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1.
The effects of combinations of Hg, As, Ph, Cu, Cd, and Cr on Hill activity of Azolla pinnata R.Br. were studied. All of the combinations of heavy metals decreased Hill activity of chloroplasts over control values. The effects were most pronounced with the treatments of (Hg + As + Pb + Cu + Cd + Cr), followed by (Hg + As + Pb + Cu + Cd). The degree of inhibition of Hill activity in the species by combinations of heavy metals is less due to antagonistic effects (when 2 or 3 metals in combinations), and is much higher due to synergism (when 4 or more metals in combinations) than that by individual heavy metals tested. The harmful effects of the individual metals were, in general, found by the treatments in the order: Cd > Hg > Cu > As > Pb > Cr.  相似文献   

2.
The data on the effects of the concentrations (0.5, l, 2, 5 mg L?1) of the heavy metals, Hg, As, Pb, Cu, Cd, and Cr on changes in growth population of a fecal coliform bacterium Escherichia coli (in term of number of E. coli per 100 mL water) showed a gradual decline in growth population of the fecal coliform bacterium with the increase of exposure time, as well as concentrations of the metals over control data. The effects were markedly recorded with the treatment of 5 mg L?1. In general, the harmful effects of the metals on growth population of E. coli were found by the treatments in the order: Cd>Ph>Cu>As>Hg>Cr.  相似文献   

3.
The effects of four concentrations (0.5, 1, 5 and 10 μg mL?1) of the heavy metals Hg, As, Pb, Cu, Cd, and Cr on some senescence variables of Cuscuta reflexa Roxb. were studied. All of the treatments, except 0.5 μg mL?1, decreased Hill reaction activity, chlorophyll and protein contents and dry matter percentage in biomass and increased tissue permeability over control data. The harmful effects of the metals were best visible at 10 μg mL?1. The general order of sensitivity was As > Cd > Pb > Hg > Cu > Cr (absolute metal concentration). The data suggest that Cuscuta reflexa shows tolerance to the heavy metals tested up to 0.5 μg mL?1.  相似文献   

4.
Changes in the soil chemical environment can be expected to increase the leaching of trace metals bound in soils. In this study the mobility of trace metals was monitored in a column experiment for two contaminated urban soils. Four different treatments were used (i.e. rain, acid rain, salt and bark). Leachates were analysed for pH, dissolved organic carbon (DOC) and for seven trace metals (cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb) and zinc (Zn)). The salt treatment produced the lowest pH values (between 5 and 6) in the effluent whereas the DOC concentration was largest in the bark treatment (40–140 mg L?1) and smallest in the salt and acid treatments (7–40 mg L?1). Cadmium, Ni and Zn were mainly mobilised in the salt treatment, whereas the bark treatments produced the highest concentrations of Cu and Pb. The concentrations of Cu, Cr, and Hg were strongly correlated with DOC (r 2?=?0.90, 0.91 and 0.96, respectively). A multi-surface geochemical model (SHM-DLM) produced values for metal dissolution that were usually of the correct magnitude. For Pb, however, the model was not successful indicating that the retention of this metal was stronger than assumed in the model. For all metals, the SHM-DLM model predicted that soil organic matter was the most important sorbent, although for Pb and Cr(III) ferrihydrite was also important and accounted for between 15 and 50% of the binding. The results confirm the central role of DOC for the mobilization of Cu, Cr, Hg and Pb in contaminated soils.  相似文献   

5.
The effects of combinations of Hg, As, Pb, Cu, Cd, and Cr on the variables of Cuscuta reflexa Roxb. in natural condition were studied. All of the combinations of heavy metals tested decreased Hill reaction activity, chlorophyll and protein contents and increased tissue permeability over control values. The effects were best visible with the treatments of (As + Cd + Pb + Hg + Cu + Cr) and (As + Cd + Pb + Hg + Cu), followed by (As + Cd + Pb + Hg), (As + Cd + Pb), and (As + Cd). The degree of inhibition or increase by combinations of heavy metals is much higher due to synergism as the observed effects exceed the summed amount. The general order of sensitivity was As > Cd > Pb > Hg > Cu > Cr (absolute metal concentration).  相似文献   

