Morphological structures of the cellulose hybrids containing polyhedral oligomeric silsesquioxane and their application for removing C.I. Reactive Red 250     

Aiqin Hou  Hongwei Shen  Kai Zhang  Kongliang Xie 《Fibers and Polymers》2014,15(7):1399-1405

Cellulose hybrids containing polyhedral oligomeric silsesquioxane (POSS) were synthesized by crosslinking reaction. The chemical and morphological structures of the hybrids were characterized by elemental analysis, infrared spectrum, scanning electron microscope and atomic force microscope. The hybrids were used for adsorbing C.I. Reactive Red 250 in aqueous solution. Adsorption kinetic and equilibrium isotherm of the cellulose hybrids for the dye were investigated. The hybrids formed new adsorptive positions for dyes because of a nanometer-sized cubic core and numerous organic functional groups (-C-N-). The adsorption capacity of the hybrid materials was significantly higher than that of the control cellulose. The adsorption of the dye on the hybrids was good fit with Langmuir isotherm equation and the second-order model. The apparent activation energy of the dye on the hybrid was 14.87 kJ/mol.  相似文献   

Modification of Marine Natural Product Ningalin B and SAR Study Lead to Potent P-Glycoprotein Inhibitors     

Chao Yang  Iris L. K. Wong  Wen Bin Jin  Tao Jiang  Larry M. C. Chow  Sheng Biao Wan 《Marine drugs》2014,12(10):5209-5221

In this study, new marine ningalin B analogues containing a piperazine or a benzoloxy group at ring C have been synthesized and evaluated on their P-gp modulating activity in human breast cancer and leukemia cell lines. Their structure-activity relationship was preliminarily studied. Compounds 19 and 20 are potent P-gp inhibitors. These two synthetic analogues of permethyl ningalin B may be potentially used as effective modulators of P-gp-mediated drug resistance in cancer cells.  相似文献   

Biochar composites: Emerging trends,field successes and sustainability implications     

Liuwei Wang  Yong Sik Ok  Daniel C. W. Tsang  Daniel S. Alessi  Jörg Rinklebe  Ondřej Mašek  Nanthi S. Bolan  Deyi Hou 《Soil Use and Management》2022,38(1):14-38

Engineered biochars are promising candidates in a wide range of environmental applications, including soil fertility improvement, contaminant immobilization, wastewater treatment and in situ carbon sequestration. This review provides a systematic classification of these novel biochar composites and identifies the promising future trends in composite research and application. It is proposed that metals, minerals, layered double hydroxides, carbonaceous nanomaterials and microorganisms enhance the performances of biochars via distinct mechanisms. In this review, four novel trends are identified and assessed critically. Firstly, facile synthesis methods, in particular ball milling and co-pyrolysis, have emerged as popular composite fabrication strategies that are suitable for large-scale applications. Secondly, biochar modification with green materials, such as natural clay minerals and microorganisms, align well with the on-going green and sustainable remediation (GSR) movement. Furthermore, new applications in soil health improvement and climate change mitigation support the realization of United Nation's Sustainable Development Goals (SDGs). Finally, the importance of field studies is getting more attention, since evidence of field success is critically needed before large-scale applications.  相似文献   

