Gallium arsenide (GaAs) nanofibers by electrospinning technique as future energy server materials     

Faheem A. Sheikh  Nasser A. M. Barakat  Muzafar A. Kanjwal  S. J. Park  Hern Kim  Hak Yong Kim 《Fibers and Polymers》2010,11(3):384-390

Gallium arsenide (GaAs) does have superior electronic properties compared with silicon. For instant, it has a higher saturated electron velocity and higher electron mobility. Weak mechanical properties and high production cost are the main drawbacks of this interesting semiconductor. In this study, we are introducing production of GaAs nanofibers by electrospinning methodology as a very low cost and yielding distinct product technique. In general, nano-fibrous shape is strongly improving the physical properties due to the high surface area to volume ratio of this nanostructure. The mechanical and environmental properties of the GaAs compound have been modified since GaAs nanofibers have been produced as a core inside a poly(vinyl alcohol) (PVA) shell. GaAs/PVA nanofibers were prepared by electrospinning of gallium nitrate/PVA solution in presence of arsenic vapor. The whole process was carried out in a closed hood equipped with nitrogen environment. FT-IR, XPS, TGA and UV-Vis spectroscopy analyses were utilized to confirm formation of GaAs compound. Transmission electron microscope (TEM) analysis has revealed that the synthesized GaAs compound is crystalline and does have nano-fibrous shape as a core inside PVA nanofibers. To precisely recommend the prepared GaAs nanofiber mats to be utilized in different applications, we have measured the electric conductivity and the band gap energies of the prepared nanofiber mats. Overall, the obtained results affirmed that the proposed strategy successfully remedied the drawbacks of the reported GaAs structures and did not affect the main physical properties of this important semiconductor.  相似文献   

Effects of silver content and morphology on the catalytic activity of silver-grafted titanium oxide nanostructure     

Muzafar A. Kanjwal  Nasser A. M. Barakat  Faheem A. Sheikh  Woo-il Baek  Myung Seob Khil  Hak Yong Kim 《Fibers and Polymers》2010,11(5):700-709

As titanium oxide is a well-known photocatalyst, we investigated the effects of silver content and nanostructural morphology on the photocatalytic degradation of two dyes, methylene blue and rhodamine B. Two nano-formulations were utilized, including nanofibers and nanoparticles. Silver-grafted titanium oxide nanofibers were synthesized using the electrospinning of silver nitrate/titanium isopropoxide/poly(vinyl acetate) sol-gel. The nanoparticulate form was obtained by calcination of a ground powder prepared from the same electrospun sol-gel. The results affirmed the advantage of the silver-grafted titanium oxide nanostructures over the silver-free ones. Increasing the silver content in the nanofibers led to increases in their surface area, which is an important parameter in heterogeneous catalytic chemical reactions. Therefore, the results strongly suggest the use of silver-grafted titanium oxide in a nanofibrous form. These results further support utilizing Agloaded titanium oxide nanofibers as a photocatalyst.  相似文献   

Phytochemical screening, cytotoxicity and antibacterial activities of two Bangladeshi medicinal plants     

Roy A  Biswas SK  Chowdhury A  Shill MC  Raihan SZ  Muhit MA 《Pakistan journal of biological sciences: PJBS》2011,14(19):905-908

The objectives of the present study were to investigate phytochemical screening and to assay cytotoxicity and antibacterial activities of ethanolic extracts of leaves of two medicinal plants, Aglaonema hookerianum Schott (Family: Araceae) and Lannea grandis Engl. (Family: Anacardiaceae) available in Bangladesh. The brine shrimp lethality bioassay showed that the ethanolic extracts of Aglaonema hookerianum and Lannea grandis possessed cytotoxic activities with LC50 5.25 (microg mL(-1)) and 5.75 (microg mL(-1)) and LC90 10.47 (microg mL(-1)) and 9.55 (microg mL(-1)), respectively. Two extracts obtained from leaves were examined for their antibacterial activities against some gram positive bacteria such as Bacillus subtilis, Bacillus megaterium and Staphylococcus aureus, also gram negative strains of Pseudomonas aeruginosa, Escherichia coli, Shigella dysenteriae, Salmonella typhi, Salmonella paratyphi and Vibrio cholerae. Agar disc diffusion method was applied to observe the antibacterial efficacy of the extracts. Results indicated that both plant extracts (500 microg disc(-1)) displayed antibacterial activity against all of the tested microorganisms. These results were also compared with the zones of inhibition produced by commercially available standard antibiotic, Amoxicillin at concentration of 10 microg disc(-1). Observed antibacterial properties of the ethanolic extract of Aglaonema hookerianum Schott and Lannea grandis Engl. showed that both plants might be useful sources for the development of new potent antibacterial agents.  相似文献   