6.
长期污灌农田土壤重金属污染及潜在环境风险评价   总被引:1,自引:0,他引:1  
以西安市某典型污灌区农田土壤为研究对象,分析长期污水灌溉对表层土壤重金属含量及富集状况的影响,采用内梅罗指数法和Hakanson潜在生态危害指数法对其污染现状及潜在环境风险进行评价。结果表明:长期污灌已导致农田土壤Cd、Cr、Cu、Hg、Ni、Pb和Zn7种重金属相对自然背景有不同程度累积,其富集比例依次为100%、82.69%、100%、100%、80.77%、98.08%和100%,仅有土壤As平均含量低于其背景水平;以国家土壤环境质量标准二级限量值作为污染评价阈值,其中Cd和Hg污染表现突出,按其污染指数平均值排序为Cd〉Hg〉Ni〉Cu〉Zn〉As〉Cr〉Pb;土壤重金属综合潜在环境风险为"强"等级,Hg、Cd的环境影响占据主导;随污灌年限增长,离灌渠越近,农田土壤重金属的污染水平和环境风险越高。鉴于该区土壤重金属已呈现较强生态危害性,应及时采取必要防治措施,调整土地利用结构,确保农田环境及农产品安全生产。  相似文献   

7.

Granular activated carbon (GAC), granular activated alumina (GAA) and a ferric chloride solution (FCS) were tested for the treatment of leachate contaminated by heavy metals. The leachate was collected following the remedation of soils using weak organic acids and/or their salts, EDTA and DTPA. Only GAC was found to effectively remove heavy metals (Cd, Cu, Cr, Hg, Mn, Pb and Zn as chelates) from the leachate. At optimum pH ranging from 5.4 to 6.9, 97% of Hg was removed while at optimum pH ranging from 6.9 to 7.7, 78 to 96% of Cd, Cu, Mn, Pb and Zn were removed. Some 77% of the Cr was removed at optimum pH of 5.4. Adsorption rate constant and Langmuir adsorption capacity of GAC were found to be 0.01 min?1 and 19 mg metal chelate g?1 of GAC, respectively. Freundlich constants, k and n were found to be 21 mg g?1 and 2.778, respectively. The brown color of the leachate turned colorless after GAC treatment.

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8.
The To Lich and Kim Nguu Rivers, laden with untreated waste from industrial sources, serve as sources of water for irrigating vegetable farms. The purposes of this study were to identify the impact of wastewater irrigation on the level of heavy metals in the soils and vegetables and to predict their potential mobility and bioavailability. Soil samples were collected from different distances from the canal. The average concentrations of the heavy metals in the soil were in the order zinc (Zn; 204 mg kg?1) > copper (Cu; 196 mg kg?1) > chromium (Cr; 175 mg kg?1) > lead (Pb; 131 mg kg?1) > nickel (Ni; 60 mg kg?1) > cadmium (Cd; 4 mg kg?1). The concentrations of all heavy metals in the study site were much greater than the background level in that area and exceeded the permissible levels of the Vietnamese standards for Cd, Cu, and Pb. The concentrations of Zn, Ni, and Pb in the surface soil decreased with distance from the canal. The results of selective sequential extraction indicated that dominant fractions were oxide, organic, and residual for Ni, Pb, and Zn; organic and oxide for Cr; oxide for Cd; and organic for Cu. Leaching tests for water and acid indicated that the ratio of leached metal concentration to total metal concentration in the soil decreased in the order of Cd > Ni > Cr > Pb > Cu > Zn and in the order of Cd > Ni > Cr > Zn > Cu > Pb for the ethylenediaminetetraaceitc acid (EDTA) treatment. The EDTA treatment gave greater leachability than other treatments for most metal types. By leaching with water and acid, all heavy metals were fully released from the exchangeable fraction, and some heavy metals were fully released from carbonate and oxide fractions. The concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the vegetables exceeded the Vietnamese standards. The transfer coefficients for the metals were in the order of Zn > Ni > Cu > Cd = Cr > Pb.  相似文献   

