共查询到20条相似文献，搜索用时 46 毫秒
1.
Conductive polyaniline (PAn)/poly(ethylene terephthalate) (PET) composite fibers were prepared by chemical polymerization
of aniline in the presence of PET fibers using benzoyl peroxide (Bz2O2) in organic solvent/aqueous hydrochloric acid mixtures. The effects of polymerization conditions such as organic solvent/water
ratio, oxidant, aniline and hydrochloric acid concentrations and temperature were investigated on the amount of PAn deposited
on PET fiber and the electrical surface resistance of composite fibers. The maximum PAn content and the lowest electrical
surface resistance of composite fibers were observed at HCl concentrations of 0.5 mol L−1. The properties of PAn/PET composite fibers such as density, diameter, tensile strength and breaking elongation were also
investigated in comparison with those of pure PET. Characterization of conductive composite fibers was carried out by FTIR,
TGA, SEM techniques, surface resistance measurements, and cross section images taken by optical microscope. 相似文献
2.
Khadija M. Zadeh I. M. Inuwa Reza Arjmandi Azman Hassan M. Almaadeed Zurina Mohamad P. Noorunnisa Khanam 《Fibers and Polymers》2017,18(7):1330-1335
This work investigated the effects of date palm leaf fiber (DPLF) content on the thermal and tensile properties; and morphology of compatibilized polyolefin ternary blend. Recycled polyolefin ternary blend consisting of low density polyethylene (RLDPE), high density polyethylene (RHDPE) and polypropylene (RPP) were fabricated at different parts per hundred resin (phr) of DPLF. Maleic anhydride grafted polyethylene (MAPE) was used as compatibilizer to enhance the adhesion between filler and polymer matrix. The composites were prepared using melt extrusion and tests samples were produced via injection molding process. Thermal conductivity results showed that as much as 11 % reduction in thermal conductivity was achieved with the incorporation of 30 phr DPLF. Highest tensile strength was observed with the incorporation of 10 phr DPLF. The elongation at break was reduced with the addition of DPLF due to impediment of chain mobility by the fillers. Initial degradation temperature increased with the addition of DPLF. Hence, it is concluded that DPLF can be used to develop green and thermally insulating composites. It is hoped that the present results will stimulate further studies on the thermally insulative materials based on natural fibers reinforced polymer composites for applications in the building industries. 相似文献
3.
1-Ally-3-methylimidazolium chloride ([AMIM]Cl) was successfully synthesized and was used as a green spinning solvent for cellulose. The celluloses of various degrees of polymerization (DP) were dissolved in the [AMIM]Cl to obtain 5 % (w/w) cellulose solutions, which were regenerated to cellulose fibers through wet spinning process. Of three different regenerated cellulose fibers with different DPs, a DP of 2,730 was gave the strongest regenerated fiber without drawing having a tensile strength of 177 MPa and an elongation at break of 9.6 % respectively, indicating that celluloses of higher molecular weight can be entangled and oriented more easily. Also maximum draw ratio of the as-spun fibers increased from 1.2 to 1.7 with increasing degree of polymerization leading to a tensile strength and modulus of 207 MPa and 48 GPa, respectively. Particularly the tensile modulus was substantially higher than those of lyocell and high performance viscose fibers of 20 GPa or less. The higher DP of pristine cellulose was critical in increasing the mechanical properties such as tensile strength and elongation at break of the as-spun fibers coupled with higher tensile modulus after drawing. 相似文献
4.
The ever-increasing importance of vegetable natural fibers on the global scale, the comparatively low production of this group
of fibers, and the growing fiber imports by the Iranian textile industry have required numerous studies in recent years to
be carried out on long natural cellulosic fibers extracted from Typha australis plant leaf. In this study, such tensile properties of the fiber under study as tenacity, modulus, elongation and work of
rupture, X-ray and FTIR are investigated by alkali retting at 100 °C for 2 and 4 h. It is found that Leafiran is lignocellulosic
with a tenacity approximately 25–40 cN. Tex-1, a linear density of about 4 tex, and a crystallinity of about 60 %, which are
all considered to be suitable properties compared to those of other natural cellulosic fibers. 相似文献
5.