Investigating potential roles of extruded flaxseed and α-tocopherol acetate supplementation for production of healthier broiler meat     

R. Parveen  M. I. Khan  F. M. Anjum  M. A. Sheikh 《British poultry science》2016,57(4):566-575

1. The present study was conducted to evaluate the role of extruded flaxseed (EFS) and α-tocopherol acetate (ATA) for the enhancement of polyunsaturated fatty acids ratio (PUFA) over saturated fatty acids (SFA) in broiler meat as a source of healthier meat.

2. A total of 96 one-d-old Cobb 550 broilers were randomly divided into 8 treatments with three replicates having 4 birds in each. EFS (extruded at 155°C) at 100, 150 and 200 g/kg alone and in combination with ATA at 200 mg/kg were supplemented through normal feed from the third week onward.

3. During the 6-week growth period, body weight gain (BWG), feed intake (FI), feed conversion ratio (FCR) and mortality were recorded. At slaughter, weight of liver, heart and kidney and fat content in breast and leg meat were measured. Fatty acid profiles in breast and leg meat were developed to estimate the PUFA to SFA ratio.

4. The results revealed that FI and FCR changed significantly in all groups and BWG increased in all the supplemented groups. The weight of liver, kidney and heart increased more in the supplemented group containing the maximum level of EFS with ATA compared with single supplementation of EFS.

5. The fat content in breast and leg meat decreased as the inclusion level of EFS increased. The level was low in leg meat compared with breast meat. Mortality decreased in all supplemented groups.

6. The PUFA to SFA ratio was significantly higher in leg meat (3.23) compared with breast meat (1.81) and the study therefore indicates that ATA and EFS supplementation could be used to improve the PUFA to SFA ratio in broiler meat.

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Permeability and meniscus phenomenon in four Korean softwood species     

Su Kyoung Chun  Sheikh Ali Ahmed 《中国林学(英文版)》2006,8(3):56-60

1 Introduction A number of studies have been carried out to examine the process of liquid impregnation into different kinds of wood (Stamm and Raleigh, 1967; Bolton and Petty, 1978; Olsson et al., 2001). Different techniques and methods have been developed so far to obtain quanti- tative and qualitative information about this process (Stamm, 1953; Stone, 1956; Rudman, 1965). Penetra- tion of liquid in wood depends on several factors. The penetration rate and amount varies in different spec…  相似文献   

Modeling the relationship between the main emulsion components and stability, viscosity, fluid behavior, zeta-potential, and electrophoretic mobility of orange beverage emulsion using response surface methodology     

Mirhosseini H  Tan CP  Hamid NS  Yusof S 《Journal of agricultural and food chemistry》2007,55(19):7659-7666

The possible relationships between the main emulsion components (namely, Arabic gum, xanthan gum, and orange oil) and the physicochemical properties of orange beverage emulsion were evaluated by using response surface methodology. The physicochemical emulsion property variables considered as response variables were emulsion stability, viscosity, fluid behavior, zeta-potential, and electrophoretic mobility. The independent variables had the most and least significant ( p < 0.05) effect on viscosity and zeta-potential, respectively. The quadratic effect of orange oil and Arabic gum, the interaction effect of Arabic gum and xanthan gum, and the main effect of Arabic gum were the most significant ( p < 0.05) effects on turbidity loss rate, viscosity, viscosity ratio, and mobility, respectively. The main effect of Arabic gum was found to be significant ( p < 0.05) in all response variables except for turbidity loss rate. The nonlinear regression equations were significantly ( p < 0.05) fitted for all response variables with high R (2) values (>0.86), which had no indication of lack of fit. The results indicated that a combined level of 10.78% (w/w) Arabic gum, 0.56% (w/w) xanthan gum, and 15.27% (w/w) orange oil was predicted to provide the overall optimum region in terms of physicochemical properties studied. No significant ( p > 0.05) difference between the experimental and the predicted values confirmed the adequacy of response surface equations.  相似文献   

Studies on kinetics and thermostability of a novel acid invertase from Fusarium solani     

Bhatti HN  Asgher M  Abbas A  Nawaz R  Sheikh MA 《Journal of agricultural and food chemistry》2006,54(13):4617-4623