9.
Retention of Cd, Cu, Pb and Zn by Wood Ash, Lime and Fume Dust   总被引:2,自引:0,他引:2  
Heavy metals are of interest due to their deleterious impacts on both human and ecosystem health. This study investigated the effectiveness of wood ash in immobilizing the heavy metals Pb, Cd, Cu and Zn from aqueous solutions. The effects of initial metal concentrations, solution pH, ash dose and reaction time on metal sorption, as well as the metal sorption mechanisms were studied. To investigate the effect of initial metal concentrations, solutions containing Cd, Zn (25, 50, 75, 100 or 125 mg L?1), Cu (25, 50, 75, 100, 125, 150 or 175 mg L?1) or Pb (250, 500, 750, 1000, 1250, or 1500 mg L?1) were reacted with 10 g L?1 ash for two hours. For the effect of pH, solutions containing 100 mg L?1 of Cd, Cu or Zn or 1500 mg L?1 of Pb were reacted with 15 g L?1 ash over a pH range of 4 to 7. The wood ash was effective in immobilizing the four metals with a sorption range of 41–100 %. The amounts of metals retained by the ash followed the order of Pb > Cu > Cd > Zn. As expected, absolute metal retention increased with increasing initial metal concentrations, solution pH and ash dose. Metal retention by the ash exhibited a two-phase step: an initial rapid uptake of the metal followed by a period of relatively slow removal of metal from solution. Metal retention by the ash could be described by the Langmuir and Freundlich isotherms, with the latter providing a better fit for the data. Dissolution of calcite /gypsum minerals and precipitation of metal carbonate/sulfate like minerals were probably responsible for metal immobilization by the ash in addition to adsorption.  相似文献   

10.

Purpose

Our main aim objective was to evaluate the transfer of Cd, Cr, Cu, Ni, Pb and Zn to barley (Hordeum vulgare) grown in various soils previously amended with two sewage sludges containing different concentrations of heavy metals. This allowed us to examine the transfer of heavv metals to barley roots and shoots and the occurrence of restriction mechanisms as function of soil type and for different heavy metal concentration scenarios.

Material and methods

A greenhouse experiment was performed to evaluate the transfer of heavy metals to barley grown in 36 agricultural soils from different parts of Spain previously amended with a single dose (equivalent to 50 t dry weight ha?1) of two sewage sludges with contrasting levels of heavy metals (common and spiked sludge: CS and SS).

Results and discussion

In soils amended with CS, heavy metals were transferred to roots in the order (mean values of the bio-concentration ratio in roots, BCFRoots, in brackets): Cu (2.4)?~?Ni (2.3)?>?Cd (2.1)?>?Zn (1.8)?>?Cr (0.7)?~?Pb (0.6); similar values were found for the soils amended with SS. The mean values of the soil-to-shoot ratio were: Cd (0.44)?~?Zn (0.39)?~?Cu (0.39)?>?Cr (0.20)?>?Ni (0.09)?>?Pb (0.01) for CS-amended soils; Zn (0.24)?>?Cu (0.15)?~?Cd (0.14)?>?Ni (0.05)?~?Cr (0.03)?>?Pb (0.006) for SS-amended soils. Heavy metals were transferred from roots to shoots in the following order (mean values of the ratio concentration of heavy metals in shoots to roots in brackets): Cr (0.33)?>?Zn (0.24)?~?Cd (0.22)?>?Cu (0.19)?>?Ni (0.04)?>?Pb (0.02) for CS-amended soils; Zn (0.14)?>?Cd (0.09)?~?Cu (0.08)?>?Cr (0.05)?>?Ni (0.02)?~?Pb (0.010) for SS-amended soils.

Conclusions

Soils weakly restricted the mobility of heavy metals to roots, plant physiology restricted the transfer of heavy metals from roots to shoots, observing further restriction at high heavy metal loadings, and the transfer of Cd, Cu and Zn from soils to shoots was greater than for Cr, Ni and Pb. Stepwise multiple linear regressions revealed that soils with high sand content allowed greater soil-plant transfer of Cr, Cu, Pb and Zn. For Cd and Ni, soils with low pH and soil organic C, respectively, posed the highest risk.  相似文献   

11.
The effects of cadmium and copper on larval metamorphosis and mortality of cultured Capitella sp Y were investigated. Metatrochophore larvae were exposed to 0.013 (control), 0.030, 0.080, 0.120, and 0.170 mg Cd L?1 and 0.017 (control), 0.025, 0.060, and 0.075 mg Cu L?1 for 34 days. Larval mortality significantly (p < 0.01) increased with increasing Cd and Cu concentrations (Kruskal-Wallis test), with similar effects for both metals for day 10 (LC50 = 0.035 mg Cd L?1 and 0.035 mg Cu L?1). Metamorphosis was inhibited in larvae exposed to the two metals in the absence of food, the effect of Cu being the most severe. This study suggests that Cd and Cu exposure could be harmful to early developmental stages of Capitella sp Y producing a delay in recruitment into natural populations.  相似文献   