Haydar U. Zaman Mubarak A. Khan Ruhul A. Khan Nusrat Sharmin 《Fibers and Polymers》2011,12(6):727-733
Coir fibers (Cocos nucifera) were treated with 1-ethyl-2-pyrrolidone (1-E-2-P) mixed with methanol (MeOH) under UV radiation. A series of solutions of different concentrations of 1-E-2-P in methanol along with a photoinitiator, Darocur-1173, were prepared. Monomer concentration, soaking time, and radiation dose were optimized in terms of grafting and mechanical properties. Ten percent 1-E-2-P, 6 min soaking time, and a 15th pass of radiation produced higher tensile strength (53 %) and elongation at break (230 %) than those of virgin fiber, as well as the highest grafting value (4.9 %). The effect of additives (1 %), such as urea and silane (3-trimethoxysilyl propyl methacrylate) on the properties of coir fiber was studied. Among the additives used, silane showed the best performance. For further improvement of the properties, the fibers were treated with alkali (potassium hydroxide) solution of different temperatures (0–60 °C). A 10 % alkali-treated fiber showed the best properties such as grafting (6.2 %), tensile strength (72 %) and elongation at break (330 %) over virgin fiber. The silane-treated fiber produced the minimum loss of the properties, as well as a lower water uptake than those of the untreated one. The effect of simulating weathering on the degradation properties of samples was also performed. 相似文献
6.
Shuiping Li Qing Lin Huajun Zhu Chong Cui Haijun Hou Tingting Lv Yanbo Li 《Fibers and Polymers》2016,17(2):282-288
Glass fiber, GF, which was first hydroxylated and silanized, was incorporated into epoxy resin modified with amino-terminated hyperbranched polymer (ATHBP) to obtain high performance composite. The effects of GFs content on the mechanical properties of composites were investigated, discussing the results from flexural, tensile, and impact tests. The composites revealed noticeable improvement in flexural strength, tensile strength as well as impact strength but slow decrease in elongation at break, compared to the epoxy/ATHBP thermoset. FESEM morphology results indicated the good compatibility between epoxy matrix and GF in the appearance of ATHBP and showed that the toughening mechanism was mainly attributed to the stress transfer mechanism. 相似文献
7.
A hitherto uninvestigated ligno-cellulosic seed fiber from the plant Pergularia Daemia has been chosen for the current study to unravel its physical properties, and potentialities in textile applications. The raw, NaOH treated, and wax removed fibers were tested for their morphological and structural features by X-ray diffraction, SEM, FT-IR spectra, and thermal analysis by thermogravimetry and differential scanning calorimetry. The raw fibers have low cellulose content and less crystalline compared to cotton and are having hollow, smooth surface, and less density. The brittle nature and low elongation at break of virgin fiber makes it difficult for the spinning. It becomes spinnable after NaOH treatment due to the increased elongation at break by partial removal of lignin. 相似文献
8.
To increase the spinning speed of poly(trimethylene terephthalate) (PTT) fibers, polystyrene (PS) was selected as an additive
polymer in the PTT matrix. Mixing of the immiscible PS with PTT led to an increase in spinning speed up to 5,500 m/min. PS
was employed to improve the extensibility of the matrix PTT in the spinning process as it can prevent PTT molecular orientation.
Experimental results show that the mixing of PS achieved this. The elongation at break of spun fibers increased with the amount
of PS. PS addition prevented fiber orientation, especially amorphous orientation, and improved drawability, and as such, increased
spinning speed up to 5,500 m/min. 相似文献
9.