The present investigation deals with purification and thermal characterization of an acid invertase produced by Fusarium solani in submerged culture. The maximum enzyme activity (9.90 U mL(-1)) was achieved after 96 h of cultivation at pH 5.0 and 30 degrees C in a basal medium containing molasses (2%) as the carbon and energy source supplemented with 1% peptone. Invertase was purified by ammonium sulfate fractionation and column chromatography on DEAE-cellulose and Sephadex G-200. The purified enzyme was proven to be homogeneous by sodium dodecyl sulfate polyacrylamide gel electrophoresis. The molecular mass of the enzyme was 65 kDa. The optimum pH and temperature for activity were 2.6 and 50 degrees C, respectively. The Km value for sucrose was 3.57 mM with an activation energy of 4.056 kJ mol(-1). Enthalpies of activation (DeltaH) were decreased while entropies (DeltaS) of activation increased at higher temperatures. The effects of alpha-chymotrypsin and 4 M urea were tetraphasic with periodic gain and loss of enzyme activity. A possible explanation for the thermal inactivation of invertase at higher temperatures is also discussed.  相似文献   

An Abnormal Outbreak of Ringworm among Sudanese Calves     

Muk. T. Abu-Samra  S. E. Imbabi  El Sheikh Mahgoub 《Zoonoses and public health》1976,23(2):171-178

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Effects of irrigation interval and tillage systems on irrigated cotton and succeeding wheat crop under a heavy clay soil in the Sudan     

Sheikh El Din Abdel Gadir El-Awad 《Soil & Tillage Research》2000,55(3-4):167-173

A water crisis that occurs in Sudan during winter due to the competition for water to irrigate cotton (Gossipium barbadense L.) and wheat (Triticum aestivum L.) and to produce hydroelectric power necessitates a search for efficient means and ways of conserving water. Tillage is one of the methods for soil moisture conservation. Experiments were conducted in Gezira, Sudan on a Vertisol to determine if tillage practices and the lengthening of irrigation interval beyond two weeks during the period October–February would conserve irrigation water and maintain cotton yields. The residual effects of cotton tillage systems on the following wheat were also evaluated. The cotton experiment was conducted in split plot design with three replications. Three irrigation treatments of two-, three- and four-week intervals during the period October–February were used as main plots. Six tillage treatments were used as split plots (combinations of disc ploughing, cultivator and ridging). Treatments were compared by measuring cotton plant height and yields. Significant decreases in cotton yield were found between the four-week, and the two- and three-week irrigation intervals. However, no significant differences in cotton yields between the two- and the three-week irrigation intervals were detected. The lengthening of irrigation interval from two to three weeks during the period of irrigation water crisis (October–February) would result in conservation of about 3000 m³ ha⁻¹ of irrigation water. This corresponds to about 600 000 000 m³ of water for the cotton irrigated area in the Sudan. Therefore, the three-week irrigation interval during the period October–February has the potential for water conservation for cotton production in Gezira Vertisols, with the use of economical shallow tillage. The tested deep and shallow cotton tillage treatments did not have residual effects on the following wheat crop.  相似文献   

Secondary Effluent Treatment by Slow Sand Filters: Performance and Risk Analysis     

Sadiq  Rehan  Husain  Tahir  Al-Zahrani  A. M.  Sheikh  Anwar Khalil  Farooq  Shaukat 《Water, air, and soil pollution》2003,143(1-4):41-63

The objective of this study is to examine the reuse of wastewaterfor beneficial purposes. To accomplish this objective, the efficiency of slow sand filters in removing total coliforms (TC) was studied using a probabilistic method. Three pilot scale slowsand filters were constructed at Alkhobar wastewater treatment plant, Dhahran, Saudi Arabia. The removal efficiency of filters was estimated under different operating control parameters, which included filtration rate (q), sand bed depth (d) and sand grain size (c). The Type III extreme value distribution best fitted theremoval efficiency data. A multiple linear regression analysis was performed to develop a relationship for mean removal efficiency as a function of control parameters. The predicted mean response and experimental results of previous studies werecompared to validate the empirical regression model. The controlparameters and influent concentrations of total coliform were used in Monte Carlo (MC) simulations for calculating the reliability index (β). The reliability index and corresponding risk were calculated for lognormally distributedsafety margins (SM). An effluent standard of 100 total coliform/100 mL was defined as capacity of the filter to ascertainthe risks of exceedence, which was approximately less than 50 for95% of the time. Pre and/or post disinfection would be necessaryto meet the stipulated effluent standards for unrestricted agriculture use.  相似文献