12.
以当前农业研究的热点领域——重金属污染为切入点,研究了大田Cd、Pb、As、Hg、Cr5种重金属胁迫对小麦(郑麦9023、小偃22)籽粒产量及构成因素的影响。结果表明重金属胁迫下,cd、Pb、As、№、cr重金属对产量三要素中单位面积群体穗数的影响最大,其次为穗粒数,对千粒重的影响最小;单位面积群体穗数对重金属Cr、Pb最为敏感,在旱田偏碱性的土壤上,Cr、Pb胁迫对小麦单位面积的群体穗数影响的临界含量分别约为187.5mg·kg^-1和175mg·kg^-1。对两个小麦品种的籽粒产量影响不同,郑麦9023籽粒产量依次为Cr2〈Crl〈CK〈Cd2〈Hgl〈As2〈Asl〈Hg2〈Pbl〈Cdl〈Pb2;小偃22籽粒产量依次为Cr2〈Crl〈CK〈Hgl〈As2〈Hg2〈Cdl〈Cd2〈Pb2〈Asl〈Pb1。重金属Cr对小麦的产量表现为抑制效应,Cd、Hg、Pb、As对小麦产量的影响表现为增产效应;不同种类重金属胁迫对小麦产量影响作用依次为Hg〈Cd〈As〈Pb〈Cr。  相似文献   

13.
Chromium occurs naturally at trace levels in most soils and water, but disposal of industrial waste and sewage sludge containing chromium compounds has created a number of contaminated sites, which could pose a major environmental threat. This study was conducted to enumerate and isolate chromium-resistant microorganisms from sediments of evaporation ponds of a metal processing plant and determine their tolerance to other metals, metalloids and antibiotics. Enumeration of the microbiota of Cr-contaminated sediments and a clean background sample was conducted by means of the dilution-plate count method using media spiked with Cr(VI) at concentrations ranging from 10 to 1000 mg L?1. Twenty Cr(VI) tolerant bacterial isolates were selected and their resistance to other metals and metalloids, and to antibiotics was assessed using a plate diffusion technique. The number of colony-forming units (cfu) of the contaminated sediments declined with increasing concentrations from 10 to 100 mg L?1 Cr(VI), and more severely from 100 to 1000 mg L?1 Cr(VI). The background sample behaved similarly to 100 mg L?1 Cr(VI), but the cfu declined more rapidly thereafter, and no cfu were observed at 1000 mg L?1 Cr(VI). Metals and metalloids that inhibited growth (from the most to least inhibitory) were: Hg > Cd > Ag > Mo = As(III) at 50 μg mL?1. All 20 isolates were resistant to Co, Cu, Fe, Ni, Se(IV), Se(VI), Zn, Sn, As(V), Te and Sb at 50 μg mL?1 and Pb at 100 μg mL?1. Eighty-five percent of the isolates had multiple antibiotic resistance. In general, the more metal-tolerant bacteria were among the more resistant to antibiotics. It appears that the Cr-contaminated sediments may have enriched for bacterial strains with increased Cr(VI) tolerance.  相似文献   

14.
The effect of added heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) on the rate of decomposition of glutamic acid was studied in four Dutch soil types in order to determine if such measurements would serve as sensitive indicators of heavy metal pollution in soil. The time required to reach the maximum respiration rate (referred to as the decomposition time) with glutamic acid was linearly related to increasing concentrations of Ni in a sandy loam soil.Changes in decomposition time were measured 18 months after addition of 55, 400 or 1000 mg kg? of Cd, Cr, Cu, Ni, Pb or Zn respectively to sand, silty loam, clay and sandy peat soils. A significant increase in the decomposition time occurred with a concentration of 55 mg kg?1 of Cd, Cu or Zn in the sand soil. At 400mgkg?1 adverse effects in the various soils are distinct. The sensitivity of the decomposition time of glutamic acid as a method to measure soil pollution is discussed.  相似文献   