Green composites from Pattawia pineapple leaf fiber (PALF) and poly(lactic acid) (PLA) were prepared. The mechanical method was chosen to extract PALF from fresh leaves due to this method gave high yield of fiber, short extraction time, and environmental friendly. Tensile and thermal properties, together with morphology of the fibers were disclosed. The fibers were conducted into a specified length of 1–3 mm and blended with PLA, using a twin screw extruder, with the PALF content of 10–50 wt%. Tensile testing, morphology investigation and thermogravimetric analysis were applied. Preliminary results showed that tensile modulus of the composites depended on PALF content. The tensile modulus and elongation at break of the composite containing 40 % PALF was about 48 %, and 111 % increase, respectively, compared with that of PLA. With addition of maleic anhydride coupling agent, such the composite showed the tensile modulus of 5.1 GPa, which was 34 % higher than that of the non-coupling agent composite, and about 104 % higher than that of PLA. Although the elongation at break of the composite containing 40 % PALF was found to dramatically increase by 111 %, the introduction of maleic anhydride in such the composite caused only 57 % increase in the elongation at break compared with that of PLA. Finally, a pilot product of square boxes was produced successfully from the proposed composite, by conventional injection molding process. 相似文献
10.
This article describes a new process for strengthening natural silk fibers. This process is simple yet effective for mass production of high strength silk fibers, enabled by drawing at a lower temperature and immediately heat setting at a higher temperature. The processing conditions were investigated and optimized to improve the strength. Silk fibers drawn to the maximum ratio at room temperature and then heat set at 200 °C show best tensile properties. Some salient features of the resulting fibers are tensile strength at break reaching 533±10.2 MPa and Young’s modulus attaining 12.9±0.57 GPa. These values are significantly higher than those of natural silk fibers (tensile strength increased by 44 % and Young’s modulus by 135 %). Wide-angle X-ray diffraction and FTIR confirm the transformation of silk I to silk II crystalline structure for the fiber obtained from this process. DSC and TGA data also provide support for the structural change of the silk fiber. 相似文献
11.
Study on the characteristics of blended ring and rotor spun yarns is a topic of major interest to the researchers. The overall properties of these blended yarns are affected by the relative proportion, properties of the components and their interactions. The main focus of this work is on comparing and analyzing effects of blend ratio on tensile properties of the yarns produced in different spinning systems using concept of hybrid effects that has not received enough attention from researchers. Various blends of cotton-polyester ring and rotor spun yarns were prepared. Tensile properties of the samples were examined as well. Interactions between cotton and polyester fibers was evaluated through predicting strength and elongation at break of the yarns using simple rule of mixtures (ROM) and hybrid model. Experimental results showed that, the effect of different blend ratios on tensile properties of the samples is different. In comparison with 100 % cotton yarn, promotion in braking strength of the ring and rotor spun samples occurred after increasing fraction of the polyester fiber to 50 and 66.5 % respectively. The prominent finding of the present work is that the trend of change in tensile properties of different yarns versus blend ratio is predictable via hybrid model and migration behavior of the constituent fibers. Coefficients representing the intensity of the interaction and migration index of the fibers were calculated and all results were discussed based on these calculated factors. 相似文献
12.
Haydar U. Zaman Mubarak A. Khan Ruhul A. Khan Sushanta Ghoshal 《Fibers and Polymers》2012,13(5):593-599
Coir fibers were modified with methyl acrylate (MA) mixed with methanol (MeOH) under thermal curing method at different temperatures (40?C80 °C) for different curing times (20?C60 min). A series of solutions of different concentrations of MA in methanol along with 2 % benzoyl peroxide, were prepared. Monomer concentration, curing temperature, and curing time were optimized with the extent of grafting of monomer and mechanical properties of cured fiber and found to be 30 % MA, 60 °C and 40 min curing time registered as better performance (Grafting (Gr) = 5.7 %, tensile strength (TS) = 72 %, elongation at break (Eb) = 88 %) than those of untreated fiber. For further improvement of the properties, untreated coir fibers were pretreated with gamma and UV radiations at different doses and then pretreated fibers were soaked in the optimized monomer and cured under optimum conditions. Coir fiber pretreated with UV radiation and grafted with optimized monomer showed the best properties such as Gr (7.12 %), TS (132 %), and Eb (153 %) over raw fiber. Water uptake and simulated weathering test of untreated and treated coir fibers were studied. 相似文献
13.
