stand of Scots pine planted in 1968 to 1970 are presented. Field plots, 75 m2 in size, were supplied with 50 mm of artificial rain 38 times from 1974 to 1981. "Rain" of varying acidities was produced using groundwater mixed with H2SO4. Lime was applied at four levels in 1974 in a factorial acid treatment-liming design. Tree growth and foliar nutrient concentrations were measured annually from 1974 to 1988. The soil was sampled periodically from 1975 to 1988 at mainly 3 yr intervals. Tree growth was initially stimulated by increased acid loadings. Negative effects occurred after 5 yr. Positive effects of liming developed after 9 yr. No major signs of recovery from the most acid treatments have yet been found. Treatment effects appeared to be linear, indicating no threshold values for growth reactions. Treatment effects on foliar concentrations were found for a majority of elements analyzed. Increased acid loadings decreased the Mg, Ca and Mn concentrations, while K concentrations increased — especially during later years. Liming improved the nutrient status at increased acid loadings for Mg, Ca and Mn and decreased K concentrations. Soil sampling in 1984 showed major losses of Mg, Ca and Mn by increased acid loadings, while the K content was less affected. A link seems to exist between tree growth and the Mg situation in soil and foliage.  相似文献   

15.
Abstract

Two lysimeter experiments were conducted on annual leaching losses of calcium (Ca), potassium (K), sodium (Na), chloride (Cl), sulphate‐sulphur (SO4‐S), and magnesium (Mg) (one experiment only) from a sandy soil in central England during 1988–1995 to provide information on typical nutrient losses under arable agriculture below 1.2 m (Experiment 1) or 1.5 m (Experiment 2). Total annual losses, in the absence of manure additions, were highly dependent on the amount of drainage; flow‐weighted average concentrations were similar between years within experiments. Concentrations, averaged over the duration of the experiments were 74 and 78 mg L‐1 Ca, 17 and 27 mg L‐1 Na, 11 and 8 mg L‐1 K, 74 and 77 mg L‐1 Cl, and 57 and 38 mg L‐1 SO4‐S for the two experiments respectively; Mg concentration was 17 mg L‐1. Applications of chicken litter were made to some of the lysimeters in the last three years, and all nutrients showed increased leaching as a result. Application rates akin to disposal (rather than for crop fertilization) produced the largest losses. Following a total application of 125 t ha‐1 over three years, average concentrations in water draining below 1.5 m in the final year were 57 and 277 mg L‐1 Ca, 22 and 75 mg L‐1 Cl, 7 and 14 mg L‐1 K, 22 and 57 mg L‐1 Na, 27, and 125 mg L‐1 SO4‐S for the untreated and manured soils, respectively.  相似文献   

16.
The Nandong Underground River System (NURS) is located in Southeast Yunnan Province, China. Groundwater in NURS plays a critical role in socio-economical development of the region. However, with the rapid increase of population in recent years, groundwater quality has degraded greatly. In this study, the analysis of 36 groundwater samples collected from springs in both rain and dry seasons shows significant spatial disparities and slight seasonal variations of major element concentrations in the groundwater. In addition, results from factor analysis indicate that NO 3 ? , Cl?, SO 4 2? , Na+, K+, and EC in the groundwater are mainly from the sources related to human activities while Ca2+, Mg2+, HCO 3 ? , and pH are primarily controlled by water–rock interactions in karst system with Ca2+ and HCO 3 ? somewhat from anthropogenic inputs. With the increased anthropogenic contaminations, the groundwater chemistry changes widely from Ca-HCO3 or Ca (Mg)-HCO3 type to Ca-Cl (+NO3) or Ca (Mg)-Cl (+NO3), and Ca-Cl (+NO3+SO4) or Ca (Mg)-Cl (+NO3+SO4) type. Concentrations of NO 3 ? , Cl?, SO 4 2? , Na+, and K+ generally show an indistinct grouping with respect to land use types, with very high concentrations observed in the groundwater from residential and agricultural areas. This suggests that those ions are mainly derived from sewage effluents and fertilizers. No specific land use control on the Mg2+ ion distribution is observed, suggesting Mg2+ is originated from natural dissolution of carbonate rocks. The distribution of Ca2+ and HCO 3 ? does not show any distinct land use control either, except for the samples from residential zones, suggesting the Ca2+ and HCO 3 - mainly come from both natural dissolution of carbonate rocks and sewage effluents.  相似文献   

