Sex pheromone of the oak processionary moth Thaumetopoea processionea. Identification and biological activity     

Quero C  Bau J  Guerrero A  Breuer M  De Loof A  Kontzog HG  Camps F 《Journal of agricultural and food chemistry》2003,51(10):2987-2991

The sex pheromone of the oak processionary moth Thaumetopoea processionea has been characterized from female gland extracts as a mixture of (Z,Z)-11,13-hexadecadienyl acetate (1), (E,Z)-11,13-hexadecadienyl acetate (3) and (Z,Z)-11,13-hexadecadienol (2) in 88:7:5 ratio. The amount of the major compound 1 was 20-30 ng/gland. No trace of (Z,Z)-11,13-hexadecadienal was found in the extract, and therefore, T. processionea appears to be the only "summer" processionary moth lacking this compound as a pheromone compound. The alcohol 2 had also been previously found but is electrophysiologically inactive, and in wind tunnel assays it lowers the number of contacts with the source when mixed with the major compound 1. The major component 1 elicited males to display the complete behavioral sequence, but the amount of chemical needed was unexpectedly high in comparison to the activity displayed by virgin females and gland extracts. (E,E)-11,13-hexadecadienyl acetate (5) inhibits the attractant activity of the major component 1 when mixed with 1 in 1:10 and 1:1 ratios. The main constituent 1 is active in the field, but its tendency to isomerize into the corresponding E,E isomer (5) must be considered if effective formulations are to be prepared.  相似文献   

Pathway of dephosphorylation of myo-inositol hexakisphosphate by phytases of legume seeds     

Greiner R  Larsson Alminger M  Carlsson NG  Muzquiz M  Burbano C  Cuadrado C  Pedrosa MM  Goyoaga C 《Journal of agricultural and food chemistry》2002,50(23):6865-6870

Using a combination of high-performance ion chromatography analysis and kinetic studies, the pathway of dephosphorylation of myo-inositol hexakisphosphate by the phytases purified from faba bean and lupine seeds, respectively, was established. The data demonstrate that the legume seed phytases under investigation dephosphorylate myo-inositol hexakisphosphate in a stereospecific way. The phytase from faba bean seeds and the phytase LP2 from lupine seeds degrade phytate by sequential removal of phosphate groups via D-Ins(1,2,3,5,6)P(5), D-Ins(1,2,5,6)P(4), D-Ins(1,2,6)P(3), and D-Ins(1,2)P(2) to finally Ins(2)P, whereas the phytases LP11 and LP12 from lupine seeds generate the final degradation product Ins(2)P via D-Ins(1,2,4,5,6)P(5), D-Ins(1,2,5,6)P(4), D-Ins(1,2,6)P(3), and D-Ins(1,2)P(2).  相似文献   

Determination of thiamine and its esters in beers and raw materials used for their manufacture by liquid chromatography with postcolumn derivatization     

Viñas P  López-Erroz C  Balsalobre N  Hernández-Córdoba M 《Journal of agricultural and food chemistry》2003,51(11):3222-3227

Thiamine and its mono- and pyrophosphate esters were determined in beer and the raw materials used for its manufacture (brewer's yeast, malt, raw grain, and hops) after separation using reversed-phase liquid chromatography. The method used fluorescence detection and a new amide-based stationary phase, which avoids the need to form ion pairs, leading to narrower peaks and a simpler mobile phase. Analyses were performed by isocratic elution with a phosphate buffer mobile phase and using a postcolumn derivatization system based on the oxidation of thiamine to fluorescent thiochrome with potassium ferricyanide in alkaline solution. Only thiamine was found in the beers and raw products, especially in brewer's yeast and malt. A stability study pointed to a faster decrease in the thiamine content of samples stored at room temperature and in sunlight.  相似文献   

Study of low molecular weight phenolic compounds during the aging of sparkling wines manufactured with red and white grape varieties     

Pozo-Bayón MA  Hernández MT  Martín-Alvarez PJ  Polo MC 《Journal of agricultural and food chemistry》2003,51(7):2089-2095

Thirty-two phenolic compounds of low molecular weight were identified in 36 white, blanc de noir, and rosé sparkling wines by using HPLC with photodiode array and mass spectrometry detection. Some of the identified compounds, such as cis- and trans-ethylcaftaric, cis- and trans-ethylcaffeic, and cis- or trans-ethyl-p-coumaric acids, 2R,3R-dihydroquercetin, 2R,3R-dihydrokaempferol 3-O-beta-d-glucoside, and a lignan derivative are described for the first time in sparkling wines manufactured with grapes of red varieties. This is also the first time that cis- or trans-diethylfertaric acids have been identified in wines. When cluster analysis was applied to the data of 19 of the 32 identified compounds, the greatest differences found in the low molecular weight phenolic compounds in sparkling wines were due to the grape variety from which they were manufactured, whereas aging time did not significantly influence phenolic composition. Nine phenolic compounds, that is, trans-p-coumaric and trans-caftaric acids, trans-resveratrol glucoside, cis-coutaric, trans-coutaric, cis-p-coumaric, and cis-caftaric acids, tryptophol, and syringic acid, permit the wines to be classified correctly in accordance with the grape variety from which they were manufactured.  相似文献   

Hypolipemic and hypoglycaemic activity of bergamot polyphenols: From animal models to human studies     

Vincenzo Mollace  Iolanda SaccoElzbieta Janda  Claudio MalaraDomenica Ventrice  Carmen ColicaValeria Visalli  Saverio MuscoliSalvatore Ragusa  Carolina MuscoliDomenicantonio Rotiroti  Franco Romeo 《Fitoterapia》2011,82(3):309-316