A comparison of poly(trimethylene terephthalate)(PTT) and poly(ethlene terephthalate)(PET) fibers spun at various take-up
speeds was presented. Fiber characterization included tensile and thermal properties, optical birefringence, density, sonic
modulus, boil-off shrinkage, and wide-angle X-ray diffraction. The phenomenon of stress-induced crystallization was inferred
from the X-ray diffraction diagrams for fibers spun with take-up speeds over 4000 m/min. The tenacity and elongation of PTT
and PET fiber showed typical results, but the initial modulus of PTT fiber was nearly unchanged over the entire take-up speed
range (2000–7000 m/min), whereas that of PET, as expected, increased monotonically with increasing take-up speed. This divergent
behavior could be explained by the different molecular deformations in the c-axis as determined from X-ray diffraction patterns.
The fiber crystallinity, density, and heat of fusion of both polymers increased with take-up speed. The boil-off shrinkage
decreased with increasing take-up speed. The optical birefringence of the two fiber types showed a maximum level at a take-up
speed of ca. 5000 m/min. The melting temperature behavior of PTT fiber was different from that of PET fibers. It was found
that PTT is less sensitive to stress induced changes at high spinning speeds than is PET. 相似文献
14.
Catalina Gómez Hoyos Vera A. Alvarez Piedad Ga?án Rojo Analia Vázquez 《Fibers and Polymers》2012,13(5):632-640
Fique fibers were treated using Na(OH) solution at 5 w/v%, slack and under 1 N of tension, at room temperature, for 4 and 24 h respectively. Changes in their structure and composition were monitored using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and X-ray diffraction (XRD). Additionally their mechanical properties were evaluated and analyzed. Results showed that tensile load application during alkali treatment improves their tensile strength and modulus. The most important change in mechanical properties was achieved in fibers treated for 24 h under tension. However, these fibers presented a high standard deviation; due to this treatment causing an important defibrillation. Moreover, fibers treated for 4 hours under tension, enhance their tensile strength around 56 %, while slack treated fibers improve only 38 %. When fibers were treated under tension, cellulose microfibrills were rearranged in the direction of tensile application and the spiral angle decreased, increasing the molecular orientation. 相似文献
15.
Jin Liu Yuxia Bai Zezhuo Song Ying Wang Zhihao Chen Qiongya Wang Debi Prasanna Kanungo Wei Qian 《Fibers and Polymers》2018,19(11):2372-2387
This paper displays an experimental study of the effect of basalt fiber on the strength properties of polymer reinforced sand. Laboratory trials of unconfined compression test (UCS), direct shear test, and tensile test were conducted on the specimens treated with polymer and basalt fiber, and several factors including polymer content, fiber content and dry density of sand that will influence the strength behaviors are investigated in detail. Based on test results and scanning electron microscope (SEM) images, the reinforcement mechanism was analyzed. The results showed that the polymer content, basalt fiber content and dry density of sand had greatly improved the strength behaviors of reinforced specimens. The increase in polymer and fiber content had an active effect on strength characteristics, while the angle of internal decreased slightly. The strength properties were enhanced with the increase in dry density, and the effect of dry density on tensile strength is affected by fiber content. The presence of randomly distributed fibers has formed a spatial fiber-sand net in sand, and the additive of polymer solution formed membrane to enwrap sand particles and connect sand and fibers, thereby formed a stable structure in sand. These structures have increased the bonding and interlocking forces between sand and fibers, and decreased the void ratio of reinforced specimens. 相似文献
16.
Electrically conducting textile fibers were produced by wet-spinning under various volume fractions using thermoplastic polyurethane (TPU) as a polymer and carbon black (CB), Ag-powder, multi-walled carbon nanotubes (MWCNTs), which are widely used as electrically conducting nanofillers. After applying the fiber to the heat drawing process at different draw ratios, the filler volume fraction, linear density, breaking to strength, and electrical conductivity according to each draw ratio and volume fraction. In addition, scanning electron microscopy (SEM) images were taken. The breaking to strength of the TPU fiber containing the nanofillers increased with increasing draw ratio. At a draw ratio of 2.5, the breaking to strength of the TPU fiber increased by 105 % for neat-TPU, 88 % for CB, 86 % for Ag-powder, and 127 % for MWCNT compared to the undrawn fiber. The breaking to strength of the TPU fiber containing CB decreased gradually with increasing volume fraction, and in case of Ag-powder, it decreased sharply owing to its specific gravity. The electrical conductivity of the TPU fiber containing CB and Ag-powder decreased with increasing draw ratio, but the electrical conductivity of the TPU fiber containing MWCNT increased rapidly after the addition of 1.34 vol. % or over. The moment when the aggregation of MWCNT occurred and its breaking to strength started to decrease was determined to be the percolation threshold of the electrical conductivity. The heat drawing process of the fiber-form material containing the anisotropic electrical conductivity nanofillers make the percolation threshold of the electrical conductivity and the maximum breaking to strength appear at a lower volume fraction. This is effective in the development of a breaking to strength and electrical conductivity. 相似文献
17.