华南芒果种植区寒冻害危险性区划与评估     

孙朝锋  林雯  黄川容  吴立  陈家金  王加义  林辉阳 《中国农业气象》2022,43(7):563-574

利用华南（广东、广西、福建）芒果种植区115个气象站1961−2016年观测资料,结合芒果寒冻害指标,采用加权综合评价法,确定种植区各气象站点的寒冻害危险性指数,建立寒冻害危险性指数与地理因子之间的多元线性回归模型,并基于GIS技术对华南芒果种植区寒冻害危险性进行区划。结果表明：华南芒果种植区寒冻害危险性与地理因子之间关系密切,总体呈现由沿海到内陆,寒冻害危险性逐渐变大的趋势,此外,随着纬度和海拔的增高,从南到北芒果寒冻害危险性程度也逐渐增大。轻度危险区主要分布在华南芒果种植区南部沿海地带及部分内陆地市的低海拔地区,占种植区面积比例为56.85%,该区域适合大规模种植芒果;中度寒冻害危险性区域主要分布在华南芒果种植区内陆中低海拔地区以及北部高纬度沿海地区,占种植区面积比例为37.03%;重度以上的寒冻害危险性区域主要分布在华南芒果种植区内陆高海拔地区,占种植区面积比例为6.12%。通过历史灾情和各县区年产量资料验证,区划结果与实际较为吻合,研究结果可为华南地区芒果的优化布局和防灾减灾提供参考。  相似文献   

黄河流域水资源、能源与粮食生产的时空匹配及阻尼效应   总被引：1，自引：0，他引：1  

陈帅  侯孟阳  李园园  邓元杰  姚顺波 《农业工程学报》2022,38(18):246-254

水、能源与粮食是人类生活与可持续发展的重要保障,探究水资源、能源对粮食生产作用对于优化资源配置与保障粮食安全有着重要的意义。该研究运用洛伦兹曲线与基尼系数评估黄河流域上中下游水资源、能源与粮食生产之间的匹配度,并基于柯布-道格拉斯函数引入粮食增长阻尼模型测算出黄河流域水资源与能源对于粮食生产的制约程度。结果表明：1）黄河流域水资源、能源对粮食的基尼指数呈现出先减小后增大情形,黄河下游区域的匹配度要比上中游区域更为合理,2019年,下游区域水资源、能源对粮食都呈现出高度匹配状态情形。2）黄河流域水资源对于粮食生产的阻尼系数波动较大,阻尼系数变化范围为0.005～0.032,且水资源对粮食增长阻尼作用呈现出6 a一周期情形。能源对于粮食生产的阻尼作用呈现出稳步上升情形,且在2015后上增较快。在水资源与能源约束条件下,2019年黄河流域粮食产量增长要比上一年分别降低0.76%与5.28%。3）黄河流域水资源阻尼系数呈现出西部小东部大情形,能源阻尼效应呈中高约束状态集中在黄河上游东部区域与下游区域,低约束状态集中于黄河中游区域。另外,黄河流域水资源与能源阻尼系数具有典型的空间集聚特征,水资源阻尼效应高-高集聚区主要分布在黄河下游区域,能源阻尼效应低-低集聚区分布在中游北部区域。研究结论可为黄河流域粮食的稳定增长与资源有效配置提供科学依据。  相似文献   

梯形渠道衬砌冻胀破坏弹性地基板模型   总被引：1，自引：1，他引：0  

何鹏飞  候光亮  董建华  曹海涛  马永斌 《农业工程学报》2022,38(23):91-100

为探讨开放系统中梯形混凝土衬砌渠道的冻胀问题,根据衬砌板与冻土地基的相互关系,采用 Winkler弹性地基板理论建立了考虑冻胀力和冻结力作用的衬砌板冻胀破坏力学模型,使用解析法得到了衬砌板变形和内力解,对不同地下水埋深、衬砌板几何参数的影响规律进行了分析。通过与已有现场观测值和计算值进行对比,验证了弹性地基板理论计算结果的正确性。研究结果表明：坡板在非均匀分布的冻胀力作用下,挠度、弯矩和剪力也表现为非均匀分布,挠度最大值在坡顶距坡脚2/3处,弯矩最大值靠近底板位置,拉应力分布与内力分布规律一致,与已有研究结果吻合。与梁理论相比,板理论计算结果表明衬砌板的挠度和内力沿板宽方向为非均匀分布,挠度和弯矩在自由边界（纵向伸缩缝）处增大,扭矩主要分布在衬砌板的拐角处。切向冻结力对渠道冻胀影响较小,在原渠道工况下,不考虑切向冻结力与考虑最大切向冻结力之间,最大挠度相差0.7 mm。针对不同地下水位的渠道,给出了衬砌板的安全厚度,可为现浇混凝土梯形渠道的抗冻胀设计提供参考和理论依据。  相似文献   

