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21.
Homogeneus Polypyrrole (PPy)/poly(acrylonitrile-co-styrene) (SAN) composite thin films were prepared by chemical polymerization of pyrrole on poly(acrylonitrile-co-styrene) matrix. Ce (IV) is used as an oxidant for in-situ polymerizion of pyrrole on SAN matrix, having an advantageous over the impregnation method. The formation and incorporation of PPy in the copolymer matrix were confirmed by FTIR-ATR and UV-Visible spectrophotometric measurements. Thermal analyses showed that after polymerization of Py in copolymer matrix, thermal behavior of SAN was changed and derivative of weight loss at this temperature was increased by increasing of PPy content. XPS and FTIR-ATR analysis of composite films indicated cerium salt with nitrate ion acted as a dopant. The increase in the AC electrical conductivity of the PPy/SAN composites over pure SAN was observed. At lower frequency up to 105 Hz, conductivity was shown an independent behavior from frequency; but at high frequencies (105–107 Hz), dependence on frequency was explained by polaron and bipolaron formations of PPy. The dispersion of PPy particles in copolymer matrix was proven by SEM, AFM and digital camera. By the increase of PPy content in the composite films, increase in AC conductivities, and decrease in dielectric constants and loss were observed.  相似文献   
22.
In this study, chemical composition of berries of 10 sea buckthorn (Hippophae rhamnoides L.) genotypes in Turkey was investigated. The total phenolic content of the berries ranged from 21.31 mg gallic acid equivalents (GAE) per g dry weight basis to 55.38 mg GAE per g. The highest antioxidant activity was 93.54% (similar to the standard BHT at 200 mg/L) and the lowest was 80.38%. There was no correlation (R = 0.688) between the total phenolic content and the antioxidant activity. The major fatty acids in berries were palmitoleic acid (35.48%), followed by palmitic acid (28.13%), oleic acid (22.89%) and linoleic acid (3.96%). Total soluble solid content of sea buckthorn genotypes varied from 10.15 to 14.80%, titratable acidity varied from 2.64 to 4.54%, the pH varied from 2.63 to 2.98 and Vitamin C varied from 19 to 121 mg/100 mL. The average content of minerals in the sea buckthorn berries of different genotypes was 20,800 ppm N, 7100 ppm P, 7260 ppm K, 1960 ppm Ca, 1465 ppm Mg, 32 ppm Zn, 24 ppm Cu, 22 ppm Mn and 7 ppm Fe.  相似文献   
23.
Turkey ranked third place in the world for chestnut production after China and South Korea and the country has unique chestnut forests including valuable and diverse chestnut genotypes. This study was conducted to select superior chestnut genotypes within seedling populations found in natural wild grown chestnut forest located in Isparta province in Turkey during 2010–2011 years. A total of 2500 wild grown chestnut trees were examined on the field first year and among them the most promising 22 genotypes were chosen according to relatively high yield capacity, earliness, tolerance to chestnut blight (Cryphonectria parasitica), ink disease (Phytopthora cambivora), and fruit quality characteristics. The selected 22 genotypes were evaluated for their detailed morphological, phenological and pomological traits in 2010 and 2011. According to average of 2 years, nut weight, the number of nut per kilogram, nut width, nut length, nut height and nut shell thickness of 22 promising genotypes ranged from 10.26 to 22.32 g, 97.47 to 44.80/kg, 26.80 to 42.47, 16.92 to 25.91, 27.74 to 39.73, and 0.26 to 1.01 mm, respectively. The ash, crude protein, and total fat content of kernels were between 0.85 to 1.94, 3.69 to 7.06 and 1.32 to 4.52, respectively. The genotypes were evaluated with weighted ranking method and the highest general quality score was observed in genotypes of IY17, IY01, IY42, IY43 and IY12.  相似文献   
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In this study, some selected physico-chemical properties (antioxidant activity, ascorbic acid, fatty acids, fruit colour, fruit juice yield, fruit weight, organic acids, pH, total phenolic and total soluble solid contents) of five black mulberry (Morus nigra L.) genotypes grown in the Northeast Anatolia region of Turkey was investigated. The total phenolic and antioxidant activity of methanol extract of black mulberry fruits were determined according to Folin-Ciocalteu and β-carotene bleaching method assays, respectively. Fatty acids of mulberry fruits were determined by using gas chromatography. Total phenolic content was observed in black mulberry fruits between 1943 and 2237 mg gallic acid equivalents/100 g fresh mass. The vitamin C content of genotypes varied between 14.9 and 18.7 mg/100 ml. The major fatty acids in all mulberry fruits were linoleic acid (53.57–64.41%) and palmitic acid (11.36–16.41%). Antioxidant activity of black mulberry genotypes was found between 63% and 76%, which lower than standard BHA and BHT. Regarding organic acid content, malic acid was the most predominant with a range of 123–218 mg/g followed by citric acid (21–41 mg/g). The results of the study are helpful for attempting crop improvement in black mulberry for bringing to cultivation.  相似文献   
27.