15.
The objective of this work was to evaluate the affects of the application of composted biosolids on the accumulation of heavy metals (Cd, Cu, Ni, Pb and Zn) in lettuce leaves. Pots containing different proportions (0 to 100%) of composted biosolids were used to grow lettuce plants under greenhouse conditions. Dry and fresh weight, leaf area and Cd, Cu, Ni, Pb and Zn uptake were determined after harvest. It was found that the dry and fresh matter productions of the plants were significantly lower in the control treatment. The addition of composted biosolids caused a 20 and 40% increase in biomass accumulation. Cd and Pb concentrations in leaves were below detection limits (0.05 mg kg?1) in all treatments. Zn concentration in leaves increases as compost proportion decreases, ranging from 57.2 to 80.4 mg kg?1. Composted biosolids application increased the Cu and Ni plant concentrations, ranging from 5.1 to 9.8 mg Cu kg?1 and 2.3 to 3.7 mg Ni kg?1. In all treatments the proportions of heavy metals in plants were below the international standards of toxicity. The results allow us to suggest that, in short-term applications, composted biosolids could be used as soil amendment for lettuce production, without toxic effects in the chemical composition of the plant.  相似文献   

16.
The toxic effects and accumulation of the heavy metals, Cd, Cu, and Zn by the sheath forming blue-green alga Chroococcus paris were investigated. All three of the metals were bound rapidly. Approximately 90% of the total amount of the added metal was bound within 1 min. Further significant binding occurred at a slower rate. The maximum metal binding capacity, as determined by filtration studies, was determined to be 53, 120, and 65 mg g?1 dry algal weight for Cd, Cu, and Zn, respectively. Binding curves for the metals followed the Langmuir adsorption isotherm model. The amount of metal bound increased with increasing pH. Metal binding increased significantly when pH was increased from 4 to 7. Nearly all of the metal was found to be rapidly EDTA extractable. Metals were found to be increasingly toxic to growing cultures in the order, Zn, Cd, and Cu. All of the metals studied exhibited toxic effects at concentrations greater than 1.0 mg L?1. The lowest concentrations used which showed detectable toxicity were 0.1 mg L?1 for Cu and >0.4 mg L?1 for Cd and Zn.  相似文献   

17.
The Algal Assay Procedure Bottle Test was used to investigate the effect of Cd, Cu, and Cr (VI) on the growth of Nile water algae. The results of this investigation indicated that Cd has slight inhibitory effects on algal growth at low concentration (0.05 mg L?1), while it was inhibiting algal growth at higher concentration (> 1.0 mg L?1). In contrast, Cu and Cr did not affect algal growth in all investigated concentrations. Combinations of Cd with Cu and Cr seemed to interact synergistically. The synergism between Cd and Cu was more pronounced than between Cd and Cr. Clear changes in the diversity and redundancy of algal structure took place after metal addition. The inhibitory effect of the studied metals was in the following order: Cd-Cu > Cd - Cr > Cd > Cu > Cr.  相似文献   

18.
A greenhouse experiment was designed to determine the cadmium (Cd) and lead (Pb) distribution and accumulation in parsley plants grown on soil amended with Cd and Pb. The soil was amended with 0, 5, 10 20, 40, 60, 80, and 100 mg Cd kg?1 in the form of cadmium nitrate [Cd(NO3)2] and 0, 5, 10, 50 and 100 mg Pb kg?1 in the form of lead nitrate [Pb(NO3)2]. The main soil properties; concentrations of the diethylenetriaminepentaacetic acid (DTPA)–extractable metals lead (Pb), Cd, copper (Cu), iron (Fe), zinc (Zn), and manganese (Mn) in soil; plant growth; and total contents of metals in shoots and roots were measured. The DTPA-extractable Cd was increased significantly by the addition of Cd. Despite the fact that Pb was not applied, its availability was significantly greater in treatments 40–100 mg Cd kg?1 compared with the control. Fresh biomass was increased significantly in treatments of 5 and 10 mg Cd kg?1 as compared to the control. Further addition of Cd reduced fresh weight but not significantly, although Cd concentration in shoots reached 26.5 mg kg?1. Although Pb was not applied with Cd, its concentration in parsley increased significantly in treatments with 60, 80, and 100 mg Cd g?1 compared with the others. Available soil Pb was increased significantly with Pb levels; nevertheless, the increase was small compared to the additions of Pb to soil. There were no significant differences in shoot and root fresh weights between treatments, although metal contents reached 20.0 mg Pb kg?1 and 16.4 mg Pb kg?1 respectively. Lead accumulation was enhanced by Pb treatments, but the positive effect on its uptake was not relative to the increase of Pb rates. Cadmium was not applied, and yet considerable uptake of Cd by control plants was evident. The interactive effects of Pb and Cd on their availability in soil and plants and their relation to other metals are also discussed.  相似文献   

19.

