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81.
Case-based e-learning may allow effective teaching of veterinary radiology in the field of equine orthopedics. The objective of this study was to investigate the effectiveness of a new case-based e-learning tool, compared with a standard structured tutorial, in altering students' knowledge and skills about interpretation of radiographs of the digit in the horse. It was also designed to assess students' attitudes toward the two educational interventions. A randomized, single-blinded, controlled trial of 96 fourth-year undergraduate veterinary students, involving an educational intervention of either structured tutorial or case-based e-learning, was performed. A multiple-choice examination based on six learning outcomes was carried out in each group after the session, followed by an evaluation of students' attitudes toward their session on a seven-point scale. Text blanks were available to students to allow them to comment on the educational interventions and on their learning outcomes. Students also rated, on a Likert scale from 1 to 7, their performance for each specific learning outcome and their general ability to use a systematic approach in interpreting radiographs. Data were analyzed using the Mann-Whitney test, the t-test, and the equivalence test. There was no significant difference in student achievement on course tests. The results of the survey suggest positive student attitudes toward the e-learning tool and illustrate the difference between objective ratings and subjective assessments by students in testing a new educational intervention.  相似文献   
82.
Leaf mass per area (LMA) is a parameter the variability of which contributes to architectural plasticity. However its variations according to environment remain not completely understood. We hypothesise that LMA variations of winter oilseed rape (WOSR) follow an ontogenetic trajectory that can be modified by the environment. This was assessed at plant and leaf levels comparing four genotypes field-grown under different environmental conditions characterised by year and nitrogen nutrition. Leaves of the main stem of plants sampled between emergence and harvest were surfaced, oven-dried and weighed to calculate LMA of each individual leaf. At the plant level, LMA presented a common ontogenetic trajectory, which increases from seedling emergence to bolting and from then on decreases. Variations in LMA were related to the variations in plant demand, LMA decreased when demand increased. The trajectory was modified by low N nutrition that increased LMA but differently according to year and genotype, reflecting the plant plasticity. At the leaf level, variations for each individual leaf were related to the variations at the plant level. Plant plasticity and genotypic variability of the responses of LMA to N deficiency seemed to be related to differences in biomass allocation between leaves and stems.  相似文献   
83.
Phenolics from grapes and wines can play a role against oxidation and development of atherosclerosis. Stilbenes have been shown to have cancer chemopreventive activity and to protect lipoproteins from oxidative damage. A method for the direct determination of stilbene oligomers (viniferin and pallidol) as well as astilbin in different types of wine using high-performance liquid chromatography with UV detection is described. In a survey of 21 commercial wines from the south of France, levels of pallidol and viniferin are reported for the first time in different types of wines. Viniferin was found to be present only in red and botrytized sweet white wines with levels between 0.1 and 1.63 mg/L; pallidol was not found in dry and sweet white wines but only in wines made by maceration with stems, with levels between 0.38 and 2.22 mg/L. Highest levels of astilbin were found in Egiodola (15.13 mg/L), Merlot (11.61 mg/L), and Cabernet Sauvignon (8.24 mg/L) for red wines and in Sauvignon (5.04 mg/L) for white varietal wines. Astilbin levels are highest for recent vintages, but pallidol is not found in older vintages. During noble rot development in Sauvignon or Sémillon grapes from the Sauternes area, levels of trans-astringin, trans-resveratrol, trans-piceid, and pallidol are quite low (<0.5 mg/kg of grapes). Viniferin and astilbin levels become optimum at 2 and 30 mg/kg, respectively, during spot grape and speckle grape stages.  相似文献   
84.
The adsorption of procyanidins (condensed tannins) on cell-wall material was quantified by bringing into contact solutions of procyanidins and suspensions of cell-wall material. A model was developed on the basis of the Langmuir isotherm formulation and a factorial experimental design. The parameters that influenced the adsorption were the concentration and molecular weight of the procyanidins, the ionic strength of the solution, the temperature, and the apple cell-wall concentration. The model was applied to partitioning of procyanidins from apple between juice and mash. The parameters to be taken into account are the composition of the apples and, specifically, (i) the concentration and molecular weight of the procyanidins, (ii) their acidity and pH as a determinant of the ionic strength, and (iii) their cell-wall content and the temperature at pressing. To estimate the ability of the model to relate procyanidin concentrations in the juice to their concentration in the apple, apples of three varieties of widely different procyanidin compositions were pressed in conditions that prevent oxidation. In these conditions, yields in the juice were >80% for phenolic acids or catechin monomers but <50% for procyanidins, with the lowest rates obtained for the higher polymers in accordance with the model.  相似文献   
85.
  • ? Methods based on near infrared spectroscopy used to assess wood properties are susceptible to variations in physical parameters (temperature, grain size, etc.). As wood is a hygroscopically sensitive material, we studied the effects of moisture on near infrared absorbance and calibration to accurately determine the application potential of this technique under routine.