Bergamot juice produces hypolipemic activity in rats though the mechanism remains unclear. Here we investigated on the effect of bergamot extract (BPF) in diet-induced hyperlipemia in Wistar rats and in 237 patients suffering from hyperlipemia either associated or not with hyperglycaemia. BPF, given orally for 30 days to both rats and patients, reduces total and LDL cholesterol levels (an effect accompanied by elevation of cHDL), triglyceride levels and by a significant decrease in blood glucose. Moreover, BPF inhibited HMG-CoA reductase activity and enhanced reactive vasodilation thus representing an efficient phytotherapeutic approach in combating hyperlipemic and hyperglycaemic disorders.  相似文献   

Analysis of diagnostic cases of turkey viral enteritis in commercial turkey poults in California     

Shayne Ramsubeik  Carmen Jerry  Beate Crossley  Aníbal G. Armién  Daniel Rejmanek  Maurice Pitesky  H.L. Shivaprasad  Simone Stoute 《The Journal of Applied Poultry Research》2022,31(2):100238

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Protein requirements of preschool children consuming rice-milk,rice-toasted mung bean,and rice diets     

Maria A. Isabel Cabrera-Santiago  Carmen LL. Intengan  Benigan V. Roxas  Bienvenido O. Juliano  Consuelo M. Perez  Anacleta S. Loyola  Emma R. Alejandro  Jovina N. Abadilla  Gracia FE B. Yu  Aida C. Mallillin 《Plant foods for human nutrition (Dordrecht, Netherlands)》1986,36(3):167-178

Rice-milk and rice-toasted mung bean diets, and a high-protein rice (IR58 milled rice) were evaluated as part of a study on the protein requirements of toddlers consuming rice-based diets following the multilevel N balance method. Milk or mung bean contributed 1/3 of dietary N. At a daily energy intake of 418 kJ/kg body weight, weight losses were observed for all diets. The safe level of protein intakes obtained allowing 10 mg N/kg body weight/day for miscellaneous integumental losses and 15 mg N/kg body weight/day for growth was 1.11 g/kg body weight/day for the rice-milk diet and 1.34 g for the rice-mung bean diet. Preliminary data on four children indicate a safe level of protein intake of 1.44 g/kg/day for the IR58 milled rice. The protein quality of the high-protein rice as determined by the very short term N balance index on three children was 79–80% relative to milk.  相似文献   

Marine and Semi-Synthetic Hydroxysteroids as New Scaffolds for Pregnane X Receptor Modulation     

Valentina Sepe  Francesco Saverio Di Leva  Claudio D’Amore  Carmen Festa  Simona De Marino  Barbara Renga  Maria Valeria D’Auria  Ettore Novellino  Vittorio Limongelli  Lisette D’Souza  Mahesh Majik  Angela Zampella  Stefano Fiorucci 《Marine drugs》2014,12(6):3091-3115

In recent years many sterols with unusual structures and promising biological profiles have been identified from marine sources. Here we report the isolation of a series of 24-alkylated-hydroxysteroids from the soft coral Sinularia kavarattiensis, acting as pregnane X receptor (PXR) modulators. Starting from this scaffold a number of derivatives were prepared and evaluated for their ability to activate the PXR by assessing transactivation and quantifying gene expression. Our study reveals that ergost-5-en-3β-ol (4) induces PXR transactivation in HepG2 cells and stimulates the expression of the PXR target gene CYP3A4. To shed light on the molecular basis of the interaction between these ligands and PXR, we investigated, through docking simulations, the binding mechanism of the most potent compound of the series, 4, to the PXR. Our findings provide useful functional and structural information to guide further investigations and drug design.  相似文献   

Assessment of Eco-Physiological Performance of Quercus ilex L. Leaves in Urban Area by an Integrated Approach     

Carmen Arena  Anna De Maio  Flavia De Nicola  Lucia Santorufo  Luca Vitale  Giulia Maisto 《Water, air, and soil pollution》2014,225(1):1-12

Bioretention cells, also known as raingardens, are increasingly being constructed as a means to collect, infiltrate, and treat stormwater runoff. There are concerns, however, about how stormwater management practices might function in terms of infiltration and pollutant removal as they age. Saturated hydraulic conductivity (K _sat) values were obtained for eight cells in 2006 and again for three of those cells in 2010 using an infiltrometer. A strong positive correlation of mean K _sat with service time was observed (slope = 10.2?±?2.4 cm/h per year, R ² = 0.67). Results from metals analyses of bioretention media cores collected from six bioretention cells showed the expected trend of Cu and Zn enrichment at the surface while Cd was detected only in one out of 72 media samples analyzed. Sorption isotherms from batch testing of field media samples (T = 22.5 °C, pH = 7.2) were used to estimate metal sorption capacities based on representative stormwater Cd and Zn concentrations. Cu was not considered, as very little of the metal is dissolved under these conditions (22.8?±?7.1 %). The mean equilibrium sorption capacities for Cd (10.2?±?3.1 mg/kg) and Zn (294.9?±?14.9 mg/kg) far exceeded observed levels in the bioretention media such that the remaining sorption capacity was ≥83 % for Zn and ≥90 % for Cd for the cells. Overall, the results of this investigation suggest that bioretention cells can provide many years of effective infiltration (>6 years) and metals removal performance (>25 years).  相似文献   

Nutritional assessment of charitable meal programmes serving homeless people in Toronto     

Tse C  Tarasuk V 《Public health nutrition》2008,11(12):1296-1305

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