Purpose

The effect of soil heavy metals on crops and human health is an important research topic in some fields (Agriculture, Ecology et al.). In this paper, the objective is to understand the pollution status and spatial variability of soil heavy metals in this study area. These results can help decision-makers apportion possible soil heavy metal sources and formulate pollution control policies, effective soil remediation, and management strategies.

Materials and methods

A total of 212 topsoil samples (0–20 cm) were collected and analyzed for eight heavy metals (Cd, Hg, As, Cu, Pb, Cr, Zn, and Ni) from agricultural areas of Yingbao County in Lixia River Region of Eastern China, by using four indices (pollution index (PI), Nemerow pollution index (PIN), index of geo-accumulation (I geo), E i /risk index (RI)) and cluster analysis to assess pollution level and ecological risk level of soil heavy metals and combining with geostatistics to analyze the concentration change of heavy metals in soils. GS+ software was used to analyze the spatial variation of soil heavy metals, and the semi-variogram model is the main tool to calculate the spatial variability and provide the input parameters for the spatial interpolation of kriging. Arcgis software was used to draw the spatial distribution of soil heavy metals.

Results and discussion

The result indicated that the eight heavy metals in soils of this area had moderate variations, with CVs ranging from 23.51 to 64.37 %. Single pollution index and Nemerow pollution index showed that about 2.7 and 1.36 % of soil sampling sites were moderately polluted by Cd and Zn, respectively. The pollution level of soil heavy metals decreased in the order of Cd?>?Zn?>?Pb?>?As?>?Cu?>?Cr?>?Ni?>?Hg. The I geo values of heavy metals in this area decreased in the order of Zn?>?Cd?>?As?>?Pb?>?Cu?>?Cr?>?Hg?>?Ni. According to the E i index, except Cd that was in the moderate ecological risk status, other heavy metals in soils were in the light ecological risk status, and the level of potential ecological risk (RI) of soil sampling sites of the whole area was light.

Conclusions

The results of four indices and the analysis of spatial variation indicated that the contents of Cd and Zn were contributed mainly by anthropogenic activities and located in the south-east of this study area. However, the contents of Hg, As, Cu, Pb, Cr, and Ni in soils were primarily influenced by soil parent materials.
  相似文献   

20.
应用实验生态方法研究了褶牡蛎对8种常见的重金属生物富集动力学特性,得出了褶牡蛎对重金属的生物富集系数、生物半衰期以及生物富集曲线。结果表明,到积累实验结束时褶牡蛎对Pb、Zn、Cd、Cr、Ni和Hg的生物富集系数分别是15.60、26.53、60.06、7.61、5.82和47.88,褶牡蛎对Cu和As的富集规律不明显,生物富集曲线分别为yPI7=0.4046e^0.1168xR^2=0.7378,yZn=0.0408x^2+0.2909x+59.969 R^2=0.9307,yGl=2.5263e^0.0867x R^2=0.7089,YCr=0.6832e^0.0942x R^2=0.8544,yNi=0.4178e^0.0714x R^2=0.6856和yHg=0.0015x^2+0.0444x+0:0644 R^2=0.8301,以积累实验结束时的生物富集系数为基准,褶牡蛎对这几种重金属的富集能力为Cd〉Hg〉Zn〉Pb〉Cr〉Ni;到释放实验结束时褶牡蛎对Pb、Zn、Cd、Cr和Hg的生物半衰期分别是23.1、13031.7、67,7、32.9和36.1d,褶牡蛎是Zn、Cd和Hg的强的净积累者,以释放实验结束时的生物半衰期为基准,褶牛十蛎对这几种重金属的排毒释放顺序为Pb〉Cr〉Hg〉Cd〉Zn。  相似文献   

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