N transformation mechanisms and N dynamics of organic fertilisers as partial substitutes for chemical fertilisers in paddy soils     

Hou  Hongqian  Liu  Xiumei  Zhou  Weijun  Ji  Jianhua  Lan  Xianjin  Lv  Zhenzhen  Liu  Yiren  Zhang  Jinbo  Müller  Christoph 《Journal of Soils and Sediments》2022,22(9):2516-2529

Journal of Soils and Sediments - Knowledge of nitrogen (N) dynamics of organic fertilisers as partial substitutes for chemical fertilisers could improve the retention of mineral N and optimise...  相似文献   

In Vitro Anti-Inflammatory Activity of Three Peptides Derived from the Byproduct of Rice Processing     

Qu  Tingmin  He  Shuwen  Ni  Ce  Wu  Ying  Xu  Zhou  Chen  Mao-Long  Li  Honghui  Cheng  Yunhui  Wen  Li 《Plant foods for human nutrition (Dordrecht, Netherlands)》2022,77(2):172-180

Plant Foods for Human Nutrition - Inflammation is a contributing factor to the initiation and progression of many diseases, and some food-derived biofunctional peptides show high anti-inflammatory...  相似文献   

荔枝P型ATP酶基因家族鉴定及其在采后贮藏过程中响应拮抗菌N-1的表达模式分析     

王鑫  邵远志  汤月  李雯 《热带作物学报》2022,43(11):2366-2374

P型ATP酶是植物体内一种重要的膜转运蛋白,在果实能量代谢和酸代谢中发挥重要作用,并广泛参与植物离子运输、抗逆、细胞信号转导等各项生命活动,然而在荔枝或其他无患子科植物中尚未对P型ATP酶基因家族进行全面分析,本研究基于‘妃子笑’荔枝转录组数据,通过对这些基因进行生理生化分析、生物信息学分析和表达分析,共鉴定了28个P型ATP酶基因家族成员基因,探讨P型ATP酶在荔枝采后贮藏过程中的潜在功能。结构和系统发育分析表明该基因可以分为5个亚家族,同一亚族的基因在基因结构和motif基序方面具有很大的相似性,其蛋白二级结构主要以α-螺旋为主,亚细胞定位预测分析发现LcPAs多定位于线粒体（21/28）。通过转录组分析,在采后贮藏期间,荔枝P型ATP酶家族基因中上调表达的基因明显高于下调表达基因,暗示其可能在荔枝采后品质劣变过程中发挥着积极的抵御作用。使用拮抗菌N-1处理荔枝可以有效抑制其果实采后褐变和病害的发生,结合RT-qPCR结果,发现拮抗菌N-1处理能诱导LcPA1、LcPA7、LcPA8和LcPA19在整个贮藏过程中的上调表达,并维持了较高的ATP酶活性,进一步说明P型ATP酶家族基因在抑制荔枝病变过程中发挥着重要作用。本研究为了解荔枝P型ATP酶基因家族基因的进化和功能分析提供了参考,为深入了解拮抗菌N-1保鲜机理的分子调控机理提供新的证据。  相似文献   

山西各类沙棘叶总黄酮的含量测定   总被引：3，自引：0，他引：3  

侯霄  万强  付永峰  卫罡 《国际沙棘研究与开发》2014,(1):6-9

目的：研究山西不同产地及不同采收期各类沙棘叶中总黄酮的含量,为评价与开发利用沙棘叶资源提供依据。方法：采用紫外分光光度法测定沙棘叶中的总黄酮含量。结果：5月-7月份沙棘叶中总黄酮含量相对较高;沁源和方山产区的沙棘叶中总黄酮含量较高。同时看到,普遍沙棘桔红果叶总黄酮含量高于橙黄果叶;沙棘雌株叶总黄酮含量高于雄株叶。结论：6月份沙棘叶中总黄酮含量最高,沁源和方山地区可能为山西沙棘叶的最佳产区。  相似文献