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131.
This review focuses on the present distribution of populations of the crayfish Astacus leptodactylus that are harvested in Turkey. It also examines the history of this harvest and the impact that crayfish plague has had on them. Crayfish plague, caused by the fungus-like organism, Aphanomyces astaci Schikora, 1906, is a severe parasite of freshwater crayfish and has caused a lot of damage to A. leptodactylus populations in Turkey since 1984. Turkey was the largest provider of A. leptodactylus to Western Europe from 1970 (or possibly earlier) until 1986. For example, the peak production was reached in the early 1980s, with over 5,000 tonnes being exported in 1984. On the other hand, as a result of the crayfish plague the harvest of A. leptodactylus was reduced severely in most populations in Turkey after 1985. The harvest was only 320 tonnes in 1991. After the occurrence of crayfish plague in Turkey, in order to increase crayfish production uncontrolled A. leptodactylus stockings have been carried out in many waterbodies throughout Turkey. These introductions have caused an increase in the number of A. leptodactylus populations, but exploitation of A. leptodactylus is still under the pressure of the plague, although there has been a steady increase in crayfish production in recent years. The harvest increased to 2,317 tonnes in 2004. Fortunately, among those populations affected by crayfish plague, large amounts of A. leptodactylus can still be harvested from three lakes, ?znik (Bursa), E?irdir (Isparta) and Çivril (Denizli). Thus, it seems that A. leptodactylus has a degree of resistance to crayfish plague. It is therefore interesting to investigate the resistance of A. leptodactylus caught from these populations to crayfish plague.  相似文献   
132.
The diel feeding rhythm and ontogenesis during early life stage of loach Misgurnus anguillicaudatus were investigated under experimental conditions (light: L 06:00–18:00, D 18:00–06:00 h). Morphological and behavioral developments of loach from newly hatched to 40 days after hatching were observed. Larvae were able to prey on daphnia 3–4 days after hatching at 23 ± 0.5°C. As the larvae grew, they showed an increasing feeding capacity and a distinct feeding rhythm. Feeding intensity and incidence for day-4 larvae were highest at 10:00 and 16:00 h. The highest levels of feeding intensity for day-12 larvae occurred at 08:00, 12:00, and 18:00 h as did feeding incidence. By day 20, when the larvae metamorphosed, the highest levels of feeding intensity occurred at 06:00, 18:00, and 24:00 h and were concurrent with the highest feeding incidence. After metamorphosis, feeding capacity had again increased considerably and, in contrast to the earlier stages before day 20, feeding intensity for day-30 juveniles peaked at 05:00 and 20:00 h, about 1–2 h after the maximum feeding incidence. The feeding rhythm of loach juveniles at day 40 was almost the same as the day-30 juveniles. The estimated maximum daily feeding rates were 43.1%, 33.4%, 19.0%, 12.8%, and 5.8% of body weight on days 4, 12, 20, 30, and 40, respectively. Thus, loach was found to have different feeding rhythms in the pre- and post-metamorphosis stages, with the highest feeding activity in daytime during the larval planktonic stage before metamorphosis, and intensely nocturnal feeding behavior during the juvenile benthic stage after metamorphosis.  相似文献   
133.
Wool fabric was treated with liquid ammonia at -40 °C for 30 and 60 s prior to the application of polypyrrole (PPy). The polymer was deposited on wool fiber using the chemical oxidation method with 0.02 and 0.05 mol/l (Py) monomer concentration and FeCl3 as a catalyst. Functional groups of wool samples were analyzed using FT-IR, and surface morphology was investigated using SEM micrographs. Properties such as water absorbency, surface resistivity, abrasion resistance, weight add-on, and air permeability of coated specimens were explored. The FT-IR outcomes revealed the liquid ammonia pre-treatment changed the amount of amide I (NH), cystic acid, cystic monoxide, and dioxide content of the fiber. SEM micrographs revealed the descaling of wool surface after pre-treatment and smooth coating of polymer. Pre-treatment of wool in liquid ammonia improved absorbency of wool fabric with respect to the treatment duration. The surface resistivity of wool fabric decreased with the increase of monomer concentration and pre-treatment duration. The results of abrasion resistance confirmed that the pre-treated fabric exhibited lower loss of polymer after 200 cycles of abrasion. The weight of the fabric was increased and air permeability decreased when the monomer concentration and liquid ammonia pre-treatment duration was increased.  相似文献   
134.
