Lime application to reduce phosphorus release in different textured intact and small repacked soil columns     

Eslamian  Faezeh  Qi  Zhiming  Tate  Michael J.  Romaniuk  Nikolas 《Journal of Soils and Sediments》2020,20(4):2053-2066

Purpose

Phosphorus (P) losses from agricultural fields through leaching are the main contributors to eutrophication of lakes and rivers in North America. Adoption of P-retaining strategies is essential to improve the environmental quality of water bodies. The main objective of this study is to evaluate lime as a soil amendment in reducing phosphorus concentration in the leachate from three common soil textures with neutral to alkaline pH.

Materials and methods

Phosphorus leaching from undisturbed soil columns (10 cm in diameter and 20 cm deep) as well as small repacked columns was investigated and compared in this study. Lime (high calcium hydrated lime) at the rate of 1% by air-dried soil mass was applied to the topsoil of the columns. Both sets of experiments followed a full factorial design with two factors of soil texture at three levels (sandy loam, loam, and clay loam) and treatment at two levels (control and limed) with three replicates. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy was performed on the control and limed soil samples to confirm the formation of calcium phosphate compounds.

Results and discussions

For both intact and repacked columns, dissolved reactive phosphorus (DRP) concentrations in the leachates from limed sandy loam and limed loam soil columns was significantly reduced, while DRP in the limed clay loam column leachates was not changed. Elemental mapping demonstrated that in limed sandy loam and loam soils, the calcium loadings on the soil surface were always linked with phosphorus. The formation of calcium phosphate compounds and the increased phosphate adsorption on the soil surface through Ca bridging could be the two main phosphorus-lime retention mechanisms. Total dissolved phosphorus (TDP) in the leachates of limed loam and limed clay loam indoor intact and repacked columns was reduced, while there was no change in that of the sandy loam soil. In finer textured soils, lime can increase TDP retention through the immobilization of organic phosphates.

Conclusions

The impact of lime application on DRP and TDP varied with the soil texture. The lime-induced reduction in the DRP and TDP was variable between the intact and repacked columns demonstrating the importance of soil structure on phosphorus and lime interactions in the soil. Overall, lime application at the studied rate can be considered a promising soil amendment in mitigating phosphorus loss from non-calcareous neutral to alkaline soils.

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Antifeedant and toxicity effects of thiophenes from four Echinops species against the Formosan subterranean termite, Coptotermes formosanus     

Fokialakis N  Osbrink WL  Mamonov LK  Gemejieva NG  Mims AB  Skaltsounis AL  Lax AR  Cantrell CL 《Pest management science》2006,62(9):832-838

Over 220 crude extracts from repositories generated from plants native to Greece and Kazakhstan were evaluated for termiticidal activity against the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Emerging from this screening effort were bioactive extracts from two Greek species (Echinops ritro L. and Echinops spinosissimus Turra subsp. spinosissimus) and extracts from two Kazakhstan species (Echinops albicaulis Kar. & Kir. and Echinops transiliensis Golosh.). Fractionation and isolation of constituents from the most active extracts from each of the four species has been completed, resulting in the isolation of eight thiophenes possessing varying degrees of termiticidal activity. 2,2':5',2"-Terthiophene and 5'-(3-buten-1-ynyl)-2,2'-bithiophene demonstrated 100% mortality against C. formosanus within 9 days at 1 and 2 wt% concentrations respectively. In addition, all but two of the eight compounds tested were significantly different from the solvent controls in the filter paper consumption bioassay.  相似文献   

Influence of soil physicochemical and biological properties on the degradation and adsorption of the nematicide fosthiazate   总被引：1，自引：0，他引：1  

Pantelelis I  Karpouzas DG  Menkissoglu-Spiroudi U  Tsiropoulos N 《Journal of agricultural and food chemistry》2006,54(18):6783-6789

The degradation and adsorption of the organophosphorus nematicide fosthiazate were investigated in nine soils with various physicochemical and biological characteristics. Fosthiazate was more persistent in acidic soils (pH <6), with half-life (t1/2) values ranging from 53.3 to 57.7 days, compared to soils with higher pH (pH >7), with t1/2 ranging from 14.1 to 20.7 days. Application of antibacterial and antifungal antibiotics to soil samples resulted in a significant inhibition of fosthiazate degradation only in two of the three acidic soils. In contrast, soil autoclaving resulted in doubling the t1/2 of fosthiazate in all studied soils, suggesting that both microbial and abiotic processes contribute to fosthiazate degradation. Statistical analysis indicated a significant negative correlation (P < 0.01) between soil pH and t1/2. Fosthiazate was generally weakly adsorbed with Freundlich adsorption coefficient (Kf) values ranging from 1.23 to 2.74 mL/g. Fosthiazate concentration was strongly correlated with soil organic matter content with higher Kf values in soils with higher organic matter content (P < 0.01). The mean t1/2 and Kf values derived from the laboratory studies were used to parametrize the FOCUS groundwater (GW) models PRZM, PELMO, PEARL, and MACRO for nematicide application in potato and tomato crops. Predicted environmental concentrations produced by the models PEARL and MACRO suggested a potential risk for GW in several scenarios, unlike PELMO and PRZM, which predicted low risk for GW. These findings suggest that the environmental fate of fosthiazate is strongly influenced by soil characteristics and that this nematicide should be used with care in acidic, light soils with low organic matter content.  相似文献   

A reassessment of the diversity of green toads (Bufotes) in the circum-Aegean region     

Christophe DUFRESNES  Nikolas M. PROBONAS  Ilias STRACHINIS 《Integrative zoology》2021,16(3):420-428

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Combining double sampling for stratification and cluster sampling to a three-level sampling design for continuous forest inventories     

Nikolas von Lüpke  Joachim Saborowski 《European Journal of Forest Research》2014,133(1):89-100

We extend the well-known double sampling for stratification sampling scheme by cluster subsampling to a three-level design and present corresponding estimators based on the infinite population approach in the first phase. After stratification of the sample points (phase I), a second-phase sample is drawn independently among the first-phase points within each stratum. On level III, clusters are formed of those phase II points and a sample of clusters is finally drawn without replacement. We used the forest planning units compartment and subdistrict as clusters and moreover formed clusters with a heuristic for the vehicle routing problem. The precision of the new estimator was compared to that achieved with classical double sampling for stratification in a case study. The results indicate that the expected increase in sampling errors caused by clustering cannot be compensated by the reduced inventory costs under the conditions given in the case study.  相似文献