Electropolymerization of carbazole (Cz) by cyclic voltammetry (CV) onto carbon fiber microelectrodes (CFME) (diameter ∼7 μm) in dichloromethane (CH2Cl2) solution of 0.1 mol·dm−3 tetraethyl ammonium perchlorate (TEAP) results in the formation of polycarbazole (PCz) thin film coatings. CV results showed that these PCz thin films have reversible redox behavior in monomer-free electrolyte solution. The resulting thin polymer films were characterized using Fourier transform infrared attenuated total reflectance spectroscopy (FTIR-ATR) and atomic force microscopy (AFM). Results performed at optimum experimental conditions indicate that electrodes show a reversible and stable behavior over sixty eight days of testing for dopamine in 100 μmol·dm−3 buffer solution. A detection limit for PCz thin films as low as 0.1 μM (3S/N) was obtained for the polycarbazole (PCz) thin films formed using CV. Hence, this novel sensor can be considered as promising sensor for dopamine detection.  相似文献   
28.
The consumer acceptance and the quality standard of agricultural products such as apple are determined mostly by their colour. Colour is measured with a colorimeter and quantified using the C.I.E. L*, a*, b* colour space system. It is used commonly by researchers for the classification and identification of apple fruit. To the best of our knowledge, the present study is the first study investigating the prediction of some colour properties of six apple varieties through artificial neural networks (ANN). The apple varieties are ‘Amasya’, ‘Starking’, ‘Granny Smith’, ‘Pink Lady’, ‘Golden Delicious’, ‘Arapk?z?’ and the colour properties are L* (lightness), a* (redness), b* (yellowness), C* (chroma), h* (hue angle), CI (chroma index). General Regression Neural Networks (GRNN) and Adaptive Neuro Fuzzy Interface System (ANFIS) structures were employed to predict the colour properties. According to the experimental and simulation results, the proposed ANFIS predictor had a superior performance in prediction of these colour parameters.  相似文献   
29.
Loquat (Eriobotrya japonica L.) grown well for commercial purposes in subtropical regions nearly 30 countries and originated from China. The most important loquat producers in the world are China, Spain, Turkey, Pakistan, India, Italy and Brazil. In this study, ten pre-selected promising loquat genotypes sampled from eastern Black region and analyzed for their important morphological, biochemical and antioxidant characteristics. The standard cultivar ‘Sayda’ is also included in the study. The results indicated differences for all of the morphological, biochemical and antioxidant characteristics among tested genotypes. Fruit mass and fruit flesh percentage of the genotypes ranged from 35.40?g (LOQ-8) to 46.90?g (LOQ-5) and from 79.40 (%) to 86.32 (%) indicating some local genotypes had higher fruit mass and fruit flesh percentage than standard cultivar ‘Sayda’. Total phenolic content was the highest as 263?μg GAE/g in LOQ-7 genotype while the lowest in LOQ-8 genotype (185?μg GAE/g). LOQ-7 genotype had the highest total antioxidant capacity. Local genotypes in general have higher total phenolic, total carotenoid, vitamin C and antioxidant activity than cv. ‘Sayda’.  相似文献   
30.
A comprehensive analysis of various horticulturally important morphological traits of sixty pear accessions located in five districts of Azad Jammu and Kashmir (Pakistan) was carried out. Several qualitative and quantitative traits were investigated in situ and after the harvesting of leaf and fruit samples. The rich diversity was observed for qualitative traits (i.?e. growth habit, blooming time, intensity of flowering, fruit setting, ripening time, productivity, and fruit shape and color) among pear accessions. As for the quantitative traits, significant variation was observed for leaf area (8.96–27.17 cm2), flowering duration (11–24 days), fruit weight (68.1–322.3 g), average fruit length (2.68–9.87 cm) and average fruit width (1.82–8.12 cm) between pear accessions. Based on qualitative and quantitative data, two dendograms were constructed by using cluster analysis which separated pear accessions into three distinct groups. The cluster analysis showed considerable differences between the accessions for qualitative and quantitative traits. Furthermore, a close association between accessions was noted inside the clusters for qualitative and quantitative traits. The results showed rich diversity and similarity between the pear accessions and needs further assessment at molecular level to elucidate their phylogenetic relationship.  相似文献   
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