Polypyrrole (PPy) film was prepared via in-situ chemical polymerization of pyrrole monomer on the surface of red-clay-brick (RCB) substrate. The deposited PPy film was characterized and used as an adsorbent for removal of benzene polycarboxylic acids from aqueous solutions. The effects of solution pH, contact time, initial concentration, and temperature on the adsorption process were systematically investigated to find the optimum operating conditions. Adsorption kinetic data were best fitted by pseudo-second order kinetic model. The adsorption equilibrium data were most represented by the Freundlich isotherm model. The maximum adsorption amounts of Trimellitic, Hemimellitic, and Pyromellitic acids were 189.27, 177.26, and 203.31 mg/g, respectively. The thermodynamic studies indicate that the adsorption was an endothermic and spontaneous process. Also, the PPy-RCB film was successfully regenerated using sodium hydroxide solution. The regenerated PPy-RCB can be reused for more than four successive cycles with a low reduction in adsorption efficiency.  相似文献   
135.
This account showed that nanometer-active calcium carbonate (CaCO3) improved polyamide 1010/organic montmorillonite (OMMT) composites and OMMT boosted polyamide 1010/CaCO3. The mechanical performance suggested the composites to be reinforced through adsorption forces present between the nanofillers and the matrix. The synergistic effect of CaCO3 and OMMT increased the yields and shrunk cavities when observed by scanning electron microscopy. The obvious resulting synergism was verified by X-ray scattering techniques after the addition of OMMT. The concentration of CaCO3 did not change lamellar-size or influence the crystal growth. The effect of CaCO3 on melting behavior was found less significant than that exert on crystallization behavior.  相似文献   
136.
This work investigated the effects of date palm leaf fiber (DPLF) content on the thermal and tensile properties; and morphology of compatibilized polyolefin ternary blend. Recycled polyolefin ternary blend consisting of low density polyethylene (RLDPE), high density polyethylene (RHDPE) and polypropylene (RPP) were fabricated at different parts per hundred resin (phr) of DPLF. Maleic anhydride grafted polyethylene (MAPE) was used as compatibilizer to enhance the adhesion between filler and polymer matrix. The composites were prepared using melt extrusion and tests samples were produced via injection molding process. Thermal conductivity results showed that as much as 11 % reduction in thermal conductivity was achieved with the incorporation of 30 phr DPLF. Highest tensile strength was observed with the incorporation of 10 phr DPLF. The elongation at break was reduced with the addition of DPLF due to impediment of chain mobility by the fillers. Initial degradation temperature increased with the addition of DPLF. Hence, it is concluded that DPLF can be used to develop green and thermally insulating composites. It is hoped that the present results will stimulate further studies on the thermally insulative materials based on natural fibers reinforced polymer composites for applications in the building industries.  相似文献   
137.
Surface properties of fibrous and ground cotton and linen were investigated by inverse gas chromatography (IGC) and the contact angle with different liquids was also measured on fabrics composed of both fibers. Results proved that dispersion component of surface tension (γ s d ) determined by IGC depends not only on the surface energy, but also on several factors influencing the adsorbability of probe molecules on the cellulosic substrates. For cotton samples, the trapping of n-alkanes among waxy molecules in the outer layer of fibers can be presumed. This effect results in larger γ s d for cotton fibers than for linen in spite of the higher wettability of the linen fabrics. Besides the surface energy and trapping effects, the grinding also influences the γ s d values. Specific enthalpy of adsorption (ΔH A ab ) of polar probes could be determined on all linen samples, but only on the ground cotton sample. Lewis acid-base character calculated for linen and ground cotton samples depends on the same effects as the γ s d does. The similar ΔH A ab values of chloroform (acidic) and THF (basic) measured on each of the samples support the conclusion that the surface character is amphoteric, which is also proved by the high ΔH A ab values of the amphoteric ethyl acetate and acetone probes.  相似文献   
138.