Ultrahigh molecular weight polyethylene (UHMW PE) has high chemical resistance, good flexibility and remarkable strength along with low density, which makes it a good choice for lightweight textile reinforced composites. One drawback is the low melting point, limiting the possible applications at high temperatures. However its chemical structure leads to almost no chemical interactions of the interface. One way to enhance these interactions is the application of atmospheric pressure plasma. Polyethylene (PE) as yarn and in woven form was plasma treated in atmospheric air plasma generated by means of dielectric barrier discharge technique and the resulting effects on wettability, chemical composition and surface structure were studied. It was found that oxygen containing functional groups are introduced into the outer layer of the PE, thus increasing wettability and dyeability significantly. It could be shown that the changes last for at least 3 months in air without the necessity of any precautions. A degradation of the textile fibre during air plasma treatment was also observed, leading to a decrease of tensile strength and maximum elongation after more than five minutes of air plasma treatment. 相似文献
18.
The surface topography, tensile properties, and thermal properties of ramie fibers were investigated as reinforcement for
fully biodegradable and environmental-friendly ‘green’ composites. SEM micrographs of a longitudinal and cross-sectional view
of a single ramie fiber showed a fibrillar structure and rough surface with irregular cross-section, which is considered to
provide good interfacial adhesion with polymer resin in composites. An average tensile strength, Young’s modulus, and fracture
strain of ramie fibers were measured to be 627 MPa, 31.8 GPa, and 2.7 %, respectively. The specific tensile properties of
the ramie fiber calculated per unit density were found to be comparable to those of E-glass fibers. Ramie fibers exhibited
good thermal stability after aging up to 160°C with no decrease in tensile strength or Young’s modulus. However, at temperatures
higher than 160°C the tensile strength decreased significantly and its fracture behavior was also affected. The moisture content
of the ramie fiber was 9.9%. These properties make ramie fibers suitable as reinforcement for ‘green’ composites. Also, the
green composites can be fabricated at temperatures up to 160°C without reducing the fiber properties. 相似文献
19.
After the addition of a surface-active agent, sodium dodecyl benzene sulfonate (SDBS), electrospun polyvinyl alcohol (PVA) nanofibres showed a significant enhancement in the mechanical properties, such as improved tensile strength and elongation at break. The improved crystallinity and strong intermolecular hydrogen bonds between the molecules of SDBS and PVA were the two main factors that improved the mechanical properties. In addition, a sharp decrease in surface tension of PVA solution with the addition of SDBS was observed, and the protruding droplet at the tip of needle diminished in the electrospinning process. 相似文献
20.
In this study, we evaluated the effect of the molecular weight of the polymer on electrospun poly(ethylene terephthalate)
(PET) nonwovens, and their mechanical properties as a function of the linear velocity of drum surface. Polymer solutions and
electrospun PET nonwovens were characterized by means of viscometer, tensiometer, scanning electron microscope (SEM), wide
angle X-ray diffraction measurement (WAXD) and universal testing machine (UTM). By keeping the uniform solution viscosity,
regardless of molecular weight differences, electrospun PET nonwovens with similar average diameter could be obtained. In
addition, the mechanical properties of the electrospun PET nonwovens were strongly dependent on the linear velocity of drum
surface. From the results of the WAXD scan, it was found that the polymer took on a particular molecular orientation when
the linear velocity of drum surface was increased. The peaks became more definite and apparent, evolving from an amorphous
pattern at 0 m/min to peaks and signifying the presence of crystallinity at 45 m/min. 相似文献