  • ? A collection of Eucalyptus urophylla × E. grandis hybrid wood pieces were analysed to obtain reference calibration of polyphenol contents in wood extracts via NIR spectra acquired under constant moisture conditions. Other specimens from the same source were assessed to obtain spectra for eight moisture contents spanning a broad variation range. The effects of moisture on absorption and on estimates based on a reference model were analysed.
  • ? An increase in moisture content prompted a rise in near infrared absorption over the entire spectrum and for water O-H absorption bands. The polyphenol content estimates obtained by assessing specimens against the reference calibration at variable moisture contents revealed prediction bias. Five correction methods were then tested to enhance the robustness relative to moisture.
  • ? In-depth calibration and external parameter orthogonalization (EPO) were found to be the most efficient methods for offsetting this factor.
  •   相似文献   
    86.
    Gum arabic production from Acacia senegal is lower in sub-humid areas than arid areas. Water stress is thought to be the reason for higher yields in arid areas. The application of ethephon is thought to mimic the effect of water stress in other plants. The objective of this study was to determine if the application of ethephon would increase the gum yields of Acacia senegal under sub-humid conditions in Cameroon. Trees receiving 40 or 120 mg ethephon were compared to controls in field experiments at a semi-arid and a sub-humid location in Northern Cameroon, over two seasons. Two provenances from drier areas (Sudan) were compared to the local one. In the first season, gum yield of the local provenance treated with ethephon was increased by 400–600 % compared to the untreated trees. Gum yield at the semi-arid location was 77, 313 and 214 g/tree with 0, 40 and 120 mg ethephon/tree, respectively, while at the sub-humid location, it was 30, 186 and 114 g/tree with 0, 40 and 120 mg ethephon/tree. However, in the second season, the effect of ethephon was not significant in the semi-arid area, whereas it was evident in the sub-humid area (up to 478 g/tree). Moreover, ethephon did not affect gum yield of provenances from drier areas (Sudan). This showed that the water-stress hypothesis has to be refined. The development of ethephon-based tapping systems is promising, but requires further studies with a wider range of environmental conditions and A. senegal provenances.  相似文献   
    87.
    Influence of prefermentary clarification on the composition of apple musts   总被引:1,自引:0,他引:1  
    The polyphenol contents and colors of cider apple juices were compared before (NCM, not clarified must) and after five clarification treatments: enzymatic depectinization by pectinases followed by (i) sedimentation (depectinized and decanted juice), (ii) tangential microfiltration (microfiltered juice) or (iii) fining using gelatin (gelatin-treated juice); (iv) enzymatic gelification of pectin by pectin methylesterase followed by natural keeving by a cider manufacturer (producer keeved juice), or (v) flotation (floated with nitrogen gas juice). The pressing of the apples led to the highly selective extraction of the flavan-3-ols with the lowest molecular weights: In the apples, the number average degree of polymerization of the flavanols was 14.7, and it dropped to 2.2 in the NCM. Keeving had the highest impact on the reduction of both flavanol content and number average degree of polymerization. The flavanol concentrations were decreased in the permeate by fining (30%) much more than by depectinization. The clarification step led to a further decrease of the number average degree of polymerization. Hydroxycinnamic acids were less affected by the extraction process (with extraction yields >50%) and not affected by clarification. The color evolved with all treatments: L*, a*, b*, and chromaticity distance index measures indicated a reduction of orange-yellow saturation except after sedimentation.  相似文献   
    88.
    89.
    In the first part of this work, the analysis of the polyphenolic compounds remaining in the wine after different contact times with yeast lees during simulation of red wine aging was undertaken. To achieve a more precise view of the wine polyphenols adsorbed on lees during red wine aging and to establish a clear balance between adsorbed and remnant polyphenol compounds, the specific analysis of the chemical composition of the adsorbed polyphenolic compounds (condensed tannins and anthocyanins) after their partial desorbtion from yeast lees by denaturation treatments was realized in the second part of the study. The total recovery of polyphenol compounds from yeast lees was not complete, since a rather important part of the initial wine colored polyphenols, especially those with a dominant blue color component, remained strongly adsorbed on yeast lees, as monitored by color tristimulus and reflectance spectra measurements. All anthocyanins were recovered at a rather high percentage (about 62%), and it was demonstrated that they were not adsorbed in relation with their sole polarity. Very few monomeric phenolic compounds were extracted from yeast lees. With the use of drastic denaturing treatments, the total recovery of condensed tannins reached 83%. Such tannins extracted from yeast lees exhibited very high polymeric size and a rather high percentage of galloylated residues by comparison with initial wine tannins, indicating that nonpolar tannins were preferentially desorbed from yeast lees by the extraction treatments.  相似文献   
    90.
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