Polysulfonamide (PSA) has been widely used in many fields because of its excellent thermodynamic properties. In this study, PSA fibers were prepared separately via two different spinning ways, including conventional wet spinning and electrospinning. Fluid motion of wet spinning and electrostatic field of electrospinning were modeled using finite element analysis to investigate the spinning process. The properties of fabricated PSA fibers were characterized systematically by scanning electron microscope (SEM), fourier transform infrared spectrometer (FTIR), X-ray diffraction (XRD), thermal gravity analysis (TGA) and electronic strength tester. Based on the simulation and theoretical analysis of spinning process, it was found that the extruding force of the wet spinning is larger than that of the electrospinning. The larger extruding force makes the alignment of macromolecules inside fiber relatively uniform, and a higher proportion of crystallization happens. Accordingly, the mechanical properties and thermal stability of PSA fibers could be improved due to a higher proportion of crystallization. The experimental results of mechanical strength and TG test are coincided with the simulation results. PSA fiber prepared by wet spinning has better thermal stability and mechanical properties than that fabricated by electrospinning.  相似文献   
139.
Graphene is classified as a carbon-based material. Structurally, graphene is made up of carbon-based two-dimensional atomic crystals and a one atom thick planar sheet of sp2-bonded carbon atoms. This sort of arrangement in graphene makes it a unique material with exceptional mechanical, physicochemical, thermal, electrical, optical, and biomedical properties. Methods for graphene-based fabric production mainly use graphene-based materials such as graphene (G), graphene oxide (GO), and reduced graphene oxide (rGO) coated on fabric or yarn. Waterborne polyurethane (WPU) is one of the most rapidly developing and active branches of polyurethane chemistry. More and more attention is being paid to graphene-coated fabrics owing to their low temperature flexibility, the presence of zero or very few VOCs (volatile organic compounds), water resistance, pH stability, superior solvent resistance, excellent weathering resistance, and desirable chemical and mechanical properties. It is used as a coating agent or adhesive for fibers, textiles, and leather. Also, graphene-containing materials have been used to enhance the properties of WPU. In this study, graphene/WPU composite solution and film was prepared to conduct basic research for developing electrical heating textiles which is not harmful to the human body, flexible and excellent in electrical properties. Graphene/WPU composite solutions were prepared with a graphene content of 0, 2, 4, 8, and 16 wt%, and graphene/WPU film was prepared with solution casting method. The graphene contents were analyzed for their surface morphology, electrical properties, and electrical heating properties.  相似文献   
140.
Poly(2-hydroxyethylmethacrylate) (PHEMA)/hydroxyapatite (HAP) nanocomposites were synthesized through a new route involving nano-sized HAP (nHAP) particles or modified nHAP mixed with monomer 2-hydroxyethylmethacrylate via in situ polymerization in supercritical carbon dioxide (scCO2). Fourier-transform infrared spectroscopy showed phosphate peak increased with nHAP content in composite. X-ray diffraction patterns of PHEMA/nHAP revealed the presence of crystallized nHAP. Thermogravimetric analysis showed that the ultimate nHAP content in PHEMA/nHAP composites is consistent with its initial amount. Scanning electron microscopy revealed that nanocomposite particles are much smaller than PHEMA particles. PHEMA/nHAP composites with average diameter of approximately 600 nm were obtained in scCO2 with 94 % yield. Mechanical properties of PHEMA/nHAP nanocomposites were better than those of PHEMA, and compressive modulus and strength of composites with 30 wt.% nHAP were 193 and 29 MPa, respectively. Nanocomposite adsorption toward bovine serum albumin was evaluated, and results indicated that analyte adsorption amount can reach up to 282 mg/g.  相似文献   
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