17.
Abstract

A serial batch leaching experiment was carried out to evaluate the release of elements from wood ash mixed with a strongly acidic forest soil sample. Wood ash application resulted in increased leachate pH, dissolved organic carbon (DOC), and electrical conductivity (EC). Increasing application of wood ash increased cumulative release of inorganic carbon (IC), chloride (Cl), nitrate (NO3), sulfate (SO4), potassium (K), sodium (Na), calcium (Ca), magnesium (Mg), manganese (Mn), phosphorus (P), and copper (Cu). Release of NO3, P, iron (Fe), aluminum (Al), Cu, and lead (Pb) continued. Large amounts of DOC, K, Ca, and SO4 were mobilized. Inorganic C, Fe, and Mg were released in moderate quantities. Manganese, Na, Al, Cl, and NO3 were released in limited amounts. Amounts of leached P, Pb, and Cu were lower. The mixed order equation adequately described the release of elements in the soil‐ash mixture. Accumulation of elevated amounts of trace elements does not appear to be a problem when higher wood ash rates are avoided. Wood ash should be applied in split application to avoid short‐term concentrated alkaline and salty conditions that could interfere with plant growth.  相似文献   

18.
To elucidate the influence of airborne materials on the ecosystem of Japan??s Yakushima Island, we determined the elemental compositions and Sr and Nd isotope ratios in streamwater, soils, vegetation, and rocks. Streamwater had high Na and Cl contents, low Ca and HCO3 contents, and Na/Cl and Mg/Cl ratios close to those of seawater, but it had low pH (5.4 to 7.1), a higher Ca/Cl ratio than seawater, and distinct 87Sr/86Sr ratios that depended on the bedrock type. The proportions of rain-derived cations in streamwater, estimated by assuming that Cl was derived from sea salt aerosols, averaged 81?% for Na, 83?% for Mg, 36?% for K, 32?% for Ca, and 33?% for Sr. The Sr value was comparable to the 28?% estimated by comparing Sr isotope ratios between rain and granite bedrock. The soils are depleted in Ca, Na, P, and Sr compared with the parent materials. At Yotsuse in the northwestern side, plants and the soil pool have 87Sr/86Sr ratios similar to that of rainwater with a high sea salt component. In contrast, the Sr and Nd isotope ratios of soil minerals in the A and B horizons approach those of silicate minerals in northern China??s loess soils. The soil Ca and P depletion results largely from chemical weathering of plagioclase and of small amounts of apatite and calcite in granitic rocks. This suggests that Yakushima??s ecosystem is affected by large amounts of acidic precipitation with a high sea salt component, which leaches Ca and its proxy (Sr) from bedrock into streams, and by Asian dust-derived apatite, which is an important source of P in base cation-depleted soils.  相似文献   

19.
Abstract

Soil samples were collected under blight‐affected and healthy citrus trees at 30‐day intervals for 24 months, at 20‐to 50‐cm depth. Analyses of water extracts (1:1 soil: water) for K, Ca, Mg, Na, SO4, and Cl showed few differences in cations, but lower anion levels under blighted trees. The cation/anion ratio was significantly higher under blight‐affected trees. Samples collected once at different locations in the same time period showed the same differences. In one location, K was lower and Na higher under healthy trees than under blight‐affected trees, in others K was higher too.  相似文献   

20.
The Geological Surveys of Finland and Norway, and the Central Kola Expedition, Russia, carried out an environmental geochemical mapping project, including investigation of stream water quality. The project was carried out in 1992–1993 in the border areas of Finland, Norway and Russia, covering an area of 12 000 km2, to determine the impacts of smelting industries at Nikel and Zapoljarnij. Stream water was one of eight different indicators providing an estimation of the degree and distribution of contamination in the study area. Contamination of surface water was assessed by analyses of 44 samples, 41 variables were measured on each sample. Indicators of human activities in surface waters are NO3, K, electrical conductivity (EC), SO4, Na, Cl and acidification indicated by alkalinity and pH. On the coast Na and Cl contents are also affected by marine salts. The results show considerably higher contents of K, Ca, Mg, SO4, Na, heavy metals and EC in the samples close to Nikel and Zapoljarnij smelters than those sites more distant from the polluting sources. Especially chemical effects of high emissions of Ni, Cu and SO2 on stream water quality from Nikel and Zapoljarnij smelters are clearly seen near the sources of emissions.  相似文献   

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